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1 AITS-CRT-I (Paper-1)-PCM (Sol.

)-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS
CONCEPT RECAPITULATION TEST – I
PAPER-1

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

1. ABC 19. ABC 37. BD


ALL INDIA TEST SERIES

2. BC 20. AD 38. AD

3. BC 21. ACD 39. AD

4. BCD 22. AC 40. ABC

5. BC 23. BC 41. AB

6. BD 24. ABCD 42. BD

7. AB 25. ACD 43. ABD

8. C 26. D 44. C

9. C 27. C 45. D

10. C 28. B 46. D

11. B 29. C 47. A

12. B 30. C 48. D

13. A 31. A 49. B

14. 6 32. 7 50. 3

15. 2 33. 3 51. 6

16. 1 34. 3 52. 6

17. 5 35. 9 53. 5

18. 7 36. 2 54. 7

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AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 2

Physics PART – I

SECTION – A

1. ABC
Sol. When t = 3s block just about to move and F=t
t2 B A
acceleration of block given by a  t>3
1 fk = 1N fk = 1N
v 10 fs = 1N fs = 2N
0
dv    t  2 dt
3
2 10
t 9 
v   2t   50  20     6 
2 3  2 
 30  1.5  31.5 m/s

2. BC
Sol. As the tank allowed to fall vertically, so bouyant force becomes zero, so the spring
compresses more than its equilibrium compression.

3. BC
Sol. v 2  a  bx 2
differentiating both side w.r.t. time
dv  dx  dv
2v  2bx    A (acceleration)
dt  dt  dt
A  bx
b
Hence motion will be S.H.M. 2  b , 4 2 f 2  b , f
2
1 1 a 1
T.E.  m2 (Amplitude)2  2 m b b  2 ma
2

4. BCD
Sol. Sign between x and t is  hence wave is propagating in negative x direction.
coefficient of t 3
wave velocity  
coefficient of x 1
Max value of y is amplitude, y has maximum value when denominator is least i.e.
when (x  3t)2 is zero
y  3m
6
shape of pulse is given by y  (t  0)
2  x2
shape of pulse is symmetrical out y-axis

5. BC

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3 AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

P1 P
Sol. tan   – [slope at (P1, V1)] 
V1
P1 A (P1, V1)
tan  
V1 P1
 
O V
 =  V1
M D
OM  MD  V1
 OD  2V1
1 1
Area of triangle AOD   AM  OD   P1  2V1   P1V1  nRT
2 2

6. BD
Sol. Now, potential difference across C1 is 20 V and across 20V 40V 60V
C2 is zero.
 charge stored in C1 is 40 C and in C2 is zero.
1 C12 C2 3

2 1 3
40V 20V 60V

120V

7. AB
Sol.
C

2f2
d

f1

8. C
Sol. Fraction of volume submerged = d1 /d2 = 1.

9. C
Sol. When ratio of extra weight to total base area is minimum.

10. C
Sol. When ratio of extra weight to total base area is maximum.

11. B
Sol. Qoutside = earthed plate will have zero charge on outer surface for its zero potential
condition.

12. B
Sol. Earthed plate will have zero charge on outer surface for its zero potential condition.

13. A
Sol. Qoutside = (Q1+Q2)/2, and conservation of charge.

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AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 4

SECTION – C

14. 6
Q dT
Sol.  KA A
t dx
dT
in conductor A = slope of graph = 3
dx
Since both conductors are connected in series, same heat current will flow in A and B.
KA (dT/dx)A = KB(dT/dx)B
KB = 6

15. 2
Sol. For getting null point x
5
R1 R2 1 3

R3 R 4
6 G 7
as R2 = R4 2 4
R1 = R3
8
Let the pointer at point 5 is moved to left by distance x to get nul
point as shown in the figure. If resistance per unit length of wire
3 is r then that of wire 1 will be 2r.
(8  x)2r = x  2r + 8  r
4x = 8
x = 2m

16. 1
g
Sol. = = 1 rad/sec
R

17. 5
Sol. N1 + N2 = mg . . . (1) N1
N2
N1 = N2 . . . (2)
mg
N2 = N1

1  2 
mg N2
N1 = mg
1   
2

Torque about centre of mass


1
(N1 + N2)R = mR2 
2

2 N1  N2  2 1    g
= =
mR 1    R
2

2 = 02  2
20
=
2

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5 AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

=

20 1   2 R
2  2 1    g
Hence number of turns

N=

=
02R 1   2 ; N=

20R 1   2  
2 4 1    g.2 8g 1   

18. 7
Sol. Given, voltage V = (100  5)V
Current I = (10  0.2)A
According to Ohm’s law, V = IR or R = V/I
Taking log of both sides,
Log R = log V – log I
Differentiating, we get
R V I
 
R V I
R V I
For maximum error,  
R V I
Multiplying both sides by 100 for taking percentage, we get
R V I
 100   100   100
R V I
Percentage error in resistance R
V I
  100   100
V I
5 0.2
  100   100 = 7%.
100 10

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AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 6

Chemistry PART – II

SECTION – A

19. ABC
Sol. O O
O
O

O O O O O O

O O

O O
O O O O O

20. AD
Hydrolysis
Sol. AlCl3  3H2 O   Al  OH 3  3 HCl
B3+ cannot exist in aqueous media

21. ACD
Sol. NO, O22 and oxygen having unpaired electrons in molecular orbital.

22. AC
Sol. CN– and NO+ total no. of electrons is 14. Hence bond order is 3.

23. BC
Sol. 2C  3H2  C2 H6
s g  g
0 0
H  2  H  3  B.E H  H   B.E.  C  C   6  B.E  C  H
f sub

 85   2  718    3  436     x  6y 


 x  6y  2829 …..1
Similarly for C3H8  g 
2x  8y  4002 …..2
Solving (1) & (2), x = 345
y = 414

24. ABCD
H 40,600
Sol. S    54.42 J / K
T 373

25. ACD

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7 AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

Sol.
- O
O
H3C O O O-

O CH3
Br
Br -
O

H3C +
O
O
Br

26. D
Sol. Attack of H+ on oxygen and then nucleophilic attack of Cl–

27. C
Sol. Pinawl formation-diracdical formation of Mg complex, then recombination and then
hydrolysis.

28. B
Sol. Attack of H+ on oxygen and then nucleophilic attack of Cl–

29. C
Sol. An oxalic acid is strong reducing agent having C – C bond length longer than C – C
bond length in ethane.

30. C
Sol. N=C=O
H3C
N is sp2 hybridized having two bp and one lp and so bent.

31. A
Sol. Silyl isocyanate is linear due to p-d bonding in between nitrogen and silicon.

SECTION – C

32. 7
Sol. 2KMnO4 + KI + H2O  2KOH + 2MnO2 + KIO3
3.5 moles of potassium iodide requires 7 mol of potassium permanganate.
33. 3
Sol. CoCl2 + H2S  CoS  + 2HCl
3CoS + 6HCl + 2HNO3  3CoCl2 + 2NO + 3S + 4H2O
aqua regia
KNO2 + CH3COOH  CH3COOK + HNO2
CoCl2 + 2KNO2  Co(NO2)2 + 2KCl
Co(NO2)2 + 2HNO2  Co(NO2)3 + NO + H2O
Co(NO2)3 + 3KNO2  K3[Co(NO2)6]
Oxidation number of cobalt in this compound is +3.

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AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 8

34. 3
Sol. Pt NH3 NH2OHNO2 py  NO2
All four ligands are different, so it can be compared to M abcd. Three geometrical
isomers are possible as follows
a c a b a b

M M M

d b d c c d

35. 9
Sol. Kb = 10-5, pKb = 5
BOH + HCl  BCl + H2O
At half neutralization, 50% of the base is converted to its salt, with strong acid HCl, it
forms a basic buffer.

pOH  pK b  log
salt 
base
pOH  5  log
 salt 
base
[salt] = [base]
pOH = 5
pH = 14 – pOH = 9

36. 2
Sol. CH3 - CH - CH3

CH3

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9 AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

Mathematics PART – III

SECTION – A

37. BD
1 Pn+1
Sol. Sn  Pn Pn1 sin 
2
Pn  n  1
Sn
Pn
Pn 1  n  2

P   i   1 
arg  n1   arg 1    tan1  
 Pn   n 1  n 1

38. AD
 
Sol. Let a  cos  ˆi  sin ˆj, b  cos  ˆi  sin ˆj, , ,   0,2 

c  cos  ˆi  sin ˆj
 cos       cos       cos        3  
let A    , B    
 cos A  cosB   3 cos  A  B 
cos A  cosB  B  2m  A
 B  A,B   A,B  2  A,B  2  A
 B  A,B  2  A rejected.
 when B   A,B  2  A
 cos A   3 cos  2A  2  or cos A   3 cos 2A
3 1
 cos A  ,
3 2
  1 1
a.b  cos 2A  ,
3 2

39. AD
t
Sol. Let  f u du  F  t   F '  t   f  t  and F  0   0
0
t
Also f  t   0   f  u  du  0  t  0,1
0
t
 f  t   1  2 f  u  du
0

F ' t
 F '  t   1  2F  t    1 as f  t   0
1  2F  t 
t t
F '  t  dt
   dt  t  0, 1
0 1  2F  t  0

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AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 10

 1  2F  t   t  1
2
 f  t   t  1 Also 1  2F  t    t  1
 2F  t   t 2  2t
t
t2 t2
 F t   t   f u  du   t
2 0
2

40. ABC
1
Sol.  x f '  x  dx, Put x  sin   dx  cos  d
0
 /2  /2
J  f  sin   cos   d   f cos   sin  d
0 0
 /2
2J   f  sin   cos   f cos   sin  d
0
 /2

2J   1.d  I  4 and equality holds if f  x   1  x 2
0
1
Put x  y  xf  x  
2
1 1
1
  x f  x  dx   dx
0 0
2
1 1
x2 x2 1
 f  x   f ' x dx 
2 0 0
2 2
1
 f 1   x 2 f '  x  dx  1
0
1

Also  f  x  dx  4 (Again use By parts)
0

41. AB
Sol. Using sine law A
b c a
 
sin2 sin  sin    3  c
d
b a b
 c
2cos  3  4 sin2 
2 
 b  2c cos  and a  4 cos2   1 c   B a C a/3 D
2 2
 ca  b  c (eliminate cos  )
Also cos  ACB   cos  ACD   0

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11 AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

a2
2 2 2 b2   d2
a b c 9 1
   0  d   3c  2a 
2ab a  b 3
2  
3
2
 4a 
c 2  d2   
Also cos    3 
2cd
a2
 On manipulation cd 

3 sin2
2
3 3 1 cot 
ABC   ABD     cdsin  = BC2
4 8 4 2

42. BD
Sol. Given f  j   j  f i   i  i  j
Let g  k   f k   k  g k  is decreasing function. Also
1  f k   2018
.  1  k  g k   2018  k .
Also g  k  1 will always be in the desired range as long as g (k) is in the desired Range.
We are supposed to select g 1 ,g  2  ,......g  2018  values in decreasing order from
 2017, 2017 
 4035 C 2018 ways.
n 2 4035
2n
Cn  
i 0
 C
n
i  4035C2018 
2018
4034
C2017

43. ABD
Sol.  
Let h  x   f f  f  x    x  x  R
 h  x  is a strictly increasing and bijective
Also if f is strictly decreasing, f  f  is increasing function,
 
 f f  f  x   is decreasing, hence contradiction.
Also if for x 2  x1, f  x 2   f  x1 
 f  f  x2   f  f  x1  
 f  f  x 2   f  f  f  x2  
 h  x 2   h  x 2  not possible for x 2  x1
If f is a strictly increasing function
 f  f  is a strictly increasing function
 f  f  f   is a strictly increasing function
Also Range of h  x   R  Range of f  x 

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AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 12

 f  x  is on to  hence bijective.
Also h  0   0  f  f  f    0 and f  x  and f  f  x   are inverse of each other  f  0   0
and increasing i.e. Non – zero slope. Hence will cut y = x2 at two distinct points.
44. C
45. D
46. D
(Sol. 44 to 46)
A  C  B  D  D :  2,1,8 
BA  1,  1,5  ,BC   0,2, 4 
Equation of plane  is 7x  2y  z  8  0

Equation of line PF r   2,1,0     7,2,  1


    2  7,1  2,    , for other point put   1
For point F: 7  2  7   2 1  2     8  0 i.e. satisfying in Plane 
4

27
 26 19 4 
F:  , , 
 27 27 27 
 2 11 8 
I :2F  P :  , , 
 27 27 27 
Foot of perpendicular from A to BC:
Equation of BC : (1, 0, –1) +  (0, 1, 2)
: 1, ,  1  2 

 
For foot of perpendicular ˆj  2kˆ . ˆi   1    ˆj   5  2  kˆ  0 
9  9 13 
  1, ,
 
5  5 5 
Line L intersects plane  at (1, 0, –1) (Solve plane and line L)
Equation of Projection of line L is passing through F and (1, 0, –1)
Equation of mirror image of line L in Plane is line passing through I and (1, 0, –1)
Let  be the acute angle between line L and plane 

 cos  
 ˆi  ˆj  kˆ  .  7iˆ  2ˆj  kˆ 
where,    

3 . 54 2

8

9 2
 8 
   sin1  
9 2 
For distance between AB and CD say H
 
Area of parallelogram ABCD  AB  BC  2 54

HBA   2 54 when BA  27

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13 AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

47. A
48. D
49. B
(Sol. 47 to 49)
x cos  y sin 
Equation of tangent is  1
a b
a = 4, b = 3
 A :  4 sec ,0  ,B :  0,3 cos ec  
1 12
OAB   45 sec  3 cos ec   
2 sin 2 

 OAB min  12 where  
4
 4 3 
P: ,
 2 2
  
 , A : 4 2, 0 ,B : 0,3 2 
 1   1 
x  y 
2 2
Equation of tangents:    1
4 3
 3x  4y  12 2
Let Q :  ,    3  4  12 2
 12 2  4 
Equation of CD : x  y  12  x    y  12
 3
 
 
 12 2x  36    3y  4x   0
 3 4 
 Point of concurrency:  , 
 2 2
12 2
Also distance of (0, 0) from 3x  4y  12 2  0 is as radius of circle is 12
5
dis tance 24
  1
radius 25
 cuts at 2 points.

Let (h, k) be the circumcentre of QCD


 h,k  is midpoint of (0, 0) and  ,  
 2h  , 2k  
Also 3  4  12 2  3h  4k  6 2

For R equation of director circle of ellipse


For (iv) equation of director circle of circle
For (S) Any line passing through one focus of ellipse will pass through other focus after
reflection.

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AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 14

SECTION – C

50. 3
Sol. y  mx touches circle
 
 D  0 for m2  1 x 2  2a  m  2  x  4a 2  0
2

 4a2  m  2   4 m2  1 4a2  
4
 m  0,
3
Let A :  x1,m1x1  ,B :  x 2 ,m2 x 2 
2 2
AB2  9   x1  x 2    m1x1  m2 x 2   9 where

x1 
m1  2 a, x2 
 m2  2  a, m  0, m2 
4
2 2 1
m 1
1 m2  1 3
3 5
get a 
4

51. 6
Sol. Let 1  x  a, 2  y  b, 3  z  c  a,b,c  0
 b c
E   abc   3  a   
 2 3
 b  c  b c
E  6 a      3  a   
 2  3  2 3
Apply AM  GM
b c  b c
a    3  a    1/4
2 3  2 3    b  c  b c 
  a      3  a    
4   2  3  2 3 
243 3 3 9
E and equality holds for a  , b  , c 
128 4 2 4
1 1 3
  x0 , y 0 , z0    , , 
4 2 4

52. 6
Sol. sin x  sin y  sin  x  y 
xy xy xy
 Either sin    0 or cos    cos  
 2   2   2 
x y
 x  y  2m  or  p or  k  m,p,k Integer 
2 2
 x  y  2m  or x  2p or y  2k
 1 1   1 1 
Plot and get (0, 1), (0, –1) , (–1, 0), (1, 0)  ,  ,  , 
2 2   2 2

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15 AITS-CRT-I (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

53. 5
 t2  t 2 1 x t2
Sol. Equation of normal at point T  t,  to C is y    x  t   y   1
 2 2 t t 2
If circle S touches curve C at T.
  x  t  , y  t   must lie on normal
t2 x  t 
 y t  1 
t 2
Also distance of centre of circle from T equals radius = distance of centre of circle from x
– axis.
2
2  t2  2
  x  t  t   y t      y  t
 2

x t 

t 1  t2  1  , y t  t 2
 1  t2  1
2 2
1 3 2
 x t y t   t t 1
4
1
1 3 2
lim  t t  1dt
r 0
r 4
Let 1  t 2  z  2tdt  2z dz
2
1 2 2 1
 lim
r 0
 4
 
z  1 z2 dz 
30
1r 2

54. 7
Sol. Let E1 : first ball drawn red from Urn A and 2nd ball drawn black from B.
E 2 : first ball drawn while from A and 2nd ball drawn black from B
E3 : first ball drawn red from B and 2nd ball drawn black from B
E 4 : first ball drawn black from B and 2nd ball drawn black from B.
P E1   P E3 
P
P E1   P E2   P E3   P E4 
 1 2  3  1  6
P E1           
2 6
     6 2 144
 1   4   1   3  12
P  E2           
 2   6   2   6  144
 1 3  1  3  9
P  E3           
 2   6   2   5  120
 1 3  1  2  6 7
P E 4            P 
 2   6   2   5  120 15

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