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Silicon-Ceramic

Composite
Substrate
Michael Fischer, Sebastian Gropp,
Johannes Stegner, Astrid Frank,
Martin Hoffmann, and Jens Mueller

T
he starting point for integrating RF func- ceramic layer) must take place
tions in silicon (Si) and low-temperature before any micro or nano struc-
cofired multilayers with an Si-ceramic turing is performed. Thus, the
(SiCer) composite substrate was the need influence of these processes on
for cross-sectional construction and con- sensitive structures (especially
nection of both parts from the nanometer to millimeter on sensitive mechanical systems)

IMAGE LICENSED BY INGRAM PUBLISHING


range. The application of nano and micro effects and can be minimized.
structures in microelectromechanical systems (MEMS) For the manufacturing of RF compo-
requires the fabrication of intelligent and robust con- nents, different substrate materials are used depend-
nections (electrical, mechanical, fluidic, and thermal) ing on the particular application. Because of their
to a manageable carrier system or a printed circuit outstanding dielectric properties, ceramic materials in
board. These functions are enabled using SiCer sub- a 3D multilayer technology [low-temperature cofired
strates [1]. Crucial back-end processes such as assembly ceramic (LTCC)] are primarily used for passive com-
and packaging (mechanical Si bonding or wiring in the ponents (capacitors and inductors), functional groups

Michael Fischer (michael.fischer@tu-ilmenau.de) and Jens Mueller (jens.mueller@tu-ilmenau.de) are with the Electronics Technology Group,
IMN MacroNano, Technical University of Ilmenau, Germany. Sebastian Gropp (sebastian.gropp@tu-ilmenau.de) and Martin Hoffmann
(martin.hoffmann@tu-ilmenau.de) are with the Micromechanical Systems Group, IMN MacroNano, Technical University of Ilmenau, Germany.
Johannes Stegner (johannes.stegner@tu-ilmenau.de) is with the 3RF and Microwave Research Group, IMN MacroNano, Technical University of
Ilmenau, Germany. Astrid Frank (astrid.frank@imms.de) is with the Institute for Microelectronics and Mechatronics Systems, Ilmenau, Germany.

Digital Object Identifier 10.1109/MMM.2019.2928675


Date of publication: 10 September 2019

28 1527-3342/19©2019IEEE October 2019


(filters, phase shifters, and antennas), and circuit structures such
boards. Mechanical (moving) RF components (switch- as moving ele-
es and acoustic resonators) as well as electronic RF ments and hinges
components (amplifiers, buffers, and bias circuits) are are realized in the
realized with semiconductor substrates [Si and gal- Si layer due to Si’s
lium nitride (GaN)/Si carbide] using semiconductor superior mechanical
and thin-film technologies [2]–[4]. However, a limiting properties. After MEMS
element in classical ceramic technology is the achiev- processing, individual ele-
able geometrical resolution (minimally printable con- ments and areas in the Si layer
ductor widths at 40  µm and minimally punchable can be separated from each other by
vias at 75 µm). Because of their surface and material deep reactive ion etching (DRIE). Simultaneously,
properties, semiconductor technologies (CMOS and other LTCC areas can be exposed for mounting noninte-
MEMS) enable the use of thin-film technology. During grable devices (e.g., CMOS devices). Because its thermal
processing, it is possible to achieve significantly high- expansion coefficient is similar to that of Si, the LTCC
er lateral resolutions and thereby significantly shorter material can also be used to manufacture functionalized
signal paths than in ceramic technology. On the other housings. Figure 1 shows the fabrication concept of SiCer
hand, such semiconductor materials have generally composite substrates.
poorer dielectric properties than ceramic materials.
Due to the conductivity of the semiconductor materi- Si-Bonding Techniques
als, the dissipation factor is significantly higher com- Back-end processes in wafer format require wafer-
pared to ceramic. bonding techniques. These techniques are divided
Monolithic SiCer-composite substrates combine the into wafer bonding without intermediate layers
advantageous properties of both substrate classes (Si (e.g., direct Si and anodic bonding) and bonding
and LTCC). Current bonding concepts for Si on ceram- with intermediate layers using solder, adhesive,
ics require auxiliary materials such as solders, adhe- glass frits, or eutectic bonding. In either case, both
sives, or glass frit, which are usually avoided due to wafers need to be TCE-matched to avoid bending,
differences in thermal coefficient of expansion (TCE). delamination, or cracking under thermal load. Typi-
Alternatively, Si components can be mounted to a TCE- cal bonding partners are Si, glass [5], [6], and glass
matched, prefired LTCC by anodic bonding. The latter ceramics, including LTCC [7]. The use of LTCC can
requires expensive surface polishing, which becomes be very beneficial because it can already contain
obsolete with new techniques [1]. horizontal and vertical wiring (minimization of par-
SiCer-composite substrates can be manufactured asitic elements). However, the typical as-fired sur-
and processed by standard LTCC and Si technologies. face roughness is insufficient for an anodic bonding
The stack basically consists of an LTCC layer, ensur- procedure; expensive grinding and polishing steps
ing passive electronic functionality, and usually a thin are necessary.
Si layer that ensures thin-film processing for MEMS
components. The technology design is more complex Bonding of Wafer-Shaped LTCC and Si
than a classic design for semiconductor MEMS devices, Substrates Using Anodic Bonding
because the assembly and packaging technology must One suitable method for bonding LTCC and Si wafer-
be taken into account from the beginning. However, shaped substrates is anodic bonding. For the fabrica-
this added complexity in the design phase is worth the tion of an anodically bondable LTCC wafer,
effort, because with SiCer it is possible to combine very a sodium-containing ceramic material is
short vertical signal paths with integrated functions in necessary. This LTCC material (devel-
the system housing. oped by the Fraunhofer Institute for
Usually, the manufacturing process begins with the Ceramic Technologies and Systems)
preprocessing of both sublayers of the composite sub- consists in the initial state of a powder
strate. In the LTCC multilayer, for example, wiring and mixture of alumina, cordierite, and a
electrical vias are generated, and thin-film structures sodium-containing glass as well as
such as holes and thin wetting layers are produced in the a polymer binder. The LTCC wafer is
Si layer. After preprocessing, both layers are connected by manufactured separately using stan-
pressure-assisted sintering. The resulting quasi-mono- dard LTCC technologies. After sintering,
lithic composite substrate can be further processed like a the LTCC wafer has a relatively high surface
normal wafer to build the RF component in the Si layer. roughness (Ra $ 200 nm). Because a surface rough-
RF transmission lines can be provided in the ceramic ness of Ra 1 50 nm is necessary for anodic bonding, the
layer due to ceramic’s better dielectric properties. MEM LTCC wafer must be lapped and polished. Subsequently,

October 2019 29
Si and LTCC wafers are aligned to each other and heated establish an electrical connection between the sub-
to 400 °C, and a dc voltage exceeding 600 V is applied. strates [Figure 2(a)]. To avoid the expense of polish-
The electric field causes sodium depletion at the bond ing. Ihle et al. [9] used a glassy carbon with a very low
interface, electrostatic attraction, and formation of oxy- surface roughness as a nonwetting separating plate
gen bridges between the Si surface and the glass portion during the sintering of the preprocessed LTCC wafer
of the LTCC, resulting in hermetic bonding. [Figure  2(e)]. In this way, the expenditure for polish-
Mohri et al. [8] used this method to bond prestruc- ing can be minimized or completely avoided. Ihle et
tured Si and LTCC wafers together and simultaneously al. have demonstrated the technological feasibility
and use of anodic bonding to provide preprocessed Si
wafers with sensor structures having robust electrical
contacts (vias and wiring).
Via Holes Si One disadvantage with both methods is that the
substrates cannot be processed further after the bond-
ing because sodium-containing substrates are no
longer compatible with standard semiconductor pro-
cesses. Furthermore, process-induced LTCC shrink-
age tolerances, which can also occur locally, lead to
Via, Wiring, Resistors, LTCC
Inductors, Capacitors problems in alignment of both joining partners
(a) because the positions of the electrical structures dif-
fer between the materials. This effect also increases as
wafer size increases.

(b) SiCer Bonding Techniques


MEMS Devices With TSVs The bonding between the two layers of the SiCer
substrate always occurs during the sintering of the
ceramic multilayer. For this, a family of alkali-free,
Si-adapted LTCC tapes [material designation: bond-
(c) able ceramic tape (BCT)] has been developed [10]. In
MEMS Switch MEMS Resonator principle, BCTs consist of a powder mixture (Figure 3;
particle size in the 400-nm range) of nonmelting com-
ponents and a melting glass component (sodium-free)
(d) as well as a polymer binder. Various ceramic tapes are
available for the construction of the SiCer substrates.
MEMS LTCC
MEMS BCT6 is used most often, as it has the best properties
Switch Housing
Resonator for bonding to Si. BCT6’s nonmelting filler compo-
BAW nent is quartz. Another tape, BCT1, has significantly
improved properties for screen printing (resolution) of
metal pastes, for example, but it also has lower bond-
ASIC 1 ASIC 2 ing properties (adhesion to Si). The nonmelting filler
Oscillator
(e) component of BCT1 is alumina.
If the glass component reaches the liquid phase
Figure 1. The concept for fabricating SiCer composite during the sintering process, the natural oxide layer
substrates along with the subsequent assembly on the Si surface is wetted by the glass. Depending on
technology. (a) The preprocessing of both substrate the technology employed, the wetting is maintained
layers: Si: hole etching, thermal oxidation, and bond under constraint (pressure sintering, p = 800 kPa) or
interface; LTCC (bondable ceramic tape): via punching, induced by means of thin, wetting intermediate layers
filling, and screen printing. (b) The bonding: lamination in an unconstrained manner (pressure-assisted sinter-
and pressure-assisted sintering (3 kPa, 900 °C). (c) The ing, p = 3 kPa).
MEMS processing: thin-film sputtering/evaporation,
lithography, etching, chemical vapor deposition
processes, and plasma etching. (d) The separation and
Original SiCer Bonding Procedure
exposure of mounting areas: DRIE and etch-stop on With Nanostructures
LTCC. (e) The packaging and mounting of external A nanotextured Si surface is generated by a modi-
devices: soldering, wire bonding (if necessary), and chip fied reactive ion etching (RIE) process that leads to
bonding. TSV: through-Si via; BAW: bulk acoustic wave; homogeneously distributed Si needles, also known
ASIC: application-specific integrated circuit. as black Si or Si grass, across a full wafer. In this case

30 October 2019
a parallel plate reactor (STS 320, Surface Technology there is the possibility of an inhomogeneous bond
Systems, Newport, UK) with a cooled wafer elec- interface between the LTCC and Si if the wedge error
trode and a sulfur hexafluoride (SF6) /oxygen plasma compensation of the sintering furnace does not work
is used. Depending on the process time, needles up properly due to impurities on the sinter plate. A
to 2.5  µm in length can be achieved, with a diameter closer inspection of the bond interface between the
varying from top to bottom between 5 and 400 nm, as LTCC and nanostructured Si surface after the sinter-
can be seen in Figure 3(b). The needle-like structures ing process reveals the problem: the softened glass of
have a pitch between 100 and 200 nm. For an adequate the LTCC matrix does not wet the Si surface properly.
penetration into unfired ceramic tape, the needles are Only the areas where there is high ambient pressure
too long and flexible. Therefore, an additional plasma are wetted by the glass. At regions with less or no
treatment with argon is performed for shrinking and pressure, the glass shows a typical nonwetted shape,
thinning out the needles, as indicated in Figure 3(c), to which is a well-known effect of nanostructures with
adapt the needle geometry to the powder morphology dewetting properties for liquids (Figure 4).
of the unfired BCT, as displayed in Figure 3(a). The effect of surface roughness on the wetting
The first step of the bonding procedure is a lami- behavior of liquids on structured solids was described
nation process of the nano-structured Si surface with by ­Wenzel [12]. In response, Young’s law was extended
the green BCT (“green” refers to unsintered ceramic by a so-called roughness factor r which represents the
tape) to bring the substrates into close contact. The ratio of the structured surface area to the (projected)
needles penetrate the polymer matrix of the green geometrical surface r $ 1, shown in Figure 5. Wenzel’s
tape, and the particles touch the needle surfaces. equation for the contact angle reads [13]
Pressure, time, and temperature, as well as the force
rising rate, are important lamination parameters cos i w = r · cos i y,
and determine the bonding properties of the final
compound. For the lamination, an isostatic press is with i w for the Wenzel contact angle and i y the
used to eliminate the risk of plate parallelism failure Young contact angle. A key result is that any kind of
with a standard press. Due to the highly increased mechanical surface modification, and thus change in
su r face a rea ( h ig h ly con-
centrated Si tips), a form-fit
bonding and a material con-

5–50 µm
nection between the glass LTCC Au LTCC
Au
phase of the BCT and Si are
generated by pressure sinter-
ing (lateral zero shrinking). SiO2 Porous Au Bump

1–20 µm
(a) Au/Pt/Cr
The firing profile works with
a pressure of 0.8 MPa and a Au
LTCC SOI Wafer
peak temperature of 900  °C.
A typical scanning electron
Diaphragm
microscope (SEM) view of the
(b) (c)
resulting interface is shown
in Figure 3(d).
Au
SiCer Bonding Procedure LTCC
Using Wetting Layers
The sintering approach with
high pressure at high temper-
atures also has drawbacks:
Si usually undergoes plastic
deformations at temperatures
(d) (e)
above 600 °C [11] if a mechan-
ical stress gradient is applied;
Figure 2. The generation of an Si LTCC wafer composite with gold (Au) vias bonded
during the sintering process by anodic bonding with a polished LTCC surface [8]. (a) The production of the LTCC
at 800 to 900  °C under high substrate. (b) Wet-etching the LTCC wafer to make a cavity. (c) The LTCC and Si
isostatic pressure, the Si base substrates are aligned. (d) Anodic bonding forms an electrical connection. (e) The surface
material could suffer struc- of a bondable LTCC wafer with gold vias fabricated using glassy carbon [9]. Pt: platinum;
tural damage. Furthermore, Cr: chrome; SOI: silicon on insulator.

October 2019 31
LTCC Glass Phase
Nonmelting
Particle

1 µm 1 µm 1 µm Si Tip
100 nm
(a) (b) (c) (d)

Figure 3. A set of SEM images showing stages in the development of BCT. (a) A view of the powder morphology of BCT
without the polymer binder. (b) Si that has been nanotextured by RIE. (c) The textured Si after treatment with argon
plasma. (d) A view of the bond interface with nano structures after sintering.

the wetting promoter should, at least, not degrade the


adhesion of the glass to the Si surface.
Si
It is well known that there are promising adhe-
sion-promoting layers in MEMS technology. Nor-
mally they are used to get a proper bond of metals
on Si: titanium (Ti) or chromium, physically vapor-
deposited in very thin layers (1 30 nm). In this case,
both materials undergo oxidation during sintering,
LTCC as this usually happens in air. For LTCC firing as
500 nm 1 µm
(a) (b)
well, oxygen is mandatory to burn the binding poly-
mers. For this reason, an oxidation of Si and Ti can be
assumed. Figure 6(a) shows Si nanostructures, man-
Figure 4. Two SEM photos from the LTCC tape fabrication
ufactured for SiCer fabrication and the particle size
process. (a) A view of typical dewetting behavior between Si
needles and the LTCC. (b) The back side of the LTCC tape of the LTCC matrix. In this case, the needles were
after sintering, showing single Si needles with their tips coated with Ti after annealing in air. The surface
sticking out of the molten glass matrix of the LTCC. exhibits an additional substructure of Ti dioxide in
the nanometer range.
Ti is known to be a suitable addition in low-TCE
glasses [14] and glass ceramics [9] based on borosilicate
σL glasses. It can be assumed that it forms a strong glassy
network close to the surface that supports wetting by
the softened glass as well as an excellent bonding of
σS θy the glass on the silica surface. As the total amount of Ti
σLS
is in the lower parts per million range, it proves chal-
lenging to identify the detailed glass composition at
Nanostructured Si Surface
the interface.
As the investigation of a SiCer substrate after suc-
cessful sintering is quite difficult, in the present study,
Figure 5. A schematic view of molten LTCC on a
the substrates were tested by performing sintering
nanostructured surface.
experiments using the previously described modified
Si nanostructures and finely ground glass powder
the roughness, intensifies the wetting behavior of that from the LTCC matrix.
surface: wetting and dewetting are amplified. Based On Si grass wafers, a thin layer of Ti (25 nm) was
on this fact, it becomes clear that the contact angle sputtered as sketched in Figure 6(b). As a reference,
between the glass melt of the LTCC and the solid Si a second wafer with uncoated Si grass was tested.
surface must be reduced by a wetting promoter to val- Small amounts of the finely ground glass powder were
ues below 90°. The nanostructures will then allow for applied on these wafers. The samples were annealed
a perfect wetting of the surface. On the other hand, at 900 °C for 25 min in air. During the sintering, the Ti

32 October 2019
reacts with the oxygen of the ambient air in the furnace such as beams and membranes, using nanocarbon
to form Ti dioxide (TiO2) [15], [16]. paste at the SiCer bond interface.
Table 1 summarizes the results of the annealed glass
powder samples, processed according to the standard Advantages of the Composite Substrate
procedure for SiCer fabrication. The SEM pictures dis- LTCC technology is a mature substrate technology
play a clear difference between the uncoated and Ti- for RF and microwave modules in different fields
coated Si surfaces. The most obvious difference is the of application, such as satellite communications,
strong corona around the molten glass powder on the automobile manufacturing, and medicine. Typical
TiO 2 sample. applications place strong requirements on LTCC sub-
The corona consists of solidified glass that has strates in terms of reliability and durability under
filled the pores between the needles during annealing. even harsh environmental conditions [19]. LTCC
Due to the fast solidification of small amounts of glass technology is also considered a high-density inter-
after sintering, the triple-phase contact line of hemi- connect technology due to its multilayer capability
wicking was identified (hemi-wicking can be described and the ability for direct integration of passive device
as an intermediate state between spreading and imbi-
bition). This type of wetting was discussed in [17] for
common liquids. Here, the nanostructured surface is
considered a porous material that “soaks” softened
glass into the structures. However, this is only a par- 1) Nanostructured Si
tial process, and so the tips of the needles around the
glass powder sample are kept free from glass wetting. 2) Bare Ti
The principle is sketched in Figure 7. Deposition of Ti Glass Power
changes the dewetting behavior of the surface into 3) Bare Ti
wetting behavior. Figure 7(b) confirms this conclusion
via SEM. 500 nm
(a) (b)
Through the Ti coating of the nanostructured Si
surface, the SiCer composite substrate can now be
Figure 6. (a) An SEM photo of Ti-coated Si needles (black
fabricated at a reduced pressure during the sintering
Si) after annealing in air. (b) A schematic view of the
process. This allows for the fabrication of compound wetting behavior of glass powder on bare and modified
substrates without pressure-induced crystal damage in nanostructures. In the first step, nanoscaled needles are
Si and presumably with much higher bond strength. etched using RIE in the Si substrate. Subsequently, the
Furthermore, new fabrication methods are now possi- substrates are locally coated with a thin layer of Ti. On these
ble for releasing movable and active MEMS structures, surfaces, the glass powder is applied.

TABLE 1. A comparison of molten glass powder on bare and Ti-coated Si needles.

Glass Powder From LTCC Matrix SEM × 50 Magnification Detail: SEM × 12 k Magnification
Bare Si grass surface

Si grass surface with 25-nm Ti

October 2019 33
functions [20]. The implementation of 3D structures accomplished at the wafer level without the additional
such as cavities or channels opens up options for flu- processing steps and interface materials required by
idic system packaging [21]. typical LTCC cofiring. Structuring the Si layer is typi-
Besides being used for fabricating integrated cir- cally accomplished after firing (postprocessing); conse-
cuits or photovoltaic cells, Si is also used for mechani- quently, the effort needed to mount such manufactured
cal systems. MEMS can be widely found in sensor MEMS devices is low. In addition, the use of conven-
applications or as RF components. Figure 8 shows an tional LTCC mounting technologies on the ceramic
example with piezoelectric MEM double-clamped layer of SiCer (soldering, flip-chip bonding, housing,
beam resonators from epitaxially grown aluminum and so on) enables real wafer-level packaging.
GaN (AlGaN)/GaN layers on Si [22]. Individual com- SiCer is, on one hand, a substrate on which a
ponents are manufactured in large arrays at wafer MEMS component (e.g., a resonator in the Si layer)
level. In most cases, they need to be hermetically can be manufactured and, on the other hand, a cir-
sealed, which can be achieved either at wafer level or cuit carrier in which an electronic control (e.g., an
by packaging after singulation and picking from the oscillator circuit in the ceramic layer) is realized. Due
wafer. The latter process provides higher design flex- to the more compact design and short vertical signal
ibility but at higher cost. paths, parasitic conduction effects (e.g., capacitance)
The SiCer composite substrate combines the advan- are reduced [23].
tages (best of two worlds) of multilayer, low-tem-
perature, cofired technology and Si microelectronic New Technological Capabilities Using SiCer
and MEM technologies. Bonding of both materials is
Cavities, Gaps, and Windows
in the Ceramic Layer
The preparation of cavities and windows in the ceramic
Triple-Phase layer of the composite substrate extends the techno-
Contact Line logical opportunities of Si-MEMS technologies to the
Liquid design of switches and resonating elements. For exam-
Air dx ple, through the integration of cavities, resonators can
be decoupled from the substrate, or Si solid joints and
membranes can be etched thinner through a window
Solid
in the ceramic; a fabrication of backside contacts in the
500 nm
Si layer is enabled by a ceramic opening.
(a) (b)
Windows are made by punching or laser cutting
all the individual ceramic layers and by exact stack-
Figure 7. (a) A sketch of the spreading and imbibition of ing and lamination. However, the pressure at peak
glass in a porous material. (b) An SEM image of a molten temperature (900 °C) of the sintering profile must be
glass sample on Ti-sputtered RIE nanostructures. The
significantly reduced (from 800 kPa to 250 kPa for a
powder forms clusters due to high surface tension. Where
100-mm wafer) to avoid a deformation of the ceramic
it contacts the modified nanostructures, the contact angle
remains below 90° [18]. dx: direction of propagation. structure. Figure  9(a) shows 4-mm-square windows
in the ceramic layer of a SiCer substrate. The prepara-
tion of cavities at the interface of Si and BCT6 was car-
ried out with the help of carbon tape (C12, Advanced
Technologies; thickness: 127 µm). For this purpose,
suitable pieces of carbon tape are inserted into a pre-
prepared BCT6 stack with exactly punched or lasered
cutouts in the top layer. The preprocessed stack is
then laminated with the carbon-filled side facing the
Si wafer (Si surface is nanostructured [4]) and is sub-
sequently sintered under pressure. Figure 9(b) illus-
trates 6-mm-square cavities in the ceramic layer of a
SiCer substrate.
20 µm It is important to reduce to a minimum the lat-
eral gap between carbon and the BCT window (by
Figure 8. An SEM image of beam resonators from selecting optimum laser parameters). The second
epitaxially grown AlGaN/GaN layers. (Source: K. Tonisch; row in Figure  9(b) depicts the behavior of the sin-
used with permission.) tered ceramic when reducing the gap by 5  µm per

34 October 2019
BCT Window
Cracks

Decrease of Gap Distance


Between Carbon and BCT
Underlying
Si Layer

(a) (b) (c)

Figure 9. A SiCer substrate with (a) windows on the ceramic side, (b) cavities at the interface of Si and BCT, and (c)
vertical gaps (light gray colored; BCT is translucent) at the interface.

column (beginning with 25  µm on the left-hand 9260 with a thickness of 8 µm was applied. Because of
side). If the lateral gap is too large, the BCT is the translucence of the BCT6 layer, the progress of Si
already damaged during lamination, which leads removal can be easily followed. Figure 10 displays sev-
to cracks during burnout and sintering. The use of eral stages of etching.
local vertical gaps simplifies the manufacture of The etching rate at the wafer edge (3.1 µm/min)
movable switch elements and solid joints because is significantly higher than in the middle (2.0 µm/min)
it is not necessary to release them subsequently by of the wafer. Obviously, this is caused by the ther-
additional etching processes (e.g., sacrificial layer mal conductivity of BCT6, 1.4 W/(m∙K), which is
etching at Si on insulator substrates). The procedure approximately 100 times lower than that of Si. Thus,
is similar to that for cavities. Instead of inserting a the helium backside cooling of the peripheral area of
carbon tape, a nanocarbon paste is deposited using the wafer during etching is inefficient, and the etch-
screen printing where bonding between Si and BCT ing rate increases. The open Si etching area in the
is to be prevented. This results in a vertical gap of selected mask design amounts to 38%. In this case
approximately 4 μm [Figure 9(c)]. Subsequently, the an etch selectivity between Si and AZ 9260 of 57:1 is
desired structure can be etched through the Si layer determined. During the whole etching process, the
by means of DRIE. maximum substrate temperature of 55 °C was not
exceeded (confirmed with an integrated pyrometer).
DRIE of SiCer Substrates As shown in Figure  10(d), the etched side walls of
Another advantage of the SiCer substrate is that the the Si structures are perpendicular to the surface
ceramic layer takes on the carrier function, and Si is of the substrate, which established that the etching
used only where the specific properties (mechanical
properties, thin-film functions, and lithography) are
required. It is possible to eventually remove unneeded TABLE 2. Process parameters for the DRIE of SiCer.
Si through an etching process and decouple indi-
Passivation Etching
vidual RF components in the semiconductor layer, if
C4F8 gas flow (sccm) 85 –
necessary. DRIE was chosen to structure the Si layer
because it lends itself to good process control. As the SF6 gas flow (sccm) – 130
etching device, an STS Multiplex ICP (inductively O2 gas flow (sccm) – 13
coupled plasma) tool was used. The tool provides an Cycle time (s) 7 13
advanced Si etch (ASE) process that consists of alter- Coil power (W) 600 600
nating cycles of etching and polymer deposition to Platen power (W) – 18
protect the side walls from further etching. The basic Chamber pressure valve Constant at 82%
process parameters are listed in Table 2. The etching
Chamber temperature (°C) 40
behavior was tested on a 100-mm SiCer substrate. The
Plate temperature (°C) 20
wafer has a thickness of 634 µm (Si layer: 380 µm; BCT6
Helium backside cooling Yes
layer: 254  µm). For masking, positive photoresist AZ

October 2019 35
A good heat transfer in the substrates, compatible metal pastes for soldering
and wire bonding needed to be found. This section
substrate ultimately determines the describes the process and results of the investigations
integration density of the electronic aimed at finding the best available paste systems from
components and thus the size of the third-party sellers.
The workability (printing and sinter behavior) of
RF modules to be assembled. cofired metal pastes on BCT has been visually assessed
in [24]. However, for the integration of external devices
(SMD or bare chip) on SiCer composite substrates,
behavior of SiCer wafers using DRIE is consistent quantitative investigations of wire bondability and
with that of standard Si wafers. Only the homogene- solderability of BCT to metal pads are also essential.
ity of the etching rate across the whole wafer appears To assess this, test patterns of candidate metal pastes
to be slightly lower. (Table 3) were created for the different BCTs using
For separating areas protected by photoresist screen printing and pressure-assisted sintering.
(rapid Si removal), the described etching process is After substrate dicing, 50 wire bonds (ball-wedge,
adequate. For the etching of finer structures (e.g., Au, 25 -µm wire th ick ness) per metal pad were
flexure hinges and springs; structure size: <20 µm), applied, using an automatic wire bonder (Delvotec
an adaptation of the etching process is necessary 5610). For the evaluation of solderability, solder paste
(e.g., adjusting the gas ratio in the plasma). Due to was applied (Alpha, OM 338, lead-free) by stencil
the lower thermal conductivity of the ceramic layer, printing on the pads, and SMD resistors (type 0402)
an increased temperature in comparison with a stan- were mounted on the patterned BCT carrier with
dard Si wafer is observed on the substrate surface an automatic chip placer (Vico, Häcker GmbH) and
during etching. This leads to a reduction of the poly- reflowed in a box furnace (RP 6, SEF Systec GmbH).
mer deposition rate (passivation cycle) and therefore Figure  11 illustrates a typical result. Subsequently,
to a premature etch attack. Here, two strategies are all connections were destructively tested with the
conceivable: the platen temperature could be low- Condor 70 pull and shear tester (XYZTEC). Pull and
ered (e.g., from 20 to 15 °C), or the passivation cycle shear strengths of the wire bonds as well as shear
time could be increased (e.g., from 7 to 9 s). Further- strengths of the soldered devices were determined
more, an inhomogeneous heat dissipation and thus a and compared.
reduced etch uniformity are to be expected when a The experiments show that the gold pastes exhibit
SiCer substrate with windows in the ceramic layer is the highest wire bonding strengths on BCT1 and BCT6;
structured by DRIE. This will be the subject of fur- however, silver-palladium pads also exhibit acceptable
ther investigations. strengths in combination with BCT1 (Figures  12 and
13). On BCT6, the silver-containing pastes show a highly
Metal Pastes for BCTs glazed surface; thus, no wire bonds can be realized.
At this time, there are no commercially available, spe- For soldering, the silver pastes have the highest
cially developed metal paste systems for SiCer technol- shear strengths, especially on BCT1 (Figure 14). Above
ogy. Thus, to integrate electronic components, such as all, silver-platinum pads (TC 7601) have the highest
surface-mount devices (SMDs) or bare dies, on SiCer shear strength in combination with BCT1.

Freestanding
Si Chip

BCT 6

5 mm
(a) (b) (c) (d)

Figure 10. Photos documenting several stages of Si etching on SiCer after (a) 131 min, (b) 163 min, and (c) 185 min. (d) A
detail view of separated test chips.

36 October 2019
Thermal Behavior of SiCer Measuring Assembly
It is important to know the thermal behavior (thermal The thermal resistance of a SiCer junction is determined
resistance) of a novel RF circuit carrier material. In by a self-adjusting temperature difference between the
particular, it is essential to ensure good heat dissipa- Si and the ceramic of the SiCer wafer at a defined heat
tion for lossy components (power amplifiers). A good flow through the substrate. A SiCer carrier structure
heat transfer in the substrate ultimately determines the was fabricated containing a thermal test chip (PST1-02,
integration density of the electronic components and Delphi Corporation). The square-cut chip has an edge
thus the size of the RF modules to be assembled. length of 3 mm and was glued with a silver-filled adhe-
The BCT layer in a SiCer substrate has a signifi- sive (m = 60 W/(m $ K )) to the SiCer carrier. The chip
cantly lower thermal conductivity [<0.9 W/(m∙K)] includes a planar resistor for generating a thermal load
than the Si [150 W/(m∙K)]. This leads to a consider- (P ) and diodes that are used as a temperature sensor
ably increased thermal resistance of the composite to measure the chip temperature (TJ) . To ensure stable
substrate compared to a standard Si wafer of similar measuring conditions, the SiCer carrier was placed on a
dimensions. However, fully metallic thermal vias can temperature-stabilized heat sink. The heat sink consists
be generated in the LTCC layers to reduce the thermal of a Peltier element, a water cooler on the back side, and
resistance of the BCT layer [24], making it is possible a copper heat spreader on top of the Peltier element. Fig-
to build up a substrate with locally adjustable ther- ure 15 depicts the setup.
mal resistance. The following section describes the
procedure for determining the thermal resistance as
well as the technological implementation of various 40
36 36
SiCer configurations. 35 33 34
Shear Strength (cN) 30
30
27 25
25 23

Not Bondable

Not Bondable

Not Bondable

Not Bondable
20
TABLE 3. The evaluated metal pastes for BCTs.
15
Name Manufacturer Material Recommended Use 10
TC 7601 Heraeus AgPt Fine line, solderable 5
0 0 0 0 0
TC 7305 Heraeus Ag Fine line, solderable
01

05

02

01

02
QG 150 DuPont Au Fine line, etchable
15
76

73

71

74

74
G
Q
TC

TC

TC

TC

TC
TC 7102 Heraeus Au Fine line, AI/Au wire
bondable
BCT1 BCT6
TC 7401 Heraeus AgPd, Fine line,
27:1 development state
Figure 12. A comparison of the shear strength of ball bonds
TC 7402 Heraeus AgPd, 6:1 Fine line, solderable
(Au, 25-µm diameter) on the investigated metal pads on
AgPt: silver platinum; AgPd: silver palladium.
BCT. The metal pastes used are detailed in Table 3.

10
9
9 8 8
8 8 8
Pull Strength (cN)

7 7
6 6
Not Bondable

Not Bondable

Not Bondable

Not Bondable

5
(a) 4
3 3
2
1
0 0 0 0
0
01

05

02

01

02
15
76

73

71

74

74
G
Q
TC

TC

TC

TC

TC

(b)
BCT1 BCT6
(c)
Figure 11. (a) A sheet of BCT substrate with mounted Figure 13. A comparison of the pull strength of wire bonds
SMD resistors. (b) A closeup of a soldered resistor. (c) A (Au, 25-µm diameter) on the investigated metal pads on
sheared wire bond on a pad with QG 150 metal paste. BCT. The metal pastes used are detailed in Table 3.

October 2019 37
The copper heat spreader includes a temperature-
1,200 dependent resistor (PT1000; accuracy: 100 mK at 22 °C)
1,060
for measuring the temperature of the heat sink (TGND).

Pad Sinks Into BCT6


Shear Strength (cN) 1,000
811 The input power of the Peltier element was adjusted by
800

Pad Dissolves
624 a proportional-integral-derivative controller (TED4015,
600 510 Thorlabs Inc.; ! 1 mK stability) using the heat-sink tem-
400 perature as the current value [25]. An ohmic heating
265 285
200 157 generated a thermal load that led to an increase in the
105 110 121
0 0 chip temperature. After reaching thermal equilibrium,
0
the thermal resistance (R th) of the demonstrator was cal-
01

05

02

01

02
15 culated using the following formula:
76

73

71

74

74
G
Q
TC

TC

TC

TC

TC
TJ - TGND
BCT1 BCT6 R th = .
P

Figure 14. A comparison of the shear strength of soldered


Technological Realization of the SiCer Carrier
SMD resistors on the investigated metal pads on BCT. The
metal pastes used are detailed in Table 3. To determine the thermal resistance of a SiCer junc-
tion, various configurations on the substrates were
realized. For a constant via diameter of 200 µm, the
number (from 0 to 9) and the arrangement (distance
Adhesive Thermal Test Chip (P, TJ)
between the outer vias and the chip center) of ther-
BCT Thermal Vias mal vias were varied. The structure of the SiCer wafer
Si was carried out as described previously. The LTCC
TGND SiCer Carrier multilayer consists of five BCT6 layers and one outer
PT1000 Resistor BCT1 layer. The LTCC layers were prestructured by
Copper Heat Spreader punching the via holes and filling with via pastes (TC
701, DuPont, gold/silver mixed-metal paste; and 6141,
Peltier Element DuPont, silver paste), as shown in Figure 16(a). With
Water Cooler the punching operation, the wafer contour of LTCC
(100-mm diameter) was generated simultaneously.
The conducting path for the electrical connection of
the thermal test chip (QG 150, DuPont, gold paste)
Figure 15. The measurement setup, consisting of the SiCer and a metal pad for a better wetting of the adhesive
carrier with a thermal test chip and a temperature-stabilized (6146, DuPont, silver/palladium paste) were applied
heat sink. by screen printing at the BCT1 layer. Subsequently,
all BCT layers were aligned and stacked together by
a lamination step with a 300-µm-thick, double-side
polished Si wafer. A subsequent pressure-assisted
Thermal Vias sintering step generated the monolithic SiCer wafer.
After a substrate cleaning step, the thermal test chips
were assembled on the SiCer wafer with an automatic
chip placer (Vico) using silver adhesive (DM6030,
(b) (c) Diemat). The thermal test chips were connected to
the conducting paths by wire bonding [Figure 16(b)]
before the various SiCer carriers were separated by
sawing [Figure 16(c)].

(a) Behavior Depending on the Number of Vias


(d) Basically, the thermal resistance in the corresponding
substrate area decreases with increasing via number
(or via area). But there must also be enough ceramic
Figure 16. (a) A SiCer wafer (ceramic side) with mounted material to hold the metal vias. In addition, the sinter-
test chips. (b) A test layout with two thermal vias. (c) A ing behavior of the materials used must be taken into
wire-bonded thermal test chip. (d) Several separated SiCer account because, for example, air inclusions (voids) in
carrier modules. the thermal via cause the functionality to fail.

38 October 2019
200-µm Vias Adhesive Layer 200-µm Vias

Voids
Paste: 6141
Paste: TC 701 Air Inclusion

(a) (b) (c)

Figure 17. Several X-ray images of SiCer test modules. (a) Voids that developed in thermal vias. (b) Uniformly distributed air
in the adhesive layer. (c) Homogeneously formed thermal vias.

Increasing the number and therefore total area of SiCer substrate. In the following section, the design,
the thermal vias in the SiCer resulted in a significant simulation, and implementation on a SiCer substrate
reduction of thermal resistance. However, initial simu- are described in detail.
lations with ANSYS of the thermal resistance showed
poor correlation with the measurements. It was found MEMS Switching Topologies
that the paste (TC 701) used for via filling was not suit- Over the last few decades, many MEMS switch topolo-
able for thermal vias in SiCer because voids develop in gies have been presented in the literature. From a cir-
the via holes during sintering [Figure  17(a)]. Further- cuit function point of view, MEMS switches can be
more, uniformly distributed air inclusions formed in divided into two main types: series and shunt switch
the adhesive layer [Figure 17(b)] during the assembly of configuration, as shown in Figure  19. The MEMS-
the semiconductor die. based switching element is part of an RF transmis-
Using a different paste [6141, Figure 17(c)] and consid- sion line. If the switch is deactivated, the signal path
ering all previous findings, a good agreement between is open. By activating the switch, a membrane or beam
the measurements and the simulation (thermally static is deflected, and the transmission line is closed and
analysis using ANSYS Workbench) was achieved. The establishes a low-ohmic contact between input and
theory curve shown in Figure 18 is based on the ther- output [28]. One design example that is often used for
mal resistor network of the individual material layers.
The insert in Figure 18 shows a simulated temperature
distribution of the chip model.
45
Example of a SiCer Platform: MEMS Switch 40
Thermal Resistance (K/W)

One of the most obvious applications of SiCer technol- 35


ogy is the use of a SiCer composite substrate for RF
30
MEMS components. Si is known to be a suitable mechan-
ical material for MEMS, including RF MEMS devices 25
[26], but it also has drawbacks such as a high attenu- 20
ation constant at radio frequencies. RF MEMS devices 15
also suffer during system integration, as they need a 1-mm
10
first-level package that enables assembly on printed cir- Test Vias
cuit boards. In many cases, the parasitic effects of the 5
package and the additional effort for assembly wipe out
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6
the benefits of Si. On the other hand, LTCC is a very Via Area (mm2)
good carrier for RF components, although is not suit-
able for implementing micromechanical devices. To Measurement Simulation Theory
combine these advantages, a MEMS RF switch design
was set up. The advantages and disadvantages of dif- Figure 18. The trend of thermal resistance as a function of
ferent topologies were taken into account to find the the effective area (number) of thermal vias. The inset shows
most suitable MEMS switch for implementation on the the simulated temperature distribution in the test setup.

October 2019 39
The required switch for the switches, a push–pull configuration is used to lift up
the cantilever in the off state and so reduce the elec-
LTE receiver, the SiCer system trical capacitance between the open transmission line
demonstrator, is realized using three and the cantilever [31].
single-pole, single-throw switches Another RF switch topology is the capacitive shunt
switch, which can also be employed as a varactor. In
connected at one port. this type, also called the Raytheon capacitive MEMS
shunt switch [31], a movable membrane forms part
of a transmission line, as sketched in Figure  19(b).
the realization of series MEMS switches is the Rock- Located below the membrane is a pull-down elec-
well Science Center [28] design shown in Figure 19(a), trode. The membrane is actuated by an electro-
which has been optimized by other scientists and static force induced by a bias voltage in the range of
institutions for frequencies up to more than 40 GHz 10–60 V. It is pulled down toward the electrode and
[29]. The switch consists of an RF transmission line increases its capacitance to ground, resulting in a
with a gap that can be closed by a metallic cantilever. capacitive short circuit to ground. The design of the
To move the cantilever onto the transmission line, a dc capacitive shunt MEMS switch depends on the fre-
voltage in the range of 20−80 V must be applied [28]. quency range of the target application because the
This type of MEMS switch actuation is called electro- switch capacitance depends on frequency, whereas
static [28]. To improve the electrical isolation of MEMS the operating-frequency range of a series switch is
inherently broadband.

MEMS Switch on SiCer


Switch Contact
To demonstrate a MEMS switch within SiCer, a single-
pole, triple-throw band-select switch had to be imple-
mented on the SiCer substrate. Because this article
Pull-Down Electrode RF Line With Cavity
focuses on presenting the benefits of the technology
(a)
platform (combination of LTCC and Si, buried cavi-
Membrane
RF Out
ties, and Si etching), the required switch for the LTE
RF In
receiver, the SiCer system demonstrator, is realized
using three single-pole, single-throw switches con-
Pull-Down Electrode nected at one port. Hence, a capacitive shunt-switch
(b) implementation is not possible, as switching off at one
band would induce a short circuit at the antenna port.
Figure 19. (a) A Rockwell Science Center MEMS series Instead, a series switch topology using electrostatic
switch [28]. An electrostatic force is generated by applying actuation was selected. The complete specifications are
a dc voltage at the pull-down electrode. The beam is then
summarized in Table 4.
pulled down, and the metallization (switch contact) closes
Based on these specifications a MEMS series switch
the RF line. (b) A Raytheon capacitive MEMS shunt switch
[31]. A membrane is part of an RF transmission line. The was designed, using Si MEMS technology, that inter-
membrane can be pulled down by applying a dc voltage rupts a transmission line realized on LTCC at the bond
at the pull-down electrode and, consequently, forms a interface of the SiCer substrate. As the demonstrator
capacitive shunt to ground. is specified for use in handheld devices, it requires
low power consumption, low-voltage actuation for
switching, and bistable operation, or at least very low
TABLE 4. The LTE MEMS switch parameter. power for the switched state. Furthermore, a switch
design with an in-plane movement was selected, as it
Parameter Value
is best suited for the SiCer technology and highlights
Actuation Electrical, in-plane movement the performance of the new platform, including DRIE
Movement In-plane, parallel plate and buried cavities. Various designs for electrostatic
Voltage < 20 V actuators are available that enable large movements
Transmission line Grounded coplanar waveguide of more than 10  µm with low voltages. The result-
Bandwidth 0–10 GHz ing switch design, shown as a finite element method
Insertion loss < 2 dB (FEM) model in Figure 20 [32], consists of three main
parts. The moving element of the switch is the piston,
Isolation > 25 dB @ 3 GHz
which is attached to a frame and mechanically con-
Switching time < 50 ns
nected to the LTCC carrier substrate by a meander

40 October 2019
spring. The spring also produces the mechanical force different levels of abstraction. The blue line indicates the
that pulls the piston into the in-plane transmission RF simulation in Cadence; the red dashed curve is based
line. The electrostatic force causing the switch to move on the FEM field simulation results. Figure  21(c) illus-
is applied by a dc voltage between two electrode pairs. trates the RF simulation model. The metallic parts—
The two parallel-plate actuators consist of Si cantile- piston and transmission line—are modeled by the
vers that are narrow (20-µm gap) compared with the resistances R 1, R 2, and R 3 . The capacitances between
fixed parts and thus flexible enough to move in plane. the piston and the transmission-line elements, as well
These actuators are suspended above the LTCC mono- as the capacitances between the two transmission-line
lithically and connected to the stiff piston. When an elements, are modeled using variable capacitances C 1,
actuation voltage of about 20  V is applied, the elec- C 2, and C 3 because deflection of the piston changes the
trostatic force between the electrodes bends the free capacitive behavior of the structure. Two static capaci-
ends of the electrode plates toward one another. The tances, C 01 and C 02, represent the capacitive effect of the
concept was adopted from an optical fiber switch that transmission lines to ground. The agreement between
needed large displacement at a high force [33]. This
leads to a reduction of the initial gap between the par-
allel plates, and the attracting force increases due to a
self-amplifying effect [Figure 20(b)]. Consequently, the Isolation
piston and spring move, and the signal is switched off.
An insulating layer prevents direct contact and thus –30
electrical breakdown between the electrodes [34]. In –40

|S21|2 (dB)
the open state, the isolation of the transmission line is
–50
very important, whereas, in the closed state, insertion
loss is the important parameter. –60
RF Simulation
Figure  21 shows the forward transmission param-
–70 RF Model
eter S 21 in the open and closed states over frequency for
0 5 10
Frequency (GHz)
(a)
Insertion Loss
Electrode Pair 1 Electrode Pair 2 0
|S21|2 (dB)

–1
Ground
Signal
Piston RF Simulation
Fixed
Return Spring RF Model
–2
0 5 10
Frequency (GHz)
(b)
(a)
Materials: Si Au R2
R1 C1 C2 R3
+

C01 C3 C02
(c)

Figure 21. The forward-transmission parameter S 21 (a)


in the open state of the switch and (b) in the closed state of
the switch. The isolation of the switch reaches 29 dB at a
deflection of 1 μm; the insertion loss remains below 1.4 dB.
(b) (c) The extracted simulation model is shown, consisting
of resistive elements R 1, R 2, and R 3 for the conductors
Figure 20. An FEM representation of the switch design and capacitive elements C 1, C 2, C 3, C 01, and C 02 for the
(a) in the closed state and (b) in the open state. For the open interaction of the transmission-line elements with ground,
state, a dc voltage must be applied. the piston, and each other.

October 2019 41
the RF field simulation and the schematic, model-based the plate-capacitor formula and the equation for ohmic
simulation proves the consistency of the RF model. The losses in materials). As discussed previously, these equa-
deviations of the insertion loss between the two mod- tions are suitable for computing the equivalent-circuit
els are negligible. For the isolation, a deviation of up to model of the switch. The element values for the resis-
3 dB can be observed at 10 GHz, but the model fits the tance and capacitances are given in Table 5. An example
FEM-simulated results quite well at lower frequencies. of a fabricated RF MEMS switch is shown in Figure 22.
Therefore, the schematic model is sufficient for use in
system simulations below 5 GHz and is an efficient tool Conclusions
to reduce simulation effort and simulation time. A mini- This article presented the concept of SiCer substrates as
mum isolation of 29  dB can be determined for deflec- well as an example of a SiCer platform suitable for the
tions of the piston of 1 μm, and the maximum insertion integration of RF components. The platform enables the
loss was simulated to be 1.4 dB. The specifications given combination of thin-film and LTCC technology, allow-
in Table 4 can hence be met by this type of RF MEMS ing significantly higher lateral resolutions and signifi-
switch. For the generation of the schematic model of the cantly shorter signal paths than in common ceramic
switch, elementary electrical equations are used (i.e., technology combined with chip assembly. Different
components can be realized in their respective opti-
mum layer (wiring inductances and capacitances in
the ceramic layer; mechanical switches and resonators
TABLE 5. The LTE MEMS switch parameter overview. in the Si layer). Components (e.g., CMOS devices) that
Parameter Value cannot be realized with the SiCer technology shown
in this article can be integrated with classic packaging
R 1, R 3 0.24 X
technologies (e.g., flip chip). The material properties of
R2 1.8 X
the substrate and the combination with different paste
C 1, C 2 9.4 fF systems were studied. The substrate behavior using
C3 0.51 fF DRIE, which is necessary to separate various compo-
C 01, C 02 180 fF nents on the platform, was investigated. The fabrication
Gap between transmission line and piston 10 nm of free-moving MEMS elements (e.g., switches) in SiCer
Gap between transmission lines 31 nm was greatly simplified by the use of carbon paste (local
vertical gaps). The thermal behavior of SiCer was also
Width of transmission line 20 nm
investigated. For MEMS requiring a high temperature

Piston
Spring
Cavity

LTCC
Mount

S4800 10.0 kV 10.1 mm ×2.00 k SE(M) 20.0 µm


Piston
(b)
Electrode Pair 1

Electrode Pair 2

LTCC

S4800 10.0 kV 8 mm × 30 SE(M) 1.00 mm S4800 2.0 kV 10.3mm × 300 SE(M) 100 µm

(a) (c)

Figure 22. (a) An SEM image of the produced RF MEMS switch on SiCer. A detail view of (b) the piston hovering over the
LTCC surface and (c) the two electrode pairs.

42 October 2019
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