TEST Book1

THE STAR INSTITUTE SIALKOT CAMPUS
NEAR RESCUE 1122, KATCHERY ROAD SIALKOT

STUDENT NAME:_________________ROLL NO.__________ DATE:________
TEST NO= 1
CHAPTER 1 (BOOK 1) TIME 1:30 HOURS
Q: Each question has four possible answers. Select the correct answer and encircle it. (10)
i- Most of the atoms show diameter in the order of
a. 2 x 10 -10 cmb. 0.1 mc. 10 -10 cmd. 0.2 nm
ii- One mole of SO2 contains
a. 6.02 x 1023 atoms of oxygenb. 6.02 x 1023 atoms of sulphur
c. 1.003x10 23 molecules of SO2d. 3.01x1023 atoms of SO2
iii-In combustion analysis, CO2 produced during the combustion of an organic compound is absorbed in
a. Mg(ClO4)2b. 50% KOHc. Al2O3d. H2SO4
iv-Isotopes of an element differ in
a. Arrangement of electrons in orbital b. Chemical properties
c. Electronic configuration d. Properties which depends upon mass
v- Number of moles of CO2 which contains 8.0 g of oxygen
a. 0.25 moleb. 0.50 molec. 1.0 moled. 1.50 moles
vi- Which of the following elements has maximum number of isotopes
a. Nib. Cac. Pdd. Sn
vii-Which of the following statements about atom is correct
a. May or may not exist independentlyc. Take part in chemical reaction
b. Made up of more than 100 subatomic particles d. All
viii- Relative atomic mass is the mass of an atom of an element which is obtained after
comparison with mass of
a. Oxygen b. Carbonc. Nitrogend. Chlorine
ix- The mass of one mole of electrons
a. 1.008 mgb. 0.55 mgc. 0.184 mgd. 1.673 mg
x- Which of the following statement is not involved in determination of empirical formula?
a. Determination of %age of each element b. Determination of mole of each element
c. Determination of isotopes of each element d. Determination atomic ratio of element
SHORT QUESTIONS (14)

i - N2and CO has same number of electrons, protons and neutrons. Justify it
ii- What is limiting reactant. How the limiting reactant is identified
iii- Mg is twice heavier than that of carbon atom. How
iv- Define empirical formula. How it is related to molecular formula.
v- Why experimental yield less than theoretical yield.
vi- 23 gram sodium of and 238 gram of Uranium have equal number of atom in them
vii- Write four steps for determining the empirical formula
LONG QUESTIONS
Q1 (a) What is stoichiometry? Give its assumption? Mentioned two important laws which help to perform the
stoichiometric calculation (4)
(b) Write down the combustion analysis for the determination of the empirical formula of a compound (4)
Q2 (a) Define the following (4)

i) Mole ii) Avogadro’s number iii) Relative atomic mass iv) Molar volume
(b) Define Ion? Differentiate between cation and anion (4)
PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

TEST NO= 6
Attempt any five questions
Q1: Calculate the number of grams of Al2S3 which can be prepared by the reaction of 20g of Al
and 30 g of sulphur.How much the non limiting reactant is in excess? (5)
Q2: A sample of 0.600 mole of a metal M reacts completely with excess of fluorine to from 46.8 g MF2
i) How many moles of F are present in the sample of MF2 that forms.
ii) Which elements is represented by the symbol M. (5)
Q3: A well known ideal gas is enclosed in a container having volume 500cm3 at STP. Its mass comes out
to be 0.72g. What is the molar mass of this gas. (5)
Q4: Ethylene glycol is used as automobile antifreeze. It has 38.7% carbon, 9.7% hydrogen and 51.6%
oxygen. Determine its empirical formula. (5)
Q5: Calculate the number of gram of K2SO4and water produced when 14g of KOH are reacted with excess
of H2SO4. Also calculate the number of molecules of water produced. (5)
Q6: a) Calculate number of O atom in 10.037g of CuSO4.5H2O. (2.5)

b) Mass in gram of 2.78 x 1023 molecule of CrO2Cl2. (2.5)
Q7: NH3 gas can be prepared by heating together two solid NH4Cl and Ca(OH)2. If a mixture containing
100 g of each solid is heated then calculate the number of grams of NH3 produced. (5)
Q8: 10 g of H3PO3 has been dissolved in excess of water to dissociate it completely into ions calculate
(5)
a) Number of molecules
b) Number of positive and negative ion

TEST NO= 2
Attempt any five questions
Q1: How many molecule of water are there in 10g of ice? Also calculate the number of atoms of
oxygen and hydrogen separately, The total number of atoms and the covalent bonds present in the
sample, (5)
Q2: When lime stone (CaCO3) is roasted, quick lime (CaO) is produced accordingly to the following
equation. The actual yield of CaO is 2.5 kg. When 4.5 kg lime stone is roasted. What is the Percentage
yield of this reaction.(5)
CaCO3 → CaO + CO2
Q3: An unknown metal M reacts with S to form a compound with a formula M2S3. If 3.12 g of M
reacts with exactly 2.88 g sulphar. What are the name of metal M and the compound M 2S3 (5)
Q4: Aspartame, the artificial sweetener, has molecular formula of C14H18N2O5 (5)
a) What is the mass of one mole of aspartame?
b) What is the mass in gram of 10.122 moles of aspartame?
c) How many hydrogen atoms are present in 2.43 g of aspartame?
Q5: Ascorbic acid (vitamin C) contain 40.97% of carbon, 4.58% of Hydrogen and 54.5% of oxygen
by mass. What is the empirical formula of ascorbic acid.(5)

Q6: A mixture of two liquids, Hydrazine N2H4 and N2O4 are used as a fuel in rocket. They produce
nitrogen and H2O. How many gram of nitrogen gas will be formed by reacting 100 g of N2H4 and 200
g of N2O4 (5)
2N2H4 + N2O4 → 3N2 + 4H2O
TEST NO= 3
i- Solvent extraction is particularly useful technique for separation when product to
be separated is
a. Non volatile or thermally unstable b. Volatile or thermally stable
c. Non volatile or thermally stabled. Volatile or thermally unstable
ii- Chromatography in which stationary phase is solid is called
a. Partition chromatographyb. Adsorption chromatographyc. Paper chromatographyd. HPLC
iii-The agent which is not used in vacuum dessicator as drying agent is
a. CaCl2 b. Silica gelc. P2O5 d. Dil. H2SO4
iv-The dried pattern obtain on the filter paper in the form of separated component of mixture
is called
a. Histogramb. Chromatogramc. Oscillographyd. Mass spectrum
v- Which of the following can not be used as mobile phase
a. A gasb. A liquidc. A Solid d. A liquid crystal
vi- The liquid passed through filter paper during filtration is known as
a. Residue b. Filtrate c. Mother liquor d. Suspension
vii-Premature crystallization is prevented by
a. Cold finger apparatusb. Vacuum dessicatorc. Separating funnel d. Hot water funnel
viii-Chromatography is employed for
a. Qualitative analysis b. Quantitative analysisc. Bothd. none
ix-Which of the following is not sublime substance
a. Iodine b. Ammonium chloride c. Benzoic acidd. Potash alum
x- To achieve a good separation, the two liquids are gently shaken to increase
a. Their area of contactb. Their miscibilityc.Their separationd.Their solubility into each other
SHORT QUESTIONS (any 15) (30)

i- What is difference between Qualitative and quantitative analysis.
ii- Mention the steps involve in crystallization.
iii- Differentiate between filtrate and residue.
iv- Write the uses of chromatography.
v- Mention the steps involve in Quantitative analysis.
vi- Define distribution coefficient and in which technique it is applicable.
vii- What are disadvantages of drying crystal by using filter paper
viii- Define Chromatography? What are its types.

ix- What are characteristic of solvent used in crystallization?
x- Define solvent extraction and distribution law.
xi- Define Sublimation with an examples.
xii- How does undesirable colours can be removed from crystals'
xiii- Differentiate between mobile and stationary phase.
xiv- Describe procedure for preparation of saturated solution for crystallization.
xv – How does the process of filtration can be speed up.
xvi- What is meant by analytical chemistry and mother liquor.
xvii- What is crystallization? Why there is a need to crystallize the crude product.
TEST NO= 4
i- Temperature at which molecular motion ceases is called
a. Absolute zerob. Critical temperaturec. Absolute temperatured. Difficult to predict
ii- General gas equation is combination of
a. Boyle’s lawb. Charles’s lawc. Avogadro’s lawd. all
iii- Which of the following formula is correct for density of any gas
a. d= RT/PMb. d= MT/PRc. d= PM/RTd. d= RM/PT
iv- Pressure remaining constant at which temperature the volume of gas become twice of what is at 0 0C.
a. 5460C b. 2000C c. 546Kd. 273K
v- Which of the following have a definite shape
a. Gas b. Solid c. Liquidd. Plasma
vi- Which of the following is exact relationship between F and 0C
a. F=5/9[ 0C-32 b. F=9/50C+32 c. 0C=5/9F+32 d. all
vii- Relationship between volume of gas and prevailing conditions of temperature and pressure
a. Gas lawsb. Rate laws c. Equilibrium lawsd. none
viii- The expression P = P1 + P2 + P3 represents __________ mathematically.
a. Graham’s Law b. Avogadro’s Law c. Dalton’s law of partial Pressure d. All
ix- Which one of the following is the SI unit of pressure?
a. Atmosphere b. Torrc. Pascald. Pound per square inch
x- If absolute temperature of a gas is doubled and the pressure is reduce to one half, the
volume of gas will
a. Remain unchangedb. Increase four timesc. Reduce to 1/4d. Be doubled

i- Calculate value of R in SI units?
ii- Lighter gases diffuse more quickly than heavier gases.
iii- Define Daltons law of partial pressure? Give its expression
iv- What is isotherm. Why it goes away from both axis at high temperature?
v- Differentiate between diffusion and effusion of gas?
vi- Throw some light on the factor 1/273 ?
vii- Justify that 1 cm3 of H2 and 1 cm3 of CH4 at STP will have same number of molecules.
LONG QUESTIONS
Q1 (a) State Graham’s law of diffusion. Verify it experimentally (4)
(b) Define thermometry? How various scale of temperature are interconvert. (2)

(c) What is absolute zero? What happen to real gases while approaching it. (2)
Q2 (a) Give applications of Dalton’s law of partial pressure. (4)

(b) Drive an expression for general gas constant. What are its unit at S.T.P. (4)
TEST NO= 5
i- A real gas obeying Vander wall’s equation will resemble ideal gas if
a. Both ‘a’ and ‘b’ are largeb. Both ‘a’ and ‘b’ are small
c. ‘a’ is large and ‘b’ is smalld. ‘a’ is small and ‘b’ is large
ii-In intense electrical field and at a very high temperature matter generally exist in
a. Solid state b. Liquid state c. plasma state d. Gaseous state
iii-Under which conditions, real gasses deviate from ideal behaviour
a. Low temperature and low pressure b. High temperature and high pressure
c. Low temperature and high pressured. High temperature and low pressure
iv- Compressibility factor for and ideal gas is
a. 1.5b. 2.0c. 1.0d. 0.5
v- Which of the following gases shows more ideal behaviour at 0 degree
a. Hb. Hec. CH4d. NH3
vi- Which one of the followings has least critical temperature
a. H2O b. Hec. CH4d. NH3
vii- Excluded volume of gas” b” is equal to
a. Vmb. 4Vmc. Vm/4d. 2Vm
viii- The collision among the gas molecules of ideal gases are
a. Elasticb. Perfectly elasticc. Inelasticd. None of these
ix- When a compressed gas is allow to expand into a region of low pressure, it produce
a. Cooling effect b. Heatc. Vapoursd. None of thes
x- Lind’s method of liquefaction of gases is based on
a. Charle’s lawb. Boyle’s lawc. Joule Thomson effectd. Graham’s law

i- Write two faulty postulate of kinetic molecular theory?
ii- Drive the units of Vander Waal’s constant “a” and “b”..
iii- What is critical temperature of gas? What is its importance in liquefaction of gases?
iv- Water vapour do not behave ideal at 273K ?
v- What is meant by compressibility factor? What is its value for ideal gases?
vi- Write down any two application of plasma ?
vii- Drive Graham’s law of diffusion from kinetic theory of gases.
LONG QUESTIONS
Q1 (a) Define Joule Thomson effect? Explain Lind’s method of liquefaction of gases (4)

(b) Explain with the help of graph the ideal and non ideal behaviour of gases (4)
Q2 (a) Drive Boyle’s law and Avogadro’s law with the help of kinetic molecular theory of gases (4)
(b) Define plasma? How plasma produce. What is difference between natural and artificial
plasma. (4)
TEST NO= 6
Attempt any six questions
Q1: Calculate the mass of 1 dm3 of NH3 gas at 30 oC and 1000 mmHg pressure considering that
NH3 is behaving ideally (5)
Q2: Calculate the density of CH4 in gm at 0 oC and 1 atm. What will be happen to the density if
temperature is increased to 27oC. (5)
Q3: 250 cm3 of the sample of hydrogen effuses four time as rapidly as 250 cm3 of an unknown
gas. Calculate the molar mass of unknown gas.(5)
Q4: What pressure is exerted by a mixture of 2 g of H2 and 8 g of N2 at 273 K in a 10 dm3

Vessel.(5)
Q5:one moles of CH4 are enclosed in a 250 cm3 flask at 27oC.Calculate the pressure exerted by
the gas assuming that gas behaves like a real gas.
a= 2.253 atm dn6 mol-2 b= 0.0428 dm3 mol-1 (5)
Q6:A sample of Krypton with a volume of 6.25 dm3 and a pressure of 765 torr and a temperature
of 200oC is expended to a volume of 9.55 dm3 and a pressure of 375 torr. What will its final
temperature ( in oC ) (5)
Q7:There is a mixture hydrogen and helium occupying a vessel of volume 13 dm3 at 37oC and
pressure of 1 atm.The masses of hydrogen and helium are 0.8g 0.12g respectively.Calculate the
partial pressure of each gas in mmHg in the mixture.

TEST NO= 7
i- Evaporation of water takes palace a
a. 0 degree centigradeb. 100 degree centigradec. Above 100 d. All temperature
ii- Down the group polarizibility generally
a. Increasesb. Decreasesc. Remain constantd. No regular trend
iii- At equilibrium, rate of evaporation and rate of condensation become
a. Equalb. Very highc. Very lowd. None
iv- Distillation under very reduced pressure is called as
a. Fractional distillationb. Vacuum distillationc. Steam distillationd. None
v- London dispersion forces are the only forces present among the molecules of
a. Water in liquid stateb. Helium gaseous state at high temp
c. Solid iodined. Hydrogen chloride gas
vi- When water freezes at 0 degree centigrade its density decreases due to
a. Cubic structure of iceb. Empty spaces
c. Change of bond lengthsd. Change of bondangles
vii- Liquid crystals are not used in
a. LCDb. Oscillographyc. Lightening dischargesd. Chromatography
viii- DNA has two spiral chains. They are linked through H-bonding which is dominant
between
a. C and Hb. N and Hc. O and H d. N and O
ix- Interaction between ion and polar solvent is called:
a. Dipole Dipole interactionb. London forcesc. Debye forcesd. Ion dipole forces
x- If atmospheric pressure decreases then boiling point
a. Decreasesb. Increasesc. Remain unchanged d. None of these
i- Boiling needs a constant supply of heat. why
ii- Evaporation cause cooling.
iii- In a very cold winter fish in garden ponds owe their lives due to hydrogen bonding ?
iv- Why boiling point of water is higher than HF?
v- Why heat of vaporization of iodine is very high?
vi- The boiling point of water is different at Murree hills and Mount Everst?
vii- One feels sense of cooling under the fan after bath.

LONG QUESTIONS
Q1 (a) What is vapour pressure? Explain how it is measured. (5)
(b) What are intermolecular forces? Explain dipole – dipole forces? (3)
Q2 (a) What are liquid crystals? Give their uses in daily life (5)
(b) Define vacuum distillation and what the advantages of vacuum distillation are. (3)
TEST NO= 8
i- The solids are very rigid which is due to
a. Definite shapeb. High density c. Fixed position of particlesd. Giant structures
ii- Which one of the solid is brittle?
a. Glassb. Copperc. Irond. Gold
iii- Which one of the following is amorphous solid?
a. Glass b. Plasticc. Glued. All
iv- The small region in amorphous solids where particles have regular arrangement is called
a. Crystal latticeb. Unit cellc. Crystallites d. Voids
v- Melting point can be used to identify crystalline solids because they
a. Low melting point b. High melting point
c. Sharp melting point d. Low range of melting point
vi- Which of the following substance shows anisotropic behaviour in electrical conductivity
a. Diamondb. Graphitec. Solid NaCld. ice
vii- The electrical conductivity of metals
a. Decreases with decreasing temperature b. Increases with increasing temperature
c. Decreases with increasing temperatured. All
viii- The molecule of CO2 in dry ice forms the
a. Ionic bond b. Molecular solidsc. Covalentd. Metallic solid
ix- Which of the following crystal system is the most unsymmetrical
a. Monoclinic b. Triclinicc. Hexagonald. Trigonal
x- Existence of an element in more than one crystalline forms is called
a. Polymorphismb. Isomorphismc. Allotropyd. isomerism
i- Diamond is hard and electrical insulator. Why?
ii- Why ionic crystals are brittle ?
iii- Define lattice energy and transition temperature
iv- Write down the name of seven crystal system.
v- Why electrical conductivity of metal decrease with the increase of temperature?
vi- Why molecular crystals are softer than ionic crystals?
vii- Why graphite is anisotropic in electrical conductivity?
LONG QUESTIONS
Q1 (a) Differentiate between polymorphism and isomorphism. (4)

(b) Write the characteristic of metallic solid. (4)
Q2 (a) Differentiate between crystalline solids and amorphous solids. (4)

(b) Define the following
i) symmetry ii) Allotropy iii) Habit of crystal iv) Unit cell. (4)
TEST NO= 9
i- Which of the following has the highest energy?
a. Gamma rays b. X-rays c. Ultra-violet radiation d. radio waves
ii- Which particle has a mass 1/1836 time that of hydrogen
a. Proton b. Positron c. Electron d. Neutron
iii- Which is not decay product of neutron
a. Proton b. Electron c. Neutrino d. Anti neutrino
iv- The nature of positive rays depends on
a. The nature of electron b. The nature of discharge tube c. The nature of residual gas d. All
v- Energy and wave length of a photon are related as
a. Direct b. indirect c. No correlation d. Inverse under root
vi- The e/m ratio of cathode rays is-------than e/m ratio of positive rays
a. Smaller b. Greater c. Same d. None of these
vii- The angular momentum of an electron revolving around the nucleus of atom is ______
a. nh/2π b. n2h2/2 π c. nh3/3 π d. n2h2/ π
viii- Canal rays are produced from __________.
a. Anode b. Cathode c. Ionization of gas in the discharge tube d. Both a and b
ix- A proton is
a. A positively charged particle of mass 1.67 x 10-27 kg b. A helium ion
c. A positively charged particle of mass 1/1837 that of Hydrogen atom d. None of these
x-The charge on an electron is __________.
a. -2.46 x 104 coulombs b. -1.6 x 10-19 coulombs c. 1.6 x 10-9coulombs d. None
i- What are the defects of Rutherford’s atomic model?
ii- Why the radius of He+ is smaller than hydrogen (H) atom.
iii- What species are formed by the decay of free neutron? Write equation.
iv- How the slow neutrons to be more effective than the fast neutron.
v- How positive rays are produced
vi- Whatever gas is used in the discharge tube, the nature of cathode rays remains same, why

vii- How mass of electron can be calculated by e/m ratio and charge
LONG QUESTIONS
Q1 (a) Explain Millikan,s oil drop experiment to determine charge on electron. (4)
(b) Describe discharge tube experiment for the discovery of cathode rays and give four
properties of cathode rays. (4)
Q2 (a) Derive formula to calculate radius of nth orbit of an atom. (4)

(b) Define spectrum? Differentiate between continuous and line spectrum (4)
TEST NO= 10
i- Balmer series lies in
a. Ultra violet region b. Visible region c. Infra red region d. microwave region
ii-P-orbitals are __________ in shape.
a. spherical b. diagonal c. dumb bell d. complicated
iii- The wavelengths of X-rays are mathematically related to the ____ of anticathode element.
a. atomic weight b. atomic number d. Avogadro’s number d. Mole
iv- According to __________ electrons are always filled in order of increasing energy.
a. Pauli’s Exclusion Principle b. Uncertainty Principle c. Auf bau Principle d. All of these
v- Principle Quantum number describes __________.
a. Shape of orbital b. size of the orbital. C. Spin of electron in the orbital d. Splitting of orbital
vi- Quantum number value for 2p sub shell are
a. n=2 , l=1 b. n=2 , l=0 d. n=1 , l=1 d. n=2 , l=2
vii- The two electrons in the “k” shell will differ
a. Principal quantum number b. Azimuthal quantum number
d. Magnetic quantum number d. Spin quantum number
viii- A region in space, around the nucleus in an atom, where the probability of finding the
electron is maximum is called
a. A wave b. A shell d. A orbit d. An orbital
ix- If value of Azimuthal quantum number “l” is 3 the value of “m” will be
a. +3, +2, +1, 0, -1, -2, -3 b. 0, 1, 2 d. +1, 0, -1, d. 0, 1, 2, 3
x- An orbital can accommodate maximum of
a. 2 electrons b. 1 electrons d. 8 electrons d. 18 electrons

i- State Mosley’s law. Write its mathematical form.
ii- What is Heisenberg uncertainty principle. Write its mathematical form.
iii- Write down the electronic configuration of Br35 and Cr24
iv- Define Hund’s rule and Pauli exclusion principle.
v- Draw the shape of d-orbital.
vi- How the Balmer series are obtained in spectrum of hydrogen.
vii- What is the importance of principal quantum number.

LONG QUESTIONS
Q1 (a) What are the defects of Bohr’s atomic model (4)
(b) Explain dual nature of matter. (4)
Q2 (a) Discuss azimuthal quantum number and magnetic quantum number. (4)
(b) What is (n+l) rule? Arrange the orbitals according to this rule. (4)
TEST NO
= 11
i- Which of the following sets of species does not follow octet rule.
(A) CO, PCl5 PCl3 , AICl3 (C) AICl3 , BF3 PCl5 ,SF6
(B) CO, B2 H 6 , NH 3 , H 2O (D) H 2 O, NH3 ,CO2 , AICI3
ii-An electrovalent bond is formed between
(A) two electronegative atoms (C) electropositive and electronegative atoms
(B) two metals (D) two electropositive atoms
iii-The electronegativity of cesium is 0.7 and that of fluorine is 4.0. The bond formed between
the two
(A) covalent (B) electrovalent (C) coordinate (D) metallic
iv- Maximum energy is required to remove an electron from
(A) s-orbital (B) p-orbital (C) d-orbital (D) f-orbital
v- In the formation of methane molecule, the carbon atom makes use of
(A) sp3 hybridization (B) sp 2 hybridization (C) sp Hybridization (D) None of these
vi-In which of the following molecules, the bond angle is maximum
(A) CH 4 (B) H 2 O (C) NH 3 (D) CO 2
vii-The type of bonds present in CaO are:
(A) electrovalent, covalent and coordinate (C) electrovalent and coordinate
(B) electrovalent (D) covalent and coordinate
viii-The species in which the central atom uses sp 2 hybrids in its bonding is:
(A) PH 3 (B) AsH 3 (C) NH 3 (D) BH3
ix-Atomic radii can be determined with the help of:
(A) X-rays (B) microwaves (C) I.R waves (D) UV waves
x- Electron affinity depends on
(A) Atomic size (B) Nuclear charge
(C) Atomic number (D) Atomic size and nuclear charge both.

i- Why is the cationic radius
is smaller than the parent atom.
ii- Ionization energy is an index to the metallic character. Why?
iii- Why the atomic radius increase down the group
iv- Why second ionization energy greater than first ionization energy
v- Why NH3 and PH3 give coordinate covalent bond with H+

vi.- How does the electronegative difference decide the nature of bond
vii- Why the lone pair of electrons on an atom occupy greater space than bond pair
LONG QUESTIONS
Q1 (a) Explain what do you understand by the term electronegativity. How it is determined. Discuss
it tend in periodic table (4)
(b) Write the postulate of VSEPR theory (4)
Q2 (a) Define ionization energy? Explain the factors which effect the ionization energy of ofan
element (4)
(b) What do you mean by covalent and coordinate covalent bond. Discuss the type of covalent
bond on the basis of nature (4)
TEST NO= 12
i- Which of the hydrogen halides has the highest percentage of ionic character
a. HF b. HClc. HBrd. HI
3
ii- A sp hybrid orbital contains
a. ¼ s-character b. 2/3 s-character c. ½ s-character d. ¾ s-character
iii- The number of bond in nitrogen molecule is
a. 1 sigma & 1 pi b.1 sigma & 2 pi c. 3 sigma & 1 pi d.2 sigma & 2 pi
iv- molecule in which the distance b/w the two carbon atom is largest is
a.Ethane b. Ethene c. Ethyned. Benzene
v- During the process of hybridization there happen
a. Removal of electron pairb. Mixing up of atomic orbital
c. Separation of orbitald. Addition of an atomic electron
vi-The theory which state that covalent bond is formed by overlapping of orbital is
a. VSEPR theoryb. MOTc. V.B.T d. LFT
vii- Structure of molecule can be decided on the basis of
a. Symmetryb. Polar moleculec. Size of atomd. Dipole moment
viii- The paramagnetic behaviour of O2 molecule is best explained by
a. VSEPR theoryb. MOTc. V.B.T d. LFT
ix- Which molecule does not have Sp3 hybridization
a. CH4b. NH3c. H2Od. BF3
x- Molecular orbitalare filled with electrons according to
a. Auf – Bau principleb. Hund,s rulec. Pauli exclusion principle d. All of these
i-Why sigma bond is stronger than pi bond
ii- The bond angles of H2O and NH3 are not 109.5 like that of CH4 although O and N are sp3
hybridized
iii- Why bond energy of multiple bonds are greater than those of single bond
iv- How the %age of ionic character of a polar bond can be determined
v- Dipole moment of CO2 is zero but that of CO is 0.12 Debye. Why
vi- Explain the term bond order. Write bond order of H2 and He
vii- Why the actual bond dissociation energy of HCl molecule is greater than theoretical bond
dissociation energy

LONG QUESTIONS
Q1 (a) What is bond length. How it is calculated. Explain the factor which effect the bond length (4)
(b) Briefly describe dipole moment (4)
Q2 (a) Write the postulate of molecular orbiral theory (4)

(b) Draw MOT diagram of the following (4)
i) O2 ii) N2
TEST NO= 13
Q:Each question has four possible answers. Select the correct answer and encircle it. (10)
i- All of the following are state functions except
a. P b. V c. qd. H
ii- All of the following processes are spontaneous except
a. Reaction of H2 with O2 to form H2O b. Combustion of natural gas
c. Neutralization of HCI by NaOH d. Synthesis of glucose by plants
iii- In endothermic process the temperature of system
a. Fallsb. Risesc. Remains constantd. First increases then decreases
iv- In order to predict whether reaction is spontaneous or non spontaneous we should study
a. Enthalpy of system b. State of the system
c. Free energy change of systemd. Heat change of system
v- Heat absorbed by gaseous system at constant pressure is equal
a. Change in internal energy b. Pressure volume workc. Change in enthalpyd. None
vi- A bomb calorimeter is used to determine the accurate enthalpy of
a. Solutionb. Neutralizationc. Combustiond. Atomization
vii- In bomb calorimeter oxygen is provided with pressure of about
a. 10 atmb. 20 atmc. 100 atmd. 200 atm
viii- Which of the following is called Hess’s law of constant heat summation?
a. First law of thermodynamicsb. Second law of thermodynamics
c. First law of thermo chemistryd. Second law of thermo chemistry
ix- First law of thermodynamics is represented as
a. ΔE= q + RT b. ΔE = ΔH c. ΔE= q + Δp d. ΔE= q + w
x- The heat content of system is known as
a. Entropy b. Enthalpy c. Work d. Free energy

i- Differentiate between spontaneous and non spontaneous reaction.
ii- Define standard enthalpy of formation and atomization.
iii- What is the function of bomb calorimeter.
iv- Differentiate between exothermic and endothermic reaction.
v- Define state function and state of system.
vi- Define internal energy and mention the factors which effect the internal energy.

vii- Why is it necessary to mention the physical states of reactants and products in a
thermo chemical reaction.
LONG QUESTIONS
Q1 (a) What is the first law of thermodynamics? How does it explain that i) ΔE=qv ii) ΔH= qp (4)
(b) How you determine the enthalpy of reaction by bomb calorimeter. (4)
Q2 (a) Define lattice energy? How does Born Haber cycle help to determine the lattice energy
ofNaCl . (5)
(b) Define the following i) Surrounding ii) System iii) Standard enthalpy of solution (3)
TEST NO= 14
i- The rate of chemical reaction is directly proportional to the product of the molar
concentration of______.
a. Reactants b. Products c. Both reactants and products d. None of these
ii- In exothermic reaction, lowering of temperature will shift the equilibrium to _____.
a. Right b. Left c. equally on both the direction d. None of these
iii- When a high pressure is applied to the following reversible process: N2 + O2→ 2NO The
equilibrium will______
a. Shift to the forward direction b. Shift to the backward direction c. Not change d. All
iv- A reaction is reversible because

a. Reactions are reactive b. Product are reactive
c. Productive are stable d. Reactants are stable
v- Almost forward reaction is complete when value of Kc is

a. Neither large nor very smallb. Very smallc. Very larged. None of these
vi-NH3 is prepared by the reaction N2 + 3H2→ 2NH3 ΔH = -92 kj/mole. The maximum
yield of NH3 is obtained __________.
a. At low temperature and high pressure b. At high temperature and low pressure
c. At high temperature and high pressure d. At low temperature and low pressure
vii- Distillation under very reduced pressure is called as

viii- Extent to H2 + I2→ 2HI can be increased by

a. increasing pressure b. Increase product c. Increasing temperature d. Adding a catalyst
ix- Law of mass action was given by

a. Ramsay and Reylelgh b. Berkeley and hartly c. Berthelot d. Guldberg and waage

x- Equilibrium constant Kc used when the concentration expressed in

a. Mole b. Mole fraction c. Partial pressure d. Mole dm-3
i- Solubility of glucose in water is increased by increasing temperature. why?
ii- What is difference between reversible and irreversible reactions.
iii- Write Kc expression for N2 + O2→ 2NO when volume of reaction mixture is “V”
iv- A catalyst does not effect the equilibrium constant. Justify it
v- Before the curve become parallel, the steepness of curve falls. Why
vi- What is the effect of change in temperature on reversible reaction.
vii- Mention the conditions for the synthesis of ammonia by Haber’s process.
LONG QUESTIONS
Q1 (a) State and explain law of mass action and derive the expression for equilibrium constant (5)
(b) State and explain chemical equilibrium. (3)
Q2 (a) Give application of equilibrium constant i) Direction of reaction ii) Extent of reaction. (5)
(b) Explain the effect of pressure on equilibrium position with examples (3)
TEST NO= 15
i- PH of 0.01M HCl is
a. 0 b. 1 c. 2 d. 3
ii- Negative log of ionization constant of water is

a. pKw b. pKa c. pKb d. Kw
iii- Capability of buffer solution to resist a change in its pH is called its

a. Solubility effect b. Ionization effect c. Common ion effect d. Buffer capacity
iv- Solubility of KClO3 is suppressed by

a. HCl b. NaClc. KCld. Na2CO3
v- Which pair ca be used to make a Buffer solution

a. NaOH + Na2CO3b. NaOH + CH3COOH c. NH4OH + NH4Cl d. KCl + Na2CO3

vi- A conjugate acid of a strong base is
a. Strong acid b. weak acid c. Strong base d. weak base
vii- The ionic product of water is

a. Mole2 dm-6b. Mole-2 dm-6c. Mole-2 dm-3d. Mole-1 dm-3
viii-Solubility product of slightly soluble salt is denoted by ________

a. Kc b.Kp c. Ksp d. Kn
ix-The logarithm of reciprocal of hydroxide ion is represented as _________

a. pH b. pOH c. Kb d. Ka
x- _______ is an example of strong acid.

a. Acetic Acid b. Carbonic Acid c. Hydrochloric Acid d. Phosphoric aci

i- How NaCl is purified by common ion effect?
ii- What is the effect of common ion solubility. Give example
iii- Describe the percentage of ionization of a acid.
iv- Why we need buffer solution.
v- Define conjugate acid and conjugate base.
vi- Calculate the pH of NaOH having concentration 10-4mol dm-3
vii- Define pH and pOH
LONG QUESTIONS
Q1 (a) Define buffer solution. How buffer solution are prepared. Give example (4)
(b) Prove pKa + pKb = 14 at 25.C (4)
Q2 (a) What is solubility product? Derive the solubility product expression for sparingly soluble compound
i) AgCl ii) Ag2CrO4 . (5)
(b) Derive Henderson’s equation for calculation of pH of buffer solution. (3)

TEST NO= 16
i-Which concentration unit is temperature depend
a. Molarityb. Molality c. Mole fraction d. ppm
ii-In which of the following concentration unit. Solution is taken in kg?
a. Molarityb. Molalityc. Mole fraction d. None of these
iii-Which of the following pair of liquids is not completely miscible?
a. Alcohol and waterb. Alcohol and etherc. Phenol and waterd. Benzene and cyclohexane
iv- The critical solution temperature of phenol water system is
a. 35.5 degree centigrade b. 49.5 degree centigrade
c. 65.9 degree centigraded. 57.8 degree centigrade
v- Relative lowering of vapour pressure is independent of
a. Amount of solvent b. Amount of solute c. Temperature d. None
vi- The solubility curve for Ce2(SO4)3 is
a. Rising curve b. Falling curve c. Straight line d. Discontinuous line
vii- “A” is one molar NaCl solution and “B” is one molalNaCl solution
a. A is less concentrated than B b. A is more concentrated than B
c. A and B have same strength d. None
viii- 0.05 M H2SO4 solution has amount of
a. 9.8 g dm-3 b. 4.9 mole dm-3 c. 4.9 g dm-3 d. 9.8 mole dm-3
ix- A aqueous solution containing KCl , KNO3 , KBr can be separated into constituents
component by a process by
a. Distillation b. Fractional distillation c. Crystallization d. Fractional crystallization
x- Alloy is an example of solution type
a. solid in gas b. Liquid in gas c. Gas in solid d. Solid in solid
i- Why glucose is not soluble in CCl4 but dissolve in water
ii- why the relative lowering of vapour pressure is independent of temperature.
iii- What do you mean by concentration. Give five way to express concentration.
iv- The sum of mole fraction of all the component in a solution is equal to unity. Justify it.
v- The concentration in term of molality is independent of temperature but molarity depend upon
temperature
vi- What is the effect of temperature on the conjugate solution of water and phenol.
vii- Define zeotropic and azeotropic mixture
LONG QUESTIONS
Q1 (a) Define solubility curve? Discuss the type of solubility curve. (5)
(b) Define Rauolt,s law by three ways. (3)
Q2 (a) Define fractional crystallization? Describe the method of fractional crystallization. (4)
(b) What is meant by non ideal solution? Discuss positive and negative deviation. (4)
TEST NO= 17
i- When NH4Cl is hydrolyzed, the solution will be __________.
a. Acidic b. Basic c. Neutral d. None of these
ii- Heat of hydration depends upon
a. Size/Charge b. Charge/Size c. Amount of heat provided d. None of these
iii- Crystalline solids which contain chemically combined water of crystallization are called
a. Hydrocarbon b. Hydride c. hydroxide d. Hydrate
iv- Freezing point depression can be measured by
a. Beckmann method b. Landsberger,s method c. Ostwald method d. Manometric method
v- Elevation of boiling point ΔTfis directly proportional to a factor
a. Molarity b. Molality c. Normality d. Molecularity
vi- The study of colligative properties is useful in the calculation of
a. Equivalent masses of solute b. Molar mass of solute
c. Atomic mass of solute d. Valance of ions
vii- __________ is opposite of Neutralization.
a. Hydration b. Hydrolysis c. Ionization d. Hydroxide
viii- Formula of Borax is
a. CaSO4.5H2O b. MgSO4.7H2O c. Na2B4O7.10H2O d. CaSO4.2H2O
ix-When Na2CO3 is hydrolyzed, the solution will be __________.
a. Acidic b. Basic c. Neutral d. None of these
x- Which of the following solutions has the highest boiling point.
a. 5.58% NaCl b. 18% glucose c. 6% of urea solution d. All have same boiling point
i- Why Beckmann’s thermometer is used to note depression in freezing point
ii- Give the list of colligative properties
iii- What are hydrate? How are the formed? Give example
iv- How a non volatile, non electrolyte solute lowers the vapour pressure of solution
v- In summer the antifreeze solution protect the radiator from boiling over.
vi- Aqueous solution of CuSO4 is acidic, where as aqueous solution of CH3COONa is basic. Justify it
vii- Why the freezing point of solution is always less than pure solvent.

LONG QUESTIONS
Q1 (a) Describe the method to determine boiling point elevation (5)
(b) Differentiate b/w hydration and hydrolysis with example (3)
Q2 (a) Define freezing point. Explain with the help of graph freezing point depression. (5)
(b) What are heat of hydration and water of crystallization? Give example (3)
TEST NO= 18
i- The gain of electron during a chemical reaction is known as
a. Oxidation b. Reduction c. Neutralization d. Hydrölysis
ii- The ions, which are attracted towards the anode, are known as
a. Anions b. Cations c. Positron. d. Neutron
iii- Such substances, which allow electricity to pass through them and are chemically
decomposed, are called
a. Electrolytes b. Insulators c. Metallic conductors d. Non electrolyte
iv-Sulphur has the highest oxidation number in
a. SO2 b. H2SO4 c. H2SO3 d. H2S
v- The increase of oxidation number is known as
a. Oxidation b. Reduction c. Hydrolysis d. Neutralization
vi- When fused NaCl is electrolyte, the common electrolytic cell is
a. Kastnerkelner cell b. Nelson cell c. Down cell d. Hg-Cell
vii- Stronger the oxidizing agent ,greater is its
a. Redox potentialb. Reduction potential c. Oxidation potential d. none of these
viii- Rechargeable voltaic cell are called
a. primary cell b. Secondary cell c. Tertiary cell d. Quaternary cell
ix- Silver oxide has anode which is made up of
a. Zn - metal b. KOH c. Ag2O d. Ni
x- Oxidation state of oxygen in KO2 is
a. +1 b. -1 c. -1/2 d. -2

i- Differentiate between electrolytic and voltaic cell.
ii- Impure Cu can be purified by an electrolytic process. Explain it.
iii- Na and Kcan disperse hydrogen from acids but Pt, Pd, Cu can not why
iv- Differentiate between standard electrode potential and single electrode potential
v- Why a salt bridge is not required in lead storage battery.
vi- Define oxidation number. What is the oxidation number of Mn in KMnO4 and MnO2
vii- What is SHE.

LONG QUESTIONS
Q1 (a) Define electrochemical series. Write its three applications (4)
(b) Write a note on fuel cell (4)
Q2 (a) Define electrolysis. Write its four applications (5)

(b) What is a salt bridge? Give its function. (3)
TEST NO= 19
i- The sum of exponents of the concentrations of reactants is called __________.
a. Order of reaction b. Molecularity c. Equilibrium Constant d. Rate of reaction
ii-Concentration of the products _____ with the passage of time during a chemical reaction.
a. Increases b. Decreases c. Does not alter d. None of these
iii-The rate of reaction at a particular time is called __________.
a. Average Rate of reaction b. Absolute rate of reaction c. Instantaneous rate of reaction d. All
iv-__________ is the change of the concentration of reactant divided by the time.
a. Rate of reaction b. Velocity Constant c. Molecularity d. None of these.
v- A reaction with very low Ea has a rate of reaction
a. Very slow b. Very fast c. Zero d. None of these
vi- The unit of rate constant for second order reaction
a. Mole-1 dm+3s- b. Mole-1 dm+3 c. Sec-1 d. Mole+1 dm+3s
vii- A pseudo uni molecular reaction has the order
a. 3 b. 1 c. 2 d. 0
viii- Which property of a liquid is measured by polarimeter
a. Change in volume b. Optical activity c. Refractive index d. Conductance
ix- The order of reaction cannot be measured by
a. Graphical method. b. Differential method c. Half life method d. Spectrometry
x- In zero order reaction, the rate is independent of
a. Pressure b. Concentration of reactant c. Concentration of product d. Temperature

i-What is meant by rate of reaction? Give its unit.
ii- Describe the relationship of half life period and order of reaction.
iii- Why the radioactive decay is always a first order reaction.
iv- Why the rate of reaction is changing at every moment.
v- What is difference between average rate and instantaneous rate..
vi- Write name of physical method to determine concentration of reacting species for calculating the
rate of reaction.
vii- Differentiate first order reaction and second order reaction.
LONG QUESTIONS
Q1 (a) The rate determining step of a reaction is found out from the mechanism of that reaction.
Explain it with the help of example. (4)
(b) How order of reaction is found out by half life method. (4)
Q2 (a) Define energy of activation .How the potential energy of exothermic and endothermic reaction can
be explained on the basis of Ea . (5)
(b) Explain the half life period and order of reaction. (3)
TEST NO= 20
i- The rate of chemical reaction is independent of
a. Temperature b. Nature of reactant c. Concentration of reactant d. Molecularity
ii- The influence of temperature on reaction rate is predicted by
a. Vander waal equation b. Kinetic equation c. Arrhenius equation d. All of these
iii- By using catalyst, rate of reaction is increased by decreasing
a. Enthalpy b. Effective collision c. Energy of activation d. None of these
iv- A catalysis reaction where all the reactant and catalyst are in same phase is called
a. Auto catalysis b. Homogeneous catalysis c. Heterogeneous catalysis d. None of these
v- A substance which retards the rate of reaction is called
a. Inhibitor b. Activator c. Auto catalyst d. None of these
vi- In heterogeneous catalysis , what are in different phase
a. Reactants, products and catalyst b. Reactant and product
c. Product and catalyst d. Reactant and catalyst
vii- Collision theory explains
a. Rate of reaction b. Order of reaction c. Molecularity of reaction d. All of above
viii- Enzyme utilized for hydrolysis of urea is called
a. Maltase b. Urease c. Zymase d. Invertase
ix- During the reaction between Cu and HNO3, HNO2 is produced which act as
a. Poison b. Activator c. Auto catalyst d. Inhibitor
x- With increase in 10 degree temperature, rate of reaction double.This increase in rate of
reaction is due to
a. Decrease in Ea of reaction b. Increase in number of effective collision
c. Increase in EA of reactant d. None of these

i- Differentiate between homogeneous and heterogeneous catalysis.
ii-Why catalyst is specific in their action
iii- How the rate of reaction is increased with an increase in temperature.
iv- Define activator and inhibitor.
v- Name the factors which influence the rate of reaction.
vi- Equilibrium constant of a reversible reaction is not changed in the presence of catalyst? Why.
vii- What is the role of temperature on a catalyst.
LONG QUESTIONS
Q1 (a) How does Arrhenius equation help us to calculate the energy of activation of reaction. (4)
(b) In what ways concentration of reactants and surface area effect the rate of reaction. (4)
Q2 (a) What are enzyme and write the mechanism of enzyme action. (4)
(b) What is catalyst? Give characteristic of a catalyst. (4)
TEST NO= 21
CHAPTER 1,2,3 (BOOK 1) TIME 2:00 HOURS
i-The mathematical relationship for m/e in terms of radius of curvature of ions, strength of
electrical field (E) and Magnetic field strength (H) is
a. m/e = 2H/H 2 r 2 b. m/e = 2H/E 2 r 2 c. m/e= H2r2/2E d. m/e = 2r/E 2 H 2
ii-The formation of an uni negative is process
a. Exothermicb. Endothermicc. Both a and bd. None of these
iii- the volume occupied by 1.4 g of N2 at S.T.P
a. 2.24 dm3 b. 22.4 dm3 c. 1.14 dm3 d. 112cm3
iv- The number of water molecules in one dm3 of water is
a. 6.02 x 10 2 3 b. 6.023/22.4 14 c. 18/22.414 x 10 23 d. 55.6 x 6.02 x 10 23
v- The number of covalent bonds in 36 g of H2O are
a. 36 x 6.023 x 10 23 b. 2 x 6.023 x 10 23 c. 4 x 6.023 x 10 23 d. 2 x 6.023 x 10 24
vi- 1 amu is equal to
a. 1.661 x 10 -20 kg b. 1.661 x 10 -22 kg c. 1.661 x 10 -27 kg d . 1.661×1024 Kg
vii- 27g of Al react completely with how much mass of O2 to produce Al2O3
a. 8 g of O2 b. 16 g of O2 c. 32 g of O2 d. 24 gof O2
viii- 4 g of H2 gas at S.T.P will occupy
a. 60 litre b. 44.8 litre c. 35.5 litre d. 22.4 litre
ix- For an ideal gas, the value of PV/RT is
a. less than one b. Equal to zero c. Greater than 1 d. Equal to 1
x- The SI unit of pressure is
a. torr b. mmHg c. Nm-2 d. atm
Attempt any twelve short questions (24)
i-Calculate the mass in gram of 10-3 moles of water.
ii-What is molar volume? Why masses of different gasses are different but volume of gas remain
same in a mole.
iii- What do you means by molecular ions. Give types.
iv- What is mass spectrometer. Write the equation involve in mass spectrometry.
v- What is the effect of value of K on the distribution of solute b/w stationary and mobile phase?
vi- Why the gases deviate from ideal behaviour at high pressure and low temperature.
vii- Write method of drying of crystals.
viii- Define atmospheric pressure and give their units.
ix- Why rate of diffusion of NH3 greater than HCl.
x- Which solvents are mostly used in crystallization?

xi- What is the difference b/w adsorption and partition chromatography.
xii- What do you understand the inter conversion of various scales of temperature.
xiii- SO2 is comparatively non- ideal at 273K but behaves ideally at 373.C.
xiv- Define distribution law and in which technique it is applicable.
xv-Throw some light on the factor 1/273 in Charle,s law?
LONG QUESTIONS (Attempt any two questions)
Q1 (a) write the postulate of kinetic molecular theory of gases? (4)
(b) calculate the number of grams of Al2S3 which can be prepared by the reaction of 20 g of Al and 30 g
of sulphur. How much the non limiting reactant is in excess? (4)
Q2 (a) A sample of 0.600 mole of a metal M reacts completely with excess of fluorine to from 46.8 g MF2
i) How many moles of F are present in the sample of MF2 that forms.
ii) Which elements is represented by the symbol M. (4)
(b) Define Dalton law of partial pressure. Derive an equation two find the partial pressure of gas.
Q3: A well known ideal gas is enclosed in a container having volume 500cm3 at STP. Its mass comes out to
be 0.72g. What is the molar mass of this gas. (4)
(b) Explain with the help of graph the ideal and non ideal behaviour of gases (4)
TEST NO= 22
CHAPTER 4,5 (BOOK 1) TIME 2:00 HOURS
i- Which does not show hydrogen bonding
a- water b- ethyl alcohol c- phenol d- diethyl ether
ii- Hydrogen bonding involves in

a- solubility b- detergent c- biological molecules d- all
iii- Conversion of vapours back into their liquid state is called

a- crystallization b- Vapourization c- condensation d- distillation
iv-B.p increases down the zero group due to

a- London forces b- ion dipole forces c- hydrogen bonding d-all
v- As solid may be made up of

a- atoms b- ions c- molecules d- all
vi- Bucky ball is an allotropic form of

a- sulfur b- carbon c- silica d- tin
vii- The shape of diamond crystals is

a- hexagonal b- cubic c- tetragonal d- none

viii- Which one of the following is the strongest

a- H-bonding b- dipole-dipole c- London forces d- Debye forces
ix- Which of the following crystal system is the most symmetrical

a. Monoclinic b. Triclinicc. Cubicd. Trigonal
x- Which of the following liquids has lowest vapour pressure at

a. Diethyl etherb. Acetonec. Waterd. Ethyl alcohol
xi- if the external pressure is 23.7torr, boiling point of water is

a. 25 ℃b. 98 ℃c. 100 ℃d. 200 ℃
xii-Quantum number values for 3d orbitals are

a. n = 3, = 2 b. n = 2,  3 c. n  1,  3 d. n  3,  3
xiii- Cathode rays are

a. Electromagnetic waves b. Stream of -particles c. Stream of electrons d. Radiations
xiv-The highest value of e/m of anode rays has been observed when the discharge tube is
filled with
a. Nitrogen b. Oxygen c. Hydrogen d. Helium
xv- In which of the following orbitals, the lobes lie on the axis
a. d x 2  y2 b. d xz c. d xy d. d yz
xvi- The total number of electrons in a subshell can be determined by

a. 2n2 b. 2(2l +1) c. 2l+1 d. n 2
xvii- When electron jumps from n2=2,3,4,… orbit to n1 =1, the radiations emitted give spectral lines
in
a. U.V. region b. I.R. region c. Visible region d. None of these
Subjective
Q1- Attempt any twelve short questions (24)
i-Why earthenware keeps water cool?
ii- What is the origin of the intermolecular forces in water?
iii- Density of water more than ice. Why?

iv- What is meant by boiling point of water? Is it related with the external pressure?
v- Discuss the liquid crystals can be used as a temperature sensor.
vi- Why cleavage of the crystals is itself anisotropic behaviour?
vii- Lower alcohols are water soluble but corresponding alkanes are insoluble in water. Why
viii- Why the positive rays are also called canal rays?
ix- Compare line emission and line absorption spectrum.
x- Calculate the number of electrons in p and f sub-shells from the formula.
xi- Why is it necessary to decrease the pressure in the discharge tube to get the cathode rays?
xii- Write the electronic configuration of element i) Cu= 29 ii) K=19
xiii- What is the difference between orbit and orbital ?
xiv- Why HF is weaker acid than HCl.
xv- What is the role of fast and slow neutron in nuclear reaction ?
LONG QUESTIONS
Attempt any two questions
Q1 (a) What are London forces? Explain factors affecting these forces? (5)
(b) Why heat of sublimation of substances is greater than that of heat of vaporization? (3)
Q2 (a) Explain J.J Thomson experiment to determine e/m value of electron (4)
(b) Explain plank’s quantum theory? (4)
Q3 (a) Write a procedure to separate a mixture of ink by paper chromatography and

calculation of Rf value (4)
(b) What type of intermolecular forces will dominates in i) NH3 ii) Argon (2)
(c) Define i) Metallic bond ii) Molar heat of fusion (2)

TEST NO= 23
CHAPTER 6,7,8 (BOOK 1) TIME 2:00 HOURS
i- Atomic radii can be determined with the help of:
(A) X-rays (B) microwaves (C) I.R waves (D) UV waves
ii- A chemical bond between the most electropositive and most electronegative elements
shall be ____ in nature
(A) covalent (B) co-ordinate covalent (C) hydrogen (D) ionic
iii- Energy can neither be created nor destroyed but can be changed from one form to
another is stated by:
(A) Henry’s law (B) First law of thermodynamics (C) Joule’s principle (D) Raoult’s
law
iv- The number of bonds in Nitrogen molecule is:

(A) one and one  (B) two  and one  (C) one  and two  (D) three 
v-Which type of bonding is present in PCl3

(A) ionic (B) covalent (C) coordinate covalent (D) all of these
vi-----------has dipole moment

(A) CO (B) benzene (C) CO2 (D) all of these
vii---------hybridization leads to a regular tetrahedral structure

(A) sp3 (B) sp (C) sp2 (D) all of these
viii-Which of the following bonds has minimum bond energy

(A) C – F (B) C – Cl (C) C – I (D) C – Br
ix-Which of the following is true for spontaneous process?

(A) Always exothermic (B) Always endothermic (C) Both A and B (D) None of these
x-Which of the following formation is endothermic reaction

(A) 2H 2 g   O2 g   2H 2 O( ) (C) C s   O2 g   CO2 g  (B) N 2 g   O 2 g   N 2 O2 g  (D) none of these
xi- Fluorine molecule is formed bythe overlap of?

(A) s – s orbital (B) s – p orbital
(C) p – p head on overlapping orbitals (D) p –p parallel on overlapping orbitals

xii-Which of the following has the smallest size in ionic form

(A) Al+3 (B) Mg+2 (C) Na+1 (B) all of these
xiii-The compound whose aqueous solution has highest pH , is

(A) NaCl (B) NH 4 Cl (C) CH 3COONH 4 (D) Na 2 CO3
xiv-pKa values of four acids are given below at 25C. The strongest acid is
(A) 2.0 (B) 2.5 (C) 3.0 (D) 4.0
xv- Which of the statements is correct?

(A) pK w increases with increase of temperature (C) pK w  14 at all temperatures
(B) pK w decreases with increase of temperature (D) pK w  pH at all temperatures
xvi-The chemical equilibrium of a reversible reaction is not influenced by

(A) catalyst (B) pressure (C) temperature (D) concentration
xvii-For N2 + 3H2 → 2NH3

(A) K p  K c  RT  (C) K p  Kc  RT 
2 1
(B) K p  K c (D) K p  K c  RT
TEST NO= 23
CHAPTER 6,7,8 (BOOK 1)
Q1- Attempt any twelve short questions (24)

i- What is difference between octet rule and duplet rule
ii- Give the factors which influence the ionization energy
iii- Why the ionization energy of VIA group are less than that of VA ?
iv- Give the limitation of Lewis concept.
v- What is difference between sigma and pi bond?
vi- Explain how bond energy of HF is greater than HI
vii- Write the application of dipole moment.
viii- CO2 is non polar molecules although its bondsare polar. Why

ix- Discuss the variation of electronegativity in periodic table.
x- Burning of candle is a spontaneous process, Comment on it.
xi- state the first law of thermodynamics and give its mathematical term.
xii- Describe the effect of rise in temperature on the solubility of KI in water
xiii- Discuss the ionization constant of base
xiv- Describe the application of solubility product
xv- Write the Kc when the volume of reaction mixture is “V” for N2 + 3H2→ 2NH3
LONG QUESTIONS
Attempt any two questions
Q1 (a) Define and explain Hess’s law of constant heat summation. Explain it with example (4)
(b) How do you measure the heat of combustion of a substance by bomb calorimeter (4)
Q2 (a) what is chemical bond? Discuss the formation of ionic bond (4)
(b) Ca(OH)2 is sparingly soluble compound. Its solubility product is 6.4 x10-6 .Calculate the solubility
of Ca(OH)2 (4)
Q3 (a) The given solution contains 4 g of alkali metal hydroxide(MOH) dissolved per dm 3 .Calculate
atomic mass of metal M volumetrically. (4)
(b) Define electron affinity? Discuss its variation in periodic table? (4)

TEST NO= 14
a. Right b. Left c. Equally on both the direction d. None of these
vi-NH3 is prepared by the reaction N2 + 3H2→ 2NH3 ΔH = -92 kj/mole. The maximum
yield of NH3 is obtained __________.
a. At low temperature and high pressure b. At high temperature and low pressure
c. At high temperature and high pressure d. At low temperature and low pressure
vii- Distillation under very reduced pressure is called as
viii- Extent to H2 + I2→ 2HI can be increased by
a. increasing pressure b. Increase product c. Increasing temperature d. Adding a catalyst
ix- Law of mass action was given by
a. Ramsay and Reylelgh b. Berkeley and hartly c. Berthelot d. Guldberg and waage
x- Equilibrium constant Kc used when the concentration expressed in
i- Solubility of glucose in water is increased by increasing temperature. why?
ii- What is difference between reversible and irreversible reactions.
iii- Write Kc expression for N2 + O2→ 2NO when volume of reaction mixture is “V”
iv- A catalyst does not affect the equilibrium constant. Justify it
v- Before the curve become parallel, the steepness of curve falls. Why
vi- What is the effect of change in temperature on reversible reaction.
vii- Mention the conditions for the synthesis of ammonia by Haber’s process.
LONG QUESTIONS
Q1 (a) The following reaction was allow to reach the state of equilibrium
2A + B (4)
(b) N2 and H2 combine to form NH3. The value of Kc at 500 oC is 6.0 x 10-2. Calculate the numerical value
of Kp for this reaction. (4)
TEST NO= 15
Q: Each question has four possible answers. Select the correct answer and encircle it.(10)
i- PH of 0.01M HCl is
a. 0 b. 1 c. 2 d. 3
ii- Negative log of ionization constant of water is
a. pKw b. pKa c. pKb d. Kw
iii- Capability of buffer solution to resist a change in its pH is called its
a. Solubility effect b. Ionization effect c. Common ion effect d. Buffer capacity
iv- Solubility of KClO3 is suppressed by
a. HCl b. NaClc. KCld. Na2CO3
v- Which pair ca be used to make a Buffer solution

a. NaOH + Na2CO3b. NaOH + CH3COOH c. NH4OH + NH4Cl d. KCl + Na2CO3
i- How NaCl is purified by common ion effect?
ii- What is the effect of common ion solubility. Give example
iii- Describe the percentage of ionization of acid.
iv- Why we need buffer solution.
v- Define conjugate acid and conjugate base.
vi- Calculate the pH of NaOH having concentration 10-4mol dm-3
vii- Define pH and pOH
LONG QUESTIONS
Q1 (a) the solubility product of Ag2CrO4is 2.6 x10-2 at 25 oC. Calculate the solubility of the compound. (4)
(b) What is the %age ionization of acetic acid when 01 mole of it has been dissolved in one dm3.Ka 1.8
x 10-5 at 25 oC (4)
Q2 (a) Calculate the PH of a buffer solution in which 0.11 molar CH3COONa and 0.09 molar CH3COOH
solutions are present. Ka for CH3COOH is 1.8 x 10-5. (4)
(b) The solubility of PbF2 at 25 oC is 0.64gdm-3. Calculate Ksp of PbF2 (4)

TEST NO= 14
a. Right b. Left c. Equally on both the direction d. None of these
LONG QUESTlONS
Q1 (a) The following reaction was allow to reach the state of equilibrium
2A + B→ C
The initial amount of the reactants present in one dm3 of solution were 0.50 mole of A and 0.60 mole of B.
at equilibrium the amount were 0.20 mole of A and 0.45 mole of B and 0.15 mole of C. calculate
the equilibrium constant Kc. (4)

(b) N2 and H2 combine to form NH3. The value of Kc at 500 oC is 6.0 x 10-2. Calculate the numerical value
of Kp for this reaction. (4)
Q2 (a) the solubility product of Ag2CrO4is 2.6 x10-2 at 25 oC. Calculate the solubility of the compound. (4)
(b) What is the %age ionization of acetic acid when 01 mole of it has been dissolved in one dm3.Ka 1.8
x 10-5 at 25 oC (4)
Q3 (a) Calculate the PH of a buffer solution in which 0.11 molar CH3COONa and 0.09 molar CH3COOH
solutions are present. Ka for CH3COOH is 1.8 x 10-5. (4)
(b) The solubility of PbF2 at 25 oC is 0.64gdm-3. Calculate Ksp of PbF2 (4)
TEST NO= 25
HALF BOOK ( Chapter 1 – 5 )
OBJECTIVE Time-20min
i- In combustion analysis, CO2 produced during the combustion of an organic compound is absorbed
in
ii-Isotopes of an element differ in
iii- Number of moles of CO2 which contains 8.0 g of oxygen
iv- Which of the following cannot be used as mobile phase
a. A gasb. A liquidc. A Solid d. A liquid crystal
v- The liquid passed through filter paper during filtration is known as
a. Residue b. Filtrate c. Mother liquor d. Suspension
vi-Premature crystallization is prevented by
a. Cold finger apparatusb. Vacuum dessicatorc. Separating funnel d. Hot water funnel
vii- The highest temperature at which gas can be liquefied and above which liquefaction is
impossible is called
a. boiling temperatureb. transition temperaturec. consulate temperatured. Critical temperature

viii- Which of the following is exact relationship between F and C
a. F=5/9[C-32 b. F=9/5C+32 c. C=5/9F+32 d. all
ix- Which one of the followings has least critical temperature
a. H2O b. Hec. CH4d. NH3
x- Excluded volume of gas” b” is equal to
a. Vmb. 4Vmc. Vm/4d. 2Vm
xi- Interaction between ion and polar solvent is called:
a. Dipole Dipole interactionb. London forcesc. Debye forcesd. Ion dipole forces
xii- If atmospheric pressure decreases then boiling point
a. Decreasesb. Increasesc. Remain unchanged d. None of these
xiii- The nature of positive rays depends on
a. The nature of electron b. The nature of discharge tube c. The nature of residual gas d. All
xiv- Energy and wave length of a photon are related as
a. Direct b. indirect c. No correlation d. Inverse under root
xv- Quantum number value for 3p sub shell are
a. n=2 , l=1 b. n=2 , l=0 d. n=3 , l=1 d. n=2 , l=2
xvi- The two electrons in the “k” shell will differ
a. Principal quantum number b. Azimuthal quantum number
d. Magnetic quantum number d. Spin quantum number
xvii- An orbital can accommodate maximum of
a. 2 electrons b. 1 electrons d. 8 electrons d. 18 electrons
SectionI Time- 2.40min.

Attempt sixteen short questions from section I and three questions from section ii
I- Why experimental yield less than theoretical yield.
ii- 23 gram sodium of and 238 gram of Uranium have equal number of atom in them
iii- Differentiate between micro molecule and macromolecule.
iv-Mention the steps involve in Quantitative analysis.
v- Define distribution coefficient and in which technique it is applicable.
vi- Throw some light on the factor 1/273 ?
vii- Justify that 1 cm3 of H2 and 1 cm3 of CH4 at STP will have same number of molecules.

viii- Write two faulty postulate of kinetic molecular theory?
ix- Drive the units of Vander Waal’s constant “a” and “b”..
x- Mention the steps involve in crystallization.
xi- What is critical temperature of gas? What is its importance in liquefaction of gases?
xii- In a very cold winter fish in garden ponds owe their lives due to hydrogen bonding ?
xiii- Why boiling point of water is higher than HF?
xiv- Why heat of vaporization of iodine is very high?
Xv- Why electrical conductivity of metal decrease with the increase of temperature?
xvi- Why molecular crystals are softer than ionic crystals?
xvii- Why graphite is anisotropic in electrical conductivity?
xviii- Why the radius of He+ is smaller than hydrogen (H) atom.
xix- What species are formed by the decay of free neutron? Write equation.
xx- How the slow neutrons to be more effective than the fast neutron.
xxi- State Mosley’s law. Write its mathematical form.
xxii- What is Heisenberg uncertainty principle. Write its mathematical form.
Section II
Q.NO.1. (a) A mixture of two liquids, Hydrazine N2H4 and N2O4 are used as a fuel in rocket.
They produce nitrogen and H2O. How many gram of nitrogen gas will be formed by reacting 100
g of N2H4 and 200 g of N2O4.(4)
2N2H4 + N2O4 → 3N2 + 4H2O
(b) What is vapour pressure? Explain how it is measured. (4)
Q.NO.2. (a) Give applications of Dalton’s law of partial pressure. (4)
(b) Define spectrum? Differentiate between continuous and line spectrum (4)
Q.NO.3. (a) What are the defects of Bohr’s atomic model (4)
(b) Define plasma? How plasma produce.Write its two applicatons (4)
Q.NO.4. (a) Derive Van der Waal equation for real gases.
(b) An unknown metal M reacts with S to form a compound with a formula M2S3. If 3.12 g of M
reacts with exactly 2.88 g sulphar. What are the name of metal M and the compound M2S3 (4)
Q.NO.5(a) Derive formula to calculate radius of nth orbit of an atom. (4)
(b) Calculate the number of gram of K2SO4 and water produced when 14g of KOH are reacted with excess
of H2SO4. Also calculate the number of molecules of water produced. (4)

CHAPTER NO 6 - 11
MULTIPLE CHOICE QUESTIONS.
i. During the formation of ammonia by Haber’s process then at low temperature and high
pressure
a. Rate of formation of ammonia is low b. Yield of ammonia is high
c. Rate of formation of ammonia is high d. Both ‘b’ and ‘a’
ii. A buffer solution containing 0.1M each of acetic acid and sodium acetate has pH value at
room temperature.
a. 2.89 b. 4.44 c. 4.74 d. 4.92
iii. For zeotropic mixture the ratio of composition of vapors and liquids is always at any
temperature.
a. Same b. Different c. Same or different d. All a, b and c
iv. If in a same solvent for same quantity, different solutes having same amounts are
dissolved, then value of Kf for different solutions will be
a. Different b. Same c. Same of different d. All a, b and c
v. A solution of glucose is 10% W/V, the volume in which 1g mole of it are dissolved will be
a. 1 dm3 b. 1.8 dm3 c. 200 cm3 d. 900 cm3
vi. Those solutions which can be completely separated by fractional distillation are
a. Completely miscible liquids b. partially miscible liquids
c. Practically immiscible liquids d. All a, b and c
vii. Those metals that react with steam and produce hydrogen gas and oxide are
a. Li, Na, K and Fe b. Fe, Cr, Zn and Mn c. Pb, Sn, Fe and Co d. Cu, Ag, Au and K
viii. A cell which is a source of electricity is
a. Electrochemical b. Nelson cell c. Galvanic cell d. Down’s cell
ix. If energy of activation for a reaction is zero, then reaction is
a. Spontaneous b. Non spontaneous c. Exothermic d. Endothermic
x. If different catalysts are used for same reactants then products will be
a. Different b. Same c. Depend upon reactant d. None
xi. If pKa values difference of two acids is 2 then one acid is how many stronger than other
acid
a. Ten b. Hundred c. Thousand d. None
xii. Which of the following is an example of buffer solution
a. NH4Cl and Ca (OH) 2 b. H2S and HCl c. NH4Cl and NH4OH d. NH4Cl and NH4OH
xiii. Smaller the value of Ksp lesser the capacity of
a. Ionization b. Association c. Precipitation d. All a, b and c
xiv. On hydrolysis AlCl3 produces solution
a. Acidic b. Basic c. Amphoteric d. Neutral
xv. The freshly anodized Al is hydrated and can absorb
a. Oxygen b. Nitrogen c. Dyes d. None
xvi. MgSO4 contains molecules of water of crystallization
a. 2 b. 4 c. 6 d. 7
xvii.1.5/ Ka2 relation is for which order of reaction
a. First b. Second c. Third d. All a, b and c

SectionI Time- 2.40min.

Attempt sixteen short questions from section I and three questions fromsection II
i. How does mixture of acetic acid and sodium acetate give us acidic buffer?
ii. A necessary condition for colligative properties is that solute should be non electrolyte, why?
iii. Why Beckmann’s thermometer is used for determination of depression and elevation in
boiling points?
iv. Explain construction of Lead accumulator.
v. Slow step is known as rate determining step, why?
vi. The unit of rate constant of second order reaction is dm3 mol-1 sec-1, but the unit of rate of
reaction is mol dm-3 sec-1, why?
vii. Why rate constant of a reaction does not change with the passage of time but rate of reaction
is an ever changing parameter?
viii. How Copper can be purified electrolytically?
ix. Discuss SHE.
x. How molecular mass of a solute can be determined from lowering in vapor pressure, derive an
equation.
xi. How solubility of a substance can be determined?
xii. Why solutions show positive and negative deviation from ideal behaviors?
xiii. How can a chemist get maximum yield in a reversible reaction?
xiv. What are conjugate acid and conjugate base
xv. Energy of activation determines the tendency of a reaction to take place, how?
xvi. Explain electrolysis of fused NaCl.
xvii. Write all possible reactions of fuel cell.
xviii. Compare hydration energy of Lithium and potassium ions.
xix. In summer antifreeze solution protect the liquid of radiator for boiling over, how?
xx. Prove that colligative properties depend upon number of solute particles?
xxi. Why ionization energy of VA group more than VIA group.
xxii. Why second ionization energy greater than first ionization energy
Section II
Q.NO.1(a) Write a note on standard electrode potential. (4)
(b) Write name of physical method for determination of rate of chemical reaction. Discuss
any two (4)

Q.NO.2(a)Calculate the PH of a buffer solution in which 0.11 molar CH3COONa and 0.09 molar
CH3COOH solutions are present. Ka for CH3COOH is 1.8 x 10-5. (4)
(b) Derive Arrhenium equation showing relation between rate constant of reaction and energy of activation.
(4)
Q.NO.3(a) Balance the following equations by ion electron method
i. Cu + NO3-1 → Cu+2 + 2NO2 (acidic medium) (4)
-1
ii. CN + MnO4 -1
→ CNO-1 + MnO2 (basic medium)
(b)Define solubility curve? Discuss the type of solubility curve (4)
Q.NO.4(a) Derive Arrhenium equation showing relation between rate constant of reaction and
energy of activation. (4)
(b) N2 and H2 combine to form NH3. The value of Kc at 500 oC is 6.0 x 10-2. Calculate the
numerical value of Kp for this reaction. (4)
Q.NO.5(a) Write a note on bond length (4)
(b) How you determine the enthalpy of reaction by bomb calorimeter. (4)

BOOK TEST FIRST YEAR

Q.NO.1.i. the number of moles of CO2 which contain 8.0 g of oxygen
a. 0.25 b. 0.50 c. 1.0 d. 1.50
ii. The largest number of molecules is present in
a. 3.6 g of water b. 4.8 g of ethanol c. 2.8 g of CO d. 5.4 g of N2O5
iii. The comparative rates at which solutes move in paper chromatography depend on
a. The size of paper b. Rf values of solutes
c. Temperature of the experiment d. Size of chromatographic tank used
iv. Pressure remining constant, at which temperature the volume of a gas will become twice of
what is at OoC.
a. 546oC b. 200oC c. 546K d. 273K
v. The molar volume of CO2 is maximum at
a. STP b. 127oC and 1atm c. 0oC and 2 atm d. 273oC and 2 atm
o
vi. When water freezes at O C, its density decreases due to
a. Cubic structure of ice. b. empty spaces present in structure of ice
c. Change of bond lengths d. Change of bond angles
vii. Diamond is a bad conductor because of
a. It has a tight structure b. it has a high density
c. There are no free electrons d. is transparent to light
viii. The wave number of the light emitted by certain source is 2x 106 m-1. The wavelength of this
light will be
a. 500nm b. 500m c. 200nm d. 5x107 m
ix. Orbitals having same energy are called
a. Hybrid orbitals b. Valence orbitals
c. degenerate orbitals d. d – orbitals
x. The number of bonds in nitrogen molecule is
a. One sigma and one pi b. One sigma and two pi
c. Three sigma only d. two sigma and one pi
xi. Which of the hydrogen halide has the highest percentage of ionic character?
a. HCl b. HBr c. HF d. HI
xii. For a given process, the heat changes at constant pressure qp and at constant volume qv are
related to each other as
a. qp = qv b. qp< qv c. qp> qv d. qp = qv/ 2
xiii. An excess of aqueous of silver nitrate is added to aqueous barium chloride and precipitate is
removed by filtration. What are the main ions in the filtrate?
a. Ag+ and NO3-1 b. Ag+ and Ba+2 and NO3- c. Ba+2 and NO3- d. Ba+2 and NO3- and Cl-
xiv. Which of the following solution has the highest boiling point?
a. 5.85% solution of sodium chloride b. 18% solution of glucose c. 6 % solution of urea d. All
xv. Stronger the oxidizing agent, greater is the
a. Oxidation potential b. Reduction potential c. Redox potential d. E.M.F of cell
xvi. If the rate equation of a reaction 2A + B → product is, rate = {A} 2 {B}, and A is present in
large excess, then order of reaction is
a. 1 b. 2 c. 3 d. 4
xvii. The change in heat energy of a chemical reaction at constant temperature and pressure is
a. Enthalpy change b. Heat of sublimation c. Bond energy d. Internel energy change
SUBJECTIVETime- 3.10 min.

NOTE.. Attempt 8, 8 and 6 short questions from Q.2, Q.3 and Q.4 respectively. Attempt any
three questions from 5, 6, 7, 8 and 9.
Q.NO.2.i. Write two conditions of stoichiometric calculations.
ii. Two grams of H2 and 16g of CH4 at STP occupies volume 22.414dm3, although masses and
sizes of molecules are very different from each other.
iii. Calculate mass of one mole of electrons.
iv. Write four steps for quantitative determination of a substance.
v. Write characteristics of an ideal solvent.
vi. Prove that Charl’s law is only applicable for Kelvin scale.
vii. Why gases show deviation from ideal behaviours?
viii. Derive units of Vander Waal’s constant ‘a’ and ‘b’.ix. Draw figure of glass calorimeter.
x. Why we preferred change in enthalpy as compared to changed in internal energy?
xi. How catalyst effect equilibrium position and equilibrium constant?
xii. Prove that water is a weak electrolyte.’
Q.NO.3.i. why we need Azimuthal quantum number?
ii. Define Moseley’s law, write its applications.

iii. How positive rays are produced? iv. What is fine structure or multiple structures?
v. Why ionic compounds don’t possess 100% ionic character?
vi. Write any two applications of MOT.vii. Define atomic orbital hybridization.
viii. Why first ionization energy of IIIA group elements is lesser as compared to IIA group
elements in same period?
ix. Why b.p of 3rd period hydrides is greater as compared to 4th period hydrides?
x. Amorphous solid like glass is also called supercooled liquid.
xi. Why boiling needs a constant supply of heat?
xii. Cleavage of a crystal is itself anisotropic behaviour. Why?
Q.NO.4.i.Compare hydration energy values of Li, Na and K.
ii. Write two applications of colligative properties.
iii. Why boiling point of a solvent increase due to presence of a solute?
iv. What is a silver oxide battery? v. Define salt bridge, write its functions.
vi. Define specific rate constant or velocity constant of a reaction.
vii.How impure Cu can be purified by electrolytic process?
viii. Rate of a chemical reaction is an ever changing parameter under the given conditions, how?
ix. How a finely divided catalyst may prove more effective.
LONG QUESTIONS.
Q.NO.5.a. Calculate the number of grams of Al2S3 which can be prepared by the reaction of 20g
of Al and 30g of sulphur. How much the non limiting reactant is in excess?
b. Explain followings polymorphism,isomorphism, Habit of a crystal, Transition temperature,.
Q.NO.6.a. Define Dalton’s law of partial pressure, write its applications.
b. Define X-rays, how are they produced?
Q.NO.7.a. Discuss structure of ethene and ethyne according to hybridization.
b. Define following terms with examples. State function, enthalpy, internel energy and boundry.
Q.NO.8.a. Write a note on Raoult’s law.
b. Define electrochemical series, write its three applications.
Q.NO.9.a. What is percentage ionization of acetic acid in a solution in which 0.1 moles of it has
been dissolved per dm3 of solution.
b. How temperature and concentration effect rate of reaction?


BOOK TEST FIRST YEAR GREEN

Q.NO.1. i. During the non stoichiometric reactions one of the reactant is taken in a larger quantity
for purpose
a. To make reaction occur faster b. For completely consumption of expensive reactant
c. How to get maximum yield? d. All a, b and c
ii. The mole of any substance is the Avogadro’s number of
a. Atoms b. Molecules c. Formula units d. All a, b and c
iii. For heating the solution containing inflammable solvent is used for heating purpose
a. Sand bath b. Water bath c. Dessicator d. Both ‘a’ and ‘b’
iv. Existence of an element in more than one crystalline forms is called
a. Polymorphism b. Isomorphism c. Allotropy d. isomerism
v. If absolute temperature of a gas is doubled and the pressure is reduced to one half, the volume
of the gas will be
a. Remains unchanged b. Increases four times c. Reduced to ¼ d. Be doubled
vi. The nature of bonding present in SiC is
a. Metallic b. Electrostatic c. London forces d. Covalent
vii. NH3 shows a maximum boiling point among the hydrides of Vth group elements due to
a. Very small size of nitrogen b. Lone pair of electrons present on N
c. Enhanced E.N character of N d. Pyramidal structure of NH3
viii. The mass of an electron in amu is
a. 1.0087 b. 1.0073 c. 5.4858 x 10-4 d. 9.1095 x 10-31
ix. The velocity of photon is
a. Independent of its wavelength b. Depends on its wavelength
c. Equal to square of its amplitude d. Depends on its source
x.The number of bond in oxygen molecule is
a. 1 sigma & 1 pi b.1 sigma & 2 pi c. 3 sigma & 1 pi d.2 sigma & 2 pi
xi. Which of the following species has unpaired electrons in antibonding molecular orbitals?
a. O2+2 b. N2-2 c. B2 d. F2
xii. Most of the thermodynamic parameters are
a. Spontaneous b. Non spontaneous c. State functions d. All a, b and c
xiii. Equilibrium constant Kc used when the concentration expressed in
xiv. pH value of gastric juice is
a. 2.3 b. 4.6 c. 2.0 d. 6.5
xv. What type of solutions show azeotropic nature
a. Positive deviation b. Negative deviation c. any solution d. Both ‘a’ and ‘b’
xvi. If a salt bridge is not used between two half cells, then the voltage
a. Decrease rapidly b. Decrease slowly c. Does not change d. Drops to zero
xvii. In Haber’s process, the impurity acts as poison
a. HCl b. CO c. As d. All a, b and c
.

SUBJECTIVETime- 2.40 min.
NOTE.. Attempt 8, 8 and 6 short questions from Q.2, Q.3 and Q.4 respectively. Attempt any
three questions from 5, 6, 7, 8 and 9.
2.i. Calculate the number of moles of CO2 which contain 8g of oxygen.
ii. Mg atom is twice heavier than that of carbon atom, how?
iii. How modern spectrograph work?
iv. Differentiate between partition and adsorption chromatography.
v. How crystals can be collected by cooling process?
vi. Write different relations between thermometry scales.
vii. Define one atmosphere, how different units of pressure are related with each other?
viii.Differentiate between natural and artificial plasma.
ix. Define solubility product, write an expression for Ksp for AxBy substance.
x. Colligative properties are studied for molal solutions and not for molar solutions, why?
xi. Define Kb and Kf.xii. Derive a Kc expression for dissociation of N2O4.
3.i. Why iodine is a solid at room temperature, while F2 and Cl2 are gases.
ii. The enthalpies order is as follow &Hs >&Hv >&Hf, why?
iii. How vacuum distillation can be used for the distillation of sensitive liquids?
iv. In the closest packing of metals only 74% space is occupied, why?
v. Write nuclear reactions of slow neutron. vi. Calculate wave number of first three lines in
Balmer series.
vii.Draw and labeled figure showing production of X-rays.
viii. Draw electronic configuration of Cu29 and La 57.
ix. Define upper consulate temperature and critical solution temperature.
x. Why porous plate or a salt bridge is not required in Lead storage cell?
xi. Calculate oxidation states of underlined atoms. Ca (OCl) 2, Fe2 ( SO4) 3.
xii. Write rules for assigning oxidation states.
4. i. Write any two characteristics of rate of reaction. ii. What are pseudo first order reactions?
iii. Prove with examples that catalysts are specific in their actions.
iv. Bond distance is the compromise distance between the two atoms, how?
v. Draw and labeled figure of bomb calorimeter vi. Why qp is greater than qv, prove
mathematically.
vii. Why E.A value of ‘F’ is smaller as compared to ‘Cl’? viii. Write two applications of Lewis model.
ix. Calculate bond energy value for HCl molecule from H2 and Cl2.
LONG QUESTIONS.
5. a. How many water molecules are there in 10g of ice? Also calculate the number
atoms of hydrogen and oxygen separately, the total number of atoms and the covalent bonds
present in the sample. 4
b. Define liquid crystals; write its any four applications. 4
6. a. Define universal constant ‘R’. Derive its values in different units. 4
b. Derive an equation for calculating radius of nth orbit for hydrogen atom.
7.a. Explain nitrogen molecules according to MOT. 4
b. Write a note on Born Haber’s cycle. 4
3
8.a. The solubility of PbF2 is 0.64g/dm . Calculate its solubility product.. 4
b. Define order of reactions; write a note on any three order of reactions. 4
9.a. `Derive an expression for determination of molar mass of a solute from
elevation in boiling point graphically. 4
b. Dfine electrolysis. Write its three applications 4

TEST NO= 1
i- Most of the atoms show diameter in the order of
a. 2 x 10 -10 cmb. 0.1 mc. 10 -10 cmd. 0.2 nm
ii- One mole of SO2 contains
a. 6.02 x 1023 atoms of oxygenb. 6.02 x 1023 atoms of sulphur
c. 1.003x10 23 molecules of SO2d. 3.01x1023 atoms of SO2
iii-In combustion analysis, CO2 produced during the combustion of an organic compound is absorbed in
iv-Isotopes of an element differ in
v- Number of moles of CO2 which contains 8.0 g of oxygen
vi- Which of the following elements has maximum number of isotopes
a. Nib. Cac. Pdd. Sn
vii-Which of the following statements about atom is correct
a. May or may not exist independentlyc. Take part in chemical reaction
b. Made up of more than 100 subatomic particles d. All
viii- Relative atomic mass is the mass of an atom of an element which is obtained after
comparison with mass of
a. Oxygen b. Carbonc. Nitrogend. Chlorine
ix- The mass of one mole of electrons
a. 1.008 mgb. 0.55 mgc. 0.184 mgd. 1.673 mg
x- Which of the following statement is not involved in determination of empirical formula?
a. Determination of %age of each element b. Determination of mole of each element

c. Determination of isotopes of each element d. Determination atomic ratio of element

i- N2and CO has same number of electrons, protons and neutrons. Justify it
ii-What is limiting reactant. How the limiting reactant is identified
iii-Mg is twice heavier than that of carbon atom. How
iv-Define empirical formula. How it is related to molecular formula.
v- Why experimental yield less than theoretical yield.
vi- 23 gram sodium of and 238 gram of Uranium have equal number of atom in them
vii- Write four steps for determining the empirical formula
viii-What is stoichiometry? Give its assumption
ix- Define the following i) Mole ii) Avogadro’s number
x- Define Ion? Differentiate between cation and anion
xi- 180g of glucose and 342 g of sucrose have the same number of molecules but different number of atoms
present in them
xii-Law of conservation of mass has to be obeyed during Stoichiometric calculations.
xiii- Many chemical reactions taking place in our surrounding involves the limit reactants.
xiv- No individual neon atom in the sample of the element has a mass of 20.18a.m.u.
xv-What is the function of electrometer mass spectrometer.

TEST Book1

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THE STAR INSTITUTE SIALKOT CAMPUS

NEAR RESCUE 1122, KATCHERY ROAD SIALKOT

SHORT QUESTIONS (14)

Q2 (a) Define the following (4)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

Q6: a) Calculate number of O atom in 10.037g of CuSO4.5H2O. (2.5)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

Attempt any five questions

CaCO3 → CaO + CO2

a) What is the mass of one mole of aspartame?

b) What is the mass in gram of 10.122 moles of aspartame?

c) How many hydrogen atoms are present in 2.43 g of aspartame?

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

SHORT QUESTIONS (any 15) (30)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

SHORT QUESTIONS (14)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

Q2 (a) Give applications of Dalton’s law of partial pressure. (4)

SHORT QUESTIONS (14)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

Q4: What pressure is exerted by a mixture of 2 g of H2 and 8 g of N2 at 273 K in a 10 dm3

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

Q2 (a) Differentiate between crystalline solids and amorphous solids. (4)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

Q2 (a) Derive formula to calculate radius of nth orbit of an atom. (4)

SHORT QUESTIONS (14)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

SHORT QUESTIONS (14)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

Q2 (a) Write the postulate of molecular orbiral theory (4)

SHORT QUESTIONS (14)

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

iv- A reaction is reversible because

v- Almost forward reaction is complete when value of Kc is

vii- Distillation under very reduced pressure is called as

viii- Extent to H2 + I2→ 2HI can be increased by

ix- Law of mass action was given by

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

x- Equilibrium constant Kc used when the concentration expressed in

ii- What is difference between reversible and irreversible reactions.

iv- A catalyst does not effect the equilibrium constant. Justify it

vi- What is the effect of change in temperature on reversible reaction.

ii- Negative log of ionization constant of water is

iii- Capability of buffer solution to resist a change in its pH is called its

iv- Solubility of KClO3 is suppressed by

v- Which pair ca be used to make a Buffer solution

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)

vii- The ionic product of water is

viii-Solubility product of slightly soluble salt is denoted by ________

ix-The logarithm of reciprocal of hydroxide ion is represented as _________

x- _______ is an example of strong acid.

SHORT QUESTIONS (14)

ii- What is the effect of common ion solubility. Give example

iii- Describe the percentage of ionization of a acid.

iv- Why we need buffer solution.

v- Define conjugate acid and conjugate base.

vi- Calculate the pH of NaOH having concentration 10-4mol dm-3

vii- Define pH and pOH

PREPARED BY: PROF. FAIZ MIRAN (GOVT. MURRAY COLLEGE SIALKOT)