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The
CONSTRUCTION chemical formula is Al2O3. (from bauxite,
recycled aluminum, clay)
What is cement?
Alumina imparts quick setting property
Is a binding agent that sets and hardens to the cement.
to adhere to building units such as Clinkering temperature is lowered by the
stones, bricks, tiles, etc. presence of the requisite quantity of
Cement mixed with water causes a alumina.
chemical reaction and forms a paste that Excess alumina weakens the cement.
sets and hardens to bind individual
structures of building materials. 4. Magnesia: Magnesium Oxide. Chemical
The water causes the hardening formula is MgO.
of concrete through a process
called hydration. Hydration is a Magnesia should not be present more
chemical reaction in which the major than 2% in cement.
compounds in cement form chemical Excess magnesia will reduce the
bonds with water molecules and become strength of the cement.
hydrates or hydration products.
5. Iron oxide: Chemical formula is Fe2O3. (from
Composition of Cement clay, iron ore, scrap iron and fly ash)
There are eight major ingredients of cement. Iron oxide imparts color to cement.
It acts as a flux.
The general percentage of these ingredients in At a very high temperature, it imparts
cement is given below: into the chemical reaction with calcium
and aluminum to form tricalcium
Ingredient Percentage in alumino-ferrite.
cement
Lime 60-65 6. Calcium Sulfate: Chemical formula is
Silica 17-25 CaSO4. (found together with limestone)
Alumina 3-8
Magnesia 1-3 This is present in cement in the form of
Iron oxide 0.5-6 gypsum(CaSO4.2H2O)
Calcium Sulfate 0.1-0.5 It slows down or retards the setting
Sulfur Trioxide 1-3 action of cement.
Alkaline 0-1
7. Sulfur Trioxide: Chemical formula is SO3
Presence of lime in a sufficient quantity Should not be present more than 1%.
is required to form silicates and Excess Alkaline matter causes
aluminates of calcium. efflorescence
Deficiency in lime reduces the strength Efflorescence is a crystalline deposit of
property to the cement. salts that can form when water is
Excessive presence of lime cause present in or on brick, concrete, stone,
cement to expand and disintegrate. stucco or other building surfaces. It has
a white or greyish tint and consists of
2. Silica: Silicon dioxide is known as silica,
salt deposits left behind when water
chemical formula SiO2. (from sand, clay or
evaporates.
argillaceous rock)
– Spatula
16. Low Alkali Cement
PROCEDURE:
Such types of cement are specially made
1. Weigh about 300 gm. of cement
Portland cement in which alkali content
accurately and make a paste with 0.85
is kept below in minimum amount, by
times the water required to make a
exercising very strict control over the
paste of normal consistency.
composition of the raw material used.
2. Place the paste in the rubber mold. Place
They are used in those circumstances
the paste into the apparatus then
where aggregates -for making concrete-
remove the excess paste
are suspected to contain reactive silica.
3. Bring the small end of the rod of the
When alkali- silica reactive constituents are
Vicat apparatus on the surface of the
suspected to be present in the aggregate and paste and the quickly release the needle
cement to allow it to penetrate the paste
Type III has relatively high early strength. Use Admixtures are natural or manufactured
for rapid construction. This gives the concrete chemicals which are added to the concrete
using this type of cement a three-day before or during mixing.
compressive strength equal to the seven-day
WHY USE ADMIXTURES?
compressive strength of types I and II. Its
seven-day compressive strength is almost equal • Admixtures are used to give special
to 28-day compressive strengths of types I and properties to fresh or hardened concrete.
II. The only downside is that the six-month
• Admixtures are used to overcome
strength of type III is the same or slightly less
difficult construction situations.
than that of types I and II. Therefore, the long-
term strength is sacrificed. 2 Classification of Admixtures