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Initial Calibration Daily, prior to ± 10% from 1. Reprep ICV and, reanalyze all
Verification (ICV) sample analysis, expected associated samples
(Separate source from immediately following concentration 2. Identify and document problem
ICAL standards) ICAL 3. Recalibrate and reanalyze reprepped ICV
and all associated samples, if necessary
Calibration Blank After ICV and CCVs < CRDL 1. Terminate analysis
Verification (ICB, 2. Identify and document the problem
CCB) 3. Recalibrate, verify and reanalyze all
associated samples
CRDL Verification After initial CCV ± 20% from 1. Reprep and reanalyze standard
Standard (< 2X CRDL) expected 2. Recalibrate and verify
concentration
Dilute and reanalyze samples with COD concentrations exceeding the range of the calibration curve. Results
for such reanalyses should fall within the mid-range of the calibration curve. Report results and submit
documentation for both analyses.
Method Blank One per Batch or SDGb < CRDL 1. If lowest sample concentration is more than
(MB)a (1 per 20 samples 10X the blank conc., no action
minimum) 2. If samples are non-detected, no action
3. If detected sample concentrations are less
than 10X blank conc., all associated samples
must be prepared again with another method blank
and reanalyzed
Duplicate One per batch or SDG RPD <20% for 1. Flag associated data with an "*"
Sample (DUP) (1 per 20 samples samples >5X
minimum) CRDL; ± CRDL
for samples
<5X CRDL
Matrix Spike One per batch or SDG ± 15% from 1. Flag associated data with an "N"
(MS)d (1 per 20 samples expected
minimum) value c
One Set of One set per batch or ± 15% from 1. Terminate analysis
Demand SDG (1 per 20 samples expected 2. Identify and document the problem
Reference minimum) concentration 3. Reanalyze all associated samples
Samples (2
conc. levels)