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Examples of an Acid
Isobaric process
o Constant pressure
o E.g. heating of water in open air
under atmospheric pressure
Isochoric process
o Constant volume
Sample Problem
o E.g. heating of gas in a sealed metal
A solution of HCl in water has a concentration of container
0.0215 M. Find: Reversible process
o The system is close to equilibrium at
a. pH = all times (and infinitesimal alteration
of the conditions can restore the
universe (system + surrounding) to
the original state.
b. pOH =
Cyclic process
o The final and initial state are the
same. However, q and w need not be
c. Hydrogen ion concentration
zero
d. Hydroxide ion concentration Adiabatic process
o No heat is added or removed to or
from the system
Temperature
Thermodynamics
A measure of how hot or cold something is;
The branch of physical science that deals specifically, a measure of the average kinetic
with the relations between hear and other energy of particles in an object, which is a
forms of energy (such as mechanical, type of energy associated with motion
electrical or chemical energy), and, by
extension, of the relationships between all
forms of energy
Deals with stability of systems
Temperature vs. Heat atom in a species like molecule, formula unit
or ion.
Heat is thought of, as a form of energy,
while the temperature is a measure of
energy.
Example
Convert
Convert
Convert
Convert
Sample Problems
1. Determine the ocidation state of the middle
element in H2SO4
Electrochemistry
Formulas
(J)
o 1kJ = 1000 J
o 1 cal = 4.186 J
(J/kgK)
(kg)
o 1000g = 1kg
(K)
Heat Transfer
Specific Heat
o Where:
o M(acid) = concentration of the acid
o V(acid) = volume of the acid
o M(base) = concentration of the acid
o V(base) = volume of the acid
Moles H3O+ = Moles OH-
MVn = MVn
o Where:
o M – molarity
o V – volume
o N – number of H+ ions in the acid
o N – number of OH- in the base
bye