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DROSS
FORMATION
MONITORING
Ir G HENDERIECKX
GIETECH BV
1. INTRODUCTION
Every ductile iron foundry, especially the ones producing large and or complex
castings, does know the dross problem, which is for most of them the main scrap
cause.
The factors that are increasing the dross presence should be controlled and
understood. It is clear that a correct monitoring, taken in account the mutual
interference of several of the factors, can master the problem.
Dross is the inclusion material in ductile iron that consists of all reaction products with
Mg (magnesium) and as an enlargement with RE (Rare Earths, especially Cerium).
Mg + O ---> MgO
Mg + S ---> MgS
Mg + S + O ----> MgO + S
2 Mg + SiO2 ----> Si + 2MgO
2 MgS+ SiO2 ----> Si + 2MgO + S
Ce + S -- CeS
2 Ce + 2O +S -- Ce2O2S
The question which of the reaction will be preferentially occurring can be answered
from the “free energy” chart and the presence of the elements, one compared to the
other. See figure for oxygen on next page.
The reactions will be decreased or even stopped if the availability of the reacting
elements is low or not existing, which of the elements it will be.
This indicates that the following elements are important:
1. Mg
2. RE (especially Ce)
3. S
4. O2
5. SiO2.
3.1 Mg CONTENT
3.2 S-CONTENT
3.3 O2-CONTACT
3.4 TURBULENCE
The factors are mainly the magnesium and sulfur as well as oxygen content and the
way they can act to perform the reaction.
3.1 Mg content
The magnesium content, and to a lesser degree the Cerium content, are basic for the
formation of dross. The magnesium content should be minimum level.
To assure that the Mg- and Ce- content is sufficient at the time of solidification; a
fading rate is set, depending on the type of covering and transport and pouring.
During the transport of the ladle the contact is depending on the time and cover of
the ladle; during pouring in the pouring box, it depends on the size of ladle and
pouring box as well as the height of the ladle compared to the pouring box; during the
mould filling depending on the pouring system and turbulence.
Fading in % / min
Mg Rare Earths
RE Ce La
Covered full ladles 0,0006 0,00013
Open ladle (reheated in furnace) 0,0033 0,0002 0,00025
All these figures are fairly close one to another to use them as guideline for the
fading effect of Mg and Ce (RE).
An example of the result of fading is given in next figure (fading 0,003 % Mg / min).
Minimum residual magnesium, combined with rare earths (RE) content to obtain
100 % nodular (spheroidal) free graphite
1. treatment temperature
2. type and shape of treatment ladle
3. type and size of treatment alloy
4. condition of treatment alloy.
As a conclusion, it is clear that most of the foundries do use too high residual
magnesium content that will lead to:
Up to last year, most of the foundries and labs did indicate that the S-content should
be minimised to the utmost.
Now, it is discovered that sulfur does play an important role to the nuclei and free
graphite formation. It is found that a too low S-content did lead to a low NC (nodule
count), which is an important factor for producing porosity free castings with high
mechanical strength and ductility.
When the initial S-content is too high (> 0,020 %), it is preferred to perform a
desulfurization treatment. The slag should be removed very carefully.
At level:
It is preferred to remove the dross after the nodulising treatment very carefully
because it is possible that the sulfur will re-enter the metal.
It is clear that, after a correct nodulising treatment and careful removal of the slag
from the metal surface, the S-content will be low and it will be difficult for the residual
Mg to react with sulfur (both are present at a low concentration).
The reaction with oxygen on the other hand will never stop. The metal surface, if not
or not carefully covered, is in contact with the air. During pouring in the pouring box,
there is, depending on the way of pouring, contact with the air as well as during the
filling of the mould.
For this reason, oxygen will be the most important factor for the dross formation. Due
to the fact that ductile iron castings are not poured under a protection gas (nitrogen,
argon…) or vacuum (all this is too expensive or even physically not possible for
larger castings), there will always be contact of liquid metal and air and consequently
dross formation.
The conclusion is that the foundry has to decrease the dross formation to the
maximum, but it will always happen!
3.4 TURBULENCE
Before the metal can solidify in the mould cavity, it has been flown several times:
During all these activities, the liquid metal is in contact with the air. Minimising the
reaction of magnesium with the oxygen is a matter of:
A laminar flow has very few contact, a turbulent flow has a lot of contact area. The
monitoring will be to control and minimise the turbulence of the liquid metal flow.
Turbulence means a chaotic metal flow or chaos that leads to non controlled and
unpredictable results. It is proven that:
Depending on the type of ladle (lip, T-pot or bottom pouring ladle) and the
height of the ladle above the pouring box and its metal level, dross will be
formed.
In the next figure, the dross formation and even the dross formation plus the
air inclusion (in liquid metal) is indicated. It is clear that nearly always the
distance between ladle and metal level in the pouring box will be too high. But
anyhow, the lower, the smaller the effect.
This means that at least dross will be mixed with the metal in the pouring box and it is
fact to keep it out of the sprue. This can be done by keeping it, with the plug in the
sprue opening, during 30 s (at least) to enable the dross to float to the surface.
If not possible, it enters the pouring system, which will have to bloc it.
The metal will fall into the sprue and its speed will increase till it hits the bottom. The
higher the speed, the higher the impact on the more splashing will occur. The speed
can be calculated as (one section sprue without holds):
v = (2*g*H)0,5
Schoke Ssprue
Ssprue
Schoke
NON-PRESSURISED POURING SYSTEM
A third item is the connection of the pouring box with the sprue. No liquid can bridge
90° edges and air sucking will occur again.
The dross formed in this stage of filling is important, but the following parts of the
pouring system should be able to bloc it.
The runner is the part of the pouring system that transports the metal horizontally. It
is the part that is suited for separating the metal and dross. This can be done by
decreasing the speed of the metal to that extend that the slag can float up from the
metal. The speed should be that low that the flow is not turbulent anymore.
For this reason, the section is always about the double the choke section and if
necessary even more (but it does decrease the casting yield). The ratio’s are
pressurised and non-pressurised: 1 / 2 / 0,7 – 0,85 and 1 / 2 / 2.
The runner must fill as quick as possible and even before the metal enters the mould
cavity. This is possible for the non-pressurised pouring system (ingates are on top of
the runner) but not possible for the pressurised system. Depending on the
pressurising (ratio of ingate section to the sprue section), the runner will fill.
It should be directed in a location that avoids that the metal can enter the mould
cavity. The possibilities are given on next page.
PRESSURISED
RUNNER
SLAGPIT
INGATE
NON PRESSURISED
RUNNER INGATE
RUNNER SLAGPIT
SLAG BLOCKING CORE
The longer the runner is, the more the speed will be reduced.
A broken runner, with 90° direction changes, is better than a curved one because it
reduce the speed more and the dross (less dense than metal) will not enter the
mould cavity.
The runner is not creating dross but is the item that should bloc all the previous
formed dross and prevent that it can enter the ingates and the mould cavity.
3.4.4 Ingates
The ingates are the last part of the pouring system and bring the metal into the mould
cavity. What is passing here is entering the mould cavity and will be a potential
inclusion in the casting. Nothing can prevent the entering!
The earlier formed dross can be blocked by the runner; so it is a matter of not
forming new one. This will not be done if the:
In the pressurised pouring system, the metal speed in the ingates is very high,
depending on:
The vents and as an extension the risers are very important in 2 ways:
1. decreasing the pouring rate (increasing pouring time) if the section is lower
than the choke section
2. collecting to a certain extend the dross and air.
By decreasing the pouring rate (due to the hindered escape of the mould cavity air),
the vertical metal speed will be lower and the dross can float up more.
The venting (and risers) can collect dross and remove it from the casting. To enable
this, they must be located correctly, which means there were the dross is floating up
and or taken with the metal flow.
3.4.6 Filters
The filters are the most popular tool to avoid that dross can enter the mould cavity.
But to be able to do this, they should be:
1. correctly calculated
2. located properly.
A filter with a too low flow capacity will not hold the dross and may be even break. A
filter with a too large opening pattern, will not bloc the small particles. A filter in a
pressurised pouring system will not work.
A filter located in the connection sprue – pouring box is not very effective. The filter
should be located as close as possible to the mould cavity, preferentially the ingates.
But pay attention because incorrect filters can also create dross.
It is clear that the shape of the casting is important, combines with its location in the
mould. There are 2 important features:
It is clear that the speed of the metal decides if the dross can float up from the liquid
metal. A high speed will avoid the segregation of dross and a metal with very low
speed will show the dross on top of its flow.
It is important to realise that the floating up speed is dependant on the size of the
inclusion: a large inclusion has a higher floating tendency.
INCLINED
VERTICAL
The connection of sections with totally different value will influence the speed very
much. It is known that, if this is too large, the metal will jump or fall dead completely
with a lot of turbulence.
In BB the speed has to reduce very much, which is impossible and the metal will
spout out like a fountain, which is totally turbulent and including a lot of air as well as
mixing the dross with the metal.
To float, the dross needs a very low vertical speed of the metal level.
The mould material, especially chemical bounded sand that uses S-containing
catalysts, can react with the magnesium in the liquid metal.
This reaction will increase if:
Mg content is high
Wall thickness of casting is large
Coating layer is thin
LOI, especially S-content, of the mould sand is high
High metal temperature (pouring temperature).
The dross that is formed is different from the previous discussed one (MgO) and is of
the type MgS. It will also be seen as a surface layer with dross and flake free
graphite. Depending on the factors, the layer can be 1 to 3 or 4 mm.
It is commonly accepted that the sulfur is diffusing to the metal in a gas phase, which
exist during a short time. The diffusion will increase if:
Depending on the coating, which can be sulfur absorbing or sulfur blocking, the layer
will be larger or smaller. The type of coating is important.
Zircon based coating is decreasing the contaminated metal layer, much more than
graphite based. Graphite based is even dangerous if it contains also sulfur!
An increasing cooling capacity of the coating will decrease the thickness of the
contaminated layer.
0,04
S-content in
casting
0,02
0
0 2 4 6 8 10
% in coating
0,16
0,12
0,08
0,04
0
0 1 2 3 4 5 6 7 8 9 10
Calcium-carbonite addition (% )
Coating cannot avoid the metal will have a surface layer with degenerated free
graphite and dross.
4. ACTIONS
It is a matter of decreasing the dross formation and to try to collect the (inevitable)
dross, present in the casting, in extra casting-parts that will be removed later.
The first item is the Mg, which should be properly calculated in combination with the
RE (Rare Earths). The residual content depends on the time needed for transport of
ladle to the mould, pouring time and wall thickness of the casting; it depends on the
Mg- and RE-fading.
It is also very important to remove the dross from the metal surface after nodulising,
which will take some time (dross must be able to float to the surface). It is preferred
to remove the slag again just before pouring.
It is fact to locate the casting in a way that the ferrostatic height is limited to the
maximum.
On the other hand, the vertical speed in the casting should be controlled to avoid
turbulence and to control the area where the dross can float to the surface. The
possibility to incline the casting in the mould (complicated for the pattern – split line)
or even position the mould inclined (assure a constant inclination) is a cheap but
powerful tool.
Let it be clear that dross will tend to stick to the mould and or core wall if there is
contact and the metal (dross) speed is very low.
Ensure that the pouring is done at the proper height above the mould and or pouring
box. This calls for a free area around the mould and appropriate ladles (content and
type). It is clear that the dross removal before pouring is important because dross
has float up during the transport from the nodulising area to the mould pouring area.
Bottom and T-pot ladles have fewer problems with this phenomenon.
The pouring box must be designed properly to ensure that the dross cannot enter the
sprue. This can be done with a slag dam (especially for small and medium castings)
and or a sprue-plug, which will be removed after the pouring box is filled and the
dross has floated up.
The pouring system should be properly designed concerning shape and sections.
The sprue-pit and the slag-pit at the end of the runner are very important. It is very
important to set rules about the use and decision making of pouring system.
Once the dross has entered or is formed in the mould cavity, it is necessary to get it
out of the casting (dross collector) or to collect it in the machining stock.
The cheapest solution is to collect it in the machining stock. But it is difficult to control
because the amount of dross will vary from casting to casting and mostly the
customer does not like a too high machining stock. It must be accepted that
machining material with a lot of dross will be more difficult than clean material.
The next solution is to remove the dross by the risers and vents. This is possible if
they are correctly located but has also some danger, especially the risers. If the
amount of dross is too high, compared to the riser metal amount, it can be that the
riser has a lower activity for feeding or that the feeding material is not a proper metal
(low nodularity and dross inclusions).
Another, more costly solution, is the design of slag collectors as extra casting detail.
If this collector is properly located, it can collect the dross and can be removed later
in the grinding and fettling operation. This is mostly costly because it is a hand
performed operation.
Dross collectors only work if they are properly located, which means in area where
the slag is still taken by the metal flow and the speed is sufficient to avoid the sticking
of dross to the mould walls.
For chemical bounded sand, especially reclaimed sand, the sulfur content must be
kept to a minimum. The larger the wall thickness, the lower the sulfur content of the
sand should be.
Maximum sulfur content in sand is 0,10 to 0,12 % for steel and ductile iron, for all
other materials, maximum 0,5 % is admitted. The combination of sulfur with oxygen
and nitrogen is worse.
This is sometimes solved by the use of “new sand” around the pattern and for the
cores. The sulfur content is than minimum. But this has the disadvantage that the
sand grains will have the silica-expansion by heating above 600 °C, which increase
the tendency to finning and penetration.
It is also necessary to use the correct type of coating and apply it with a correct
thickness of the layer, to bloc the contact liquid metal – mould material to the
maximum extend.
The best method is to apply two layers of coating:
Pay attention on the thickness because a too thick layer can crack easily and give
way to sulfur penetration of the metal.
The production of ductile iron is connected with the presence of dross. Dross is
mostly present in the casting surface and if it is not removed by machining (or
grinding), it can reduce the fatigue life of the casting drastically.
Top pouring, falling down of the metal, especially more than 500 mm, will always
have dross and air inclusions.
If the dross enters the mould cavity, it can be collected in the risers, vents, machining
stock and or dross collectors. This is an action to correct a none or less controlled
dross formation in previous stages of the metal pouring process.
Dross can be detected very easily by NDT tests, especially UT and MT (fluorescence
to a high extend) and PT. It is very much present in large castings.