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Optimum equipment for sulphur burning in sulphuric acid plants is not a trivial matter. However, owners and operators
can benefit from technology providers with deep knowledge of the process, command of cutting edge analysis tools,
and the ability to integrate analytical results with robust equipment designs. Thus, when analyzed by the right industry
experts, facility owners can realize improvements that meet and even exceed their goals.
T
he sulphur furnace in a sulphur drop size spectrum with a specific Pneumatic nozzles can create either a
burning sulphuric acid plant is spray coverage or distribution inside flat spray or a round spray pattern, and
generally a large horizontal the furnace. The drop size and coverage they produce the smallest droplets of
cylindrical vessel of carbon steel, lined required depends on the performance any of the conventional spray nozzles.
internally with refractory brick. Air and characteristics of the furnace. These
liquid sulphur are fed into the furnace include the length and width of the Common problems
via a sulphur gun equipped with an furnace, heat load, amount of oxygen Common problems associated with
atomizing spray nozzle or a rotary cup for combustion, placement of baffles, molten sulphur spraying include spray
burner. The internals of a sulphur and flow rate of the air through the atomization, turndown, plugged
furnace are important to ensure furnace. nozzles, and sulphur gun design.
complete combustion of sulphur to The reason that atomization and drop
sulphur dioxide. The reaction is highly Spraying Systems Co. spray size is so important is that it directly
exothermic resulting in a large affects the rate of heat transfer between
temperature increase. A waste heat nozzle types
the combustion gas and the sulphur.
boiler downstream of the furnace is Spray nozzles can be split into two
Too often, spray nozzles are chosen
used to remove much of the heat of broad categories, either hydraulic or
based mostly on their flow rate instead
combustion. pneumatic (also called air atomizing or
of on their performance. Drop size
The design of the sulphur furnace two-fluid nozzles). Hydraulic spray
affects overall surface area. For
must achieve good gas mixing and full nozzles use only the liquid back
example, by merely breaking up a
combustion of sulphur prior to leaving pressure to determine the flow rate,
single 500 micron droplet into several
the furnace and entry to the boiler spray pattern, and droplet atomization.
equally sized droplets of 100 microns
section. Sulphur droplets impinging on Pneumatic spray nozzles use an
each, the surface area can be increased
the baffle or checker walls will vaporize additional fluid, typically compressed
by almost 500%.
immediately and burn to sulphur air, to provide primary liquid breakup.
However, this is not the way spray
dioxide. Any unburned sulphur that Hydraulic spray nozzles can be further
nozzles operate. They do not create
impinges on the carbon steel surfaces classified into spray pattern types such
100% equally sized droplets. The
of downstream boilers, ducting and as hollow cone, full cone, and flat spray
sprayed volume comprises many
heat exchangers will corrode the steel. patterns.
different size droplets that make up the
For sulphur burning, the most
drop size spectrum. The volume
Understanding spray technology common types of nozzles are hollow
median diameter is a standard way of
cone hydraulic nozzles and pneumatic
When producing sulphuric acid from characterizing the size droplets that a
since these typically have larger free
molten sulphur, it is critical that the particular nozzle will produce.
passages and create smaller droplets
sulphur is atomized into sprayed However, this number is not useful
than the other nozzle styles.
droplets such that combustion occurs when dealing with mass transfer
The BA sulphur burning nozzle is a
efficiently and within the design applications such as evaporation and
commonly used hollow cone spray
parameters of the furnace. Each furnace combustion. A more useful number is
nozzle for sulphur burning. It produces
is designed to accommodate a the Sauter mean diameter (D32), which
small to medium size droplets, has a
particular throughput of sulphur to is a means of relating the volume to
fairly large unobstructed flow passage
oxidize into sulphur dioxide; however, surface area of a single droplet to the
to minimize clogging, and has a
the form or the size of the sprayed total volume to total surface area of all
relatively low cost to operate as
droplets produced becomes a major of the droplets. Another important drop
compared to a pneumatic nozzle since
factor in determining when this size parameter for applications where
it does not require compressed air.
combustion occurs. residence time is a concern, such as the
Pneumatic spray nozzles require
The spray nozzle needs to handle a gas moving through a combustion
compressed air to provide primary
bulk mass of fluid that is delivered furnace, is the maximum drop size,
atomization. The liquid and the gas can
through it at a specific pressure drop. since it is this droplet that will take the
meet either inside or outside of an air
When this mass of fluid exits the nozzle, longest to evaporate or combust. One
cap depending on the design chosen.
it is then converted into a predictable must account for it as well. When
performance is required during start-
up, low flow operation, as well as peak
sulphur throughput. Methods used to
adjust the flow rate are to use multiple
sulphur guns or to adjust the operating
pressure of the individual nozzles, or a
combination of both. When changing
the pressure to obtain different flow
rates, it is important to realize that the
performance of the respective spray
nozzle changes as well. For instance,
with a hydraulic nozzle, as you
decrease the pressure in order to
decrease the flow rate, drop size
increases and the spray pattern or
coverage collapses. Changes occur with
air atomizing nozzles as well; however,
the changes are more subtle. This is due
to the ability to alter the atomizing air
pressure along with the sulphur feed
Figure 1: Cross section of furnace and spray coverage for different nozzle types
pressure in order to help maintain a
more consistent performance across a
comparing different spray nozzles, it is moves through the furnace. wider range of flow rates.
important to clarify which drop size This shows what it looks like without Figure 3 shows a BA nozzle spraying
parameter you are using. any sulphur injected and can provide 5 gpm and 2 gpm (upper left and lower
Figure 1 shows the cross section of a valuable information about turbulent left pictures, respectively) and then a
furnace and the spray coverage of a spots and low velocity areas. This FM pneumatic nozzle spraying 5 gpm
hydraulic and pneumatic nozzle. It can information can then be used to analyze and 2 gpm (upper right and lower right
be seen in Figure 1a that the drop size the spray gun placement. Figure 2b is pictures, respectively). It can be seen
from the hydraulic nozzle is large the temperature profile with the spray that as the liquid pressure supplied to
enough and the spray pattern opens up guns turned on. And Figure 2c shows the BA nozzle is reduced in order to
enough that wetting of the furnace the particle tracking of the sulphur reduce the flow rate, the spray
bottom is a concern. None of the spray itself. All of these can be used to performance changes. It can easily be
droplets shown in Figure 1b of the compare actual performance with any seen that the spray pattern is streaky
pneumatic spray nozzle impact the wall maintenance issues or in conjunction and less uniform and that there are
and it appears that all of the sprayed with studies to optimize performance larger droplets being produced at the
sulphur is more able to be volatized. of the furnace. Getting to a solution is lower pressure. For the FM pneumatic
Further analysis would show that all of typically quicker and less costly than nozzle, the change is more subtle and
the sulphur was converted prior to the repeated online tests, and benchmarks no visual difference can be detected.
furnace exit. can be set for future analysis as well. The performance is more consistent
Atomization is key and is the critical Another problem that producers may even at the lower flow rate and
first step as the sulphur is injected into encounter is spray nozzle turndown. pressure. Plugged nozzles are yet
the combustion furnace. Knowing what Turndown of the nozzle refers to the another concern, and whenever there is
happens to these spray droplets and effective operating range of the nozzle, a set orifice size, there is potential for
how it affects the furnace operation can or the ability to turn down the flow rate something to build up or lodge within
be enhanced with CFD. Figure 2 shows from peak flow conditions to low flow that orifice. This is why installing
three different furnace profiles. Figure conditions. properly sized strainers upstream of
2a tracks the combustion gas as it Proper atomization and consistent the nozzle is important. However,
Figure 6: Pressure drop for 3 baffle walls vs 1 VectorWall Figure 7: Residence time for 3 baffle walls vs 1 VectorWall
a)
Table 1: Capital savings for a 10% reduction in furnace size (US Gulf Coast Pricing basis)
would have taken to install
conventional brick baffle walls,
resulting in substantial savings in
turnaround costs.
Table 2: Comparison of pressure atomization and air atomization for sulphur burners
five decades.
Recently, Outotec® LURO2 sulphur
burner (see Figures 12 and 13), a new
burner model has been introduced to
the industry to address the changes the
global markets have been undergoing
for example in terms of environmental
regulations and energy efficiency not to
mention a constantly changing
competitive landscape.
The atomization technology with a
rotary cup is completely different from
traditional nozzle technology and
comes with numerous advantages. The
burner is fed with molten sulphur at
145°C via steam-heated piping. When it
reaches the rotary cup atomizer, the
molten sulphur is directed into a
conical rotating cup, which is the heart
of the atomizer. On the cup’s inner
surface, a homogeneous sulphur film is
formed and atomized by an axial air
stream as it leaves the edge of the cup.
On the basis of this rotary cup
atomizing technology the Outotec®
LURO sulphur burner family comes
with the following operational and
maintenance benefits:
• formation of ultra-fine droplets
regardless of plant load;
• uniform heat distribution;
• prevention of sulphur carry over
from furnace downstream;
• elimination of steam leaks within
the sulphur combustion furnace;
• easy and fast removal of burner;
• single burner configuration;
• no changes in burner
configuration throughout whole
operation window including pre
heating phase.
These benefits have been incorporated
in every LURO sulphur burner since its
introduction in 1964, but current
market demands and today’s
technology have allowed Outotec and
its partner SAACKE, a German company
with an 80-year tradition of providing
combustion technology to the global
market, to make enhancements which
Figure 11: NORAM pressure-atomized sulphur burners increase the performance and expand
the burner’s general capabilities.
atomization are common in the burners.
The targeted increase in capacity was
sulphuric acid industry. The pressure
achieved through a 40% boost of the
atomized technology was developed for Outotec® LURO2 sulphur burning nominal sulphur burning capacity
systems that require large amounts of
SO2. These systems typically burn 33 to system reaching 35 t/h of sulphur burned by a
The LURO burner with rotary cup single unit.
1000+ t/d of sulphur (i.e. producing 66
technology has been a core element of The LURO2 can also be used during
to 2000+ t/d of SO2).
Outotec’s sulphuric acid plants based start-up processes when the sulphur
Figure 11 shows some details of
on sulphur combustion for more than furnace and converter are heated with
NORAM’s pressure atomized sulphur
diesel fuel. The oil atomization during
plant will find that switching to
Outotec’s LURO2 burner translates to
benefits in operation, maintenance and
furnace size. The efficient combustion
makes it possible to achieve a higher
throughput with the same furnace.
Thus, costs and shut down time
associated with a revamp can be
minimized with Outotec’s LURO2 as the
upgrade solution.
The windbox which has undergone a
redesign and standardization
procedure is equipped with a set of
guide vanes. With a small sight glass
integrated it allows as supplement to
the furnace sight glass the flame
monitoring from the burners position.
The pipe racks located on the burner
platform serves for the safe media
supply according to the international
standards. To ensure smooth
Figure 12: Outotec ® LURO2 sulphur burning system maintenance, the LURO2 burner is
start-up is also achieved using air and system is the BMS for the machine mounted on a moving unit allowing
the rotating cup technology – no control cabinet, a local control box and easy access to the rotary cup atomizer
additional equipment is needed. As an a secondary air windbox, which helps unit.
alternative, natural gas can also be used achieve an efficient combustion at low Outotec® LURO sulphur burner
as pre-heat fuel. emission levels. family main features can be
The burner’s drive has been modified Due to its atomization of sulphur into summarized by:
so that a flange motor is now in place ultra-fine droplets regardless of the • single burner capacity up to 35
with a magnetic coupling to the burner plant load, the burner allows the t/h of liquid sulphur
shaft thus eliminating the need for a furnace size to be minimized and limits • operational range up to 15 to
belt drive with wear parts such as the the effects from thermal shocking to the 110% of the nominal sulphur
V-belt. Replacing the rotary cup’s belt refractory lining. Typically a LURO- load
drive with a frequency-controlled equipped furnace has a 2-3 times • high operating quality also
direct drive and a magnetic coupling smaller combustion chamber than a during load changes
device enables also the sulphur film conventional one and the use of an • small furnace due to excellent
thickness to be controlled precisely internal baffle wall is obsolete. With its atomization
allowing an operation window with high performance in the partial-load • easy and fast removal of burner
extended load conditions from 15- operational range the burner requires • atomization with primary air
110%. no mechanical adjustments such as a from drying tower by rotating
In addition, an automatic grease nozzle replacement when the plant is cup.
lubrication system has replaced the old operating at lower loads. To meet
oil system as well as the burner operator’s plant control approach, the References
management system (BMS) associated LURO2 burner operation can be fully 1. Munro C (Spraying Systems Co):
with it to ensure a reliable and safe integrated into a plant’s DCS with the “Understanding spray technology to
operation. Also noteworthy is that with option of a supplementary condition optimize sulfur burning”, prepared for
the LURO there is no steam cooling monitoring system. AIChE Central Florida Section (June
2015).
inside the combustion chamber which Customers who are using a lance 2. Lamb B and Ullrich R (MECS, Inc.):
prevents leakages. equipped furnace and are evaluating a “Unique furnace challenges and highly
The new burner still includes classic capacity increase of their sulphuric acid customized designs”, written for Sulphur
features such as excellent sulphur (Dec 2015),
3. Mahecha-Botero A., Kyle Loutet K,
distribution and atomization, turndown Nikolaisen K, Murdock A and Cooper CG
flexibility, a small combustion chamber, (NORAM): “Stabilization and capacity
low sulphur feed pressure and online increase of sulphuric acid plants and
load changes which translate to zero sulphur recovery units – Use of skid-
mounted sulphur burners for SO2
down time for nozzle replacement. supplementation”, Sulphur 2015
Besides the enhanced burner, the Conference, Toronto (Nov 2015).
system typically includes a primary air 4. Schüdde J and Storch H (Outotec):
blower, pipe racks for instrument air “Outotec® LURO2 sulphur burning
system”, written for Sulphur (Jan 2016).
and liquid sulphur as well as an ignition
device. Completing Outotec’s burner
Figure 13: Outotec® LURO2 burner