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Vol. 29 No 4 (1983) 73
2. Basic Principle Measuring Method finite region (0<x<d) (Fig. 2). The temperature distribu-
tion within the specimen, u(x, t), satisfies the following
The measuring method presented here is based on the
equation of heat conduction,
principle discussed in a previous paper~14~ through improve-
ments in several points and the measuring system is now au _k 82 u .......................................... (1)
well established with easy handling and high accuracy. at axe
Here, the basic principle of the method is presented without General solution of eq. (1) and solutions under some special
reffering to the details of equipments. The measuring method conditions are known.C16,173 Here, we denote the following.
is further discussed in the experimental section of this paper. Temperature and heat flux;
u(x, t) : Temperature of the specimen at time t (sec) and posi-
tion x (cm);
y(t) : temperature of heat source plate at time t (sec) (deg);
Yo: initial uniform temperature of the specimen (deg);
q(t) : heat flux at the interface between heat source plate and
the specimen at time t (sec). (cal/cm2•sec).
Material constants of the specimen;
K: Thermal conductivity (cal/cm•deg•sec)
k : Thermal diffusivity (cm2/sec)
C: Specific heat (at constant pressure) (cal/g•deg)
p : Density (g/cm3)
The principle is shown in Fig. 1. A specimen first placed d: Thickness (cm)
Here, k = K/ PC ................................. (2)
on a plate of which temperature is kept constant. Before
measurement, the temperature of the heat source plate made Material constants of heat source plate (copper plate
with uniform thickness);
of good heat conductor, actually copper, is raised up to
Mo : Mass (g)
about 5-10 degree higher than that of the specimen and,
Co : Specific heat (cal/g•deg)
in the measurement, the plate is rested on the upper surface
of the specimen. The temperature fall of the heat source Po: Density (g/cm3)
do : Thickness (em)
plate due to the heat flow from the heat source plate is
So : Contact area of interface between the specimen and the
measured and recorded along passing time. The heat flux
is obtained by differentiating electrically the signal of the heat source (cm)
temperature fall curve. Experiments were carried out under ao : ao=MoCo/So=poCodo ..................... (3)
conditions that the temperature of the bottom surface of where ao denotes the heat content of the heat source plate
specimen is kept constant, called "the constant temperature per unit area of contact surface (cal/cm2•deg).
condition", and that the bottom surface of the specimen The purpose of this analysis is to obtain the heat flux
is thermally insulated, called "the insulated condition." flowing out from the heat source plate to the specimen and
This method enables the measurement of heat conduction relate it to the thermal properties of the specimen assuming
properties of fabrics such as thermal conductivity and ther- that the heat source plate made of good heat conductor
mal diffusivity. The heat flux, q(t), was found to exhibit a having finite heat content is rested on the upper surface of
maximum peak value, gmax, which can also be measured, the specimen, which is usually poor heat condutor.
and details of gmax will be presented in Part 2 of this series. The heat flux, q(t), which is mainly used in this analysis,
is given as follows.
3. Theory
a (t) =-ao • dy/dt ................................. (4)
We consider a one-dimensional heat conduction in the The boundary and initial conditions are given as eqs.
(5)-(8). The unknown function, y(t), expressing the tempera-
ture change of heat source plate (initial value, yo) appears
in eqs. (6) and (7). Equation (1) is solved under the
conditions (5), (6) and (8) and then y(t) is determined using
eq. (7). u(x, t) and q(t) are derived from the y(t) thus ob-
tained.
u(0, t)=0 .......................................... (5)
u(d,t)=y(t) .......................................(6)
Fig. 2 Mathematical model and its coordinate system K • au/3x1 x=a=-ao • dy/dt .................. (7)
u(x, 0)_0 .............................................(g)
Equation (5) shows that temperature is kept constant at tion. Eq. (5) in the case of (A) is replaced by eq. (20) in this
x = 0 ("the constant temperature condition (A)"), and case.
eq. (6) shows the continuity of temperature at the contact lim u (x, t) =0 .............................. (20)
surface between the heat source and the specimen, eq. (7) x=~
shows the continuity of heat flux at the contact surface and The solution is as follows :
eq. (8) shows that the temperature of the specimen is kept
constant and uniform before the contact. (C) u (x, t) =yoeA2tkerf c (AT+x/2 kt)
The partial differential equation (1) is solved by Laplace
transform method and the inverse transform is carried out by
Bromwich integral. Under the conditions (5)-(8), which we
call the constant temperature condition (A), the solution is
obtained as follows :
sin Sn . e-cant
(A) u (x, t) =2yo 1
~nCOS~n+ 1+- sln~n erfc(x)=- 2 fe_ t'dt
............... (9)
~ -lan t
y(t)=2y ° n=1 e 1 ................. (10) 4. Discussion of the Solution
a9 +1+-
a 4.1 The Solution under the Constant Temperature
a (t) =-ao ' dy/dt ........................ (11) Throughout the present study, heat flux, q(t), flowing out
where In : a series of positive roots of from heat source to the specimen is an important quantity
in the analysis. Here, the relationship between q(t) and
cot = aj3 (n = 1, 2, 3...),......... (12)
thermal properties of specimen under the constant tempera-
a : a=poCodo/pCd ..................... (13) ture condition (A) is discussed briefly.
I : l =k/d2 .............................. (14) Equation (11) can be rewritten as follows :
Here, a denotes heat content ratio of heat source and speci-
men per unit sectional area and l denotes the heat diffusion q(t) =aoy° ~Wne-t/rn ..............................
n=t
(25)
rate of specimen normalized with thickness of specimen , d. where' Wn = ,
2 19~ 1 ........................ (26)
In the next place, the solution under the condition that the a9+ 1+-
a
specimen is thermally insulated at x = 0 ("the insulated
condition (B)") is derived. In this case, eq. (5) is replaced by Tn=1/l/9„ ................................. (27)
a~ _,oCK_A
ao .....................................(28)
Within the range where the relationship (38) holds, eq. (32)
can be rewritten as,
1 d2 pCd2 cod
r, = 1~
,2= k~,2=-K a---
From this equation, K is given as,
K=ao • d/r, ....................................... (41)
Equation (41) shows that the thermal conductivity, K, of
the specimen can be obtained from the experimental values
of ri and d.
The relative error( %) of l /j32 brought about by the simpli-
fication depends on a and can be estimated using Table 2.
If 5 % relative error is allowed a> 6.7 must hold.
If 10 % relative error is allowed a> 3.4 must hold.
l=1/r1 ............................... (32Y
When the heat source constant, ao, is 0.1, the upper limit
(2) Thermal diffusivity, k, can be obtained using eq. (14)'. of thickness for the simplified method is approximated as
follows;
k=ld2 .................................. (14),
dc=0.1/pC• ac ....................................... (42)
(3) Specific heat per unit volume, pC, can be obtained using
eq. (13)'. where, a0 is the minimum a value given above correspond-
ing to percentage of error allowed.
Using this relationship, dicision can be made as to whether
(4) Using eq. (2)', thermal conductivity, K, can be obtained. the simplified method can be used. Estimated d~ values for
fabric and polymer sheet are as follows;
When d becomes large, measurement of ri becomes In the case of typical fabrics having the parameter value
difficult and suffi cient accuracy cannot be obtained for pC = 0.2; d0 = 0.75 mm if 5 % deviation in K from the
reasons discussed in section 4.1. Therefore, there is an upper correct value is allowed. d~ _ 1.5 mm if 10% deviation is
limit of thickness, d, of specimen. The upper limit of d is allowed.
given in terms of a by the approximate criterion a > 1. In the case of polymer sheet of pC 0.35; d~ _ 0.43 mm
When d becomes too small, measurement of temperature if 5 % deviation is allowed. d0 0.84 mm if 10 % deviation is
fall of heat source plate under the insulated condition be- allowed.
[An example of calculation for obtaining thermal parameters] The heat source plate is made of copper plate of 3 cm x 3
An example of calculation by the simplified method is cm square and its thickness is about 1 mm so as to make
shown in this section. In an experiment using plasticized ao equal to 0.1. The back side of the heat source plate which
PVC specimen ofd = 0.0311 cm, v = 17.1 sec is obtained. does not touch the specimen is thermally insulated by hard
Thermal conductivity is calculated as follows; polystylene foam. Temperature sensor is attached to this
side. The heat source plate is heated up to a certain tem-
K=ao•d_O.1X0.0311 '1,814X10
r, 17.1 perature, which is higher than the room temperature, by
(cal/cm •deg •sec)
putting it on the "BT Box" which consists of copper block
whose temperature can be controlled by a heater control
For comparison, calculation by the strict method given
in section 5.3 is as follows. By carrying out the experiment system.
In taking the measurement, heat source plate ("T Box")
under the insulated condition, a = 8.78 is obtained.
Procedure (1) : For the a = 8.78, l /j32 = 9.116 is ob- is taken out of "BT Box" and rested on the upper side of the
specimen. The temperature fall of the "T Box" is detected
tained using Table 2.
by a platinum wire sensor having very quick response and
l=1/r, •,8,2=9.116/17.1=0.533 (1/sec) the detected signal is transmitted to "Amp" part. In the
"Amp" part
Procedure (2) : , the signal is converted to q(t) by differentiat-
ing the signal and then the q(t) signal is converted to log
k=1d2=0.533 x0.03112
=5.155 X 10-' (cm2/sec) q(t) using "Log Amp The peak value of the initial heat
flux, gmaz, is stored by an electronic circuit for the prediction
Procedure (3) : of warm/cool feeling, which will be discussed in the follow-
ao ing paper. With this apparatus, measurement by the steady
pC_ a • d _ 8.78 X
0.1
0.0311
=0 .366 (cal/deg•cm )
state method is also possible by putting the sample between
Procedure (4) : the surfaces of the "Water Box" and the "BT Box" to
measure thermal conductivity. Thus, we have two methods,
K=pC• k=0.366 X (5.155 X 10-4) the transient method and the steady state method for
-1.887 X 10-4 (cal/cm •deg • sec) measuring thermal conductivity using the same apparatus.
The experiment were carried out under the conditions that
7. Experiment water temperature was about room temperature (22-24°C)
and the temperature difference between the heat source
To confirm the agreement between thermal conductivities
plate and the "Water Box" was 10°C. The pressure applied
measured by the transient method and by the steady state to the specimen by "T Box" was 12.5 g/cm2. It took about
method, the following experiment was carried out. Block-
20 sec per one run of transient method.
diagram of the apparatus for the transient heat conduction On the other hand, in experiments under the insulated
measurement is shown in Fig. 9. This apparatus was devel- condition, hard polystylene foam board was used in place
oped by Kawabata in the previous work~14,15~ and was
of the "Water Box" to place the specimen. In this case,
named "Thermo Labo". ideal thermal insulation could not be realized as mentioned
The dimension of the specimen used here is 3 cm x 3 cm
above. The temperature fall due to the leak of heat from the
square. Thickness of the specimen ranges from 0.1 mm to specimen to polystylene foammwas eliminated electrically
2 mm. The specimens are fabrics and polymer sheets. by an electronic correction circuit. It takes about 5-6
Before the measurement, the specimen is rested on the
"Water Box" whose temperature is kept constant by circulat- minutes per one run under this condition.
Table 3 K values obtained by the transient heat conduction method compared by the steady heat
conduction method (ao = 0.1, yo = 10)
Table 4 Comparison of the values of thermal conductivity obtained by using the simplified and the
strict methods
Table 6 Comparison between the strict method and the simplified method
References