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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING

SDS No R020 Issue No 1 Date: 01/11/2016

Revision
1.1 Identification of the preparation PVC Compound - Granular form
Product
1.2 Recommended use Thermoplastic conversion

1.3 Supplier:
Vinyl Compounds Ltd
Stephanie Works
Chinley
High Peak
SK23 6BT
Tel: 01663 750221
Fax: 01663 751877
E-mail address of person responsible for safety data sheet:
sds@stephanieworks.co.uk

1.4 Emergency telephone: 01663 750221

2. HAZARDS IDENTIFICATION

Classification according to Directive 67/548/EEC or Directive 1999/45/EC:

Xn – Harmful
Xn – Sensitising

R68: Possible risk of irreversible effects.

R42/R43: May cause sensitisation by inhalation and skin contact.

Physical and chemical hazard: Thermal decomposition giving toxic and corrosive products.
Safety phrases:
S22: Do not breathe dust.
S36/37: Wear suitable protective clothing and gloves.
S45: In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S60: This material and its container must be disposed of as hazardous waste.

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3. COMPOSITION/INFORMATION ON INGREDIENTS

Information on hazardous ingredients:

No Chemical %w/w Range CAS No EINECS No

1 Acrylic Process aid 2.5≤ Cn < 10%

2 3-acetyl-6-methyl-2H-pyran-2,4 <0.1% 520-45-6 208-293-9

(3H)-dione
3 Zinc Dibenzoate <0.1% 553-72-0 209-047-3

4 C,C’-Azodi(formamide) <1% 123-77-3 204-650-8

5 Zinc Oxide <0.1% 1314-13-2 215-222-5

6 Diphenyloxide-4,4- <0.1% 80-51-3 201-286-1

disulphohydrazide (OBSH)

No Annex -1 No Hazard Symbol Risk Phrases (see Section 16 for text)

1 Xn R22
2 Xn R22
3 N, Xi R41, R50/53
4 Xn R42, R44
5 N R50/53
6 Xn, Xi, N, E R22. Muta Cat 3. R68, R36/38, R51/53,
R2, R43

4. FIRST AID MEASURES

Inhalation: Inhalation of vapours due to thermal decomposition;

Move to fresh air
Oxygen or artificial respiration if needed
Skin Contact Cool skin rapidly with cold water after contact with hot polymer.
In case of adhesion do not try to remove the product.
Treat the affected surfaces as thermal burns
Eye Contact Cool eyes rapidly with cold water after contact with molten polymer.
Consult an ophthalmologist quickly.

5. FIRE FIGHTING MEASURES

Suitable Extinguishing Media Water Spray

Specific Hazards Thermal decomposition giving toxic and corrosive
products:
Hydrochloric acid gas
Carbon oxides
Specific Methods In case of fire nearby, remove the bags.

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If the product is burnt, wash off metallic surfaces and

walls to avoid corrosion.
Special protective Equipment Wear a self-contained breathing apparatus and
For Fire fighters waterproof clothing

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PROTECTION Evacuate non-essential staff and those not equipped

ENVIRONMENTAL PROTECTION
with individual protection apparatus.
Sweep up or vacuum to prevent hazard of slipping
Product handled when hot; wear gloves
Do not release into the environment.
Do not allow to enter drains, sewers or watercourses.
Inform respective authorities in case of seepage into
water course or sewerage system.

7. HANDLING AND STORAGE

HANDLING Provide appropriate exhaust and ventilation at machinery.

Provide electrical earthing of equipment.
Provide self-contained breathing apparatus nearby.
Provide showers, eye-baths.
Do not eat, drink or smoke where product is used.
Safe handling advice Wear dust mask and glasses if necessary.
Wear gloves (product handled when hot).
Avoid accumulation of static discharges during transfers in metallic
systems.
Whilst emptying containers, ensure vacuuming of dust.
At all stages of the operation, do not exceed the temperature at
which decomposition into toxic and corrosive products will occur.
-In case of unexpected or premature stoppage of mixing or conversion
machines; turn off the heat source.
- wear a self contained breathing apparatus (if necessary)
- Remove the product
STORAGE Store in clean dry well ventilated conditions at ambient temperatures.
Keep away from sources of ignition.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

PROTECTIVE PROVISIONS Provide ventilation of the premises, extraction of dust or

vapours likely to be given off during conversion operations.
Exposure guidelines Dusts
FRANCE 1993: VME=10 mg/m3
USA-ACGIH 1996: TLV-TWA = 10 mg/m3

PERSONAL PROTECTION EQUIPMENT-

Respiratory protection Wear a self contained breathing apparatus in case of thermal
decomposition of the product
Hand protection Neoprene gloves
Eye protection Safety glasses

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Skin and body protection Protective clothing

Specific hygiene measures Avoid contact with skin and eyes

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE (20 °C) Solid pellets (1-5mm)

COLOUR natural white or coloured
ODOUR Slight
MELTING POINT/RANGE 150 °C (approximately) (pasty)
DECOMPOSITION TEMPERATURE Beginning to decompose from 200 °C
FLAMMABILITY (Solid, Gas) Lower limit: 125 mg/m3
AUTOIGNITION TEMPERATURE 580 °C
BULK DENSITY (20 °C): 500-800 kg/m3
SOLUBILITY -
Water Insoluble (20 °C)
Solvents Slightly soluble in;
Cyclohexanone
Dimethylsulphoxide
Tetrahydrofuran

10. STABILITY AND REACTIVITY

CONDITIONS TO AVOID Store away from moisture and heat to maintain the technical
properties of the product.
Keep at temperatures below 40 °C
HAZARDOUS DECOMPOSITION PRODUCTS -
Thermal decomposition giving toxic and corrosive products:
Hydrochloric acid
Carbon oxides
MATERIALS TO AVOID Acetal resins- possible violent reaction at elevated
temperatures.
Strong oxidising agents.

11. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
Ingestion Harmful if swallowed.
Inhalation Dust inhalation:
- Possible irritation of the respiratory system.
- At high temperature, products of thermal decomposition
can be irritating to respiratory system.
- Sensitisation possible through inhalation.
Skin contact Unlikely to cause skin irritation
Sensitisation possible through skin contact
Eye contact Unlikely to cause eye irritation
Dusts: Possible irritation of eyes (mechanical action)
CHRONIC TOXICITY Polymer: No particular problems for man

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12. ECOLOGICAL INFORMATION

PERSISTENCE /DEGRADABILITY-
In water Inert polymer
Not biodegradable on the basis of its structure
Harmful to aquatic organisms.
Do not allow undiluted product or large quantities of it to reach
ground water, water course or sewage system.

13. DISPOSAL CONSIDERATIONS

DISPOSAL OF PRODUCT Recycle if possible, or

Destroy the product by incineration, note toxic and corrosive
combustion products.
Do not allow product to reach sewage system.
Dispose of in accordance with local and national regulations.

14. TRANSPORT INFORMATION

ADR/RID Not regulated

IMDG Not regulated
IATA Not regulated

15. REGULATORY INFORMATION

EC CLASSIFICATION/LABELLING Labelling not required

RESTRICTIONS

16. OTHER INFORMATION

RISK PHRASES ARISING FROM INGREDIENTS

LISTED IN SECTION 3
R2 Risk of explosion by shock, friction, fire or other sources of
ignition
R22 Harmful if swallowed
R36 Irritating to eyes
R42/43 May cause sensitisation by inhalation and skin contact
R44 Risk of explosion if heated under confinement
R50/53 Very toxic to aquatic organisms, may cause long term
adverse effects in the aquatic environment
R52/53 Harmful to aquatic organisms, may cause long term
adverse effects in the aquatic environment
R68 Possible risk of irreversible effects
_________________________________________________________

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REVISIONS

Issue: 1 Date: 01.11.2016

Revision: Date:
Changes:

__________________________________________________________

This information applies to the PRODUCT AS SUCH and conforming to specifications of Vinyl
Compounds Ltd.
In case of formulations or mixtures, it is necessary to ascertain that a new danger will not
appear.
The information is based on our knowledge of the product, at the date of publishing and it is
given quite sincerely. However the revision of some data is in progress.
Users are advised of possible additional hazards when the product is used in applications for
which it was not intended. This sheet shall only be used and reproduced for prevention and
security purposes.
The references to legislative, regulatory and codes of practice documents cannot be
considered as exhaustive.
It is the responsibility of the person receiving the product to refer to the totality of the official
documents concerning the use, the possession and the handling of the product.
It is also the responsibility of the handlers of the product to pass on to any subsequent persons
who will come into contact with the product (usage, storage, cleaning of containers, other
processes) the totality of the information contained within this safety data sheet and necessary
for safety at work, the protection of health and the protection of the environment.

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