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Compressor K-100:
26.73811 m3/sec
poly tropic efficiency 76%
Outlet temperature for poly-tropic flow:
then m 0.3759398
T2 393.19845 K 120.0485 C
Power Requirement
Reactor PFR-100:
Chemical Reactions:
C6H6 + 4.5 O2 C4H2O3 + 2CO2 +2H2O
(Maleic Anhydride)
C6H6 + 7.5O2 6CO2 +3H2O
Air 3816
Moisture 107.5 72.94 75
Benzene 59 133 53
Nitrogen 3014
Oxygen 512
Water 225 72.94 75
CO2 122
MAN 43 158 177
CO 26
Benzene 5 133 53
Quinone 0.94 182 155
Product steam (8) from the reactor is cooled from 400C to 76.5C at 152Kpa. For energy
balance around Waste Heat Boiler assume 76.5C as reference temperature.
Nitrogen 3014
Oxygen 512
Water 225 73.56 24
CO2 122
MAN 43 163 126
CO 26
Benzene 5
Quinone 0.94 189.2 104
Nitrogen 3014
Oxygen 512
Water 225 72.94 26.5
CO2 122
MAN 25.35 148 26.5
CO 26
Benzene 4.71 137 26.5
Quinone 0.71 171.2 26.5
Mixer MIX-101:
Pure water stream (16) is added to scrubbed liquid (13) to keep the concentration of MAC
solution up to 40%. Assuming water enters at 30C and 101Kpa while scrubbed liquid is
entering at 45C.
stream (15) and (17) are leaving at same temperature. So T15 = T17 = T
Scrubber T-100:
MAN is absorbed in 40% solution of MAC entering at 44.2C while the gases leaves from the top
of scubber in vent stream (14).
Feed is heated from 44.2C to 95C in vapor phase befor it enters the dehydrator
Dehydrator T-101:
Operating conditions:
Top plate temperature = 55C
Re-boiler temperature = 120 C
Operating pressure = 15.2 kpa
Assuming 100C as reference temperature
Reactions involved
Overhead condenser:
component m Cpℓ
Total Enthalpy
component m Cpℓ
Total Enthalpy
component m Cpℓ
Total Enthalpy
component m Cpℓ
Mixer MIX-102
Stream (27) entering at 120oC and 101Kpa is mixed with crude MAN strea
component m
Water 13.07
MAN 24.77
O-Xylene 3.79
Fumaric Acid 0.12
Quinone 0.71
Enthalpy of stream (28)
component m
Water 14.75
MAN 42.51
O-Xylene 3.79
Fumaric Acid 0.12
Quinone 0.94
Total Enthalpy
component m
water 17.74
MAN 1.68
quinon 0.23
514664.4
component m
Water 14.75
MAN 42.51
O-Xylene 3.79
Fumaric Acid 0.12
Quinone 0.94
component m
Water 54.15
MAN 1.03
O-Xylene 13.27
Quinone 3.06
component m
Water 36.9
MAN 0.73
O-Xylene 9.5
Quinone 2.2
component m
Water 14.75
MAN 0.29
O-Xylene 3.79
Quinone 0.87
component m
MAN 42.21
Fumaric Acid 0.12
Quinone 0.17
2
1.2976847
0.3759398 1.297685 0.297685 231.4652
R 0.0821 m3atm/kgmolK
8.314 KJ/kgmolK
Zi 1
202 Kpa
202 Kpa
m Cp
119932.5
8168.37
(R1) ∆H -1.86E+06 KJ/kgmol
KJ/hr
KJ/hr
KJ/hr
KJ/hr
KJ/hr
KJ/hr
KJ/hr
53579027 KJ/hr
nergy balance
3453016 KJ/hr
ration of MAC
CpℓΔTℓ ∆H
1092 4833662
3097.5 1535771
2464.5 1749.795
∆H
331320.1 (T-30)
97240.85 (T-30)
∆H
17202.64 (T-30)
5139.785 (T-30)
116.653 (T-30)
C
C
leaves from the top
(maleic acid)
CpℓΔTℓ ∆H
199.444 601204
200.668 102742
494.904 115807.5
266.9 32561.8
981.92 24891.67
203.388 5332.833
906.44 4269.332
1135.6 806.276
KJ/hr
CpℓΔTℓ ∆H
58.24 257795.3
165.2 81907.81
131.44 93.3224
KJ/hr
∆H
88189.64 (T-44.2)
15093.76 (T-44.2)
24282.74 (T-44.2)
4777.52 (T-44.2)
62.092 (T-44.2)
759.72 (T-44.2)
617.952 (T-44.2)
(T-44.2) KJ/hr
CpℓΔTℓ ∆H
3728.1 880950
11005.8 273934.4
8853.6 6286.056
1161170 KJ/hr
∆H 3.60E+04 KJ/kgmol
∆H 3.90E+03 KJ/kgmol
2Kpa = 53.6C
15.2Kpa = 85.05C
ΔTℓ CpℓΔTℓ Cpg ΔTg Cpg∆Tg
11611566 KJ/hr
ΔTℓ CpℓΔTℓ ∆H
20 1455.4 360939.2
20 3846 276912
637851.2 KJ/hr
KJ/hr
ΔTℓ CpℓΔTℓ ∆H
70 5103 1205839
70 14868 370064.5
70 11928 8468.88
1584372 KJ/hr
1.18E+07 KJ/hr
= -234284 + 7849.169 T
T = 95.417565 C
Top plate temperature = 160C
tering at 108C
41544716
5.90E+06
4420457
∆H
34088340
5940480
12649388
2007053
4607063
290647.5
406289
103571.1
∆H
29559745
5172388
12036699
1757810
4328105
252130.3
375722
96427.83
∆H
2348207
401612.8
434904.8
128414.8
99422.7
20132.58
17099.66
3221.128
λ ∆H
4.30E+04 11191878
419688
λ ∆H
4.30E+04 618744.4
352266.6
4.10E+04 222596.2
2861.4
11722.81
Cpg∆Tg λ ∆H
Cpg∆Tg λ ∆H
Cpg∆Tg λ ∆H
Cpg∆Tg λ ∆H
Cpg∆Tg λ ∆H
1165629
5388.6
3044 46000 13130.55