Sri Chaitanya IIT Academy 29-12-19_Sr.

Icon All_GTM-6 _Key & Sol's

Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Icon All GTM-06 Date: 29-12-19

Time: 09.00am to 12.00 Max.Marks:300

Key & Solutions

MATHEMATICS
1 2 2 2 3 2 4 4 5 1
6 2 7 2 8 1 9 3 10 1
11 3 12 2 13 4 14 2 15 1
16 1 17 3 18 1 19 3 20 1
21 0003.00 22 0020.00 23 0025.00 24 0005.00 25 0030.00

PHYSICS
26 2 27 2 28 2 29 2 30 3
31 1 32 1 33 1 34 1 35 3
36 3 37 2 38 2 39 4 40 1
41 4 42 1 43 1 44 4 45 2
46 0005.77 47 0040.00 48 0000.58 49 0020.00 50 0003.54

CHEMISTRY
51 4 52 2 53 1 54 1 55 2
56 4 57 4 58 2 59 1 60 2
61 2 62 3 63 2 64 4 65 3
66 4 67 2 68 1 69 4 70 1
71 0002.00 72 0282.00 73 2480.30 74 0009.00 75 0006.56

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
SOLUTIONS
MATHEMATICS
1. a1 1, a2 2, a3 3,....., an n
a1 a2 .... an 1 2 ....n
Mean
n
1 2 3 .... n n n 1
X X
n 2n
2. The given equation is Z 2 Z 1 Z2 1 0
Z w, w2 , i, i Z 1
3
3. Slope of the give line =
2
The points on the curve at which the tangent is parallel to the given line. So,
differentiating both sides with respect to x of 3x 2 4 y 2 72 we get
dy 3x 3
given
dx 4y 2
x
2
y
2
x 72
Now 3 4 y2 9 y 3, 3
y y2
So, points are 6,3 and 6, 3
18 6 1 11
Now, distance of 6,3 from the given line =
13 13
18 6 1 13
And distance of 6, 3 from the given line =
13 13
Clearly , the required point is on 6,3 xo , yo (given)
So, xo 6, yo 3
Hence x0 yo 6 3 3
a dr
4. S
1 r 2
1 r
1
a 1, d 3, r
5
5. M a, sin a lies on sine curve

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
y
P
x 2y 2 0

0,1
Q

2,0
O

.
/2
R
,0
X

0,

6. P(number chosen is odd) = 3/5

P(number chosen is even)=2/5
a, b, c are all odd
ab c is even

c is even atleast a or b is even

E: ab c is even note that even E can occurs in two cases
3
3 27
E1 : all the three numbers a,b and ‘c’ are odd P E1
5 125
2 9 2 16 32
E2 : ’c’ is even and at least one of a or b is even P E2 1 .
5 25 5 25 125
P E P E1 or E2
P E1 P E2
59
125
n n n
Ck 1 1
7. lim lim .n Ck .
k
n k 0n k 3 n k 0
k 3 nk
n 1 1 n 1
n 1 k x
lim Ck . x 2 dx = x 2 . lim 1 dx = x 2 e x dx e 2
n k
n 0 n n
k 0 0 0
1 1
8. 4sin 2 x 2
tan 2 x 6
sin x tan 2 x
2 2
1 1
2sin x tan x 4 2 6
sin x tan x
For solution to lie exists
1 1
2 sin x 0 and tan x 0
sin x tan x

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
1
sin x , tan x 1
2
x ,
4 4
dx y 2 e2 x
9.
dy y3
dx 1 e2 x
dy y y3
2x dx 2x 1 1
e e
dy y y3
e 2x
u,
2
dx du
SO THAT e2 x
dy dy
du 2 1
u
dy y y3
2
dy
I .F . e y
e 2lny y2
1
SOLUTION IS u. y 2 dy k
y
uy 2 ln y k
2x
e
y2 ln y k
2
2x
e y2 2ln y 2k
2x 2
e y 2ln y constant
10.
y

y=1-x y=1+x
y=2

x = -1 x=1

11. 2x 4 x 2
2
2x 4 2 x
3
f x 2
4x x 0
3
4x 0 x 2

2x 4 x 2
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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
Y
2x+4

-2x-4

2x+4
-4x
4x

-2 0 X
-2/3 2

16
12. adj adj adj adjA A 48.516
A 10 x y z 10
9
No. of positive integral solution C2 36
13. R B C B
B A.B 38
A R B A C B 2
R C A.C 19
a1a2 b1b2 c1c2
14. Angle between the planes cos
a12 a22
P(1, 0, 0)

15. m
A(1, -1, 10)

m(1+2r, -1-3r, -10+8r)

Q(a, b, c)

Am.Pm = 0 r=1
M(3, -4, -2)
Q = (a, b, c) = 2m – p = (5, -8, -4)
a b c 5 8 4 7
1
7 7 7
16. clearly 0 e1 1 e2 both roots are positive a 0
2
f x x ax 2
f 1 0 1 a 2 0
3 a
a 3
a 3,
17. Equation of tangent at R r cos , r sin is x cos y sin r 1
r r
A , 0 , B 0,
cos sin

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
y
B P(h,k)
P r cos , r sin

o x
A

r r
Let P h, k then h ,k
cos sin
r r
cos , sin
h k
1 1
1 r2 2
h k2
2 2 2
Required locus x y r

18.

2
y x 1 1
Put y x
x x2 2 x 2
x 2 3x 2 0
x 1 x 2 0
x 1, 2
2
2
Re quired area 2 x x 1 1 dx
1

3 2
x2 x 1
2 x
2 3
1

1 1
2 2 2 1
3 2
5 1 1
2 1 2
6 6 3

19. Ci , C j 0 2 2 Ai , A j R CiC j 2 2 C j Ci 2 2 (symmetric)

If A1, A2 R, A2 , A3 R A1, A3 R

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
20.
P Q P Q Q P Q (P Q)
T T T F F T
T F F T T F
F T F F T F
F F T T F T
x1 x2 x3 2
21.
3 3
y1 y2 y3 7 2 7
3 Sum of coordinates = 3
3 3 3
22. Number of ways of two elements follow f xi xi is 5C2
Rest 3 unit does not satisfied f xi x j
= Number of de-arrangement of 3 things
1 1 1 1 1 3 1
3! 1 3! 6 2
1! 2! 3! 2 6 6
Required no of ways 10 2 20
23. AB AC 100m (correction)
C P
h
100 m D
900
0
90
A 100 m B
Let DP clock tower = hm
PAD cot 1 3.2 cot 3.2
1
PBD cos ec 2.6 cos ec 2.6
cot 2.4
In PAD and 9n PBD
AD h cot 3.2h BD h cot B 2.4 h
In ABD
AB 2 AD 2 BD 2
2 2
1002 3.2 2.h h2 16h 2
h 25m
2 0 2
24. f x dx x dx 2 xdx
2 2 0

1
2 1 1 4 0
2
1 4 5

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
y

-2
x
O 1 2

1 a4001 a1
25. 10
d a1 a4001
4000
= 10 a1a 4001 = 400
a1a 4001
a1 + a 4001 = 50
(a1 - a 4001 ) 2 = (a 1 + a 4001 ) 2 - 4a 1a 4001
|a1 - a 4001 | = 30

PHYSICS
e
26. [Step 1]: i
R
dB
[Step 2]: e A
dt
r 2 a2
[Step 3]: B0
6 2
( r 2 a 2 ) B0
[Step 4]: i
12 R
B

a
r D C
A R

b B
dh
27. [Step 1]: V gh gh
dt

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
h dh h
[Step 2]: t or t 2
0
gh g
[Concept]: Now at the time of meeting
[Step 3]: Time of fall of particle = time of wave pulse on reaching up to these
2( L h ) h
[Step 4]: 2
g g
L
[Step 5]: h
3
28. [Concept]: Electron moves from n-side to p-side
1
29. [Step 1]: 1000 C-lr- r-lr=00 C
2
[Step 2]: lr=40 0 C
[Step 3]: t F =00 +lr=400C
30. [Step 1]: When the wheel gets just lifted T=mg(3r/5).
[Step 2]: But when a torque of 2 is applied, we can write
[Step 3]: mg (3r / 5) Where 2mr 2
3g
[Step 4]:
10r
4
The horizontal acceleration is = r
5
4 3g 6g 60 2
[Step 5]: r 2.4ms
5 10 r 25 25
31. [Concept]: NB reaches maximum when activity of A and B will be same
[Step 1]: i.e. DA N A DB N B
DA N A
[Step 2]: NB
DB
32. [Concept]: Path difference at S2 is 2 . Therefore for minimum intensity at P.
3
[Step 1]: S1 P S 2 P ..........( i)
2
3
[Step 2]: 4 2 x 2 x
2
2 2 3
[Step 3]: 4 r x x
2
7
Solving equation, x
12
R2 4R
33. [Step 1]: Dipole moment 2.
2 3

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
3
4R
[Step 2]:
3
[Step 3]: f Ma
4 R3 MR 2
[Step 4]: E0 fR
3 2
a
[Step 5]:
R
8 E0 R 2
[Step 6]: For pure rolling a
9 M
34. [Step 1]: Energy absorbed per unit time by earth’s surface, if its radius is r, is
4 RS2TS4
[Step 2]: Qabs r2
4 R2
[Step 3]: Energy radiated per unit time by earth’s surface, Qrad (4 r 2 )T 4
[Concept]: Qabs Qrad
Ts4 Rs2
[Step 4]: T4
4 R2
Rs2
[Step 5]: T Ts
2R
35. [Concept]: With reservoirs at 273K,173K
W 273 173
[Step 1]: 0.37
Q 273
[Concept]: With reservoirs at 373K, 173K
W 373 173
[Step 2]: 0.54
Q 373
[Step 3]: W ' W (0.54 0.37)Q 0.17Q
mV0 V0
36. [Step 1]: r
B0 q B0
x 3
[Step 2]: sin 600
r 2
T
[Step 3]: t0 A
6 3B0
[Concept]: Therefore x – coordinate of particle at any time
t will be
3 B0
3 V0
[Step 4]: x V0 t cos 600
2 B0 3B0
3 V0
x t
2 B0 3B0

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's

mV 2
37 [Concept]: T , and T mg
R
mv02
mg (v v0 , r r0 )
r0
2
m 3v0
[Step 1]: mg
r1
1
r 9r0
v02
[Step 2]: a0
r0
2
1 3v0
a
9r0
[Step 3]: a1 a0
3volt
38: [Step 1]: e t/r
(3 5)volt
[Step 2]: t RC 6S
t 6s
39. [Step 1]: A 2 Rh 2( )(6.4 106 )(150)m 2
[Step 2]: 1.96 103 km 2
1 A Dm
40. [Step 1]: d cos . dDm
A 2
sin
2
41. [Step 1]: I
2 2
[Step 2]: Fb mb
3
2mb 2
[Step 3]: kbx
3
3kx
[Step 4]:
2mb
3k
[Step 5]:
2mb
2mb
[Step 6]: T 2
3k

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
m1v1 m2 v2
42. [Concept]: mn
v2 v1
14 (4.7 106 ) 1 (3.3 107 )
[Step 1]: 1.16
3.3 107 4.7 106
43. [Concept]: Q1 M x M y C 2
[Step 1]: Q2 M x M y 2me C 2
44. [Concept]: Since all voltmeters are identical
I1 3 3
[Step 1]: let I 2 x I1 x
I2 2 2
3
[Step 2]: 9 x 14 x 5 7.5 0
2
[Step 3]: x 5.0 A I 2
[Step 4]: 7.5A I1
27 x 28 x
[Step 5]: 2.5
2
Hence resistance of voltmeter is 1
[Step 6]: 25 I3 7.5 7.5 9 75
[Step 7]: I 3 3 A
Hence V3 3.0V
45. [Concept]: The detector receives maximum light when image of ‘S’ falls on ‘D’.
46. [Step 1]: VR Vx i Vy i

[Step 2]: For path AB Vx 5ms 1

[Step 3]: For path BC velocity of rain r to BC should be zero hence
5
[Step 4]: VX sin 300 Vy cos 300 Vy ms 1

3
10
[Step 5]: VR VX2 VY2 ms 1

3
dA
47. [Concept]: L / 2 m, L mvr
dt
2I
48. [Concept]: T 2 I / MBH T1 2
( pm 2 pm ) BH

2I
[Step 1]: T2 2
(2 pm pm ) BH
T1 1
[Step 2]:
T2 3
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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
I
49. [Step 1]: SL2 SL1 10 log max
I min
2
2
a1
1
I1 I2 a2
[Step 2]: 10 log 2
10 log 2
20dB
I1 I2 a1
1
a2
50. [Concept]: Current across inductor and capacitor are out of phase and same magnitude
hence only resistance will be operated 2.5 2A
CHEMISTRY
51. Due to resonance stabilization of anion

C-H
CHO
1) O3
2) DMS
52. [Step1]:
O OH

C-H
CHO aq. KOH CHO
Intra molecular
Aldol condensation
[Step-2]:
OH

CHO CHO
H 2O
[Step-3]:

53. Br and OMe attack conjugate addition

44.4
54. [Step1]: C 3.7 1
12
51.9
N 3.7 1
14
3.7
H 3.7 1
1
Formula :HCN
r1 M2 V1 t2
[Step-2]:
r2 M1 t1 V2
M2 6.8
M1 25
M1 27 HCN
55. Follows free radical mechanism & bromination is selective
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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
56.
Explanation :
3)O 2 Bond Order 2 1 and1
2) N 2 Bond Order 3 1 and 2

1)O 2 Bond Order 2.5 1 and1.5

1
4) N 2 Bond Order 2.5 and 2
2

57. 5- membered heterocyclic ring is more reactive due to excess e density

58. stable compounds has low enthalpy of hydrogenation, 1,3- butadiene requires
two moles of hydrogen
59. To prevent the hydrolysis acidic condition required
60. BCl3 H 2O B OH 3
3HCl
61. Due to reversible nature
62. Intra molecular esterifation
63. Both Ag2+ and Pb2+ gives AgCl and PbCl2 with dil HCl
both Ag2+ and Pb2+ gives AgCl2- and PbCl42- with conc. HCl
In NH4OH , Ag+ forms soluble complex [Ag(NH3)2]+
In NaOH,Pb2+ forms soluble complex Na2Pb(OH)4
w
64. 10 vol 3.03 % 0.893M 1.786 N
v
? 1.5N
8.4vol.
65. Al2O3 Electrolytic reduction
FeO Carbon reduction
CuO Self reduction
B2O3 Na- Mg reduction
66. ZnS is white precipitate.
67. HCl S . A P H closeto 1
NH 4Cl Salt of S .A WB.Close to 7 but 7
NaCl salt PH 7
NaCN salt of WA SB P H 7
V
68. [Formula]: Frequency
2 r
2.18 106 Z
n
n2
2 0.529
Z

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
6
2.18 10
2 n 3 0.529
2.18 10 6 1
3
2 3.14 2 0.529
14
8.3 10
(or)
Z2
[Formula]: Orbital frequency 6.66 1015
n3
1
6.66 1015
8
8.3 1014
69. Fe2O3 is solid has no effect
70. KClO3 I2 KIO3 Cl2
71. Reaction taken place
1
[Equation] : H H2
2
1

0 0.059 pH 2 2
[Fomula]: E E log
1 (H )
0.059 1
E 0 l0g
1 (H )
E 0.059 P H
0.118 0.059 P H
PH 2
72. [Henry’s laws Formula]: p kH x
0.195
x
1000
0.195
18
0.987
KH 282
0.195
0.195 55.55
73. G H T S 0
H T S
491.1 1000
T
198
74. H 4 P2O7

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Sri Chaitanya IIT Academy 29-12-19_Sr.Icon All_GTM-6 _Key & Sol's
0 H1 0 H2 0 H3 0
75 5C 0 C 0 C 5C
H 2 O ,l H 2O ,l H 2O , S H 2O , S

H nC p T
H2 enthalpy of fusion
H H1 H2 H3

H nC p dT Hf nC dT
p

H (1 75.3 5) 6000 1 36.8 5 J

6.560 KJ / mol / K

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