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Kapsan Academy, Ratnagiri

NEET CELL
Chemistry
Total Questions : 50 Total Marks : 50
Roll No.
15-Jan-2020
XII - A Div 10:00 AM To 12:00 PM
This is to certify that, the entry of Roll No. has been correctly written and verified.

Candidate’s Signature NEET Chemistry Invigilator’s Signature

Note :
i) All Questions are compulsory
ii) Darken ( ) the appropriate circle(#) of the most correct option/response with black ball point pen.

Some Basic Concepts in Chemistry i ri


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1) The ratio of mass percent of C and H of an
organic compound (CX HY OZ ) is 6 : 1 If one t n
4) The most abundant elements by mass in the
body of a healthy human adult are : oxygen
molecule of the above compound (CX HY OZ ) a
(61.4 % ), carbon (22.9 % ), hydrogen (10.0 %
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contains half as much oxygen as required to ) and nitrogen (2.6 % ). The weight which a 75
burn one molecule of compound CX HY kg person would gain if all 1 H atoms are

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completely to CO2 and H2 O . The empirical replaced by 2 H atoms is
formula of compound (CX HY OZ ) is

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A) 7.5 kg B) 10 kg C) 15 kg D) 37.5
A) B) C2 H4 O C) D) kg
C3 H6 O3 C3 H4 O2
Ac
C2 H4 O3

a n
ps
2) A sample of NaClO3 is converted by heat to
5) 1 gram of a carbonate (M2 CO3 ) on treatment
with excess HCl produces 0.01186 mole of

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NaCl with a loss of 0.16 g of oxygen. The CO2 . The molar mass of (M2 CO3 ) in g mol−1
residue is dissolved in water and precipitated is
as AgCl. The mass of AgCl (in g) obtained A) 118.6 B) 11.86 C) 1186 D) 84.3
will be (Given : Molar mass of AgCl = 143.5 g
mol−1 )
A) 0.54 B) 0.35 C) 0.48 D) 0.41
6) Excess of NaOH(aq) j was added to 100 mL
of FeCl3(aq) resulting into 2.14 g of Fe(OH)3 .
The molarity of FeCl3(aq.) is (Given : molar
3) For per gram of reactant, the maximum mass of Fe = 56 g mol−1 and molar mass of
quantity of N2 gas is produced in which of Cl = 35.5 g mol−1 )
the following thermal decomposition A) 0.2 M B) 1.8 M C) 0.3 M D) 0.6 M
reactions? (Given : Atomic wt. Cr = 52 u, Ba
= 137 u)
A) 2NH4 NO3(s) → 2N2(g) + 4H2 O(g) + O2(g)
7) What quantity (in mL) of a 45 % acid solution
B) Ba(N3 )2(s) → Ba(s) + 3N2(g) of a monoprotic strong acid must be mixed
C) (NH4 )2 Cr2 O7(s) → with a 20 % solution of the same acid to
N2(g) + 4H2 O(g) + Cr2 O3(s) produce 800 mL of a 29.875% acid solution?
D) 2NH3(g) → N2(g) + 3H2(g) A) 330 B) 316 C) 320 D) 325
Chemistry

8) At 300 K and 1 atm, 15 mL of a gaseous 15) A + 2B + 3C


AB2 C3 Reaction of 6.0 g of A,
hydrocarbon requires 375 mL air containing 6.0 × 1023 atoms of B, and 0.036 mol of C
20 %O2 by volume for complete combustion. yields 4.8 g of compound AB2 C3 If the atomic
After combustion the gases occupy 330 mL. mass of A and C are 60 and 80 amu,
Assuming that the water formed is in liquid respectively, the atomic mass of B is
form and the volumes were measured at the (Avogadro no. = 6 ×1023 )
same temperature and pressure, the formula A) 70 amu B) 60 C) 50 D) 40
of the hydrocarbon is amu amu amu
A) C3 H6 B) C3 H8 C) C4 H8 D) C4 H10
16) The ratio of masses of oxygen and nitrogen
9) 5 L of an alkane requires 25 L of oxygen for in a particular gaseous mixture is 1 : 4. The
its complete combustion. If all volumes are ratio of number of their molecules is
measured at constant temperature and A) 3: 16 B) 1: 4 C) 7:32 D) 1: 8
pressure, the alkane is
17) The molarity of a solution obtained by mixing
A) Isobutane B) Ethane
750 mL of 0.5 M HCl with 250 mL of 2 M HCl
C) Butane D) Propane. will be

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10) An organic compound contains C, H and S. A) 0.975 M B) 0.875 M
The minimum molecular weight of the
compound containing 8 % sulphur is (atomic
C) LOOM

a g D) 1.75 M

weight of S = 32 amu)
t n
18) In Haber s process, 30 litres of dihydrogen
and 30 litres of dinitrogen were taken for
A) 600 g mol−1
C) 400 g mol−1
B) 200 g mol−1
D) 300 g mol−1
a
reaction which yielded only 50% of the
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expected product. What will be the
11) The amount of arsenic pentasulphide that composition of the gaseous mixture under

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can be obtained when 35.5 g arsenic acid is the aforesaid condition in the end?

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treated with excess H2 S in the presence of A) 20 litres NH3 , 25 litres N2 , 20 litresH2
conc. HCl (assuming 100% conversion) is

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B) 10 litres NH3 , 25 litres N2 , 15 litres H2
A) 0.25 mol B) 0.50 mol C) 20 litres NH3 , 10 litres N2 , 30 litresH2

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C) 0.333 mol D) 0.125 mol D) 20 litres NH3 , 25 litres N2 , 15 litresH2

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12) The volume of 0.1 N dibasic acid sufficient to
p
19) On reduction with hydrogen, 3.6 g of an oxide

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neutralize 1 g of a base that furnishes 0.04 of metal left 3.2 g of the metal. If the atomic
mole of OH− in aqueous solution is weight of the metal is 64, the simplest
A) 400 mL B) 600 C) 200 D) 800 formula of the oxide would be
mL mL mL A) M2 O3 B) M2 O C) MO D) MO2

13) 3 g of activated charcoal was added to 50 mL 20) If Al, Zn and Fe scraps have the same rate
of acetic acid solution (0.06 N) in a flask. per kg, then for the production of H2 by
After an hour it was filtered and the strength action of dilute H2 SO4 [Atomic mass of Al =
of the filtrate was found to be 0.042 N. The 27, Zn = 65, Fe = 56]
amount of acetic acid adsorbed (per gram of A) Fe will be cheapest and Al will be costliest
charcoal) is
B) Al will be cheapest and Zn will be costliest
A) 42 mg B) 54 mg C) 18 mg D) 36 mg C) Fe will be cheapest and Zn will be
14) A sample of a hydrate of barium chloride costliest
weighing 61 g was heated until all the water D) Zn will be cheapest and Al will be
of hydration is removed. The dried sample costliest.
weighed 52 g. The formula of the hydrated
21) When burnt in air, a 12.0 g mixture of carbon
salt is (atomic mass Ba = 137 amu, Cl = 35.5
and sulphur yields a mixture of CO2 and SO2
amu)
, in which the number of moles of SO2 is half
A) BaCl2 .H2 O B) BaCl2 .2H2 O of that of CO2 . The mass of carbon
C) BaCl2 .3H2 O D) BaCl2 .4H2 O contained in the mixture is

Kapsan Academy, Ratnagiri 2


Chemistry

A) 4.08 g B) 5.14 g C) 8.74 g D) 1.54 g 30) Which one of the following will have largest
number of atoms?
22) Sulphur trioxide is prepared by the following
two reactions: S8(s) + 8O2(g) → 8SO2(g) A) 1 g Au(s) B) 1 g Na(s)
2SO2(g) + O2(g) → 2SO3 How many grams of C) 1 g Li(s) D) 1 g Cl2(s)
SO3 are produced from 1 mol of S8 ?
A) 1280.0 B) 640.0 C) 960.0 D) 320.0 31) Calcium carbonate reacts with aqueous HCl
to give CaCl2 and CO2 according to the
23) 2 gram −atom of Ca was burnt in excess of reaction CaCO3(s) + 2HCl(aq) + CaCl2(aq) +
oxygen and the oxide was dissolved in water CO2(g) + H2 O(l) What mass of CaCO3 is
to make up a 500 mL solution. Calculate the required to react completely with 25 mL of
normality of alkaline solution. 0.75 M HCl
A) 8 N B) 4N C) 2N D) 1/2 N A) 5 g B) 10 g C) 0.94 g D) 8.5 g
24) Calculate the percentage purity of H2 O2
sample if 10 g H2 O2 when reacted with KI 32) A welding fuel gas contains carbon and
produces 0.5 g of iodine. (I = 127) hydrogen only. Burning a small sample of it
in oxygen gives 3.38 g carbon dioxide, 0.690
A) 6.69% B) 0.669%
C) 0.0669% D) 66.9% ri
g of water and no other products. A volume
i
of 10.0 L (measured at STP) of this welding
25) A mixture of cuprous oxide and cupric oxide a g
gas is found to weigh 11.6 g. The molecular
weighing 1 g on reduction gives 0.839 g of
t n
formula of gas is

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metallic copper. Calculate the weight of A) C2 H2 B) CH4 C) C2 H4 D) C2 H6
cupric oxide in original sample (Cu = 63.5, O=
16)
y,
33) Aluminium oxide contains 52.9 % aluminium
and carbon dioxide cantains 27.27 % carbon.

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A) 0.40 g B) 0.53 g C) 0.55g D) 0.5 g
Assuming that the law of reciprocal
26) A mixture of FeO and Fe3 O4 when heated in
a d proportions is true, calculate the percentage

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air gains 10 % weight. What is the of aluminium in aluminium carbide.
composition of initial mixture? A) 47.12% B) C) D)
A) FeO = 85.5 % , Fe3 O4 = 14.5%
a n 59.33% 74.97% 61.10%
B) FeO = 25 % , Fe3 O4 = 75%
p
C) FeO = 75 % , Fe3 O4 = 25%
s 34) Charcoal (1 gram) of surface area 100 m2 per

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gram, adsorbs 60 mg of acetic acid irom an
D) FeO = 14.5 % , Fe3 O4 = 85.5% aqueous solution at adsorb 25◦ C and 1
atmosphere pressure. The number of moles
27) 0.30 g of an organic compound containing C,
of acetic acid adsorbed per cm2 of charcoal
H and O on combustion yielded 0.44 g CO2
surface is
and 0.18 g H2 O . If 1 mole of compound
weighs 60, then molecular formula of A) 10−2 B) 10−6 C) 10−5 D) 10−9
compound is
35) 2 g sample containing Na2 CO3 and NaHCO3
A) B) CH2 O C) C3 H8 O D) C4 H12 loses 0.248 g of mass when heated at 300◦ C .
C2 H4 O2 At this temperature NaHCO3 decomposes to
28) How many moles of methane are required to give sodium carbonate in the given sample.
produce 22 g CO2( g) after combustion? What is the % compostion of the mixture?
A) NaHCO3 16.8 % , Na2 CO3 83.2%
A) 3.5 mol B) 2.5 C) 1.5 D) 0.5
mol mol mol B) NaHCO3 33.5 % , Na2 CO3 66.5%
C) NaHCO3 83.2 % , Na2 CO3 16.8%
29) If the density of methanol is 0.793 kg L−1
D) NaHCO3 66.5 % , Na2 CO3 33.5%
what volume of it is needed for making 2.5 L
of its 0.25 M solution?
36) In the standardization of Na2 S2 O3 using
A) 25.5 mL B) 52.5 mL K2 Cr2 O7 by iodometry, the equivalent weight
C) 15.5 mL D) 10.5 mL of K2 Cr2 O7 is

Kapsan Academy, Ratnagiri 3


Chemistry

A) (molecular weight)/2 A) 7 g N2 B) 2 g H2
B) (molecular weight)/6 C) 16gNO2 D) 16 g O2
C) (molecular weight)/3 44) 5.85 g of NaCl is dissolved in 1 L of pure
D) same as molecular weight water. The number of ions in 1 mL of this
solution is
37) The number of moles of KMnO4 that will be
needed to react completely with one mole of A) 6.02 × 1019 B) 1.2 × 1022
ferrous oxalate in acidic solution is C) 1.2 × 1020 D) 6.02 × 1020
3 2 4
A) B) C) D) 1 45) Which of the following contains the greatest
5 5 5
number of atoms?
38) 29.2 % (w/w) HCl stock solution has a density A) 1.0 g of butane (C4 H10 )
of 1.25 g m L−1 The molecular weight of HCl
B) 1.0 g of nitrogen (N2 )
is 36.5 g mol−1 . The volume (in mL) of stock
solution required to prepare a 200 mL C) 1.0 g of silver (Ag)
solution of 0.4 M HCl is D) 1.0 g of water(H2 O )
A) 8 B) 7 C) 4 D) 5 46) The vapour density of a mixture containing

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NO2 and N2 O4 is 38.3 at 300 K. The number
39) Silver (atomic weight = 108 g mol−1 ) has a
density of 10.5 g cm−3 . The number of silver approximately g i
of moles of NO2 in 100 g of the mixture is

atoms on a surface of area 10−12 m2 can be


n a
expressed in scientific notation as y ×10x
The value of x is
A) 0.44
a t B) 4.4 C) 33.4
47) Natural titanium oxide is isomorphous with
D) 3.34

R
y,
A) 6 B) 3 C) 5 D) 7 SnO2 containing 39.95% oxygen. The atomic
weight of titanium is

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40) If we consider that 1/6, in place of 1/12, mass
A) 12.2 B) 48.08 C) 24.04 D) 36.06
of carbon atom is taken to be the relative
atomic mass unit, the mass of one mole of a
a d 48) 1.0 g of a equimolar mixture of Na2 CO3 and

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substance will NaHCO3 was reacted with with 0.2 N HCl
A) decrease to half solution. Find the volume of HCl required.
B) increase two fold
a n A) 52.5 mL B) 157.9 mL
C) remain unchanged
ps C) 105.2 mL D) 78.95 mL

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D) be a function of the molecular mass of the 49) 12 g carbon combines with 64 g sulphur to
substance. form CS2 . 12 g carbon also combines with 32
g oxygen to form CO2 . 10 g sulphur
41) For the titration of a 10 mL (aq) solution of combines with 10 g oxygen to form SO2
CaCO3 , 2 mL of 0.001 M Na2 EDTA is These data illustrate the
required to reach the end point. The
concentration of CaCO3 is A) law of multiple proportions
B) law of definite proportions
A) 5 × 10−4 g/mL B) 2 × 10−4 g/mL
C) law of reciprocal proportions
C) 5 × 10−5 g/mL D) 2 × 10−5 g/mL
D) law of gaseous volumes.
42) An unknown chlorohydrocarbon has 3.55 %
50) 3 g of a hydrocarbon on combustion in
of chlorine. If each molecule of the
excess of oxygen produces 8.8 g of CO2 and
hydrocarbon has one chlorine atom only,
5.4 g of H2 O . The data illustrates the law of
chlorine atoms present in 1 g of
chlorohydrocarbon are (Atomic wt. of Cl = A) conservation of mass
35.5 u; Avogadro constant = B) multiple proportions
6.023 × 1023 mol−1 ) C) constant proportions
A) 6.023 × 1021 B) 6.023 × 1023 D) reciprocal proportions.
C) 6.023 × 1020 D) 6.023 × 109

43) Which has maximum number of molecules?

Kapsan Academy, Ratnagiri 4

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