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Geochemistry
All data in this presentation are the intellectual property of IMEx Consulting (except where
obtained from the public domain) and must not be reproduced, copied, shared or forwarded
in any form without the express permission of IMEx Consulting.
Sometimes interpretation is erratic….
IMEx Consulting 2
Sampling – Fit for purpose?
IMEx Consulting 3
Dispersion
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Processes of Soil Formation
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Landscape Lowering
Weathering and transportation in dynamic • Nature of weathering & soil development depends
on climate to the extent that it affects the rates of
equilibrium processes, not which processes operate
• Rates of chemical solution: fastest in hot-wet &
slowest in cold dry climates
• Ratio between rates of chemical removal from
different rock types influences local relief e.g.
limestones are relatively weak in cold humid areas
and resistant in arid areas
• Where soil forming weathering processes are in
equilibrium with mechanical removal the most
developed soils will occur in moist temperate
climates. The ratio of chemical to mechanical
removal is greater than in the humid tropics
• Soils locally tend to equilibrium forms that are
most strongly developed on shallower slopes
distal to the divides. There the ratio of chemical to
mechanical mechanisms is greatest
IMEx Consulting 6
Deep Weathering
IMEx Consulting 7
Regolith Profile - WA
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Regolith Profile - WA
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Calcrete Sampling
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Impact of weathering on element mobility
Rainwater mildly acid (CO2, pH6-7) but decreased by rotting vegetation, oxidation of sulphides, Fe2+
Hydrolysis - Ca Mg K Na dissolve first as ions in solution then progressively removed. Caliche, clays (Na
conserved)
Al stabilises in clays, Fe in oxides unless extremely acid
Kaolinite 2-Layers often in Si K rich terrains (“Granite”)
Kaolinite in well drained terrains Low Metal Absorption Capacity
Smectite & mixed layer clays, immature basic volcanic terrains (“Intermediate to Mafic”)
Smectites in poorly drained or arid terrains High Metal Absorption Capacity
Release of trace elements from sites of primary crystal substitution
Reaction with ions to precipitate secondary minerals, colloids or substitute into secondary lattices
Adsorption onto secondary sesqui-oxides, clays
Weathered products often fine grained low density and therefore physically mobile
BUT Fe oxides may indurate (dehydrate) and behave as a relatively heavy mineral
IMEx Consulting 11
Anion & Cation Absorption onto Goethite
Compilation of adsorption data for anions (SO 42-, Cl-, AsO43-, PO43-, SeO32-, SiO44- and MoO42-) and cations on to goethite as a function
of pH (Thornber 1985).
IMEx Consulting 12
Metal Absorption in Soils
IMEx Consulting 13
Causes of Variability in Soil Surveys
• Primary Geological Variation & dispersion
• Secondary Mobility & Profile Development pH Eh etc
• Horizon Sampled depends on Objectives, may be more than
one horizon
– Topsoil Contamination
• Mechanical movt.
• Solution movt.
– Deeper soil non-contaminated, minimal movt.
Organosol Podsol
• Sampling Design and Protocols
• Sample Treatment & Preparation
– Total Soil
– Sieving Fine Fraction (<0.15)
– Drying (Air-dry <40oC eg loss of Hg!)
• Residual moisture promotes anaerobic reactions,
including sulphate reduction… altering partial results
• Analyses
Calcarosol Kandosol IMEx Consulting 14
Chemical Mobility of Trace Elements in the
Surficial Environment
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Chemical Mobility of Trace Elements in the
Surficial Environment
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Crustal Abundances
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Lag Sampling
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#1 - Local Correlations
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Landsat TM & Lag samples
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Prospect Lag - “Subset”
Cdppm No Data(log)Agppm(log)
Asppm(log)
3
4 0 6 0 80
Auppb(log)
Bippm(log)
0 .3
10
Link by East
0 .2
1
20
3
0 .1
0 .3
1
Fe -> As, Bi, Pb, Sb, W
0 .1
0 .3
10 20 30 10 20 30 10 20 30 10 20 30
3 004 00
Co -> part Fe
Mnppm(log)
W ppm(log)Nippm No Data(log)Coppm(log)
Cuppm(log)
1.5
6
1
200
4
40
0 .5
1 00
20
10 20 30 10 20 30 10 20 30 10 20 30
Pbppm(log)
Sbppm(log)
20
200
1.5
2
100
10
0 .5
10
Feper(log)
20 30 10
Feper(log)
20 30 10
Feper(log)
20 30 10
Feper(log)
20 30
has strong Fe and Mn
correlations spatially separate
1 00 1 50
Znppm(log)
1.5
3
1
50
0 .5
10 20 30 10 20 30 10 20 30
Mn rich layer
Fe rich layer
IMEx Consulting 23
Snppm No Data(log)Moppm(log)
Cdppm No Data(log)Agppm(log)
0 .5 1 1.5 1 2 3 0 .5 1 1.5 0 .1 0 .2 0 .3
10
10
10
10
20
20
20
20
Feper(log)
Feper(log)
Feper(log)
Feper(log)
30
30
30
30
W ppm(log)Nippm No Data(log)Coppm(log) Asppm(log)
1 2 3 0 .5 1 1.5 2 4 6 20 4 0 6 0 80
10
10
10
10
20
20
20
20
Feper(log)
Feper(log)
Feper(log)
Feper(log)
30
30
30
30
Znppm(log) Pbppm(log) Cuppm(log) Auppb(log)
50 1 00 1 50 100 200 20 40 60 801 00 0 .1 0 .3 1 3
10
10
10
10
20
20
20
20
Feper(log)
Feper(log)
Feper(log)
Feper(log)
30
30
30
30
10
10
10
20
20
20
Feper(log)
Feper(log)
Feper(log)
30
30
30
IMEx Consulting
Fe
Prospect Lag - “Subset”
Mn
24
Lessons #1
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Cobar, western NSW
IMEx Consulting 26
#2 Regional Surface Sampling
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Regional Lag Sampling
10km
Dataset 4.2 Lag
4.2a
• What elements are
correlated with Fe?
• Are the correlations
the same in each
area? 4.2b
• If different, why?
4.2c
IMEx Consulting 28
Znppm(log)Nippm No Data(log)
Coppm No Data(log)Asppm(log) W ppm(log) Moppm(log)
Cdppm No Data(log)
Agppm(log)
1 2 1 .5 2 2 .5 0 .5 1 1 .5 0 .2 0 .4
50 1 00 0 .5 1 1 .5 0 .5 1 1 .5 20 30 40 50
1
1
1
1
20
20
20
20
3
3
3
3
30
30
30
30
10
10
10
10
40
40
40
40
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
30
30
30
30
1
1
1
1
20
20
20
3
3
3
3
30
30
30
10
10
10
10
40
40
40
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
30
30
30
30
20
20
20
3
3
3
30
30
30
10
10
10
40
40
40
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
30
30
30
20
20
20
Lag Correlations
4.2c
3
3
3
30
30
30
10
10
10
40
40
40
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
30
30
30
4.2a
IMEx Consulting
Snppm No Data(log)
Moppm(log)
Cdppm No Data(log)
Agppm(log)
0 .5 1 1.5 2 3 4 0.5 1 1.5 0 .2 5 0 .3 0 .3 5
5
5
5
5
10
10
10
10
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Fe with …
10
10
10
10
Feper(log)
Feper(log)
Feper(log)
Feper(log)
10
10
10
10
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
Feper(log)
4.2b
29
RAB drilling
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Regional RAB Drilling
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Background RAB correlations
Agppm(log)
Asppm(log)
20 30
Bippm(log)
Auppb(log)
0.8
2
Agppm(log)
Asppm(log)
Mnppm No Data(log)Auppb(log)
Bippm(log)
40
0.4 0. 6 0.8
0.4
0.6
1.5
Fe with …
10
1
10
20
1
0 .4
3
0.2
0. 2
1
1. As, Co, Zn
0. 5
0. 3
0.1
5 10 5 10 5 10 5 10
Mnppm(log)
Coppm(log)
Cuppm(log)
Pbppm(log)
400
20
100
100
100
Coppm(log)
Cuppm(log)
Pbppm(log)
1.5
100
200
10
30
50
1
30
3. As, Bi, Pb, Sb
50
10
50
0. 5
10
3
4. As, Cu, Mn
3
5 10 5 10 5 10 5 10 2 4 6 8 2 4 6 8 2 4 6 8 2 4 6 8
Znppm(log)
Wppm(log)
Znppm(log)
Wppm(log)
15
100 150
6 8
10
6
10
4
5
4
50
2
Correlation with Mn
50
2
2 4 6 8 2 4 6 8 2 4 6 8
are not as
5 10 5 10 5 10
widespread as Lag.
Agppm(log)
Asppm(log)
Auppb(log)
Bippm(log)
Agppm(log)
Asppm(log)
Auppb(log)
1. 5
Bippm(log)
100
2
30
0. 4
10
0.4
10
1
Why?
30
3
10
0.2
0. 5
1
0.2
1
10
3
0.3
3
0.1
0. 1
1
10 20 10 20 10 20 10 20 2 4 6 8 2 4 6 8 2 4 6 8 2 4 6 8
10000
Mnppm(log)
Coppm(log)
Cuppm(log)
Mnppm(log)
Pbppm(log)
Coppm(log)
Cuppm(log)
Pbppm(log)
300
100 150
1000
100
60
100
6
200
40
300
30
1000
50
50
4
100
100
10
20
100
30
3
2
10
1
2 4 6 8 2 4 6 8 2 4 6 8 2 4 6 8
10 20 10 20 10 20 10 20
Znppm(log)
Sbppm(log)
Wppm(log)
Znppm(log)
Wppm(log)
15
40
10
200
6
8
10
4
6
30
100
5
4
5
20
32
10
10 20 10 20 10 20
IMEx Consulting 2
Feper(log)
4 6 8 2
Feper(log)
4 6 8 2 4
Feper(log)
6 8
IMEx Consulting 33
#3 - Hiltaba Suite Geochem
IMEx Consulting 34
Hiltaba Suite Granites
Olympic Dam
Kokatha Suite
Roxby Downs
200km
Adelaide
IMEx Consulting 35
What’s distinctive about OD?
150
10
4000
Cs (ppm)
Asi Alumi
400
400
Al2o3
100
Cao
20
Ba
Ce
Cr
5
2000
200
200
50
2
10
60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80
Fe2o3 Tota
Fe2o3 Calc
Fe2o3 Feo
30
Eu (ppm)
40
15
15
4
OD Suite - RED
2000
4
Feo
Ga
Cu
10
10
20
20
1000
K, U, Th, Rb, Nb
2
2
5
10
60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80
0.6
30
3
Hf (ppm)
Lu (ppm)
200
8
Na2o
0.4
4
Mgo
Mno
4
K2o
20
2
La
6
100
4
0.2
2
10
2
1
2
60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80
Sm (ppm)
800
1
100
80
100
20
P2o5
100
600
60
Pb
Nb
Nd
Rb
Ni
400
0.5
50
40
50
10
50
200
20
60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80
1.5
300
Tb (ppm)3
150
100
40
Tio2
200
1
Th
Sr
Y
2
V
100
1000
20
50
0.5
100
50
1
60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80 60 70 80
800
Yb (ppm)
1000
600
Zn
Zr
10
400
500
200
60 70 80 60 70 80 60 70 80
IMEx Consulting 36
Sio2 Sio2 Sio2
What’s distinctive about OD?
200
10
150
8
40
K2o
Th
6
100
20
4
50
2
60 70 80 60 70 80 60 70 80
80
High U
600
High U/Th
60
Rb
Nb
High Th
400
40
High K
200
High K/U/Th
20
High K/U
60 70 80 60 70
IMEx Consulting
80 High K/Th 37
Sio2 Sio2 OD Intrusions
Where are the right rocks?
Christie OLYMIC DAM
Wilgena
INTRUSIONS
Fowler
Nuyts
Prospective
Less prospective
GRV
Cleve
200km Coulta
Moonta
IMEx Consulting Lincoln 38
What’s distinctive about OD?
Bradman
Birthday
Lake Barry OLYMIC DAM
INTRUSIONS
Labyrinth
Cooladding
Childara
Coppadurba
Kondoolka
?Parla Burkitt
Cultana
Tyringa Gilles
Wudinna
Charleston
200km
Arthurton
Tickera
IMEx Consulting
Spilsby
39
Lessons #3
IMEx Consulting 40
#4 Granite Geochemistry
IMEx Consulting 41
Nymagee 250K
COBAR
NYMAGEE
50km
IMEx Consulting 42
Rock chemistry 16
4
4
4
3
Fe203
15
6
Al203
4
Na20
Mg0
Ca0
Fe0
K20
2
U, Cs, Li, Sn, F, Cs
14
•
3
2
2
4
1
13
2
65 70 75 65 70 75 65 70 75 65 70 75 65 70 75 65 70 75 65 70 75
1.5
• Na2O, Sn, W, Rb, Nb, P2O5
1.5
1
0.6
30
0.1
20
P205
C02
H20
H20
Mn0
Ti02
As
1
1
0.4
20
0.5
0.05
10
0.2
10
Zn
0.5
0.5
65 70
Si02
75 65 70
Si02
75 65 70
Si02
75 65 70
Si02
75 65 70
Si02
75 65 70
Si02
75 65 70
Si02
75
•
60
150
1000
300
20
40
Ni,Sc,Y,V,Nd,Co,Zr,Ga,MgO
4000
•
Ba
Cs40
Ce
Co
Cu
Cr
100
200
F
500
10
20
2000
20
100
50
60
80
8
200
100
20
60
6
400
Ga
40
Nb
Nd
Mn
La
Hf
Li
• Pb
100
40
4
50
10
20
200
20
2
65 70 75 65 70 75 65 70 75 65 70 75 65 70 75 65 70 75 65 70 75
• F, Li
60
1000
80
20
600
300
40
60
40
Pb
Sn
Sc
Rb
Sr
Ni
400
40
500
200
10
20
20
200
• As
20
100
65 70 75 65 70 75 65 70 75 65 70 75 65 70 75 65 70 75 65 70 75
40
300
400
150
20
Th
Zn
Zr
W
200
U
100
20
50
20
200
10
100
50
65 70 75 65 70 75 65 70 75 65 70 75 65 70 75 65 70 75
IMEx Consulting
65 70 75 43
Si02 Si02 Si02 Si02 Si02 Si02 Si02
Rock type
Monzodiorite
High Ni with MZDR
Tonalite
Sn, W with Pegmatite
Cu with “mafic” GR
Lithology
Quartz Diorite
Sn, W, F – high SiO2 GR
Pegmatite
Elevated Zn with Porphyry
Granodiorite
Granite
Porphyry
65 70 75
IMEx Consulting 44
Si02
Gilgunnia Area
MZDR - Ni
May Day
High Li, U
High Li, F
5km
IMEx Consulting 45
Nymagee Area
High Cu, U
Hera
High Pb
IMEx Consulting 46
Lessons #4
IMEx Consulting 47
Useful Trace Elements
IMEx Consulting 48
#5 - Soils Interpretation
IMEx Consulting 49
Copper in Soils
Birrundudu Cu
1km
16 - 35
35 - 65
65 - 103
103 - 141
141 - 280
IMEx Consulting 50
Nickel in Soils
1km
Birrundudu Ni
16 - 50
50 - 92
92 - 131
131 - 173
173 - 270
IMEx Consulting 51
Copper & Nickel v Iron
200
200
Cu Ppm(log)
Ni Ppm(log)
100
100
200
200
Cu Ppm(log)
Ni Ppm(log)
100
100
Cu Ppm(log) Bi Ppm(log)
30
0 .4
3
3
1
Elevated Zinc
10
1
0 .2
0 .3
0 .3
3
0 .1
0 .1
Two Zn - Mn, Cd, Ag
0 .0 3
1
500 00 100 00 0 150 00 0 500 00 100 00 0 150 00 0 500 00 100 00 0 150 00 0 500 00 100 00 0 150 00 0
1 00 00
60
2 00
4 00
40
3 00 0
1 00
20
2 00
1 00 0
3 00
500 00 100 00 0 150 00 0 500 00 100 00 0 150 00 0 500 00 100 00 0 150 00 0 500 00 100 00 0 150 00 0
P Ppm(log)
1 00 0
60 80
6
2 00
4
40
5 00
2
1 00
20
500 00 100 00 0 150 00 0 500 00 100 00 0 150 00 0 500 00 100 00 0 150 00 0 500 00 100 00 0 150 00 0
4 00 6 00
4 00
2 00
2 00
Cu anomaly
Zn anomaly
IMEx Consulting 55
Geology with soils interp
Granite
Cu anomaly
Zn anomaly
Limestone
Slate IMEx Consulting 56
Lessons #5
IMEx Consulting 57
#6 - Yilgarn Au
IMEx Consulting 58
Landsat TM & soils
Yilgarn Soils Au ppb
0.2 - 5
5 - 10
10 - 50
50 - 100
100 - 740
1km
IMEx Consulting 59
Gold is correlated with….?
100
100
Au1 Ppb(log)
Au1 Ppb(log)
30
30
10
10
3
3
1
1
20 40 60 80 200 400
Cu Ppm(log) Ni Ppm(log)
100
100
Au1 Ppb(log)
Au1 Ppb(log)
30
30
10
10
3
3
1
5 10 15Consulting
IMEx 50 100 150 60
Pb Ppm(log) Zn Ppm(log)
Zinc is correlated with
100
80
Au1 Ppb(log)
60
Cu Ppm(log)
30
40
10
3
20
1
15
400
Pb Ppm(log)
10
Ni Ppm(log)
200
50 100 IMEx
150Consulting 50 100 150 61
Zn Ppm(log) Zn Ppm(log)
Geology & Soils
Geology gole project structure.shp
Geological contact
D2 fault and shear
D1 thrust fault
“Ultramafic”
Bedding trend
Younging direction
No Data
Geology gole project.shp
“Intermediate”
Quartz vein
Spinifex-textured komatiite
Olivine orthocumulate
Olivine mesocumulate and adcumulate
Basalt, basaltic komatiite, dolerite, minor gabbro and sedimentary rocks
Chert
Intermediate to minor felsic volcanoclastic and volcanic rocks
Basalt, minor gabbro
Gabbro
Basaltic komatiite
Jones Creek Conglomerate
Granitoid
No Data
IMEx Consulting 62
Geology & Geochem
100
80
Au1 Ppb(log)
60
Cu Ppm(log)
30
40
10
3
20
1
15
400
10
Pb Ppm(log)
Ni Ppm(log)
200
100
80
Au1 Ppb(log)
Cu Ppm(log)
60
30
40
10
3
20
1
15
400
Pb Ppm(log)
10
Ni Ppm(log)
200
5
Zinc
Cu
Quartz vein
Spinifex-textured komatiite
Zn
Olivine orthocumulate
Olivine mesocumulate and adcumulate
Basalt, basaltic komatiite, dolerite, minor gabbro and sedimentary rocks
Chert
Intermediate to minor felsic volcanoclastic and volcanic rocks
Basalt, minor gabbro
Gabbro
Basaltic komatiite
Jones Creek Conglomerate
Granitoid
No Data
500m
IMEx Consulting 65
Lessons #6
Au prospect
Cu associated with interpreted fold closures
Cu associated with unmapped structure – remobilised?
“non mag geochem structure”
Cyprus style VHMS Cu prospect ?
?Recessive ultramafics present in intermediate sequence!
IMEx Consulting 66
#7 – Fraser Range
GSWA sampling
Morris et al, “Geochemical mapping of the Fraser Range
region”, April 2000
1 per 16km2
Sheetwash, lake sediments, sandplain & streams
Dataset 4.7 Fraser
Load data, select all elements, Data Doctor
Plot Fe v Cu, Ni first – Glink by east then interpret.
IMEx Consulting 67
Fraser Range
UM?
Ni & Cu
IMEx Consulting 68
Fraser Range
Nova
IMEx Consulting 69
#7 – Fraser Range
IMEx Consulting 70