Sheet1

Magma Viscosity Calculation after the method of Shaw (1972) A. J. Sci., 272, 870-893.
input data in yellow
Yi Xi ToC = 800
Oxide Wt. % Mol. Wt. Mol. Prop. Mol. Frac. si o
s io * X SiO2 X i ( s io * X SiO2)
SiO2 49.20 60.09 0.819 0.469
TiO2 2.03 79.88 0.025 0.015 4.5 2.11 0.03
Al2O3 16.10 101.96 0.316 0.181 6.7 3.14 0.57
Fe2O3 2.72 159.70 0.034 0.020 3.4 1.60 0.03
FeO 7.77 71.85 0.111 0.063 3.4 1.60 0.10
MnO 0.18 70.94 0.003 0.001 3.4 1.60 0.00
MgO 6.44 40.31 0.160 0.092 3.4 1.60 0.15
CaO 10.50 56.08 0.187 0.107 4.5 2.11 0.23
Na2O 3.01 61.98 0.049 0.028 2.8 1.31 0.04
K2O 0.14 94.20 0.001 0.001 2.8 1.31 0.00
P2O5 0.23 141.94 0.002 0.001
H2O 0.70 18.02 0.039 0.022 2.0 0.94 0.02

Total 99.02 1.74 1.00 1.17

Units g/100g g/mol mol/100g mol/1 mol

Mean slope (s) = SXi ( sio * XSiO2)/(1-XSiO2) = 2.20

ln h = slope*(104/TK) - 1.50*slope - 6.40 = 10.78 h = 4.79E+03 Pa sec

multiply Pa sec by 10 → poise
Baker (1998) Estimate (applies only to granite/rhyolite between 700-900 oC) J. Str. Geol 20, 1395-1404

h= 9.97E+07 Pa sec SiO2 too low 0.12 ¬ mol fraction H2O from Sheet 2

Hess and Dingwell (1996) Estimate for metaluminous leucogranites Am. Min. 81, 1297-1300

h= 8.13E+07 Pa sec

Page 1
 Calculation of Mol Fraction of H2O on an 8-Oxygen basis after the method of Burnham (1979). In
Yoder, H. S. Jr., (ed.), The Evolution of Igneous Rocks. Princeton University Press, Princeton, N. J., 439-482.

Wt% Ox Mol Wt Mol Prop Cat Prop # anions

SiO2 49.20 60.09 0.819 0.819 1.638
TiO2 2.03 79.90 0.025 0.025 0.051
Al2O3 16.10 101.94 0.158 0.316 0.474
Fe2O3 2.72 159.70 0.017 0.034 0.051
FeO 7.77 71.85 0.108 0.108 0.108
MnO 0.18 70.94 0.003 0.003 0.003
MgO 6.44 40.32 0.160 0.160 0.160
CaO 10.50 56.08 0.187 0.187 0.187
Na2O 3.01 61.98 0.049 0.097 0.049
K2O 0.14 94.20 0.001 0.003 0.001
P2O5 0.23 141.94 0.002 0.003 0.008
H2O 0.70 18.02 0.039 0.039
Anhydrous Totals:
98.32 1.528 1.755 2.729

Xwm £ 0.5:
Me = 311
Mol. Fract. H2O = Xwm/(1-Xwm) = MeWwm*(M.W.H2O*(1-Wwm)) = 0.12

Xwm > 0.5:

Me = 288
DWw = m
-0.05
Mol. Fract. H2O = Xwm/(1-Xwm) = 1 + M'eDWwm*(M.W.H2O*(1-Wwm)) = 0.27

Actual Mol. Fraction H2O: 0.12