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Physics

1. A 25 × 10–3 m3 volume cylinder is filled with 1 mol of O2


gas at room temperature (300 K). The molecular diameter of
O2, and its root mean square speed, are found to be 0.3 nm
and 200 m/s, respectively. What is the average collision rate
(per second) for an O2 molecule?
A. ~ 1012 B. ~1010
C. ~1013 D. ~1011
Ans. A
Explanation: Given that V = 25 × 10–3 m3, N = 1 mole of O2,
T = 300 K, Vrms = 200 m/s
vav
Collision frequency =

8
vav  v
3 rms
8
vav   200
3
RT

2 d2 NP
RT
P
V
V 25  103
  20
2 d2 1.4    9  10
put values, we get, frequency 0.2  1010 / sec

2. A thin disc of mass M and radius R has mass per unit area
σ(r) = kr2 where r is the distance from its centre. Its moment
of inertia about an axis going through its centre of mass and
perpendicular to its plane is :
A. 2MR2/3 B. MR2/6
C. MR2/3 D. MR2/2
1
Ans. A
Explanation: Given that, σ(r) = kr2 where r is the distance
from its centre

Assume a ring of radius r and with dr


dI = (dm)r2
R R
I   dm r 2    2r  dr r
2

0 0
R
 2k  r5 dr
0

 R 6  kR 6
 2k  
 6  3
R
mass of disc M  k  3r 3 dr
0

R 4
M  k2  
 4 
4M
k put the value
2R 4
  4M  6
I  R
3  2R 4 
2 MR 2

3

3. A moving coil galvanometer allows a full scale current of


10–4 A. A series resistance of 2 MΩ is required to convert
the above galvanometer into a voltmeter of range 0-5 V.
Therefore the value of shunt resistance required to convert
the above galvanometer into an ammeter of range 0-10 mA

2
is :
A. 10 Ω B. 500 Ω
C. 100 Ω D. 200 Ω
Ans. (Bonus)
Explanation:
Given that,
i g  104 A= 0.1103mA
V = 5V
R = 2M= 2 106
We know that,
V = i g (G+R)
5 = 0.1103(G+R)
5  104 (G+R)
5  (G+R)
104
(G+R)  5 104
 R=2 106
G =5 104  2 106
G =  195 104 (Negative)
Therefore, the value is negative so not possible.
4. An npn transistor operates as a common emitter amplifier,
with a power gain of 60 dB. The input circuit resistance is
100Ω and the output load resistance is 10 KΩ. The common
emitter current gain β is:
A. 102 B. 104
C. 60 D. 6 × 102
Ans. A
Explanation: Given that
The input circuit resistance = R  100 Ω i

The output load resistance = R  10 K  10 


0
4

3
P 
Power gain  60  10log  0 
 Pi 
P0 R
 106  2 0
Pi Ri
Ri
2  106 
R0
100
 106 
104
2  104
  100
5. A current of 5A passes through a copper conductor
(resistivity = 1.7 × 10–8 Ωm) of radius of cross-section 5 mm.
Find the mobility of the charges if their drift velocity is 1.1 ×
10–3 m/s.
A. 1.0 m2/Vs B. 1.8 m2/Vs
C. 1.5 m2/Vs D. 1.3 m2/Vs
Ans. A
Explanation:
vd E EA
The mobility ()  and resistivity () = 
E J i

Avd 1.1  103    25  106


  
i 5  1.7  108
17.27  101
  1.0 m2 / Vs
1.7

6. In the given circuit, an ideal voltmeter connected across the


10Ω resistance reads 2V. The internal resistance r, of each cell
is:

4
A. 1 Ω B. 0.5 Ω
C. 1.5 Ω D. 0 Ω
Ans. B
Explanation:
For the given circuit,

Given that VAB = 2 V

V 2 1
current i   
R 6 3
1
3
8  2r   3
2r  1
r  0.5 

7. In a meter bridge experiment, the circuit diagram and the


corresponding observation table are shown in figure.

5
Which of the reading is inconsistent?
A. 3 B. 4
C. 2 D. 1
Ans. B
Explanation:
R I

X 100  I
Using the above expression
R(100  I)
X
I
100  40 2000
For case (a) x   
60 3
100  87 8700
For case (b) x   
13 13
10  98.5 1970
For case (c) x   
1.5 3
1 99
For case (d) x   99 
1
Clearly, we can see that the value of x calculate in case (d) is
inconsistent than other cases.

8. Two wires A & B are carrying currents I1 & I2 as shown in


the figure. The separation between them is d. A third wire C
carrying a current I is to be kept parallel to them at a distance x
from A such that the net force acting on it is zero. The possible
values of x are:

6
 I1  I2
A. x  d and x  d
 I1  I2  I1  I2 
I1d
B. x
I1  I2 
 I1  I2
C. x  d and x  d
 I1  I2  I1  I2 
 I   I2 
D. x   2  d and x  
  I  I  
d
 I1  I2   1 2 
Ans. B
Explanation:

F  0
0I1I 0I2I
 0
2x 2  d  x 
0I1 I 0I2 I
 0
2x 2  d  x 
 x  2x
I1 I2

x xd
I1x  I1d  I2x
I1x  I2 x  I1d
x(I1  I2 )  I1d
I1d
x
I1  I2

7
9. One plano-convex and one plano-concave lens of same
radius of curvature 'R' but of different materials are joined side
by side as shown in the figure. If the refractive index of the
material of 1 is μ1 and that of 2 is μ2, then the focal length of
the combination is:

R R
A. B.
2   1  2  2  1  2 
R 2R
C. D.
1  2 1  2
Ans. C
Explanation:
Focal length of plano-convex lens
1 1 1  1  1
  1  1    R
f1   R 

Focal length of plano concave lens


1 2  1

f2 R

For the combination of two lens-


1 1 1 1  1 2  1
   
feq f1 f2 R R
R
Therefore, feq 
1  2

10. A message signal of frequency 100 MHz and peak voltage


100 V is used to execute amplitude modulation on a carrier
wave of frequency 300 GHz and peak voltage 400 V. The

8
modulation index and difference between the two side band
frequencies are:
A. 0.25; 2 × 108 Hz B. 4; 1 × 108 Hz
C. 4; 2 × 108 Hz D. 0.25; 1 × 108 Hz
Ans. A
Explanation: Given that
Frequency of Signal fs = 100 × 106=108, peak voltage Es =
100 V
Frequency of carrier wave fc = 300 × 109 Hz, peak voltage Ec =
400 V
Es 100
modulation index m=   0.25
Ec 400
side band F  Fmax  Fmin
 Fs  Fc   Fc  Fs   2Fs  2  108

11. A cylinder with fixed capacity of 67.2 lit contains helium


gas at STP. The amount of heat needed to raise the temperature
of the gas by 20°C is : [Given that R = 8.31 J mol–1 K–1]
A. 748 J B. 350 J
C. 374 J D. 700 J
Ans. A
Explanation:
capacity of cylinder = 67.2 lit
No. of moles of He at STP= 67.2 = 3
22.4

Q = nCvdT= 3  3R
2  20  90R  90  8.31
= 748 Joule

12. A stationary source emits sound waves of frequency 500


9
Hz. Two observers moving along a line passing through the
source detect sound to be of frequencies 480 Hz and 530 Hz.
Their respective speeds are, in ms–1, (Given speed of sound =
300 m/s)
A. 12, 16 B. 12, 18
C. 16, 14 D. 8, 18
Ans. B
Explanation: Given that, Frequency of sound source (n) = 500
Hz
speed of sound v = 300 m/s
When observer is moving away from the source apparent
frequency is given by
n 500
nA 
v
 v  vA   300  VA   480
300 
480  3
300  VA   288
5
VA  300 – 288  12 m/s
n 500
Similarly, nB 
v
 v  vB   300  VB   530
300 
VB  18 m/s

13. Given below in the left column are different modes of


communication using the kinds of waves given in the right
column?
A. Optical Fibre P Ultrasound
communication
B Radar Q Infrared
Light
C Sonar R Microwaves
D Mobile Phones S Radio
Waves
From the options given below, find the most appropriate

10
match between entries in the left and the right column.
A. A-R, B-P, C-S, D-Q
B. A-S, B-Q, C-R, D-P
C. A-Q, B-S, C-R, D-P
D. A-Q, B-S, C-P, D-R
Ans. D
Explanation:
Optical fibre communication – Infrared Light
Sonar – Ultrasound
Mobile Phones – Microwaves

14. The electric field of a plane electromagnetic wave is given


by E  E ˆi cos kz cos  t 
0

The corresponding magnetic field B is then given by:


A. B  E kˆ sin kz  cos  t  B. B  E ˆj sin kz  sin  t 
0 0

C C
C. B  E 0 ˆj sin kz  cos  t  D. B  E
0 ˆj cos kz  sin  t 
C C
Ans. B
Explanation:
Given that
E  E 0 cos(kz)cos(t)iˆ
E0 
E cos  kz  t  ˆi  cos(kz  t)iˆ  (2 cos A cos B = cos (A +B) +cos (A -B))
2  
Similarly,

11
B0 
B cos(kz  t)ˆj  cos(kz  t)ˆj
2  
B
B  0  2sin kzsin t
2
E 
B   0 sin kzsin t  ˆj
 C 

15. In an experiment, the resistance of a material is plotted as a


function of temperature (in some range). As shown in the figure,
it is a straight line.

One may conclude that:


A. R(T) = R e 0 B. R(T)  R
T2 / T02 0
2
T
–T2 / T02 –T02 / T 2
C. R(T) = R e 0 D. R(T) = R e0

Ans. D
Explanation:
Equation of given line
y   mx  c
m
ln R    c
T2
 T02

If R  R 0e T
2

T02
ln R   2  ln R 0 
T
option (D) satisfies the equation

16. A transformer consisting of 300 turns in the primary and


150 turns in the secondary gives output power of 2.2 kW. If the
current in the secondary coil is 10 A, then the input voltage and
12
current in the primary coil are;
A. 440 V and 20 A B. 440 V and 5 A
C. 220 V and 20 A D. 220 V and 10 A
Ans. B
Explanation:
turns in the primary, n p  300; turns in the secondary, n s  150
is n p

ip ns
ns
 i p  is  5A
np
2.2  103
Ps  Vs is  Vs   220
10
np 300
VP  Vs  220 
ns 150
 440 V

17. In a photoelectric effect experiment the threshold


wavelength of light is 380 nm. If the wavelength of incident
light is 260 nm, the maximum kinetic energy of emitted
electrons will be:
Given E (in eV) = 1237 .
 in nm
A. 3.0 eV B. 1.5 eV
C. 4.5 eV D. 15.1 eV
Ans. B
Explanation:

1237 1237
0  , E of photon
380 260
K  E of electron kE  E  0  1.5 eV

18. The ratio of surface tensions of mercury and water is given


13
to be 7.5 while the ratio of their densities is 13.6. Their contact
angles, with glass, are close to 135° and 0°, respectively. It is
observed that mercury gets depressed by an amount h in a
capillary tube of radius r1, while water rises by the same amount
h in a capillary tube of radius r2. The ratio (r1/r2), is then close
to:
A. 2/3 B. 4/5
C. 2/5 D. 3/5
Ans. C
Explanation: Given that water rises by the same amount h.
So,
hHg  hwater
2T cos 
h
R g
R Hg 2
  0.4
Rw 5

19. A proton, an electron, and a helium nucleus, have the same


energy. They are in circular orbits in a plane due to magnetic
field perpendicular to the plane. Let rp, re and rHe be their
respective radii, then,
A. re < rp < rHe B. re > rp = rHe
C. re < rp = rHe D. re > rp > rHe
Ans. C
Explanation:
Radius of circular path (r) in a perpendicular uniform
magnetic field is given by

14
2 mE
r E  same
Bq
m
r
q
mp m
proton  , He2
qp q
 rp  rHe
me mp
For elecron 
qe qp
 re  rp  rHe

20.A particle of mass m is moving along a trajectory given by


x = x0 + a cos ω1t
y = y0 + b sin ω2t
The torque, acting on the particle about the origin, at t = 0 is
:
A.  m  x b  y a  kˆ
0
2
B. Zero
2 0
2
1

C.  my a kˆ 0
2
1 D. m  x b  y a  kˆ
0 0
2
1

Ans. C
Explanation: A particle of mass m is moving along a
trajectory given by

x  x0  acos 1t
y  y0  b cos 2t
r  xˆi  y ˆj

F  ma  m  a12 cos , tiˆ  b22 sin 2 tjˆ 


 
f  ma2ˆi
t 0 1

rt 0  (x 0  a)iˆ  y ˆj
  r  F  my a2 kˆ 0 1

15
21. The value of acceleration due to gravity at Earth's surface is
9.8 ms–2. The altitude above its surface at which the
acceleration due to gravity decreases to 4.9 ms–2, is close to :
(Radius of earth = 6.4 × 106 m)
A. 6.4 × 106 m B. 2.6 × 106 m
C. 1.6 × 106 m D. 9.0 × 106 m
Ans. B
Explanation: Given that, of acceleration due to gravity at
Earth's surface = 9.8 ms–2
gsurface
g height   4.9m / s 2
2
g g
gh  2
, gh 
 h  2
1  
 Re 
2
 h 
1   2
 Re 
h
1  2
Re
h  Re  2 1 
h = 6400 × 0.414
h = 2649.6 km
h = 2.6 × 106 m

22. Two particles, of masses M and 2M, moving, as shown, with


speeds of 10 m/s and 5 m/s, collide elastically at the origin.
After the collision, they move along the indicated directions
with speeds v1 and v2, respectively. The values of v1 and v2 are
nearly:
16
A. 3.2 m/s and 12.6 m/s B. 3.2 m/s and 6.3 m/s
C. 6.5 m/s and 6.3 m/s D. 6.5 m/s and 3.2 m/s
Ans. C
Explanation:
Apply conservation of linear momentum in X and Y direction
for the system then
M(10cos 30°) + 2M(5 cos 45°) = 2M (v1 cos 30°) + M(v2 cos
45°)
v2
5 3  5 2  3 v1  ...(i)
2
Also
2M(5 sin 45°) – M(10 sin 30°) = 2M v1 sin 30° - Mv2 sin 45°
v2
5 2  5  v1  ...(2)
2
Solving equation (1 and 2)
 
3  1 v1  5 3  10 2  5  v1  6.5m / s
v2 = 6.3 m/s

23. A ray of light AO in vacuum is incident on a glass slab at


angle 60° and refracted at angle 30° along OB as shown in the
figure. The optical path length of light ray from A to B is:

17
2 3
A. 2a + 2b B.  2b
a
2b 2b
C. 2a  D. 2a +
3 3
Ans. A
Explanation:

From the given figure


a b sin60
AC = , BC  ,
cos 60 cos 30 sin30
path AC  BC
 2a  2b

24. Figure shows charge (q) versus voltage (V) graph for series
and parallel combination of two given capacitors. The
capacitance are:

A. 50 μF and 30 μF B. 40 μF and 10 μF
C. 20 μF and 30 μF D. 60 μF and 40 μF

18
Ans. B
Explanation:
C1 C 2 q 80
Equivalent capacitance in series,  C '     8  106
C1  C2 V 10
q 500
Equivalent capacitance in parllel,  C ''  C1  C2    50  106
V 10
Now, C ''  C '
500
C1  C 2   50F
10
CC 80
and 1 2   8F
C1  C 2 10
 C1C 2  400 F
Solving C1 = 40 μF C2 = 10 μF

25. A ball is thrown upward with an initial velocity V0 from the


surface of the earth. The motion of the ball is affected by a drag
force equal to mγv2 (where m is mass of the ball, v is its
instantaneous velocity and ν is a constant). Time taken by the
ball to rise to its zenith is:
   
A. 1 tan   V 
1
0
B. 1 tan  2 V  1
0
g  g  2g  g 
1    1   
C. sin1 
 g
V0 

D. in 1  V0 
g   g  g 

Ans. A
Explanation:
Retardation of the particle is given by

19
dv

a   g  v2   dt
v dv t

v0 g  v2
  0 dt
By int egrating
1   
t tan1  V0 
g  g 

26. A uniformly charged ring of radius 3a and total charge q is


placed in xy-plane centred at origin. A point charge q is
moving towards the ring along the z-axis and has speed v at z =
4a. The minimum value of v such that it crosses the origin is :
1/2 1/2
2  1 q2  2  2 q2 
A.   B.  
m  5 40a  m  15 40a 
1/2 1/2
2  1 q2  2  4 q2 
C.   D.  
m  15 40a  m  15 40a 
Ans. B
Explanation:

The minimum velocity (v) should just sufficient to reach the


point charge at the center, therefore
1 2 Kq2 Kq2
mv  PE  Uf  Ui  
2 3a 5a
2
2kq

15 a
4 kq2
v
15m a

27. Two coaxial discs, having moments of inertia I1 and I1/I2,


20
are rotating with respective angular velocities ω1 and ω1/2,
about their common axis. They are brought in contact with
each other and thereafter they rotate with a common angular
velocity. If Ef and Ei are the final and initial total energies, then
(Ef –Ei) is:
2
A. I  1 1
B. 3 I  1
2
1
6 8
I 2 I112
C. – 1 1 D. –
12 24
Ans. D
Explanation:
By applying conservation of angular momentum Li = LF

(I1 + I 2 )common  I11  I 2 2


51
after putting value, we get c 
6
1 1 1
Loss in K.E.  ( I121  I 2 2 2 )  (I1 + I 2 )2 common
2 2 2
I112
KE  
24

28. n moles of an ideal gas with constant volume heat capacity


CV undergo an isobaric expansion by certain volume. The ratio
of the work done in the process, to the heat supplied is :
A. nR B. nR
CV  nR C V  nR
4nR 4nR
C. D.
CV  nR C V  nR
Ans. A
Explanation:
For Isobaric process
Work done (W) = nRΔT
and Heat given (Q) = nCPΔT

21
W R R
  
Q CP CV  R

29. Two radioactive materials A and B have decay constants


10λ and λ, respectively. If initially they have the same number
of nuclei, then the ratio of the number of nuclei of A to that of
B will be 1/e after a time.
A. 1 B. 11
10  10 
1 1
C. D.
9 11 
Ans. C
Explanation: Given that,
decay constant of Two radioactive material A=10λ
and decay constant of Two radioactive material B=λ

1  10 , 2  
N1 e 10 t
 t  e9t  e1
N2 e
1
t
9

30. The displacement of a damped harmonic oscillator is given


by
x(t) = e–0.1t cos (10 πt + ϕ). Here t is in seconds.
The time taken for its amplitude of vibration to drop to half
of its initial value is close to :
A. 4 s B. 13 s
C. 7 s D. 27 s
Ans. C
Explanation:
22
The displacement of a damped harmonic oscillator is given by
x(t) = e–0.1t cos (10 πt + ϕ). Here t is in seconds
A0
 A 0e 0.1t
2
t  10ln 2 
 7 sec

Chemistry

31. Increasing rate of SN1 reaction in the following compounds


is:

A. (B) < (A) < (D) < (C) B. (A) < (B) < (C) < (D)
C. (A) < (B) < (D) < (C) D. (B) < (A) < (C) < (D)
Ans. D
Explanation:
The rate of SN1 is decided by the stability of carbocation
formed in the rate determining step.

32. Amylopectin is compound of:


A. α-D-glucose, C1 – C4 and C1 – C6 linkages
B. β-D-glucose, C1 – C4 and C1 – C6 linkages
C. β-D-glucose, C1 – C4 and C2 – C6 linkages
D. α-D-glucose, C1 – C4 and C1 – C6 linkages
Ans. A
Explanation:

23
It is fact base question.

33. Ethylamine (C2H5NH2) can be obtained from N-


ethylphatalimide on treatment with:
A. CaH2 B. H2O
C. NaBH4 D. NH2NH2
Ans. D
Explanation:
N-ethyl phthalimide on treatment with
NH2 —NH2 gives ethylamine.

34. The isoelectronic set of ions is:


A. F–, Li+, Na+ and Mg2+ B. Li+, Na+, O2– and F–
C. N3–, O2–, F– and Na+ D. N3–, Li+, Mg2+ and O2–
Ans. C
Explanation:
Isoelectronic species are those which have same no. of electron
in total. Atomic numbers of N, O, F and Na are 7, 8, 9 and 11
respectively. Therefore, total number of electrons in each of. N3–
, O2–, F– and Na+ is 10 and hence they are isoelectronic

35. The regions of the atmosphere, where clouds form and


where we live, respectively, are:
A. Stratosphere and Stratosphere
B. Stratosphere and Troposphere
C. Troposphere and Stratosphere
D. Troposphere and Troposphere
Ans. D
Explanation:

24
The lowest region of atmosphere in which human beings live is
troposphere. It extends up to a height of 10 km from sea level.
Clouds are also formed in this layer.

36. Consider the hydrated ions of Ti2+, V2+, Ti3+, and Sc3+. The
correct order of their spin-only magnetic moments is:
A. Sc3 + < Ti3 + < V2+ < Ti2+
B. Sc3 + < Ti3 + < Ti2+ < V2+
C. Ti3 + < Ti2 + < Sc3+ < V2+
D. V2 + < Ti2 + < Ti3+ < Sc3+
Ans. B
Explanation:
As we know that
  n n  2 

where n = no. of impaired electrons i.e. greater the no. of


impaired electron more will be the spin-only magnetic
moments.
Electronic configuration
Sc3+ (Z = 21) 1s22s22p63s23p6
Ti2+ (Z = 22) 1s22s22p63s23p63d2
Ti3+ (Z = 22) 1s22s22p63s23p63d1
V2+ (Z = 23) 1s22s22p63s23p63d3
Ti2+ = 3d2 ∴ n = 2
Ti3+ = 3d1 ∴ n = 1
V2+ = 3d3 ∴ n = 3
Sc3+ = 3d0 ∴ n = 0
The correct order of spin only magnetic moments is
V2+ > Ti2+ > Ti3+ > Sc3

25
37. Consider the statements S1 and S2
S1: Conductivity always increases with decrease in the
concentration of electrolyte.
S2: Molar conductivity always increases with decrease in
the concentration of electrolyte. The correct option among
the following is:
A. Both S1 and S2 are wrong
B. S1 is correct and S2 is wrong
C. Both S1 and S2 are correct
D. S1 is wrong and S2 is correct
Ans. D
Explanation:
Conductivity always increase with increase in concentration of
electrolyte.
But, molar conductivity increase with concentration of
electrolyte.

38. Consider the following table:


Gasa/(k Pa dm6 mol–1) b/(dm3 mol–1)
A 642.32 0.05196
B 155.21 0.04136
C 431.91 0.05196
D 155.21 0.4382
a and b are vander Waals constants. The correct statement
about the gases is:
A. Gas C will occupy more volume than gas A; gas B will
be more compressible than gas D
B. Gas C will occupy lesser volume than gas A; gas B will
be more compressible than gas D
26
C. Gas C will occupy lesser volume than gas A; gas B will
be lesser compressible than gas D
D. Gas C will occupy more volume than gas A; gas B will
be lesser compressible than gas D
Ans. A
Explanation:

39. Major products of the following reaction are:

A. B.
C. CH3OH and HCO2H D.
Ans. B
Explanation:
Aldehydes with α – Hydrogen give cross cannizaro reaction.
It is example of cross cannizaro reaction
HCHO acts as hydride donor because it gives less sterically
hindered tetrahedral Intermediat

27
40. The major product of the following reaction is:

A.
B. CH3CH=CH–CH2NH2

C.
D.
Ans. D
Explanation:
OH OH
| ||
CH3  CH  CH 2  CH 2  NH 2  H  C  OH
OH O
|| ||
 CH3  CH  CH 2  CH 2  NH  C  H

28
41. The correct order of catenation is:
A. C > Sn > Si  Ge B. Si > Sn > C > Ge
C. C > Si > Ge  Sn D. Ge > Sn > Si > C
Ans. C
Explanation:
The property of order of catenation of 14th group elements is
based on bond enthalpy. The decreasing order of bond enthalpy
values is
Bond enthalpy C  C  Si  Si  Ge  Ge  Sn  Sn
348 297 260 240
kJ/mol kJ/mol
∴ Decreasing order of catenation is
C > Si > Ge  Sn

42. A bacterial infection in an internal wound grows as N'(t) =


N0 exp(t), where the time t is in hours. A does of antibiotic,
taken orally, needs 1 hour to reach the wound. Once it
reaches there, the bacterial population goes down as dN/dt =
–5N2. What will be the plot of N0/N vs. t after 1 hour?

A. B.

C. D.
Ans. A
Explanation:
When drug is administered bacterial growth is given by
dN
 5N 2
dt
29
N0 N
  1  5t N 0 . Thus 0 increases linearly with t.
Nt Nt

43. Consider the following statements.


(a) The pH of a mixture containing 400 mL of 0.1 M H2SO4
and 400 mL of 0.1 M NaOH will be approximately 1.3
(b) Ionic product of water is temperature dependent.
(c) A monobasic acid with Ka = 10–5 has pH = 5. The degree
of dissociation of this acid is 50%.
(d) The Le Chatelier's principle is not applicable to
common-ion effect.
The correct statements are:
A. (a) and (b) B. (a), (b) and (c)
C. (a), (b) and (d) D. (b) and (c)
Ans. B
Explanation:
(a) H 2SO 4 +2NaOH 
 Na 2SO 4 +2H 2O
Initially 40 m mole 40 m mole
Finally 20 m mole 0 20 m mole
20 103 10  2
 H   
800
1
 H   
20
1
 log  H    ...... ....  log
20
pH  log 20
pH  1.3 approximately
(b) kw depends on temperature kw ↑ with temperature↑

30
(c) pH  5
 H   c  105
c2
Ka 
1   
[H ] 
ka 
1   
105  
105 
1
 1  2
   0.5

(d) Le Chatelier’s principle is applicable to common-ion effect


because commonion effect is itself depend on le chatelier's
principle
So, option B is correct.

44. The alloy used in the construction of aircrafts is:


A. Mg-Zn B. Mg-Al
C. Mg-Sn D. Mg-Mn
Ans. B
Explanation:
The alloy used in the construction of aircrafts is Mg-Al

45. A gas undergoes physical adsorption on a surface and


follows the given Freundlich adsorption isotherm equation x/m
= kp0.5
Adsorption of the gas increase with:
A. Decrease in p and increase in T
B. Increase in p and decrease in T
C. Decrease in p and decrease in T
D. Increase in p and increase in T
Ans. B
31
Explanation:
The given Freundlich adsorption isotherm equation. it is
applicable for physical adsorption. adsorption of the gas
increases with increase of pressure and decrease of
temperature.

46. A process will be spontaneous at all temperatures if:


A. ΔH < 0 and ΔS > 0 B. ΔH < 0 and ΔS < 0
C. ΔH > 0 and ΔS < 0 D. ΔH > 0 and ΔS > 0
Ans. A
Explanation:
At constant P and T and for the process to be spontaneous.
We should have ΔG = –ve
and we know that
ΔG = ΔH – TΔS
If ΔH = –ve and ΔS = + ve then at all the temperature the
process will be spontaneous.

47. At 300 K and 1 atmospheric pressure, 10 mL of a


hydrocarbon required 55 mL of O2 for complete combustion,
and 40 mL of CO2 is formed. The formula of the
hydrocarbon is:
A. C4H7Cl B. C4H6
C. C4H8 D. C4H10
Ans. B
Explanation:
 y 4
C0x H4 (g)   x   O2 
 xCO2 (g) H2O( )
 4 2
10 mL 55 mL 40

Hence.
1 mL of hydrocarbon = x mL of CO2 is produced
According to question
32
10 mL ... ..... = 10 x mL of CO2
∴ 10 x = 40 mL
x=4
xy
  mL of O 2 is required  x mL of CO 2
 4 
x
55 mL mL .. .. .. ..   55 mL of CO 2
 y
x  
 4
According to question
x
  55  40
 y
x  
 4
 55 x  40 x  10 y
 15 x  10 y
15  4  10y
60
 y
10
6y
Hence the compound is C 4 H 6

48. The principle of column chromatography is


A. Gravitational force.
B. Capillary action.
C. Differential adsorption of the substances on the solid
phase.
D. Differential absorption of the substances on the solid
phase.
Ans. C
Explanation:
The principle of column chromatography is differential
adsorption of substance.

33
49. At room temperature, a dilute solution of urea is prepared by
dissolving 0.60 of urea in 360 g of water. If the vapour pressure
of pure water at this temperature is 35 mm Hg, lowering of
vapour pressure will be. (Molar mass of urea=60g mol–1)
A. 0.031 mmHg B. 0.017 mmHg
C. 0.028 mmHg D. 0.027 mmHg
Ans. B
Explanation:
0.6 360
x urea   0.01 x H2O   20
60 18
0.01
x urea   0.5  103
20  0.1
3
  P  xpO H2O  0.5  10  0.175 mm of hg

50. The major product of the following reaction is:

A. B.

C. D.
Explanation:
In acidic medium Based on structure it may as following SN1
(or) SN2 pathway.

34
51. The species that can have a trans-isomer is:
(en = ehane-1, 2-diamine, ox = oxalate)
A. [Cr(en)2(ox)]+ B. [Pt(en)Cl2]
C. [Pt(en)2Cl2]2+ D. [Zn(en)C12]
Ans. C
Explanation:
[Pt(en)2Cl2]2+can have a trans-isomer

52. Three complexes,


[CoCl(NH3)5]2+ (I),
[Co(NH3)5H2O]3+ (II) and
[Co(NH3)6]3+(III)
absorb light in the visible region. The correct order of the
wavelength of light absorbed by them is:
A. (III) > (I) > (II) B. (III) > (II) > (I)
C. (I) > (II) > (III) D. (II) > (I) > (III)
Ans. C
Explanation:
In a co-ordination compound, the strong field ligand causes
higher splitting of the d-orbitals. Wavelength of the energy
absorbed by the coordination compound is inversely
proportional to ligand field strength of the given coordination

35
compound. The decreasing order of ligand field strength is NH3
> H2O > Cl.
Therefore decreasing order of wavelength absorbed is (I) > (II)
> (III).

53. Match the refining methods (Column I) with metals


(Column II).
Column I Column II
(Refining (Metals)
methods)
(I) Liquation (a) Zr
(II) Zone (b) Ni
Refining
(III) Mond (c) Sn
Process
(IV) Van (d) Ga
Arkel
Method
A. (I)-(c) ; (II)-(a) ; (III)-(b) ; (IV)-(d)
B. (I)-(c) ; (II)-(d) ; (III)-(b) ; (IV)-(a)
C. (I)-(b) ; (II)-(d) ; (III)-(a) ; (IV)-(c)
D. (I)-(b) ; (II)-(c) ; (III)-(d) ; (IV)-(a)
Ans. B
Explanation:
Mond’s process is used for refining of Ni, Van Arkel method is
used for Zr, Liquation is used for Sn and zone refining is used
for Ga. So, correct match is
(I)-(c) ; (II)-(d) ; (III)-(b) ; (IV)-(a)

54. The major product of the following reaction is:


36
A. B.

C. D.
Ans. A
Explanation:
It is SN1 reaction mechanism is favourable hence reaction
complete via SN1 mechanism

55. During the change of O2 to O , the incoming electron goes



2

to the orbital:
A. σ*2pz B. π2py
C. π*2px D. π2px
Ans. C
Explanation:
According to Molecular Orbital Theory
For O2 and O we follow this

2

37
O2   /S2 ,  /1S2 ,  * 2S2 , 2p2z , 2p2x  2p2y
 * 2p1x   * 2p1y  * 2pz
O–2   /S2 , */S2 2S2  * 2S2 2S2z 2p2z 2p2x  2p2y
 * 2p2x   * 2p1y  * 2pz

56. The synonym for water gas when used in the production of
methanol is:
A. fuel gas B. laughing gas
C. syn gas D. natural gas
Ans. C
Explanation:
The synonym for water gas is syn gas. Water gas is a mixture of
carbon monoxide and hydrogen (not water). It is produced
when steam is passed over red-hot coke (carbon). Water
gas is so named because water (steam) is the usual source
for its production. Both CO and H2 are inflammable gases,
and so water gas is used as a fuel.

57. The oxoacid of sulphur that does not contain bond between
sulphur atoms is:
A. H2S2O7 B. H2S2O3
C. H2S4O6 D. H2S2O4
Ans. A
Explanation:

2
58. The graph between |  | and r (radial distance) is shown
below. This represents:
38
A. 3s orbital B. 2s orbital
C. 2p orbital D. 1s orbital
Ans. B
Explanation:
The given probability density curve is for 2s orbital because it
has only one radial node. Among other given orbitals, 1s and
2p do not have any radial node and 3s has two radial nodes.

Hence, option B is correct.

59. The increasing order of the reactivity of the following


compounds towards electrophilic aromatic substitution
reactions is:

A. III < II < I B. III < I < II


C. II < I < III D. I < III < II
Ans. B
Explanation:

39
CH3 group when bonded to benzene increases the electron
density of benzene by +I and hyperconjugation effects and
hence makes the compound more reactive towards electrophilic
aromatic substitution. Cl group decreases the electron density
ofvbenzene by –I effect, and CH3CO group strongly decreases
the electron density of benzene by –I and –R effects. Therefore,
correct increasing order the given compounds towards
electrophilic aromatic substitution is

60. Which of the following is a condensation polymer?


A. Neoprene B. Buna-S
C. Nylon 6, 6 D. Teflon
Ans. C
Explanation:
Nylon 6, 6 is obtained by condensation polymerisation of
hexamethylenediamine and adipic acid.
H2N–(CH2)6 NH2 + HOOC–(CH2)4–COOH
Hexamethylene Adipic acid
diomine

Other polymers given, i.e., Buna-S, Teflon and Neoprene are


addition polymers.

40
Mathematics

61. The region represented by |x – y| ≤ 2 and |x + y| ≤ 2 is


bounded by a:
A. rhombus of area 8√2 sq. units
B. square of side length 2√2 unit
C. square of area 16 sq. units
D. rhombus of side length 2 units
Ans. B
Explanation:
Given that |x - y| ≤ 2 and |x + y| ≤ 2

Length of side = 22  22  2 2

62. All the pairs (x, y) that satisfy the inequality


1
sin2 x  2 sin x  5
2 .  1 also satisfy the equation
2
4sin y

A. sin x = |sin y| B. sin x = 2 sin y


C. 2 sinx = sin y D. 2|sinx| = 3 sin y
Ans. A
Explanation:
Given that,
sin2 x  2 sin x  5 1
2 . sin2 y
1
4
3
2
So,
41
It is true only if sin x = 1 and |sin y| = 1

63. If α and β are the roots of the quadratic equation, x2 + x


12 12
 
sinθ – 2 sinθ = 0,    0,   , then is equal to:
 2      .   
12 12 24

212 26
A. B.
 sin     sin   
6 12

212 212
C. D.
 sin     sin   4
12 12

Ans. C
Explanation: Given that
x2  x sin – 2 sin  0
has two roots α and β. Now
Sum of roots
     sin 
Product of roots

  2 sin 
  
12
12  12
Now, 
   
24
 1 1 
 
24

 12 12  .   
 
  
12


  
12
2
    4
12
  
 
     2  4 
 
Putting values from above
12
 2 sin  
 2 
 sin   8 sin  

42
  2sin  
12 
=  12 
 sin   sin   8  
 
212

 sin   8
12

64. If a > 0 and z  1  i


2
2
, has magnitude , then z is equal to :
ai 5
1 3 1 3
A.   i B.   i
5 5 5 5
1 3 3 1
C.  i D.   i
5 5 5 5
Ans. B
Explanation: Given that
1  i
2
(1  i)2 a  i (1  1  2i) 2ai  2
z     2
ai ai ai a2  1 a 1
magnitude
2 2
 2   2a  4(1  a2 )
|z|  a2  1    a2  1  
    (a2  1)2
2 2

5 a2  1
(squaring both side)
2 4

5 1  a2
a3
2i 3  i
 z
10
1  3i

5
65.If y = y(x) is the solution of the differential equation dy/dx =
(tanx – y) sec2x, x ∈ (–π/2, π/2), such that y (0) = 0,then y(–π/4)
is equal to:
A. 1/2 – e B. e – 2
C. 2 + 1/e D. 1/e – 2
43
Ans. B
Explanation: Given differential equation is
dy
  tan x  y  sec2 x
dx
dy
 y sec2 x  tan x sec2 x
dx
Let tan x  t
dt
 sec2 x 
dx
dy
  y  t This is a Linear differrential equation
dt
Now, If  e 
sec2  dx
 etan x  et
y.et   et  dt
Now, solution
y e t  e t  t  1  c
 y   tan x  1  ce  tan x
y(0)  0  c 1
y  tan x  1  e  tan x
 
So, y     e  2
 4

66. If the length of the perpendicular from the point (β, 0, β) (β


≠ 0) to the line, x  y  1  z  1 is 3 , then β is equal to
1 0 1 2
A. 2 B. 1
C. –2 D. –1
Ans. D
Explanation:

44
x y 1 z 1
  
1 0 1
A point on this line is A  0, 1,  1
AC . BC  0
1
we get   
2
 1 1
 C    ,1,  
 2 2
2
| BC | 
3
2 2
 1 2  1 2
   2   (1)     2   3
   
   0, 1
  1     

67.If
x sinθ cosθ x sin2θ cos2θ
1 = -sinθ -x 1 and 2 = -sin2θ -x 1 , x  0;
cosθ 1 x cos2θ 1 x
 
then for all    0,  :
 2
A. Δ1 – Δ2 = x(cos2θ – cos 4θ)
B. Δ1 + Δ2 = –2x3
C. Δ1 + Δ2 = –2(x3 + x – 1)
D. Δ1 – Δ2 = –2x3
Ans. B
Explanation: Given That
x sinθ cosθ
1 = -sinθ -x 1
cosθ 1 x
= x (–x2 – 1) – sin θ (–x sin θ – cos θ) + cos θ (–sin θ + x cos θ)
= x3 - x + x sin2 θ + sin θ cos θ – cos θ sin θ + x cos2 θ
= -x3 – x + x (sin2θ + cos2θ) = - x3 – x + x

45
⟹ – x3
Similarly Δ2 = -x3
Now, Δ1 + Δ2 = - x3 – x3 –2x3

68. Assume that each born child is equally likely to be a boy or


a girl. If two families have two children each, then the
conditional probability that all children are girls given that at
least two are girls is:
A. 1/10 B. 1/17
C. 1/11 D. 1/12
Ans. C
Explanation:

Required probability = 1/11.

69. Which one of the following Boolean expressions is a


tautology?
A. p  q  ~ p  ~ q B. p  q  p  ~ q
C. p  q  p  ~ q D. p  q  p  ~ q
Ans. B

46
Explanation:
From options
p  q  p  ~ q  p  q  ~ q  tautology

70. Let f(x) = x2, x ∈ R. For any A  R, define g (A) = {x ∈ R :


f(x) ∈ A}. If S = [0,4], then which one of the following
statements is not true ?
A. g(f(S)) ≠ S B. f(g(S))= S
C. f(g(S)) ≠ f(S) D. g(f(S)) =g(S)
Ans. D
Explanation:
Given that.
f(x) = x2, x ∈ R.
g (A) = {x ∈ R : f(x) ∈ A} and S = [0,4]
g(s) = {x ∈ R : f(x) ∈ S}
= {x ∈ R : 0 ≤ x2 ≤ 4}
= {x ∈ R : -2 ≤ x ≤ 2}

g(S) = [–2, 2]
f(g(S)) = [0,4] = S
f(S) = [0, 16] ⟹ f(g(S)) ≠ f(S)
g(f(S)) = [–4, 4] ≠ g(S)
Therefore, g(f(s)) = g(s) is not true.

x4 1 x3  k3
71. If lim  lim 2 , then k is :
x 1 x  1 x k x  k 2
3 8
A. B.
2 3
3 3
C. D.
8 8
Ans. B
47
Explanation:
x4 1
lim
x 1 x  1

(x 2 ) 2  1)
 lim
x 1 x 1
(x  12 )(x 2  1)
2
 lim
x 1 (x  1)
(x  1)(x  1)(x 2  1)
 lim
x 1 (x  1)
 lim (x  1)(x 2  1)  4 ...  i 
x 1

x3  k3
lim 2
x k x  k 2

k2  k2  k2

2k
2
3k

2k
3k
 ...  ii 
2
Then,
from  i    ii 
3k
4
2
8  3k
8
 k
3

72.If a directrix of a hyperbola centred at the origin and passing


through the point (4, –2 √3) is 5x = 4√5 and its eccentricity is e,
then:
A. 4e4 – 24e2 + 27 = 0 B. 4e4 – 24e2 + 35 = 0
C. 4e4 – 12e2 – 27 = 0 D. 4e4 + 8e2 – 35 = 0
Ans. B
Explanation:
2 2
Let hyperbola be x  y  1 and Points (4, –2√3) passes through
a2 b2

48
therefore
 2 3 
2
2
(4)
2
 2
1
a b
16 12

a2 b2
1 i  
 b2  a2 e2  1

Given 5x = 4√5
4 5 a
x 
5 e
Squaring both sides, we get,
16
 a  e 2
... ii 2

5
on solving equations i and ii
 4e4  24e2  35  0

 sin p  1 x  sin x
 , x0
 x

73. If f(x)   q , x0 is continuous at x = 0,

 x  x2  x
, x0

 x3/2
then the ordered pair (p, q) is equal to:
A.   3 ,  1  B.   1 , 3 
 2 2  2 2
 3 1 5 1
C.  2 , 2 D. 2, 2
   
Ans. C
Explanation:
 sin p  1 x  sin x
 , x0
 x

f(x)   q , x0

 x  x2  x
, x0

 x3/2
is continuous at x = 0,
So, f(0-) = f(0) = f(0+) …(i)

49
x  x2  x
RHL  f (0 ) lim
x 0 x 3/2
1  x 1 1
 lim 
x 0 x 2
sin  p  1 x  sin x
LHL  f (0 )  lim
x 0 x
  p  1  1
 p2
from equations (i)
LHL  RHL  f (0)
1 1 3
P  2  q  , so, q  and P  
2 2 2
 3 1
  p, q     , 
 2 2

74. If the coefficients of x2 and x3 are both zero, in the


expansion of the expression (1 + ax + bx2) (1 – 3x)15 in powers
of x, then the ordered pair (a,b) is equal to:
A. (28, 861) B. (28, 315)
C. (–21, 714) D. (–54, 315)
Ans. B
Explanation:

50
(1  ax  bx2 ) (1  3x)15
Coefficient of,
x3  1. 15C (3)2  a. 15C (3)  b. 15C 15 C  9  3a(15C )  0
2 1 0 2 1
15
 C  9  45a  b
2
 945  459  b = 0...........(i)
Coefficient of,
x3 15 C (3)3  a. 15C (3)2  b. 15C (3)  0
2 2 1
15 15
 27  C  9a  C  3b  C  0 15
3 2 1
 273  21a  b  0.........(ii)
Then,
from (i) + (ii)
 945  459  b+(  273)+21a  b = 0
 945  459  b +(  273)+21a  b = 0
  24a + 672 = 0
 a = 28
 b = 315

75. If the circles x2 + y2 + 5Kx + 2y + K = 0 and 2(x2 + y2) +


2Kx + 3y –1 = 0, (K∈R), intersect at the points P and Q, then
the line 4x + 5y – K = 0 passes through P and Q, for:
A. exactly two values of K
B. no value of K.
C. exactly one value of K
D. infinitely many values of K
Ans. B
Explanation: Given,
S1= x2 + y2 + 5Kx + 2y + K = 0

S2 = 2(x2 + y2) + 2Kx + 3y –1 = 0


Equation of common chord
S1  S2  0
1 1
4kx  y  k   0 ..  i 
2 2
given 4x + 5y – k = 0 ...(ii)
51
On comparing (i) & (ii) we get
4k 1 2k  1
 
4 10 2k
1 k 1/2
k 
10 k
5
k
11
⟹ No. real value of k exist

76. The sum  3


3  13 5  1  2

3


7  13  23  33 
 ...... upto 10th
12 12  22 12  22  32
term is :
A. 660 B. 680
C. 600 D. 620
Ans. A
Explanation: Given that
10
6n 2 (n  1) 2 10
3n(n  1)
S   (2n  1)   660
n 1 4n(n  1)(2n  1) n 1 2

77. Let f : R → R be differentiable at c ∈R and f(c) = 0. If g(x)


= |f(x)|, then at x = c, g is:
A. differentiable if f ' (c) = 0
B. differentiable if f ' (c) ≠ 0
C. not differentiable
D. not differentiable if f ' (c) = 0
Ans. A

52
Explanation:
f : R → R be differentiable at c ∈R and f(c) = 0. If g(x) = |f(x)|
| f  c  h  |  | f (c) |
g '(c)  lim
h 0 h
| f c  h  |
 lim
h 0
 f (c)  0 
h
f  c  h   f (c) | h |
 lim .
h 0 h h
 f (c)  0 
f  0  h   f (0) | h |
 lim .
h 0 h h
|h|
 lim | f '(c) | 0
h 0 h
if f ' (c)  0

That is, g (x) x = c if f '(c) = 0 is different.

78. If Q(0, –1 –3) is the image of the point P in the plane 3x – y


+ 4z = 2 and R is the point (3, –1, –2), then the area (in sq.
units) of ΔPQR is :
A. 65 B. 2 13
2
91 91
C. D.
2 24
Ans. C
Explanation: Given, Plane 3x – y + 4z = 2 and P(3, -1, -2)

53
Image of Q in plane
x  0 y  1 z  3 2(1  12  2)
  
3 1 4 9  1  16
x  3, y  2, z  1
P 3, 2,1 , Q 3, 2,1 , R 3, 2,1
Now area of ΔPQR
i j k
1  
1
Area  PQR   PQ QR  3  1 4
2 2
3 0 1
1

2
i(1)  j(3  2)  K(3)

1
2
 1  81  9 
91

2

dx   x  1 f(x) 
79. If   A  tan1    2 C
x 
2
2
 2x  10   3  x  2x  10 

where C is a constant of integration then :


1
and f(x)  9  x  1
2
A. A
54
1
B. A and f(x)  3  x  1
54
1
C. A and f(x)  3  x  1
81
1
D. A and f(x)  9  x  1
27
54
Ans. B
Explanation:
dx dx
 (x 2  2x  10)2 
((x  1) 2  9) 2
Let (x  1) 2  9 tan 2  ...(i)
x 1
 tan  
3
On differentiating …(i)
2(x - 1) dx = 18tan θ sec2 θ d θ
18tan  sec 2  d
I
2  3tan   81sec 4 
1 1 1
27  27 2 
I cos 2
 d   (1  cos 2)d

1  sin 2 
I    c
54  2 
  x 1  
 2  
1  1  x  1  1  3  
I tan    c
54   3  2  x 1
2
 1   
  3  
1  1  x  1  3(x  1) 
I tan    c
54   3  x 2
 2x  10 
1
So, A 
54
f(x) = 3(x - 1)

80. The line x = y touches a circle at the point (1,1). If the


circle also passes through the point (1, – 3), then its radius is

55
:
A. 3 B. 2
C. 2√2 D. 3√2
Ans. C
Explanation:

Equation of circle is given as


S  L  0
 x  1   y  1    x  y   0
2 2

Which is passes through (1, -3)


0 + 16 + λ (-3, - 1) = 0
16    4  0
   4
Now equation of circle
  x  1   y  1  4  x  y   0
2 2

x + y – 6x + 2y + 2 = 0
2 2

so, radius = 9  1  2
r 2 2

2

81. The value of  sin2 x 1  cos 3x  dx, where [t] denotes the
0

greatest integer function is:


A. 2π B. π
C. –2 π D. –π
Ans. D
Explanation:

56
2
I  sin2 x 1  cos 3x  dx
0
…(i)
As we know that
a a

 f (x)   f (a  x)dx
0 0
2
I   [ sin 2x  sin 2x.cos3x]dx
0
2
    sin x(1  cos 2x) dx ...(ii)
0

By (i)  (ii)
2
2I    dx
0

2I  (x)20  2
I  

82. Let A (3,0, –1), B(2, 10, 6) and C(1, 2, 1) be the vertices of
a triangle and M be the midpoint of AC. If G divides BM in the
ratio, 2 : 1, then cos (∠GOA (O being the origin) is equal to :
A. 1 B. 1
15 6 10
1 1
C. D.
30 2 15
Ans. A
Explanation:

57
G is the centroid of ΔABC
G  2, 4,2 
OG  2iˆ  4j ˆ
ˆ  2k
ˆ
OA  3iˆ  k
We know that,
OG . OA
cos  GOA  
| OG || OA |
62 4
 
4  16  4. 9  1 24  10
4

4 15
1

15

83. If the system of linear equations


x+y+z =5
x + 2y + 2z = 6
x + 3y + λz = μ, (λ, μ ∈ R), has infinitely many solutions,
then the value of λ + μ is :
A. 10 B. 9
C. 12 D. 7
Ans. A
Explanation:
Given that system of linear equations
x+y+z =5

58
x + 2y + 2z = 6
x + 3y + λz = μ, (λ, μ ∈ R),
x + 3y + λz – μ = a (x + y + z – 5) + b (x + 2y + 2z – 6)
comparing coefficients we get
a+b=1 …(i)
and a + 2b = 3 …(ii)
On solving (i) and (ii)
a = -1 and b = 2
(a, b)  (–1, 2)
So, x + 3y + λz – μ = x + 3y + 3z – λ
⟹ μ = 7, λ = 3

84. The number of 6 digit numbers that can be formed using


the digits 0, 1, 2, 5, 7 and 9 which are divisible by 11 and no
digit is repeated is :
A. 36 B. 60
C. 72 D. 48
Ans. B
Explanation:
a1 a 2 a3 a4 a5 a 6 digit 0, 1, 2, 5, 7, 9
(a1 + a3 + a5) – (a2 + a4 + a6) = 11 K
so (1, 2, 9) (0, 5, 7)
Now number of ways to arranging them
= 3! × 3! × 3! × 2 × 2
=6×6+6×4
= 6 × 10
= 60

85. If for some x ∈ R, the frequency distribution of the marks

59
obtained by 20 students in a test is:
Marks 2 3 5 7
Frequency (x+1) 2x–5 x – 3x x
2 2

then the mean of the marks is


A. 3.0 B. 2.8
C. 2.5 D. 3.2
Ans. B
Explanation:
(x + 1)2 + (2x - 5) + (x2 – 3x) + x = 20
⇒ x2 + x – 12 = 0
⇒x=3
4
 ni xi 2(x  1) 2  3(2x  5)  5(x 2  3x)  7x
i 1
Mean = 4
  2.8
20
 ni
i 1

86. ABC is a triangular park with AB = AC = 100 metres. A


vertical tower is situated at the mid-point of BC. If the angles
of elevation of the top of the tower at A and B are cot–1 (3√2)
and cosec–1 (2√2) respectively, then the height of the tower (in
metres) is:
A. 100 B. 25
3 3
C. 20 D. 10√5
Ans. C
Explanation:

60
 APM
h 1

AM 3 2
BPM
h 1

BM 7
ABM
 AM 2  MB2  (100) 2
 18h 2  7h 2  100  100
 h 2  4  100
 h  20

87. If a1, a2, a3, ............... an are in A.P. and a1 + a4 + a7 +


........... + a16 = 114, then a1 + a6 + a11 + a16 is equal to:
A. 38 B. 98
C. 76 D. 64
Ans. C
Explanation:

61
Given that,
a  a  a  a  a  114
1 4 10 13 16
 3(a  a )  114
1 16
 a  a  114
1 16 3
 a  a  38
1 16
S0,
a  a  a  a  2(a  a )
1 6 11 16 1 16
 2  38  76

88. Let f(x) = ex – x and g(x) = x2 – x,  x ∈ R. Then the set of


all x ∈ R, where the function h(x) = (fog) (x) is increasing, is :
A. [a, ) B. 1, 1    1 ,  
 2  2 
 1   1
C.  2 , 0  1,   D. 0, 2   1,  
   
Ans. D
Explanation: Given that
f(x) = ex – x and g(x) = x2 – x,  x ∈ R
h(x) = f(g(x))
If f(g(x)) is increasing functions.
h'(x) = f '(g(x)) g'(x) and f '(x) = ex –1
h'(x) = (eg(x) – 1) g'(x)
h '(x)  e x 2
x

 1  2x  1  0

Case: 1
2
ex x
 1 and 2x  1  0
 1
 x  0,  ... i
 2
Case: 2

62
x
 1 and 2x  1  0
2
ex
 x  [1, ) ...  ii 
from  i  and  ii 
 1
x   0,   [1, )
 2

 n  11/3 n  2 1/3  2n 


1/3

89. lim    ....   is equal to:


n   n4 /3 n4 /3 n4 /3 
 

A. 4 23/4 B. 3 24/3  3
3 4 4
4
C. 2 4 /3 3
D. 2  4 4/3

3 4 3
Ans. B
Explanation: Given that
 n  11/3 n  2 1/3  2n 
1/3

lim    ....  
n   n4 /3 n4 /3 n4 /3 
 
n 1/3
1 n  r  r 1 
 lim    n  x and n  dx 
n
r =1n n   
1 1
3 4 /3  3 3
 1  x  dx   1  x    2  
1/3 4 /3

0 4 0 4 4

x 2 y2
90. If the line x – 2y = 12 is tangent to the ellipse  1 at the
a 2 b2
 9 
point  3, 2  , then the length of the latus rectum of the ellipse is :
 
A. 8 3 B. 12 2
C. 5 D. 9
Ans. D
Explanation:
Given: line x – 2y = 12
2 2
Given: ellipse x  y  1
a2 b2

63
 9 
Given: point  3, 2 
 
Tangent at (3, – 9/2)
3x 9y
 1
a2 2b2
Comparing with x – 2y = 12
3 9 1
2
 2
a 4b 12
 a  6 and b  3 3
2b 2
length of latus rectum  9
a

64
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