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1) N 2 2) O 2 3) F2 4) He2
m
2. The bond order of superoxide ion [ O 2 ] is
co
1) 1 2) 1.5 3) 2 4) 2.5
n.
3. Bonding electrons present in N2 molecule are
io
1) 2 2) 4 3) 6 4) 10
at
4 . Bond order of H2 is similar touc
1) N2 2) O2 3) Li2 4) F2
ed
1) O2 2) O 2 3) N2 4) O2+
hi
molecular orbitals?
a
1) C2 2) N2 3) O2 4) F2
.s
1) 2) 3) 4) 2Pz
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9. H 2 and H 2 ions have the same bond order of 0.5, but H 2 is slightly less
stable than H 2 .This is due to
1) It is anion.
m
4) Two electrons in bonding orbital.
co
10. Addition of wave functions of yA and yB of atomic orbitals A and B form
n.
1) Bonding molecular orbitals
io
2) Anti-bonding molecular orbitals
at
3) Both bonding and antibonding molecular orbitals
uc
4) Hybrid orbitals
12. The bond length in O 2 , O2 ,O 2 and O2 2 follows the order
a
1) O 2 2 O 2 O 2 O 2 2) O 22 O 2 O 2 O 2 2
.s
3) O 2 O 2 O 22 O 2 4) O 2 2 O 2 O 2 O 2
w
1) Bonding molecular orbital has less energy than the combining atomic
w
orbital.
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14. Which of the following has a bond order of 0.5?
1) H2 2) H 2 3) N2 4) Ne2
15. When N2 changes to N2+, then N-N bond distance and O2 changes to
O2+, then O-O bond distance
m
1) Increases, decreases 2) Decreases, increases
co
16. The highest bond strength is for
n.
1) O2- 2) B2 3) N2+ 4) He2
io
17. Bond order of Be2 is
at
1) 0 2) 1 3) 2 4) 3
uc
18. Which one of the following correctly represents, the increasing order of
ed
their stability
1) The peroxide ion has bond order of ½ while the oxygen molecule has bond
a
order of zero
.s
2) The peroxide ion has a longer and weaker bond than the oxygen molecule
w
4) The bond length of the peroxide ion is smaller than that of O 2 molecule
w
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21. Bond order and magnetic behaviour of O2 is
1) 2, diamagnetic 2) 1, diamagnetic
3) 2, paramagnetic 4) 1, paramagnetic
22. The number of antibonding electron pairs in O2 2 ion on the basis of
molecular orbital theory is
m
1) 2 2) 3 3) 4 4) 5
co
23. According, to MOT, the number of unpaired electrons in O2 molecule is
n.
1) 2 2) 4 3) 12 4) Zero
io
24. According, to MOT, the bond order of a molecule is equal to
at
1) Total no. of bonding electrons uc
2) Total no. of anti-bonding electrons
electrons
hi
A) O2 1) 2.5
a
.s
B) O2 1 2) 1.0
w
C) O2- 3) 2
w
D) O2 2 4) 1.5
w
A B C D A B C D
1) 3 2 1 4 2) 3 1 4 2
3) 2 3 1 4 4) 2 3 4 1
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m
28. Which of the following is not paramagnetic?
co
1) N2+ 2) CO 3) O2 1 4) NO
n.
29. Which of the following species has the lowest bond order?
io
1) O2 2) O2 1 3) O2- 4) O2 2
at
30. Which set of the following species has a bond order of 2.5?
uc
N 2 , NO,O 2 O 2 , NO,CN N 2 ,CN ,O2 CN , N 2 , O 2
1) 2) 3) 4)
ed
31. Which of the following set are isoelectronic?
32. Which of the following diatomic species do you expect to have the longest
ks
bond length?
a
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34. Which one of the following statement regarding molecular orbital is
incorrect?
1) The energy of the anti bonding M.O is more than the combining atomic
orbital and it destabilizes the molecule.
2) The energy of the bonding M.O is less than the combining atomic orbital
m
and it stabilizes the molecule.
co
3) The increase in the energy of anti bonding molecular orbital is same as the
decrease in the energy of bonding molecular orbital
n.
4) The no. of bonding M.O’s is twice to Anti bonding M.O’s
io
35. For a homodiatomic molecule with a total number of electrons 14 after
at
*
filling 2s M.O the next electron goes to
uc
1) 2 pz
2px 2py 2px or 2py
2) 3) 4)
ed
36. Which of the following ion has not bond order of 2.5?
38. Which of the following species has the shortest bond length?
w
N 22-
w
1) N2+ 2) N2 3) N2- 4)
w
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KEY
11) 4 12)1 13) 4 14)2 15)1 16)3 17)1 18) 1 19)2 20) 2
m
co
21)3 22) 2 23)1 24) 3 25) 2 26)1 27)1 28)2 29)4 30) 1
n.
io
31) 2 32) 2 33)2 34)4 35)4 36)1 37) 1 38) 2 39)2 40)2
at
uc
ed
hi
a ks
.s
w
w
w
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