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UNIVERSITY OF ALLAHABAD
ALLAHABAD
FIRST PAPER
INORGANIC CHEMISTRY
(M.M. 34)
1. ATOMIC AND NUCLEAR STRUCTURE (12)
(a) Bohr’s and Sommefields’ Atomic Models, de Broglie equation, Heisenberg uncertainty
principle. Schrodinger wave egucation, Radial and angular wave function, Physical
significance and characteristics of a wave function, shapes of s, p, d and f-orbitals. Aufbau
principle and electronic configuration of atoms. Periodic classification of elements (IUPAC
recommendation), Long from the periodic table including translawrencium elements.
(b) Structure of nucleus, fundamental particles, forces in the nucleus, nuclear stability-N/P ratio
and binding energy, Packing fanction.
Relative and absolute configuration, sequence rules, D & L and R & S system of nomenclature.
‘Geometrical Isomers’- Elementry idea of geometrical isomerism determination of configuation of
geometrical isomers. E & Z system of nomenclature, geometical isomerism in oximes and alicyclic
compounds.
Cycloalkanes: Methods of formation, chemical reactions, Baeyer’s strain theory and its limitations, Ring
strain in small rings (Cyclopropane), theory of strainless rings. The case of cyclopropane ring: banana
bonds.
Methods of formation and chemical reactions of alkyl benzenes, alkynylbenzenes and biphenyl.
Aryl halides: The addition elimination and the elimination addition mechanisms of nucleophilic
aromatic substitution reactions. Relative reactivities of alkyl halides vs allyl, vinyl and aryl halides.
THIRD PAPER
PHYSICAL CHEMISTRY
(M.M. 33)
1. GASES:
Kinetic theory of gases and gas laws, specific heat ratio Cp/Cv. Non-ideality of gas behaviour,
Van der Waals equation of state, critical constants and their determination. Reference to some other
equations of state e.g. Berthelot and Dieterici. Law of corresponding states. Maxwell Law of Distrubtions
(Quantitative treatment).
3. THERMOCHEMISTRY:
Heat of reaction, formation, combusion and neutralisation, solvation, dilution and hydration,
hess’s law and its application, Bond energy and resonance energy.
4. CHEMICAL KINETICS:
Reaction rate, order and molecularity of reaction, zero, first, second and third order reactions.
Methods for determining the order of a reaction. Complex reactions opposing reactions, consecutive
reactions and side reactions with reference to first order reactions. Effect of temperature on reaction
velocity. Energy of activation and collisions theory of bi-molecular gaseous reactions.
5. ELECTROCHEMISTRY:
Electrolytic conductance: equivalence conductance, moecular conductance, variation of
conductance with concentration, Kohlrausch’s law of independent migration of ions, conductance ratio,
effect of other factors on conductance. Qualitative treatment of the interionic attraction theory. Ionic
mobilities, transport number, determination of transport number (Hittorf and moving boundary method),
some application of conductance measurements. Hydrolysis of salts. Bronsted and Lewis acids and
bases. pH and pKa, acid-base concept in non-aqueous media, Buffer solutions. Theory of acid-base
indicators.
6. CHEMICAL EQUILIBRIUM :
Law of mass action and its application to homogeneous and heterogeneous equilibria, Le-
Chatelier principle and its application to chemical equilibriam. Degree of dissociation and abnormal
molecular weights.
Syllabus for B.Sc. I
CHEMISTRY PRACTICAL
Time : 6 Hours (1day) (M.M. 50)
1. Analysis of inorganic mixture including insolubles and interfering redicals (four Radials only).
2. Volumetric Analysis :
(i) Use of K2Cr2O7 (Determination of Iron), and
(ii) Iodometry and iodimetry (Determination of Copper, dichromate, Permanganate
and arsenious oxide.)
3. Detection of elements and functional groups in organic compounds – only two compounds (one
element and one group).
CHEMICAL BOINDING: Valence bond theory, Heitler-London and Pauling-Slater theory and resonance,
molecular orbital, LCAO method, bonding, non-bonding and anti-bonding molecular orbital’s, molecular
orbital energy level diagrams for homo and hetero nuclear diatomic molecules, electronic structure, bond
order, bond length and bond strength.
SHAPES OF INORGANIC MOLECULES: Hybridization of valance shell atomic orbitals and directional
nature of the covalent bond, Sidgwick-Pawell theory, valence shell electron pair repulsion theory, shapes
of inorganic molecules and anions.
NON-IDEAL GAS BEHAVIOR: Van-der Waal’s equation of state, critical constants and their
determination, Maxwell’s law of distribution of velocities.
THERMOCHEMISTRY: Hess’s law of constant heat summation, Heat of reaction, formation, combustion,
solvation, dilution and hydration, Kirchoff’s equation.
CHEMICAL KINETICS: Reaction rate, order and molecularity of a reaction, study of first order reactions
comprising opposing reactions, consecutive reactions and side reactions, Law of mass action and its
application to homologous and heterogeneous equilibrium, Le Chateliar’s principle, its application to
chemical equilibrium.
Preparation and uses of aspirin, salol, saccharine and chloramine-T. DDT and
Grammexane.
FIRST PAPER
INORGANIC CHEMISTRY
1. SHAPES OF MOLECULES (12)
Hybridization of orbitals and directional nature of covalent bond. Sidgwick – Powell theory.
Valence Shell Electron Pair Repulsion (VSEPR) theory, shapes of inorganic molecules and
anions such as BeCl2, BF3, InCl2-5, SiF4, NH3, H2O, OF2, Cl2O, ClO2, PCl3, PCl5, SF4, CIF3, ICI3,
PPh3, BrF5, IF7, XeF4, XeF6, CO2-3, NO-3, PO3-4, CIO-4, SbF-4, SbF2-5, TeF-5, XeF+5, l-3 and l+3
related species.
2. p-BLOCK ELEMENTS (10)
Characteristic : Chemical reactivity of elements and group trends. Synthesis, properties and
structure of their hydrides and halides. Application of redox potential diagrams with reference
to N, P, S, Cl, Br and I.
3. p-BLOCK ELEMENTS (10)
Compounds : Allotropy of boron, carbon, phosphorus and sulphur. Peroxocompounds of B, C
and S oxyacids of N, P, S and halogens interhalogens, pseudohalogens and polyhalides.
4. d-BLOCK ELEMENTS (10)
Transition elements: General characteristics, variable oxidation states, complex formation,
colour, magnetic properties and catalytic properties. Comparative account of 3d, 4d and 5d,
transition metals with respect to their atomic and ionic sizes, stability of oxidation states and
magnetic properties.
5. COORDINATION CHEMISTRY (8)
Isomerism in coordination compounds (definitions and some typical examples).
Stereochemistry of metal complexes involving coordination number 3 to 7.
6. EXTRACTION OF ELEMENTS (6)
Chemical principles involved in the extraction and isolation of the following elements B, F, Si,
Ge, Cr, Ni.
7. INORGANIC COMPOUNDS – PREPARATION, PROPERTIES AND USES OF (12)
Boric acid, Borides, Diborane, Fibrous Alumina and Zirconia, Silanes, Ultrapure Si and Ge.
Hydrazine, Hydroxylamine. Hydrazoic acid. Hyponitrous acid. Trialkyl and Triarylphosphates.
Phosphate esters. Potassium hexacyanoferrate (II) and (III). Sodium hexanitrifocobaltate (III).
8. INORGANIC COMPOUNDS – STRUCTURE AND BONDING OF (10)
Diborne, Borazine, Phosphazene, Dimeric aluminum chloride, Al2Me6, Al(BH4)3, Hyponitrous
acid Nickel carbonyl.
9. GRAVIMETRY (12)
Principles of gravimetric analysis, coprecipitation, post-precipitation and supersaturation,
Numericals based on gravimetric analysis.
B.Sc. II (Effective from 2005-2006 ONWARDS)
PAPER – II (Organic Chemistry)
60 Hrs (2Hrs/Week)
1. ELECTROMAGNETIC SPECTRUM : ABSORPTION SPECTRA 10 Hrs
Ultraviolet (UV) absorption spectroscopy – absorption laws (Beer-Lambert’s law), molar
absorptivity, presentation and analysis of UV-spectra, types of electronic transitions, effect of
conjugation Concept of chromophore and auxochrome. Bathochromic, hypsochromic,
hyperchromic and hypochromic shifts. UV spectra of conjugated enes and enones.
Infrared (IR) absorption spectroscopy – molecular vibrations, Hooke’s law, selection rules,
intensity and position of IR bands, measurement of IR Spectrum fingerprint region; characteristic
absorptions of various functional groups and interpretation of IR spectra of simple organic
compounds.
2. ALCOHOLS 6 Hrs
Monohydric alcohols – Methods of formation by reduction of aldehydes, ketones, carboxylic acids
and esters. Hydrogen bonding, Acidic nature, Reactions of alcohols.
Dihydric alcohols – Methods of formation, chemical reactions of vicinal glycols, oxidative cleavage
[Pb(OAc)4 and HIO4] and pinacol-pinacolone rearrangement.
Trihydric alcohols – Methods of formation, chemical reactions of glycerol.
3. PHENOLS 6 Hrs
Preparation of phenols, acidic character, Comparative acidic strengths of alcohols and phenols,
resonance stabilization of phenoxide ion. Reactions of phenols – electrophilic aromatic
substitution, acylation and carboxylation, Mechanisms of Fries rearrangement, Claisen
rearrangement, Gatterman synthesis, Hauben – Hoesch reaction, Lederer – Manasse reaction
and Reimer – Tiemann reaction.
Separation of a mixture of primary secondary and tertiary amines. Structural features affecting
basicity of amines. Amine salts as phase-transfer catalysts. Preparation of alkyl and aryl amines
(reduction of nitro compounds, nitriles), reductive amination of aldehydic and ketonic compounds.
Gabriel-phthalimide reaction, Hofmann bromamide reaction.
Reaction of amines, electrophilic aromatic substitution in aryl amines, reactions of amines with
nitrous acid. Synthetic transformations of aryl diazonium salts, azo coupling.
THIRD PAPER
PHYSICAL CHEMISTRY
1. THERODYNAMICS
Spontaneous processes, Carnot cycle, statement of second law, concept of entropy, combined
form of the first and second law of thermodynamics, enthalpy and entropy. Thermodynamic equation of
state (energy as a function of V. and T, enthalpy as a function of T and F), entropy change in isolated
system. Variation of entropy with temperature and volume, Variation entropy with temperature and
pressure. Entropy change in chemical reaction. Helmholtz and Gibbs free energies, Properitis of Gibbs
function, Gibbs-Helmholtz equation Thermodynamic criteria of equilibrium Clapeyron-Clausium equation
and its application.
2. PHASE EQUILIBRIA :
Explanation of phase, component and degree of freedom. Phase rule and its application to one
component (water and sulphur) and two component (signle eutectics) systems. Nernst distribution law,
thermodynamic derivation of the distribution law. Limitations and applications of the distribution law.
3. ELECTROCHEMICAL CELLS :
Reversible and irreversible cell, EMF of a cell and free energy change Nernst equation. EMF and
equilibrium constant. Types of single electrodes. Electrode potentials. Standard electrode potential
concept of concentration cell without transference. Applications of EMF measurement (determination of
solubility product. pH. dissociation constants of acids, hydrolysis constant, solubility of sparigly soluble
salt).
4. SURFACE PHENOMENON :
Physical and chemical adsorption, Freundlich adsorption isotherm, Gibbs adsorption equation,
Langmuir monomolecular theory and B.E.T. theory.
6. COLLOIDAL STATE :
Stability of colloids, determination of size of colloidal particle, Electrokinetic Potential (Zeta
potential). Donnan membrane theory and its applications.
CHEMISTRY PRACTICAL
Time : 6 Hrs (1day) M.M. 50
1. Gravimetric Analysis
(i) Barium as BaSO4
(ii) Iron as Fe2O3
(iii) Zinc as ZnO
(iv) Aluminum as Ai2O3 and
(v) Copper as CuO 10 Mark
FIRST PAPER
INORGANIC CHEMISTRY
1. THEORIES OF COVALENT BOND (12)
Valence bond theory-Heitler-London and Pauling-Slater theories and resonance, Molecular orbital
theory-LCAO method, bonding, non-bonding and antibonding molecular orbitals. Molecular orbital energy
level diagrams for homonuclear and heteronuclear diatomic molecules-electronic structure, bond
order, bond length and bond energy.
2. THEORIES OF COORDINATE BOND (12)
Valence bond theory and its limitations. Crystal field theory-d-orbital splitting in octahedral and
tetrahedral crystal fields. Ligand field splitting (10Dq) and factors affecting its magnitude,
spectrochemical series. Crystal field stablization energies (CFSE) for d1to d10 systems in octahedral and
tetrahedral fields.
3. METALS AND METALLURGY (14)
Comparative study of the chemistry of d-block elements and their important compounds : Sc, Y,
La, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, Fe, Co, Ni and platinum metals (Application of reduction
potential diagrams whereever necessary). Metallurgical extraction of Ti, V, Mo, W, and Re.
4. 4 f-BLOCK ELEMENTS (10)
Characteristics: Electronic structure, lanthanide contraction and its consequences, oxidation
states, complex formation, magnetic and spectral properties and their differences from transition metals,
ion exchange and solvent extraction methods of separation of lanthanides.
5. INORGANIC CHAINS, RINGS AND CAGES (8)
Silicates, Silicones, Borazines, Phosphazenes, S-N compounds and Boranes.
6. STRUCTURES AND CHARACTERISTICS OF SOLIDS (10)
Metallic, lonic, Covalent and molecular crystals, Structures of lonic solids, radius ratio rules,
Structures of metals, close packed structures, Characteristics of Unit Cells.
7. CHEMICAL INDUSTRIES (8)
Glass, cement, artificial fertilizers, steel and Phosphorus sulphides.
8. ENVIRONMENTAL POLLUTION (8)
Air pollutants, their sources and toxic effects. Particulates, their sources and toxic effects. Acid
rain and green house effects. Water pollutants.
9. METAL IONS IN BIOLOGICAL SYSTEMS (8)
Essential and trace elements. Chemistry of chlorophyll, haemoglobin, myoglobin, and
cyanocobalamine.
SECOND PAPER
ORGANIC CHEMISTRY
1. SPECTROSCOPY 15 Hrs.
Nuclear magnetic resonance (NMR) spectroscopy, nuclear shielding and deshielding, chemical
shift and molecular structure, spin – spin splitting and coupling constants, area of signals, interpretation of
PMR spectra of simple organic molecules such as ethylbromide, ethanol, acetaldehyde, 1, 1, 2-
tribromoethane, ethyl acetate, toluene and acetophenone.
Problems pertaining to the structure elucidation of simple organic compounds using UV. IR and PMR
spectroscopic techniques.
Introduction to condensed five and six – membered heterocycles. Preparation and reactions of
indole, quinoline and isoquinoline with special reference to Fisher indole synthesis, Skraup synthesis and
Bishler-Napleralski synthesis. Mechanism of electrophilic substitution reactions of indole, quinoline and
isoquioline.
6. CARBOHYDRATES 10 Hrs.
Classification and nomenclature. Monosaccharides, mechanism of osazone formation,
interconversion of glucose and fructose, chain lengthening and chain shortening of aldoses. Configuration
of monosaccharides. Erythro and threo diastereomers. Conversion of glucose into mannose, Formation of
glycosides, ethers and esters, Determination of ring size of monosaccharides. Cyclic structure of D (+) –
glucose, Mechanism of mutarotation.
Dissocharides - maltose, Surcrose and lactose, Structure determination.
III. PHOTOCHEMISTRY :
Absorption of light, chain reaction, free radical chains (Rice-Herzfoid mechanism for the
decomposition of ethane) Lamberts and Beer’s law, Grotthug Draper law, Einstein’s law of
photochemical equivalance quantum efficiency, reasons for low and high quantum yields. Kinetics of
some typical photochemical reactions (Decompostion of acetaldehyde, dimerisation of anthracene)
Photo electric cell. Photosensitization.
IV. E.M.F. :
Concentration cells, with and without transference, liquid junction potential, fuel cells,
chemical cells without transference.
V. ATOMIC STRUCTURE :
Bohr’s theory, Sommerfeld’s model, dual nature of electron de-Broglie’s equation.
Experimental verification of the wave nature of electron (Davison & Germer’s experiment)
Heisenberg’s uncertainty principle. One dimensional Schrodinger’s wave equation and physical
significance of the wave function. Particle in a box (one dimension only).
CHEMISTRY PRACTICAL
Time : 6 Hours (1day) M.M. : 75
(20 Marks)