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JTTEE5 25:920–932

DOI: 10.1007/s11666-016-0407-7
1059-9630/$19.00 Ó ASM International
Peer Reviewed

Modeling Multi-Arc Spraying Systems


K. Bobzin and M. Öte

(Submitted November 20, 2015; in revised form March 28, 2016)

The use of plasma as energy source in thermal spraying enables among others the processing of feed
stock materials with very high melting temperatures as coating materials. New generation multi-arc
plasma spraying systems are widely spread and promise several advantages in comparison to the con-
ventional single-arc systems. Numerical modeling of multi-arc plasma spraying offers the possibility to
increase the understanding about this process. This study focuses on the numerical modeling of three-
cathode spraying systems, introducing the recent activities in this field and discussing the numerical
aspects which influence the prediction power of the models.

Keywords CFD, modeling, multi-arc spraying, net emission


independent arcs with lower fluctuations. Multi-arc sys-
coefficient, numerical analysis, plasma spraying, tems together with new torch designs promise an increase
turbulence in the reachable deposition efficiencies as well as an
enlargement of the process window with respect to parti-
cle temperatures and velocities in comparison to the
conventional single-arc systems.
In spite of the impressive developments in the last
1. Introduction decades, some of the underlying fundamentals of the
multi-arc plasma spraying are still poorly understood. The
Thermal spraying consists of a number of different intensive research in the field of single-arc technology
process variants whose common feature is a concentrated through both experimental measurements and numerical
high-energy heat source in which the spraying material is modeling have allowed a much better understanding of
incorporated and deposited onto the surface of the sub- the process with respect to plasma fluctuations, particle-
strate in the form of molten and semi-molten spray par- plasma interactions, and so on (Ref 2, 6-13). However,
ticles with high velocity. Air plasma spraying is part of apart from recent research activities this does not apply to
thermal spraying and its basic characteristic is high plasma multi-arc plasma spraying. In particular, there is still a
temperatures of up to Tp = 20,000 K, allowing the pro- need for investigations regarding the characteristics of the
cessing of even materials with very high melting points in plasma columns in the plasma torch as well as with respect
ambient air (Ref 1). The use of plasma as an energy source to the interaction of powder particles with the plasma jet.
goes back to the developments from 1920s to 1930s and The former will be the subject of this paper. An overview
found first industrial application in thermal spraying in about the recent activities to model three-cathode spray-
1950s and 1960s (Ref 1, 2). Since then several ongoing ing systems will be given and numerical aspects influenc-
developments regarding the design and working principle ing the prediction power of the numerical models will be
of the plasma torches have been realized. The 1990s were discussed.
mainly devoted for the development of new direct current
(DC) and radio frequency (RF) torches (Ref 2). One of
the main driving forces for the development of new DC 2. State of Art
torches was increasing the process stability by reducing the
plasma fluctuations.
The energy source in plasma spraying, which is
In order to minimize the fluctuations in DC torches,
responsible for the acceleration and heating of the feed-
increase the spraying efficiency as well as reduce the
stock particles up to their melting temperatures, is based
electrode heat load, Klaus Landes has developed a novel
on electrical energy. The conversion of the electrical en-
plasma spraying system with three independent cathodes
ergy into heat and kinetic energy is realized in a plasma
using a cascaded design (Ref 3-5). The generation of the
torch by changing the state of a gas or a mixture of gases
multi-arc systems is therefore one of the latest evolutions
into the plasma state. As a result of reached high tem-
of plasma torches and realized preferably with three
peratures (T > 10.000 K), the operating gas expands and
cathodes (TriplexPro-210, Oerlikon Metco Ltd.; Axial III,
leaves the torch with high velocities (v > 1000 m/s). The
Northwest Mettech Corp.) or three anodes (Delta Gun,
plasma state is achieved through the application of an
GTV Verschleißschutz GmbH) allowing the formation of
electric current between the electrodes of the plasma
torch.
K. Bobzin and M. Öte, Surface Engineering Institute, RWTH Since interior of plasma torches is not easily accessible
Aachen University, Kackertstr. 15, 52072 Aachen, Germany. for optical measurement equipment, and harsh process
Contact e-mail: oete@iot.rwth-aachen.de.

920—Volume 25(5) June 2016 Journal of Thermal Spray Technology


conditions, i.e., extremely high temperatures and veloci- magnetic fields. The set of above-mentioned equations is

Peer Reviewed
ties, hinder the mounting of measuring devices into the called magnetohydrodynamic (MHD) equations
plasma chamber, experimental examination of plasma arc and—together with the consideration of the turbulences
in plasma spraying systems is extremely difficult. There- occurring in the flow—can describe the velocity and
fore, many authors make use of numerical analysis in or- temperature fields inside the plasma torch with relatively
der to increase the understanding about the process and high precision (Ref 2, 13, 17).
plasma behavior in it. The dynamics of the arc in the torch is determined by
The most precise approach to describe plasma is the the imbalances between the electromagnetic forces and
implementation of a kinetic plasma model. This model is flow drag. Several design factors, i.e. the geometry of
based on a distribution function that describes the velocity plasma chamber and electrodes, inner diameter of the
of each species (electrons, heavy ions) at a given location nozzle etc., influence the magnitudes and directions of the
and a given time (Ref 14). Although by using kinetic above-mentioned forces, leading to different behaviors of
plasma model a very detailed description of the plasma the electrical arcs in different plasma spraying torches.
can be reached, its use is extremely limited due to the high Main characteristic geometrical feature of the so-called
computational demand imposed. non-transferred single-arc torches is that the outer surface
Another method, which is widely used by several au- of the plasma chamber works as anode, along which the
thors in order to describe the plasma, is based on contin- arc root attachment can theoretically move freely.
uum approach. In this case, the plasma is modeled as a Therefore, the variation of the arc length and change in
fluid with corresponding thermodynamic and transport the spatial position of the arc root attachment on the an-
properties. These properties are calculated using the ode cannot be excluded (Ref 18). Strongly simplified, the
temperature- and pressure-dependent mean density, mean time-dependent imbalances between flow drag, which
velocity, and mean energy of the species in the plasma gas. tends to drive arc root attachment along the anode
Since this method deals with macroscopic quantities of the downstream, and the electromagnetic forces, which acts
plasma flow and neglects the local differences of the after SteenbeckÕs minimum energy principle in contrary
properties of plasma species, it needs significantly less direction leading the arc root attachment to a thermody-
computational effort in comparison to the kinetic plasma namically more favorable position, cause that plasma
model (Ref 14). However, the precision of this method is fluctuations occur. Please note that the electromagnetic
limited to the fulfillment of local thermodynamic equilib- forces can act locally in the opposite or same direction of
rium (LTE) assumption, which is also coupled with the the drag force exerted by the cold gas on the anode arc
assumption of local chemical equilibrium (LCE). While attachment depending on the curvature of the thin column
LCE assumption implies that the plasma composition does linking the arc column to the anode.
not exhibit local differences, LTE assumption implies that The new generation multi-arc systems consist of either
the velocities or energies of plasma species, resulting from three cathodes or three anodes and a single-counter
elastic collisions, follow a particular distribution and can electrode depending on the design type. In industry, the
be characterized by a single temperature (Ref 15). High three-cathode variant has already been established as the
collision frequencies in plasma spraying lead as a general most prominent example of multi-arc systems. In Fig. 1,
rule to a state for which LTE assumption holds. Excep- the design concept of this system is presented schemati-
tions to this approximation occur at the boundaries of cally. In this system, the arcs are generated in a long
plasma, which interacts with the electrodes or with the plasma chamber between three mutually electrically
surrounding process gas flow (Ref 13). In most cases, the insulated cathodes and an anode ring located at the outlet
models relying on LTE approximation have been em- of the torch. Since the axial movement of arc attachment
ployed in the literature in order to analyze the plasma
spraying. A more detailed modeling of the plasma allow-
ing the consideration thermodynamic non-equilibrium
(NLTE) conditions can be realized using so-called two-
temperature models (Ref 16). In this case, the velocities or
energies of plasma species are characterized with two
temperatures: the electron temperature und heavy species
temperature. This model is based on the assumption that a
thermodynamic non-equilibrium exists merely between
the electrons and heavy ions in the plasma and neglect-
s—in contrast to kinetic plasma model—the NLTE con-
ditions between individual plasma species.
In order to model the plasma spraying process, it is
necessary not only to describe the plasma by means of
numerical methods but also the interaction between the
plasma and surrounding cold gas flow. This is realized by
coupling the mass, momentum, and energy conservation
equations (Navier-Stoke equations) with the MaxwellÕs Fig. 1 Representation of a three-cathode/one-anode spraying
equations which describe the evolution of the electro- torch schematically

Journal of Thermal Spray Technology Volume 25(5) June 2016—921


point is restricted with small axial dimension of the anode sults was investigated and discussed (Ref 26). In the fol-
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ring, the variation of the arc length is not pronounced. lowing, the developed numerical model in these studies
Moreover, the circumferential movement of the arcs is will be presented. The influence of numerical assumptions,
also limited because of the off-center positioning of the which are usually employed to define boundary conditions
cathodes. This means, for each cathode there is a specific and to describe the plasma gas properties, on to the results
circumferential position at the side of the anode with the will be analyzed and discussed. Furthermore, the predic-
closest path distance to the cathodes. Each arc tends to tion power of the simulations with respect to the employed
attach to the closest point at anode after SteenbeckÕs turbulence and radiation models will be discussed.
minimum energy principle. The measured voltage be-
tween the electrodes is directly proportional to arc length
and its variation to the arc stability. In case of this plasma 3. Flow Characteristics, Mathematical
spraying system, the instant voltage values read on the
user interface fluctuate around the measured mean volt- Model, and Boundary Conditions
age only slightly. The shown deviations correspond to
values which are less than a few percentiles of the mea- In this study, plasma is described as an electromagnetic
sured mean voltage. This supports the assumption that the reactive fluid in LTE using temperature-dependent ther-
positions of the electric arcs inside the torch do not change modynamic and transport properties. Although, it cannot
significantly. be excluded that the NLTE conditions exist in some re-
Intensive research and progress in the field of modeling gions of whole calculation domain, especially at the near
the single-arc plasma spraying have helped to achieve a proximity of the electrodes and plasma boundaries, it can
better understanding of the process. This applies to prin- be assumed that because of stable positions of the arcs in
ciples of arc re-attachment process, modes of plasma multi-arc systems, these should be less pronounced in
fluctuations, and so on. However, these models still lack comparison to single-arc systems. The mass, momentum,
complete predictive power, especially with respect to and energy conservation equations are coupled with
calculating the process temperatures and velocities pre- electromagnetic field equations, in order to describe the
cisely over a large range of time period. Mainly, the magnetohydrodynamic flow. The model accounts also the
complexity of physics involved in arc re-attachment pro- turbulent character of the flow. The radiation within the
cess, generally speaking during plasma fluctuations, is the torch cannot be neglected due to the very high tempera-
limiting factor for more accurate simulations. tures. In this study, the radiation is treated using the net
Multi-arc spraying promises an increase in deposition emission coefficient model. A user-defined subroutine is
efficiencies, longer electrode life times and a wider process implemented as a temperature- and pressure-dependent
window, which have already been reported by several net energy term into the energy conservation equation.
authors (Ref 19-22). Yet, this has not been investigated by The set of equations which are used for modeling plasma
means of numerical simulations intensively in order to spraying system in order to describe the plasma, plasma
achieve a better understanding of the process as well as flow, interaction of plasma with cold gas flow, turbulences,
that of its limits and possibilities. Unlike single-arc plasma and radiation will not be listed in this publication. For an
spraying, where the complexity of the arc fluctuations in- overview, please refer to (Ref 17, 24).
volved in process mainly limits the predictive capability of In Fig. 2, the interior geometry of a three-cathode
numerical models, in multi-arc plasma spraying the posi- spraying system is presented. The geometry of the torch
tions of the electric arcs inside the torch do not change nozzle shows a threefold axial symmetry. Therefore, a
significantly. This allows a steady-state numerical analysis one-third section of the whole geometry is used as the
of the multi-arc plasma process, enabling a better predic- calculation domain by defining periodic boundary condi-
tive power for the simulations regarding the calculated tions at the cutting planes which are intersecting each
velocities and temperatures. The first research activity other with an angle of 120°. The calculation domain to-
published aiming to model the operating principle of a gether with the included solid domains is depicted at the
three-cathode torch was conducted by Muggli et al. (Ref right side of Fig. 2. In this torch, the feeding of plasma gas
23) in 2007. In the previous works, the authors showed successes over 24 inlets into the convergent chamber
that the calculated temperature profiles at the outlet of a where three water-cooled cathodes are placed. Behind the
three-cathode torch exhibit a characteristic triangular chamber throat there is a long tubular section with neu-
distribution. By means of advanced computer tomogra- trode rings, which is followed by the anode ring located
phy, 3D representation of the plasma plum downstream of next to the torch outlet.
the torch exit is reconstructed. The measurements confirm In Fig. 3 the general behavior of the plasma columns in
with numerical results (Ref 17, 24). In a further study, plasma chamber is presented. Because of the inclination of
authors investigated among others the influence of pres- the inletting pipes, the flow exhibits a clear swirling
sure dependency of thermodynamic and transport prop- behavior at the rear side of the chamber. As a result of the
erties of plasma gases on the results. It was shown that pronounced swirling flow and limited interaction of the
with the consideration of pressure dependency, the tem- cold gas flow with the plasma columns at the converging
perature, and velocity profile calculated at the torch outlet part of the chamber, three clearly separated plasma col-
change significantly (Ref 25). In a further investigation, umns, which are driven by the gas flow in counter-clock
the influence of the selected turbulence model on the re- direction, can be observed. As the flow evolves along the

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Fig. 2 Interior geometry of the TriplexProTM-210 torch from Oerlikon Metco GmbH (Hattersheim, Germany) and calculation domain

Fig. 3 General characteristics of plasma columns in a multi-arc plasma spraying system for different process para

tubular section, the temperatures and velocities get higher. process parameters with low volumetric flow rates; in case
On the one hand, the separated plasma columns tend to of high volumetric gas flow rates, it is likely that a colder
merge together due to the electromagnetic forces and region forms at the middle of the torch outlet as a result of
turbulent mixing. On the other hand, the cold gas flow apparent separation of the plasma columns. In (Ref 26),
drives them apart from each other. In case of a high vol- the correlation between the results and the process
umetric gas flow and a low electric current, the separation parameters has been analyzed. It has been pointed out
of the single plasma columns along the plasma chamber that, the temperatures at the outlet increase with
even up to nozzle outlet can be recognized (Fig. 3, right). increasing electrical current and decreasing volumetric gas
Contrarily, when the volumetric flow rates are not suffi- flow. Moreover, a positive proportionality between the
cient enough to drive the plasma columns apart from each velocities at the torch outlet and volumetric gas flow and
other by overwhelming the electromagnetic forces, the electrical current has been identified.
plasma columns designated with T = 12,000 K Iso-surfaces Although the inflow into the plasma torch might be
form a bundle, and separated iso-surfaces are not any assumed to be incompressible due to the very low Mach
more recognizable along the tubular section (Fig. 3, left). numbers, the flow certainly reaches higher Mach numbers
Moreover, it can be seen that, as the velocities increase along the plasma chamber and leaves the torch out-
along the tubular section in longitudinal direction, the let—depending on the process parameters—subsonic or
swirling behavior of the flow is significantly suppressed. supersonic. Depending on the Mach numbers of the flow,
Temperatures and velocities as well as their spatial it should be evaluated whether the compressibility effects
distribution at the outlet depend on the plasma behavior need to be considered in analyses by employing full en-
in the chamber with respect to different process parame- ergy equation.
ters. While a triangular occurrence of the profiles with In Fig. 4, the difference between the results of the
radially decreasing values toward the anode is common for simulations with and without the compressibility effects is

Journal of Thermal Spray Technology Volume 25(5) June 2016—923


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Fig. 4 Velocity profiles at the outlet of the TriplexProTM-210 torch

illustrated. Average velocity and temperature values cal- cant errors in simulations. In case, the thermodynamic and
culated at the torch outlet deviate from each other at transport properties implemented in the simulations do
about 6 to 8%. This is valid for the process parameters not consider the pressure dependency, the compression of
which are listed in Fig. 4. The flow reaches up to relatively the plasma gas with increasing pressure will not be cal-
high Mach numbers (Ma  1.06) in case of these process culated during simulations. This would lead artificially
parameters. The deviation between the simulations with high specific volumes and velocities of the plasma gas
and without compressibility effects is less pronounced in especially at the rear side of the plasma chamber where
case of lower volumetric gas flow rates and higher electric pressure reaches up to 300 kPa for high volumetric gas
currents. In case of a volumetric gas flow rate of 50 SLPM flow rates. In case of high volumetric flow rates and high
and an electric current value of 500 A, the deviation pressures, numerical calculations would not converge and
amounts to <1%. Mach number at torch outlet results in terminate abruptly due to non-physical definition of the
a value of around 0.7 in this case. As a thumb of rule, it plasma gas. The deviation between the results of simula-
can be stated that the incompressibility assumption might tions with and without pressure-dependent gas properties
lead to considerable errors if the flow reaches to the is illustrated in Fig. 5 for a process parameter set for which
supersonic velocities along the plasma chamber. For the resulting pressure is relatively low (p  140 kPa). In
slower process parameters, it seems to have an insignifi- this case, average velocities at the torch outlet differ from
cant effect. In our further numerical analysis, the full en- each other with an amount of about 5%, whereby for
ergy equation is employed for a better accuracy. calculated maximal velocities this amounts to about 18%.
Another very important point is the definition of the In order to resolve the temperatures and velocities in
plasma gas properties. The prediction power of the sim- an air plasma spraying torch accurately, the size of the
ulations depends strongly on the use of accurate thermo- elements needs to be sufficiently small. However, a mesh
dynamic and transport properties. A large volume of data model consisting of too fine elements might in some of the
is available for the properties of different plasma gases in cases lead to numerical instabilities and in most of the
the literature. In this study, plasma gas properties com- cases would be too expensive regarding the computation
puted by Murphy are used (Ref 26, 27). For the calcula- time. Therefore a systematical analysis, which is usually
tions and assumptions used for determining these called mesh independence analysis, is required in order to
properties, please refer to the works of this author (Ref 27, find a compromise between the spatial accuracy of the
28). In most of the cases, the published data include the model and the computation time (Ref 26).
temperature-dependent thermodynamic and transport The calculations are carried out parallel on multi-pro-
properties, but neglects the pressure dependency. There- cessor workstations (up to 24 processors) with the com-
fore, it is a common practice that the models of plasma mercial CFD software package ANSYS CFXÒ Release
spraying systems usually do not rely on gas properties 15.0. The following convergence criteria applied to simu-
which considers the pressure effects. This leads to signifi- lations:

924—Volume 25(5) June 2016 Journal of Thermal Spray Technology


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Fig. 5 Influence of the definition of gas properties on the calculated velocity profiles at the torch outlet

– Root mean square (RMS) residual errors must be boundary is not allowed by setting a ‘‘zero flux’’ boundary
<10 5. condition. Assuming that magnetic fields induced by the
– Maximum residual errors must be <10 3. arcs are negligible at inlet positions, the Cartesian mag-
netic vector potentials are set to be zero.
– Global flow imbalances must be <1%.
– Temperature, velocity, and pressure values at monitor 3.2 Outlet
positions of interest must reach a steady solution.
The outflow boundary conditions are described at torch
outlet (Fig. 2). An average atmospheric pressure of
3.1 Gas Inlets p = 101.325 kPa is set. Analog to inflow boundary condi-
Although implementation of inflow boundary condi- tions, a ‘‘zero flux’’ boundary condition is defined for
tions is relatively straight forward, there are several issues current flow and the Cartesian magnetic vector potentials
which need to be considered for setting these boundary are set to be zero.
conditions; especially if the gas temperatures and veloci- Ideally, the calculation domain should be extended in
ties over the inlet regions are not known. Plasma spraying downstream direction in order to set the boundary con-
systems usually do monitor the volumetric flow rate of ditions far enough from plasma jet. Depending on flow
inletting plasma gas which is corrected according to stan- characteristics, this might be necessary in order to ensure
dardized conditions, but do not deal with the temperatures that the flow is not largely disturbed or interrupted by the
and velocities of this. Therefore imposing temperature outflow boundary. In the current study, the influence of
and velocity values of inflowing gas to the calculation the region downstream the torch outlet on the results
domain might require installation of further measuring obtained at the outlet boundary condition is investigated.
equipment to the regions of interest. To overcome this Several simulations with different process parameter sets
issue, the inflow boundary conditions are defined using have been conducted with an extended domain. The
mass flow rates over gas inlets (Fig. 2). These are calcu- profiles at the nozzle outlet are compared with the results
lated using the volumetric flow rates and known plasma of the simulations conducted with the calculation domain
gas densities at standard conditions (T = 0°C, shown in Fig. 2. Based on this comparison, it has been
p = 101.325 kPa). A well-posed formulation of the com- pointed out that the influence of the domain extension on
pressible flow problem is assured by specifying atmo- the results is negligible. Considering the computational
spheric pressure as outflow condition. Furthermore, inflow cost, the region downstream the torch outlet is not in-
boundary conditions need to be described regarding the cluded to the calculation domain for the further analyses
direction of gas movement. Plasma gas is usually fed in to in the course of this study.
the chamber with a swirl angle resulting from the
arrangement and inclination of feeding pipes. The feeding 3.3 Neutrodes, Ceramic Rings, and Housing
pipes are not included in the calculation domain as it is With the exception of anode and cathodes, the outer
desired considering the calculation costs and element surface of the plasma chamber is defined as non-con-
quality. The flow direction of inflowing gas is described by ducting, ‘‘no-slip’’ walls. This includes the neutrodes,
imposing the flow direction over a direction vector. Fur- which come into use during the ignition phase of the
thermore, a static temperature value of T = 300 K is set for plasma spraying system, and ceramic rings used to isolate
incoming flow. Electrical current flow through this these from each other (Fig. 2). Convenient with the

Journal of Thermal Spray Technology Volume 25(5) June 2016—925


measured temperatures of cooling water, which vary at letting the temperatures remain artificially high enough
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most between T = 293 K and T = 311 K, a constant static (T > 7000 K) at the near proximity of the electrode is a
temperature of T = 300 K is assigned to the walls of the common practice in literature (Ref 9, 29, 30). An alter-
chamber as boundary condition. The direction of the native approach is the specifying of an artificially high
magnetic fields induced by the arcs is specified to be in the electrical conductivity to the plasma gas in the regions
normal direction to the wall surfaces. close to the electrodes (Ref 7, 31).
Ideally, a solid domain surrounding the plasma cham- As it mentioned above, the arc breaks and reattaches
ber should be included into the calculation domain in somewhere upstream due to the stretching of the plasma
order to calculate the magnetic fields evolving beyond the column as a result of imbalances between flow and elec-
flow boundaries. The evolvement of the magnetic fields in tromagnetic forces. In literature, the main approach to
solid region of neutrodes and ceramic rings might have an model the re-attachment process relies on the fact that the
influence on the calculated magnetic fields within the flow dragging of the arc by the flow field causes the local
domain. The significance of this effect has not been electric field around the arc to increase (Ref 13). This
investigated in this study. approach is based on the assumption that the electric field
overcoming a certain threshold value causes that a new
attachment point occurs and the existing attachment point
3.4 Anode and Cathodes
disappears. In case of multi-arc systems, the modeling of
The definition of boundary conditions at electrodes the re-attachment process is not practicable and also not
(anode and cathodes) can be configured with varying inevitable to determine the general behavior of the plasma
complexities depending on the purpose of the simulation columns in the chamber. This can be justified with the fact
as well as depending on the physics and scales, which were that, in case of multi-arc systems, the time and spatial
to be resolved using the implemented models. Aiming the scales in which the re-attachment process occurs are sig-
determination of electrode erosion using numerical nificantly smaller than those occurring in conventional
methods, one needs to calculate the heat transfer on to the plasma spraying systems. In case of multi-arc systems, the
electrodes very accurately. This requires the incorporation arc between the plasma columns and the anode is driven
of several physical phenomena, i.e. electron condensation, with very high velocities over a small-dimensioned anode.
ion recombination, evaporation of electrode material, and A gas flow between the plasma column and the anode
so on. Therefore, the simulation cannot be conducted surface with a longitudinal velocity of, i.e., about
under the LTE assumption any more. Plasma sheaths are v = 1000 m/s and relatively low temperature of T = 6000 K,
particularly important for determining the electrode ero- for which the gas exhibit relatively low electrical conduc-
sion because their properties determine how charged tivity, causes that the arc between the plasma column and
species interact with the electrodes. Sheath regions are anode surface is driven out of the plasma chamber over a
formed as a result of electrons leaving the bulk plasma at 1-cm-long anode within almost t = 0.01 ms. In order to
the near proximity of the electrodes much more rapidly resolve the re-attachment process in a multi-arc systems,
than the positive ions. This results in a higher number of depending on the process parameters and anode dimen-
heavy ions than that of electrons remaining in the sheath sions, a magnitude order of time scale which is signifi-
region. The net positive charge in plasma sheath balances cantly less than about one-hundredth milliseconds needs
an opposite negative charge on the surface of electrode to be defined in a non-steady simulation. On one hand, a
with which it is in contact. The erosion of the electrodes time resolution with this magnitude of order would not be
depends strongly on the energy and direction of ions practicable considering the computational costs involved.
striking on to electrodes by their fall through sheath re- On the other hand, continuity of the current flow needs to
gion. Plasma sheaths have very small thicknesses in the be assured between plasma column and the anode surface.
order of magnitude of several DebyeÕs lengths. In this study, the interruption of the current flow at the
The complexity of the above-mentioned physical pro- anode side is avoided by assigning an artificial electrical
cesses together with very small time scales and lengths of conductivity to the elements which are located close to the
the sheath regions in comparison to those of bulk plasma anode surface. Here it must be noted that, by applying this
makes it difficult to incorporate these regions to the sim- measure one does not resolve the arc attachment, rather
ulations, especially considering the increased computa- assume that the arc forms somewhere between the plasma
tional cost. Furthermore, this might not be necessary, if column and anode within this region. Therefore, the
the determination of the electrode erosion is not the focus thickness of this layer and the magnitude of the artificial
of the analysis. On the other hand, it is necessary to assure electrical conductivity assigned to this layer are varied
that the electrical current flowing through the bulk systematically to investigate the influence of these values
plasma/electrode interface is not interrupted. In a LTE on the results. Here it has been pointed out that, assigning
model which does not incorporate a sheath model, the an electrical conductivity value of S = 1000 S/m is suffi-
temperatures of electrons and heavy ions are assumed to cient to ensure the flow of electric current from plasma to
be equal to each other. At the near proximity of the the anode. This value corresponds approximately to the
electrodes, where the temperatures are low due to the electrical conductivity of argon at T = 8000 K. Further
intense cooling, the electrical conductivity of the plasma increase in this value reveals no significant difference. In
gas becomes very low due to this assumption, causing that Fig. 6, the deviations of the temperature profiles at torch
the current flow is broken. In order to overcome this issue, outlet, which are calculated with different electrical con-

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Fig. 6 Calculated temperature profiles at torch outlet with different electrical conductivities assigned to the elements close to the anode
surface

ductivities, are illustrated. The contour plots in this fig- of the arc attachment spot at the surface of cathode. As
ure show almost identical temperature profiles. For this the swirling gas blows around the cathodes letting the
parameter set, increasing the assigned electrical conduc- cathode surface in the direction of swirling flow gets cold,
tivity 100 times revealed to a difference of <4% for at the other side of the cathode a thermodynamically
average values and <1% for the maximal values of tem- favorable position for arc attachment evolves.
perature and velocity. Although having an artificially In this study, solid calculation domains for cathodes
generated conductive region at the proximity of the whole and anode, which allow the solving of the energy conser-
inner surface of the anode restricts the determination of vation and electromagnetic equations beyond the flow
the arc attachment position at the anode side, it is very boundaries, are included in the simulations. The cathode
likely that the arc forms at a position that the plasma inclusion into the computational domain allows a better
column nearest to the anode surface. Furthermore, the description of the dynamics of the arc, as the coupling
thickness of the layer with artificial electrical conductivity between arc and cathode enables the calculation of the
is varied as well. In this case, the smallest thickness, for current density at the cathode tip rather than imposing it
which a steady current flow could be assured, was 0.2 mm. as a Gaussian-like boundary condition profile over the
Increasing this value to 0.5 mm and further to 1 mm re- cathode tip surface (Ref 32).
vealed only to differences <1% regarding both maximal An electrical potential value of U = 0 V and tempera-
and average values of temperature and velocity and ture value of T = 300 K are assigned to the outer surface of
showed no significant changes in profiles. As a result, it the solid calculation domain of anode. The total amount of
can be stated that although assigning an artificial electrical electric current flowing into the calculation domain is
conductivity to the elements close to the anode surface defined by assigning a uniform current flow density normal
limits the ability of the simulation to predict the exact to the outer surface of the cathode domain (see Fig. 7).
position of arc attachment at the anode boundary; this The assigned temperature at this boundary amounts to
does not influence power of the simulations regarding the T = 300 K as well. The direction of the magnetic fields is
prediction capability of the general flow characteristics. specified to be normal to the outer surfaces of the elec-
Furthermore, it is evident that the results are not sensitive trodes. In Fig. 7, the flow of electric current density in the
to assigned magnitude of the artificial electrical conduc- calculation domain is shown exemplarily for the process
tivity as well as to the thickness of the conductive layer parameter set depicted in this figure.
within the investigated ranges. The variation in the mag- It must be noted that, without including the solid do-
nitude of the artificial electrical conductivity and thickness mains to the calculation domain, numerical singularities
of the conductive layer would mostly affect the calculated occur. Especially for high gas flow rates, the incorporation
frequency of the arc re-attachment process which is of the cathode electrode to the calculation domain seems
occurring locally in a very small area within extremely to be critical regarding the numerical stability. On the
small time scales. This phenomenon cannot be predicted other hand, it is possible to exclude the coupling of mag-
by a steady-state model. netic fields induced in the solid domains from the calcu-
At the cathode side, no further measures were neces- lations without causing numerical instabilities. In this case,
sary because of the calculation elements at cathode however, the converged results using the models with and
interface being large enough to let the temperatures re- without consideration of magnetic fields in the cathode
main high enough at the cathode boundary. Moreover, the electrode differs from each other in some cases depending
high volume flow of inletting cold gas cares of the stability on the process parameters significantly. In Fig. 8, the

Journal of Thermal Spray Technology Volume 25(5) June 2016—927


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Fig. 7 Representation of the electric current density in calculation domain

deviation of the temperature profiles at the torch outlet is which are based on the solutions of the approximations of
illustrated exemplarily using the process parameter listed the time-averaged Navier-Stokes equations, dominate the
in this figure. It can be seen that, the temperature profiles plasma spraying literature due to their robustness and low
differ from each other significantly. For this process computational costs (Ref 13). Mostly, two-equation
parameter, the deviation of the results amounts to 5-7% in models such as the k-e and RNG k-e are used to calculate
case of average temperature and velocity values. For momentum and heat dissipation due to the turbulences in
maximal values of temperature and velocities, the differ- plasma torch.
ence corresponds to about 8%. Apparently, not only the In order to describe the turbulent behavior of various
shape of the arc attachment point but also the position of flow types, a wide variety of approaches have been
it on the anode surface is influenced by the incorporation developed, of which the most important ones are men-
of the cathode bodies to the calculation domain. This tioned above. Despite all efforts, it has not been yet pos-
seems to have a considerable effect on the characteristics sible to be able to describe any kind of turbulent flow with
of the flow downstream, resulting in the above-mentioned a single model. All turbulence models underlying
differences in the velocity and temperature profiles of Boussinesq approximation loses namely its validity as
nozzle outlet. Based on the discussion conducted above soon as the relationship between the Reynolds stresses
regarding the numerical instabilities and accuracy of the and the viscosity forces is no longer linear. Flows over
results, it is recommended to incorporate electrode do- curved surfaces, flows with boundary layer separation,
mains to the calculation domain. swirling flows and three-dimensional flows are some
examples where the above-mentioned assumption does
not hold. The models therefore need to be adjusted con-
4. Turbulence Model sidering the flow type by means of correction terms or
extensions for each respective problem. The main prob-
Due to the high temperature and velocity gradients in lem here is that the models are very sensitive and the
the torch and due to respective high shearing forces changes need to be validated experimentally when possi-
occurring, the flow in the torch is unstable and turbulent. ble. Considering the above-mentioned argumentation, the
Since resolving the eddies occurring in a plasma spraying question arises: Which turbulence model is suitable for
process by means of a so-called direct numerical simula- plasma spraying systems? Generally speaking, the two-
tions (DNS) is extremely challenging—if it is not feasi- equation models can be regarded to be more accurate than
ble—due to their large range of time and length scales and zero or one-equation models. The k-e model has proved
required computational power, many authors make use of its worth in fully turbulent flows at high Reynolds num-
the so-called turbulence models to describe turbulences bers. It is known that it produces in stagnation points too
(Ref 13). Although attempts to use of sophisticated tur- much kinetic energy and separation layers can only be
bulence model such as large eddy simulations (LES) have predicted inaccurately or not at all using this model.
been conducted by some authors for this purpose (Ref 33), The realizable and the RNG k-e model represents a
by far Reynolds-averaged Navier-Stokes (RANS) models, further development. The turbulent kinetic energy in the

928—Volume 25(5) June 2016 Journal of Thermal Spray Technology


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Fig. 8 Influence of the magnetic fields induced in the cathode domain on to the calculated temperature profiles at the torch outlet

stagnation points is reduced in this case. The k-x model about different sophisticated models which include for
provides good results in the near-wall region, because it example diffusion-like approaches (P1 approximation) or
includes modifications for shear flows. It is also suit- Monte Carlo methods, please refer to (Ref 13). Since a
able for small Reynolds numbers and is numerically very numerical description of the radiative transfer is as a rule
stable, and reacts however sensitively to small changes in computationally very expensive, net radiative flux in
the turbulence quantities at the edge of the flow area. plasma spraying is usually approximated using net emis-
The SST model combines the advantages of the k-e sion coefficients and implemented in the energy equations
model and the k-x model. It switches between k-e model as a source term. Net emission coefficient is the power
and the k-x model automatically through an additionally radiated per unit volume. Employing this approximation,
introduced function depending on the local Reynolds the energy loss due to the radiative emission can be cal-
numbers. As the Reynolds numbers get smaller at the wall culated in different positions of the calculation domain
boundaries, the k- x model comes into effect. Otherwise, depending on the temperature and pressure distributions
k- e model is used as the turbulence model. Therefore, this in these regions. However, this model neglects the radia-
model has been rated to be the more accurate than other tive transport within the calculation domain. This means
two-equation turbulence models (k-e and k-x) for a wide the model relies on the assumption that a particular point
range of flows (Ref 34). As already shown in (Ref 26) the in plasma column has a form of an imaginary sphere with a
turbulence model has a very significant effect on the predefined radius in which the emitted radiation can be
simulation results in case of plasma generator simulations. reabsorbed. Outside of this sphere, the radiation evolves
Although the absolute values of the results shown in (Ref through the calculation domain without interacting with
26) might differ from the absolute values shown in this the cold gas flow.
paper due to the fact that the model is further developed Radiative media are often characterized according to
with respect to the mesh model and incorporation of their optical thickness. In addition to the local parameters
electrode domains in to the calculation domain, the of the plasma i.e., temperature, pressure, the emission
statement that the turbulence model has a significant ef- coefficient depends on the thickness of the plasma. The
fect on the results preserves its validity. Further analysis emitted radiation from the central region which is the
referring to influence of different turbulence models on to hottest part will be reabsorbed as it crosses the plasma.
the results with respect to different process parameters Optically thin means that the plasma column has a theo-
needs to be conducted and will be the subject of another retical absorption radius of L = 0 mm and implies that no
study. In this study, Shear Stress Transport (SST) turbu- reabsorption takes place. However, reabsorption of emit-
lence model has been implemented considering the above- ted radiation can play an important role in modeling of
mentioned theoretical advantages for the simulations. plasma spraying in order to determine the temperature
and velocity profiles accurately. An appropriate charac-
teristic length needs to be defined prior to the calculations
5. Radiation Model depending on the thickness of the plasma column which is
subject of interest. The choice of this length scale is
however rather arbitrary and is one of the challenges in-
Another important factor which needs to be taken into
volved in using net emission coefficients (Ref 35).
consideration in order to model the plasma spraying
In literature, net emission coefficients of common
appropriately is the radiative transport. Discussion about
plasma gases and gas mixtures are published by several
the different radiation mechanisms and direct solution of
authors (Ref 35-38). For Argon gas, the published data
the radiative transfer equation in numerical models will go
differ only insignificantly from each other. In this study,
beyond the scope of this study. For an excellent overview

Journal of Thermal Spray Technology Volume 25(5) June 2016—929


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Fig. 9 Net radiative flux of pure Ar with respect to temperature

Fig. 10 Calculated temperature profiles at the torch outlet using radiation models with different path lengths

the available data from the work of Menart and Malik similar temperature distribution. For the process param-
(Ref 35) have been employed. Net radiative flux with re- eters listed in this figure, the average and maximal values
spect to temperature which is calculated by multiplying of temperatures and velocities differ from each other
the net emission coefficients with 4p is presented in Fig. 9. maximally about 6%. Since the difference between net
The simulations are conducted with net emission radiative fluxes for different length scales is more pro-
coefficients for two different path lengths (L = 1 mm and nounced in case of higher temperatures (see Fig. 8), the
L = 10 mm) in order to investigate the sensitivity of the differences between the simulation results which are cal-
simulation results to this. Since the nozzle outlet exhibits a culated using different length scales will be higher in case
diameter of 9 mm, it is likely that the plasma column(s) of process parameters for which the process temperatures
forming between cathodes and anode in plasma chamber are rather high. In other words, the results are more sen-
has a theoretical absorption radius between 1 mm and 10 sitive to the chosen length scale when the process tem-
mm. Although it cannot be ruled out that along the plasma peratures are high. In case of process parameters 180
chamber the thickness of the plasma column(s) does not SLPM volumetric flow rate and 350 A electric current
change, the radiative flux is approximated using a constant with in other respects persistent process parameters, the
characteristic length for the sake of simplicity. In Fig. 10, calculated difference due to the choice of length scales
the temperatures profiles, which are calculated using dif- remains under 3%. For a volumetric gas flow of 180 SLPM
ferent path lengths for net emission coefficients, are pre- and an electric current of 200 A, the difference amounts to
sented. Here it can be seen that, the profiles exhibit a even around 1%.

930—Volume 25(5) June 2016 Journal of Thermal Spray Technology


Since the results are rather insensitive to the choice of retical advantages of the SST turbulence model, this

Peer Reviewed
the length scale as the process temperatures are low, the model seems to be appropriate for the calculation of
definition of the length scale shall rather be based on the the plasma spraying systems.
characteristics of the processes with higher process tem-  The results are sensitive to the chosen length scale
peratures. As a thumb of rule, higher process tempera- when the process temperatures are high. In case of
tures imply a flow with thicker plasma columns (see lower process temperatures, the results are rather
Fig. 3). Therefore, the choice of a characteristic length insensitive to this.
scale of the flow which is appropriate for the geometry of
the plasma chamber, i.e., nozzle diameter, would depict The results obtained under consideration of the above-
the best practice. mentioned numerical aspects together with the verifica-
tion of these results by means of advanced computer
topographical experiments will be the subject of the fur-
6. Conclusion ther work. The above-mentioned conclusions and discus-
sions conducted in this paper shall serve as a guideline and
Although multi-arc systems promise several advantages aid for the further modeling activities, which will be con-
regarding the deposition efficiencies and coating qualities ducted to investigate the underlying fundamentals of
in comparison to the conventional single-arc systems, the multi-arc plasma spraying.
research in the field of modeling multi-arc plasma spraying
systems is still not as intensive as that for the conventional
single-arc spraying systems. In this paper, starting with the Acknowledgments
state of the art of plasma modeling, recent activities con-
ducted in this field have been introduced. General flow The authors gratefully acknowledge the financial sup-
characteristics in a multi-arc spraying system, which are port of the German Research Foundation (DFG) within
determined based on the numerical analysis, are discussed. the Project ‘‘Homogenization of Coating Properties in
Furthermore, the numerical aspects and approaches Atmospheric Plasma Spraying’’ (PAK 193/BO1979/7-2).
influencing the prediction power of the numerical models
have been analyzed and discussed. These are summarized
in the following:
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