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Triacylglycerol
Also Called triglycerides are the main dietary fats in human body
triglycerides are alcohol glycerol (hydroxyl group HO-) and Three Fatty
Acid(Carboxyl group COOH)
Categorized as simple lipids
FATS and OILS are called triglycerides because they are esters composed of
three fatty acid and one glycerol
FATS OILS
- Saturated Fatty acid - Unsaturated Fatty acid
- Solid at room temperature - liquid at room temperature
- obtain from animals - obtain from plants
Structure of Triacylglycerol
Fatty Acid
Fatty acids are also called “Carboxylic acids” due to the presence of carboxyl
group (-COOH)
Building blocks for triglycerides and phospholipids
general formula , CH3(CH2)nCOOH where usually ranges from 2 to 28 and is
always an even number
fatty acids are classified into different categories, i.e.
According to the chain length
According to the body requirement
According to the degree of unsaturation
According to the position of H-atoms
According to the chain length
1. Short chain fatty acids
Fatty acids with <6 C-atoms
liquid at room temperature.
example, Butyric acid (C-4)
2. Medium chain fatty acids
Fatty acids with 6-12 C-atoms
example, Caproic acid (C-6), Caprylic acid (C-8)
3 Long chain fatty acids
Fatty acids with 14-20 C-atoms
Found as a major part of a few vegetable oils.
For example, Myristic fatty acid (C-14), Palmitic acid (C-16), etc.
4. Very long chain fatty acids
Fatty acids with 22 or more C-atoms
These fatty acids can’t be metabolized by mitochondria, they are metabolized in
peroxisomes.
These may be physio pathologically harmful for human.
For example, Erucic acid (C-22)
According to the body requirement
Essential fatty acids
fatty acids that cannot be prepared by the body and are obtained from diet.
example, linoleic acid(Omega 6), linolenic acid (Omega3), arachidonic acid.
Non-Essential fatty acids
Fatty acids that can be synthesized by our body and are not required from
diet. For example, Palmitic acid, Stearic acid.
According to the degree of unsaturation
Saturated fatty acid
the fatty acids that contain no double bond their hydrocarbon chain.
They are solid at room temperature.
Examples Butyric acid, Caproic acid, Lauric acid 12:0, Myristic acid 14:0,
Palmitic acid 16:0, Stearic acid 18:0
Unsaturated fatty acids
the fatty acids that contain one or more double bond in their aliphatic chain.
Abundant in fish and vegetable oils
These may either be
Monounsaturated fatty acids (MUFA) Has one double bond
Poly unsaturated fatty acids (PUFA) Has two or more double bond
According to the position of H-atoms
Cis-Fatty acids
Cis- fatty acids are the fatty acids in which the adjacent hydrogen atoms are
attached on the same side of the double bond. The chain with a significant no. cis-
bonds, tend to be slightly curved.
Trans-Fatty acid
Trans-Fatty acids are the fatty acids in which H-atoms are attached on the
opposite sides of the double bond. The chain with a significant no. of Trans-fatty
acids, don’t bend much and maintain the shape.
Delta nomenclature
The delta ∆ system the notation describe the chain length and the number and
position of the double bonds
In delta numbering start from the carboxyl end of the fatty acid
Omega nomenclature
Similar to delta nomenclature.
Carbon atoms are counted from the methyl end.
Symbol used is omega instead of delta.
For omega nomenclature we need to know 3 things.
1. Total carbon atoms in the fatty acids.
2. Total double bonds in the fatty acids.
3. Number of carbon atoms are counted from the methyl end to the carbon with
first double bond.