Item 0 20180627014138320

FIITJEE - JEE (Mains)
PHYSICS, CHEMISTRY & MATHEMATICS
SECTION - 1
PHYSICS
1. Two identical capacitors 1 and 2 are connected in series to a battery as shown in figure.
Capacitor 2 contains a dielectric slab of dielectric constant k as shown. Q1 and Q2 are the
charges stored in the capacitors. Now the dielectric slab is removed and the corresponding
charges are Q1 and Q2. Then –
1 2
E
Q1 k  1 Q 2 k  1 Q 2 k  1 Q1 k
(A) = (B) = (C) = (D) =
Q1 k Q2 2 Q2 2k Q1 2
2. Charge q of mass m is projected with velocity v0 along x-

axis in uniform electric field E along y-axis. Radius of
curvature of charge when it has travelled distance d
along y-axis is ? Neglect gravity and it is given that
qEd
 2v 02
m
v 2m v 2m 5 v 02m 5v 02m
(a) 0 5 (b) 0 5 (c) 5 (d) 5
qE 2qE 2 qE qE
3. A rigid circular loop of radius r and mass m lies in the x-y plane on a flat table and has a current  flowing
  
in it. At this particular place. The earth’s magnetic field is B = Bx i + By j . The minimum value of  for
which one end of the loop will lift from the table is
mg mg mg mg
(A) (B) (C) (D)
 r Bx rB y 2r B 2x  B 2y r B 2x  B 2y
4. In the circuit shown if in steady state the potential difference 5 F B 2.9F

between points A and B is 11V, find potential difference
across 7  F capacitor. 3 F
6 F
7 F
+ 
A
(a) 1.8 V (b) 18 V (c) 9 V (d) 1V

2
1 2 3 4
5. Four identical metallic plates each having area of
cross-section A are separated by a distance d as
shown in the figure. Plate 2 is given a charge q. Find
the potential difference between plate 2 & 3.
q.d 5q.d 8q.d q.d

(a) (b) (c) (d)
0 A 30 A 30 A 30 A
6. Heat generated in the circuit when switch is shifted from 1 to 2 is
(a) 32J
(b) 16J
(c) 48J
(d) 64J
7. A network of nine conductors connects six A

points A, B, C, D, E and F as shown below.
The digits denote resistances in . Find the
D 2
equivalent resistance between B and C
1 1
1 1
E 1 F
2 2
B 1 C
2 7 5
(A)   (B)  (C)  (D) None of these
15 12 12
8. When two resistances X and Y are put in the left hand and right hand gaps in a meter bridge, the
null point is at 60cm. If X is shunted by a resistance equal to half of itself then find the shift in the
null point.
(a) 26.7 cm (b) 267 cm (c) 27 cm (d) 29.0 cm
9. A point charge q of small mass m is projected with velocity v0 from

one end of a parallel plate capacitor with plate area  and
separation d between them. For what value of v0 q will just miss upper
plate.
mgd  q  q   q  2(mgd  q )
(a) 2
m
(b)  md  g (c)  md  g (d)
m
10. Calculate the potential difference between 4

points A and B and current flowing through A
the 10 resistor in the part of the network
below – Part of
circuit 3 10 15 10V
6 3
2
B
(A) 20 V, 2A (B) 50 V, 1A (C) 40 V, 1A (D) 30 V, 1A

3
11. A block of mass m & charge q is released on a long smooth q

inclined plane. Magnetic field B is constant, uniform, horizontal g m
B
and parallel to surface as shown. Find the time from start when
block loses contact with the surface –

m cos  m cos ec  m cot 
(A) (B) (C) (D) none of these
qB qB qB
12. Find charge flown from earth when K is switch on.

(a) -Q
(b) Q
(c) 2Q
(d) -3Q
13. A charged particle is projected in a magnetic field B  (3i  4 j)  102 T . The acceleration of the
 8
particle is found to be a  (  î  yĵ ) m/s2. Find the value of y.
3
(a) 2 (b) 3 (c) 4 (d) 5
14. A point charge q is kept inside a conducting shell of radius 2R at a

distance of R from center. Magnitude of field due to induced charges
on the inner surface of the shell at point P is
Kq
(a) (b) 0
16R2
Kq Kq
(c) (d)
17R2 4R2
15. An electron is projected with velocity v0 in a uniform electric field E perpendicular to the field. Again
it is projected with velocity v0 perpendicular to a uniform magnetic field B. If r 1 is initial radius of
curvature just after entering in the electric field and r 2 is initial radius of curvature just after entering
in magnetic field then the ratio r1/r2 is equal to –
Bv 02 B Ev 0 Bv 0
(a) (b) (c) (d)
E E B E
16. A parallel plate condenser is charged by a battery. The battery is removed and a thick glass slab is
placed between the plates. Now-
(A) the capacity of the condenser is increased
(B) the electrical energy stored in the condenser is decreased
(C) the potential across the plates is decreased
(D) All of the above
17. For what value of  power across 4 will be 100 w ?

(a) 20 V (b) 10 V
(c) 15 V (d) 25 V
4
18. A point charge – q (of mass m) is revolving in a circle of radius r, around a

long positive line of charge with charge density  , as shown in diagram. Its +
 1  +
angular velocity is  k   +
 4o  q r
+
2kq kq +
(A) 2
(B) +
mr mr 2
+
kq kq
(C) 2
(D)
2mr 4mr 2
19. Wattage of three bulbs A, B and C rated at same voltage are W A, W B and
W C respectively. Their brightness are represented by PA, PB and PC. If PA B
A
= PB = PC, then correct ratio of their wattage (W A : W B : W C) is
(A) 1 : 2 : 3 (B) 1 : 2 : 2 V
(C) 1 : 4 : 4 (D) 2 : 2 : 1 C
20. A charged sphere of mass m and charge – q starts sliding along

x x x x x x
the surface of a smooth hemispherical bowl, at position P. The
region has a transverse uniform magnetic field B. Normal force by x P x
the surface of bowl on the sphere at position Q is: x 
R B
(A) mg sin  + qB 2gRsin  (B) 3mg sin  + qB 2gRsin  x Q x
x x x x x x
(C) mg sin  - qB 2gRsin  (D) 3mg sin  - qB 2gRsin 
21. A rod has a total charge Q uniformly distributed along its length L. If the rod rotates with angular
velocity  about its end, its magnetic moment is

L
++ + + + + + ++ +
Total charge = Q
QL2 QL2 QL2 QL2

(A) (B) (C) (D)
2 4 8 6
22. Two charges of unit magnitude placed at A and B produce

V(x)
electrostatic potential along the line AB as shown in the figure.
What are the value of the charges at A and B?
(A) 1, 1 (B) 1, 1 A
x
(C) 1, 1 (D) 1, 1 O B
23. Two conductors of same length are connected in parallel as shown in

figure. Their cross-sectional areas are A1 and A2 and their resistivity’s are 1,A1
1 and 2 respectively. The equivalent resistivity of this combination is:
2 ,A 2
12  A1  A 2  12  A1  A 2 
(A) (B)
A12  A 21 A11  A 22
12  A1  A 2  12  A1  A 2 
(C) (D)
A11  A 22 A12  A 21
5
24. Current shown in figure is

I
15V 2V 5V 10V 5V
2 3 5 5
(A) 7 A (B) 2 A
(C) 5 A (D) 3 A
25. In the circuit shown in figure if battery is ideal, then time after which
R3  2
1
current in R3 becomes time of maximum current through it, is
e
(A) 18 s (B) 12 s  R2  2
(C) 6 s (D) 2 s
6 F
R1  2
26. If 2% of the main current is to be passed through the galvanometer of resistance G, the resistance
of shunt required is
G G
(A) (B)
49 50
(C) 49 G (D) 50 G
27. A particle of charge (+q) and mass m moving under the influence
x x x x xY x
of uniform electric field E  Eo ˆj and uniform magnetic field
x xvo 2 x
B  B kˆ follows a trajectory from P to Q as shown in figure. The
o x x x
45o
v Px
velocity at P is v  v o ˆi  v o ˆj and velocity at Q is - o ˆj. The
x
a
2 x x x x x x
magnitude of electric field is given by Q x x x x x x
X
mv02 3mv02 L
(A) (B)
8qoa 4qa
7mv02 5mv02
(C) (D)
8qa 8qa
28. A particle of mass m and charge q enters a region of magnetic field (as shown) with speed v.
There is a region in which the magnetic field is absent, as shown. The particle after entering the
region collides elastically with a rigid wall. Time after which the velocity of particle becomes
antiparallel to its initial velocity is
x xB
x x x
x x
x x x
q x x
x x x
x x
x x x
x x
x x x
mv mv
Wall
2qB 2qB
m m
(A)    4 (B)    2
2qB qB
m m
(C)    2 (D)  2  3 
4qB 4qB
6
29. Two long parallel wires are at a distance d apart. They carry steady equal currents out of the plane
of the paper in opposite direction as shown in figure. The variation of the magnetic field B along the
line XX ' is given by
(A) X X X' (B) X X'

X
(C) X X X' (D) X X X'
30. Figure shows a cross-section of a large metal sheet carrying an electric current along its axis. The
current in a strip of width dl is kdl where k is constant. Find the magnetic field at a point P at a
distance x from the metal sheet.
P
P
x x
i
0 k
(A) (B)  0 k
2
0 k
(C) 2  0 k (D)
4
SECTION – 2
CHEMISTRY
1. What is the complementary RNA sequence for the DNA segment AATCAGTT ?
(a) AAVCAGVV (b) CCAUCGAA (c) AACUGAUU (d) UUAGUCAA
2. The major product [X] of the given reaction is

OCH 3 CH3 Cl  [X]
AlCl
O 2N 
3
(a) H3C (b) H3C
O 2N OCH3 H3CO NO2
(c) CH3 (b) CH3
O 2N OCH3
7
3.
OH

Br2 / CCl4
A
CHO
CH3
A can be
(a) OH (b) OH
H3C Br
CHO CHO
Br CH3
(c) OH (b) OBr
Br Br
CHO CHO
Br Br
4. Which has equal carbon-carbon bond length ?
(a) (b) -
O O
C O
-
O 2N O O
(c) Ph (b)
C O
Ph
5. What could be the product for the following reaction?

Ph NH

NaNO2 ,HCl
0ºC
?
CH3
(a) NHCH3 (b) +

N2
ON
(c) NO (b) H
+
NCH3 N NO
CH3
6. What is the correct order of decreasing basicity for the following anions (from the most to the least)
(I) - (II) -
O OCH 3 O CH3
8
(III) - (IV) -
O O Br
(V) O
-
O C CH3
(a) I > II > III > IV > V (b) I > II > III > V > IV
(c) I > II > IV > III > V (d) V > IV > III > II > I
7. Which of the following halides will be most reactive in SN2 reaction and in SN1 respectively ?
(I) Br (II) Br
H3C
H3C
(III) CH3
CH3
Br
(a) I, II (b) II, I (c) I, III (d) III, I
8. 


(i) H
(ii) H2 O
 B(Major) 
HBr
 C 
(CH ) CO
 D(Major)
3 3
The compound D is :
(a) CH3 (b) CH3

O C(CH3)3
(c) CH2 (d)

CH3
9. Predict the number of stereoisomers for 2,5-heptadiene.

(a) 4 (b) 3 (c) 2 (d) 5
10. Teflon, polystyrene and neoprene are all

(A) Copolymers (B) Condensation polymers
(C) Homopolymers (D) Monomers
1
11. Arrange the following in increasing order of SN reactivity -
I. CH3CH2Br II. CH2 CH CH CH3 III. CH2 CH Br IV. CH3 CH CH3

Br Br
(A) IV > II > I > III (B) II > IV > I > III (C) II > III > IV > I (D) II > I > IV > III
9
12. In the following reactions :

Br
I. Alc. KOH
Ph Me Ph + HBr
Br
II. Alc. KOH
Ph CD3 Ph CD2 + DBr
The rate of reaction of (I) is faster than of (II). Both reactions proceed by which mechanism?
(A) E1 (B) E2
(C) E1cb (D)  -elimination
13. Ethyl cyanide ‘A’ can be converted into ethyl amine ‘B’ by :
H O NH / 
(A) A  B (B) A    
Sn /HCl 3 3 KBrO

(C) A  B LiAlH

4
(D) ‘A’ and ‘C’ are correct
14. Which of the following polymer is not synthesized from acidic monomer
(a) Dacron (b) Nylon 6,6 (c) Bakelite (d) Teflon
15. Liebermann test is given by which of the following

COOH OH
CH3
(a) H3C C OH (b) CH3  CH2  COOH (c) (d)
CH3
h
16. H C Cl  Br2 (A)  (B)
CH2
CH3
In this reaction
(a) A & B are enatiomer & major product will be that compound in which Br is opposite side(threo)
to the Cl.
(b) A & B are diastereomer & major product will be that compound in which Br is opposite
side(threo) to the Cl.
(c) A & B are enatiomer & major product will be that compound in which Br is same side(erythro) to
the Cl.
(d) A & B are diastereomer & major product will be that compound in which Br is same side(erythro)
to the Cl.
17. Which of the following amino acids do not give purple colour on reaction with ninhydrin ?
(a) proline (b) glycine (c) alanine (d) both a & b
10
NO2
18. 
Oxidation
(A)
NH2

Oxidation
(B) A & B are respectively
(a) 3-nitrophthalic acid, phthalic acid (b) phthalic acid, 3-nitrophthalic acid
(c) phthalic acid, benzoic acid (d) none of these
19. Molisch’s test given by -
(a) Carbohydrates (b) Amino acid (c) Lipids (d) none of these
20. When semicarbazide (1mol) reacts with a mixture of cyclohexanone (1mol) & benzaldehyde (1mol)
then equilibrium controlled product will be
(a) Semicarbazone of cyclohexanone (b) Semicarbazone of PhCHO
(c) Both in equal amount (d) No reaction
21. The correct order of acidity of the following compound

O O O O O
|| || || || ||
(a) CH3  C OEt  CH3  C H  CH3  C CH3  CH3  C CH2  C OEt  CH2 (COOEt)2
O O
|| ||
(b) CH3  C CH2  C OEt  CH3COCH3  CH3CHO  CH3COOEt  CH2 (COOEt)2
O
||
(c) CH3  C CH2COOEt  CH2 (COOEt)2  CH3CHO  CH3COCH3  CH3COOEt
O
||
(d) CH3  C OEt  CH3CHO  CH2 (COOEt)2  CH3COCH2COOEt  CH3COCH3
22. Free energy profile for given reaction is

HO  CH3  Br 
HO  CH3  Br
Free
(a) Energ (b) Free
Energy
y
Reaction co-ordinate
Reaction co-ordinate
Free
Energy Free
(c) (d) Energy
Reaction co-ordinate Reaction co-ordinate

11
OH
23. CHCl3  NaOH 

(A)
CH3
Product (A) is :
OH OH OH OH OH
O O
(a) (b) (c) (d)
O
CO2H
CH3 CH3 CH3 CH3
24. A disaccharides which give only glucose on hydrolysis–
(A) Lactose (B) Fructose
(C) Sucrose (D) Maltose
25. Hydrolysis of sucrose is called–
(A) Saponification
(B) Inversion
(C) Mutarotation
(D) Rotatory motion
26. In a Cannizzaro reaction the intermediate which is the best hydride donor is –
H H
| |
(A) C6H5– C – O–  (B) C6H5– C – O–
| |
OH O–
H H
O– O–
(C) (D)
O– O–
O2N CH3O
PdBaSO4 Ca Salt
C6H5COCl   Intermediate   Intermediate   A
Oxidation
27.
H2 Dry Distillati on
Compound (A) in above reaction sequence is–

(A) Benzophenone (B) Benzaldehyde
(C) Acetophenone (D) Benzoquinone
12
NaBH
28. B 4 CH=CH–CHO
H /Pt
2 A, then A & B are-
(A) CH2CH2CHO,
CH=CH–CH2OH
(B) CH2CH2CH2 OH,
CH=CH–CH2OH
(C) CH=CH–CH2OH in both cases
(D) CH2CH2CH2OH in both cases
29. The disease sickel–cell anaemia is caused by–

(A) Deficiency of protein (B) Deficiency of vitamins
(C) Defective haemoglobin (D) Phenyl alanine hydroxylase
30. Correct order of stability of following species is

- - -
CH2 CH2 CH2
(I) (II) (III)
NO2 NO2 NO2

(A) I > II > III (B) III > I > II
(C) III > II > I (D) I > III > II
SECTION – 3
MATHS
1. Let f : X  Y be defined as f(x)  sinx  cos x  2 2 . If f is invertible then X  Y , is :
 3     3 
(a)  ,   [ 2, 3 2] (b)  ,   [ 2, 3 2]
 4 4   4 4 
 3 3    5 
(c)  ,   [ 2, 3 2] (d)  ,   [ 2, 3 2]
 4 4  4 4 
log(x 2  5x  6)
2. The domain of f(x)  , is
[x]  1
[Note : where [y] denotes greatest integer function less than or equal to y]
(a) (, 3)  ( 2, ) (b) ( , 3)  [2, ) (c) ( ,1)  ( 2, ) (d) None of these
x 2  9x  20
3. Range of the function f(x)  , x  R does not contain :
x 2  6x  8
1 1
(a) (b) (c) 3 (d) 4
2 4
13
4. If the function f(x) and g(x) are defined on R  R such that

x  3, x  rational  x  5, x  irrational
f(x)   and g(x)   then (f – g)(x) is :
4x, x  irrational  x, x  rational
(a) one-one and onto (b) neither one-one nor onto
(c) one-one but not onto (d) onto but not one-one
   
5. Let f : (0, )   be a function defined as f(x)  tan1(In x) and g be the inverse
 2 2 
,
function of f, then g'(0) is equal to :

(a) 0 (b) 1 (c) 1/2 (d) 1/4
 1
6. If f(x)  cos ec 1  x   , then range of f(x) is equal to :
 x
                
(a)  ,  (b)  ,   {0} (c)  ,  (d)  ,0   0, 
 6 6  6 6  6 6  6   6
7. f(x)  sin(tan1 x), | x | 1 is equal to :

x 1 1 x
(a) (b) (c) (d)
1 x 2
1 x 2
1 x 2
1  x2
3 5
8. The value of tan1(tan ) where  :
2 2
3  5
(a)  (b)   2 (c) (d)  
2 2
9. If the function f(x)  sin1 x  cos1 x and g(x) are identical then g(x) can be equal to :
(a) sin1 | x |  | cos1 x | (b) tan1 x  cot 1 x
(c) | sin1 x |  cos1 | x | (d) ( sin1 x )2  ( cos1 x )2
30  4 x  7 3 x
10. lim
x 
equals :
2  (4x  7)  3 6x  2
(a) 15 (b) 2 (c) 3/2 (d) 0
cos(tan1 x)  cos x
11. Evaluate the limit lim :
x 0 x4
(a) 1 (b) 0 (c) 1/3 (d) 2/3
12. If f(x + y) = f(x) + f(y) + c, for all real x and y and f(x) is continuous at x = 0 and f '(0)  1,
then f '(x) is equal to
(a) c (b) -1 (c) 0 (d) 1
13. Given f(x)  b([x]2  [x])  1 for x  1

= sin((x  a)) for x < - 1 ?
(where [ ] denotes greatest integer), then for what values of a, b the function is continuous
at x = -1 ?
3
(a) a  2n  ; b  R, n I (b) a  4n  2 ; b  R, n I
2
3
(c) a  4n  ; b  R , n I (d) a  4n  1 ; b  R  , n  I
2
14
3x 2  4 x  1, for x  1

14. g(x)   . If g(x) is the continuous and differentiable for all numbers in
ax  b, for x  1

its domain, then :
(a) a = b = 4 (b) a = b = - 4 (c) a = 4 and b = -4 (d) a = - 4 and b = 4
15. Which one of the following function is not differentiable at x = 2 ?

(a) f(x)  (x 2  4) | (x  1)(x  2) | (b) f(x)  sin(| x  2 |) | x  2 |
(c) f(x)  sin(| x  2 |) | x  2 | (d) f(x) | x  2 | tan x
 3  sgn(x 2  1  5x)    1  x  2x  
2

16. If f(x)  x | x 2  3x | e|x  3|          is non-derivable at x = x1, x2,
 4  x 2
   3  | x | 1 
n
x3, .... xn, then x
i 1
i equals :
[Note : [y], {y} and sgn (y) denote greatest integer, fractional part and signum function of y
respectively]
(a) 0 (b) 3 (c) 4 (d) 5
3x  2  5
17. If f(x)  and g(x) is the inverse of f(x), then g'   is equal to :
5x  3  2
4 19
(a) -19 (b) 19 (c) (d) 
19 4
2
d y
18. If y3 + y = 2cos x, then the value of 2 at the point with abscissa zero, is equal to :
dx
(a) 0 (b) 1 (c) – 1 (d) -1/2
19. Given that the function h(x)  x 3  2x  1 for x  R has an inverse h-1 on R, then the value of
(h1 )' (1) is :
1 1
(a) (b) (c) 3 (d) 2
3 2
20. Let f(x) be a one-to-one function such that f(1) = 3, f(3) = 1, f '(1)  4 and f '(3)  2 . If g  f 1 ,
1
then the slope of the tangent line to at x = 1 is :
g
1 1 1 1
(a) (b) (c) (d)
2 9 18 32
21. The y-intercept of tangent line drawn to the curve x  t 2  3t  8 and y  2t 2  2t  5 at the
point (2, - 1) is :
12 15 11 19
(a) (b) (c) (d)
7 7 7 7
2
 x  2 x
22.   x  4  e dx is equal to :
 x   x  2  x  2 2xex
(a) e x  C (b) e x  C (c) e x  C (d) C
 x  4   x  4   x  4  x4
15
pxp  2q1  qx q1

23. The evaluation of x 2p  2q
 2xp  q  1
dx is :
xp xq xq xp
(a)  p q
C (b) p  q C (c)  p q
C (d) p q
C
x 1 x 1 x 1 x 1
7 / 3
24. The value of definite integral 

7 / 4
tan2 x dx is equal to
1 3
(a) ln 2 (b) ln 4 (c) ln2 (d) ln2
2 2
2/3
ln x
1/ 3 ln(x  x )
2
dx is equal to :
1 1 1 1
(a) (b) (c) (d)
3 6 9 18
2 3 n
1 22   32   n2 
1

26. If Pn   1  2   1  2   1  2  .........  1  2  , then lim(Pn )n is equal to : 2
 n  n   n   n  n
e
(a) 0 (b) 1 (c) e (d)
2
 /2
I1
27. Let f(x)  x 4  | x | and I1   f(cos x) dx and I2   f(sin x) dx , then the value of is :
0 0
I2
(a) 1 (b) 1/2 (c) 2 (d) 1/4
x2
28. Consider the function f(x)  , then f(x) has :
(x  1)2
(a) local maxima but no local minima (b) local minima but no local maxima
(c) both local maxima and local minima (d) neither local maxima nor local minima
29. Consider the function f(x)  x cos x  sin x, then identify the statement which is correct ?
(a) f is neither odd nor even (b) f is monotonic decreasing at x = 0
(c) f has a maxima at x =  (d) f has a minima at x = - 
30. Which one of the following statements does not hold good for the function
f(x)  cos 1(2x 2  1) ?
(a) f is not differentiable at x = 0 (b) f is non-monotonic
(c) f is even (d) f has an extremum
16
ANSWERS MAINS
SR. PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE

NO
1. C P11424 D C121705 D M113411
2. D P11406 C C121809 D M113406
3. D P11613 B C121809 A M113416
4. A P11420 B C114716 D M113424
5. D P11424 C C121602 B M113406
6. D P11420 A C111302 D M113416
7. D P120215 C C124602 D M114103
8. A P11514 C C114706 B M114105
9. A P11420 B C111403 C M113414
10. B P110201 C C121701 B M110603
11. C P111611 B C124602 C M110609
12. A P111420 B C114706 D M113626
13. A P111611 B C124511 A M113619
14. C P110110 D C121701 C M113628
15. D P111614 D C124512 C M113624
16. D P110114 B C111404 B M113625
17. A P111517 A C121704 C M114103
18. A P111406 A C114302 D M114104
19. C P111517 A C121702 B M114106
20 B P111611 A C121702 C M113802
21. D P111624 C C111302 D M113803
22. C P110104 B C124601 A M113806
23. D P111506 A C121809 C M113807
24. D P110206 D C121703 D M113812
25. A P110216 B C121703 B M113811
26. A P110214 D C121704 D M113808
27. B P111611 A C121704 C M113802
28. A P111611 B C121704 A M113605
29. A P111608 C C121901 B M113604
30. A P111608 B C121901 B M113616
17
PAPER – 1
S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
(Multi Correct Choice Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE OR MORE may be correct.
1. Positive charge is uniformly distributed throughout the
spherical space of radius R having spherical cavity as shown y
in fig. Its volume charge density is  then, at origin, electric +
+ + + +
field intensity as well as potential is.
 R  5 R2  R  5 R2 + +
(A)   î, (B)   î, + o x
 4 o  4 o  6 o  12 o R
 R  5 R2  R  5 R2 +++
(C)   î, (D)   î, + + +
 2o  6 o  3 o  3  o
2. Three identical parallel conducting plates A, B and C are placed

as shown in fig. switches S1 and S2 are opened and connect A and
C to earth Q charge is given to B. A B C
(A) If S1 is closed with S2 open, a charge of amount Q will pass through S1
(B) If S2 is closed with S1 open, a charge of amount Q will pass through S2
Q 2d d
(C) If S1 and S2 are closed together, a charge of amount will pass through
3
2Q S2
S1 and a charge of amount will pass through S2 S1
3
(D) All the above statement are incorrect.
3. Initially switch is open. After some time switch is closed. Choose the
correct statements
(a) the charge flown through the switch is 54 C
(b) Point b is at higher potential than point a before the switch is
closed
(c) the potential of point b is 6V w.r.t. ground, after s is closed
(d) the potential of point b is 12V, after s is closed
4. As shown in the figure find the correct statement/s :
(a) i at instant switch is closed is 2A

(b) i after long time is 2A
16
(c) charge on 4F after long time is C (when switch is closed)
3
(d) charge on 2F at instant switch is closed is 8C
18
5. Three capacitors C1  2F, C2  3F and C3  4F are

separately charged with battery of potential
difference 40V, 30V and 10V respectively and then
disconnected. After then they are connected to
each other as shown in figure.
(a) Amount of charge flown in circuit is zero
280
(b) Final change on capacitor C3  C
13
800
(c) Final change on capacitor C2  C
13
800
(d) Final change on capacitor C1  C
13
6. An alpha particle enters in the region between the

plates of capacitor at an angle 60º and leaves the
region at an angle of 30º, then
(a) The ratio of speeds entering and leaving the region

is 3 : 1
(b) The ratio of K.E. entering and leaving the region is 1

:3
(c) The path inside the region is circular
(d) The path inside the region is parabolic
7. A thin walled, spherical conducting shell of radius r is given change q0. The same amount
of charge is also placed at its centre C. Which of the following statements are correct ?
q0
(a) on the outer surface of shell, the charge density is
2r 2
(b) the electric field is zero at all points inside shell
(c) At a point just outside the shell, the electric field is double the field at a point just inside
the shell
(d) At any point inside shell, the electric field is inversely proportional to the square of its
distance from C.
8. If the flux of the electric field through a closed surface is zero

(a) the electric field must be zero everywhere on the surface
(b) the electric field may be zero everywhere on the surface
(c) the net charge inside the surface must be zero
(d) the charge in the vicinity of the surface must be zero
9. Point charges are located on the corners of a square as shown in

figure. Find the components of electric field at any point on the z-
axis which is axis of symmetry of the square.
(a) Ez = 0 (b) Ex = 0
(c) Ey = 0 (d) None of the above
19
10. A long straight conductor of circular cross-section of radius R carries a current io whose
r
current density J is assumed to be varying with radial distance r as J = Jo   , where Jo is
R
a positive constant, then
Jo or 2
(A) Magnetic field outside varies as
3R
 J R2
(B) Magnetic field inside varies as o o
3r
(C) Inside the conductor graph between magnetic field and radial distance is parabolic
(D) outside the conductor graph between magnetic field and radial distance is hyperbolic
PART – C
(Integer Type)
This section contains 10 questions. The answer to each question is a single-digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.
1. ‘Q’ charge is uniformly distributed over the surface of a right circular 

cone of semi-vertical angle  and height h. The cone is uniformly
rotated about its axis at angular velocity . Magnetic moment
h 
Qh2 tan2 
associated with the cone is found to be where value of n
n
is
R
2. Consider a potentiometer circuit primary cell is ideal. The

length of potentiometer wire is 1 m and the resistance per unit Ep
length of the potentiometer wire varies with length as
  2x  / m where x is distance from end A. Resistance of R
x
Rheostats varies with time as R  t 2 . Null deflection point for
A B
1
secondary cell is obtained at x  m and at t = 1 sec. If emf of G
2
1
Es, r
secondary cell is times of emf of primary cell, find K = ?
K
3. A positive charge Q is uniformly distributed through out the volume of a dielectric sphere
of radius R, A point mass having charge +q and mass m is fired towards the centre of
sphere with velocity v from a point at a distance 8R from the centre of sphere Neglect any
resistance other that electric interaction charge on small mass remains constant through
out the motion. The min velocity v so that it can penetrate R/2 distance of the sphere is
c1KQq
. Find c1 + c2.
c 2MR
A v B
q 1m C
R/2
8R
4. A particle of charge q and mass m is projected with a velocity vo towards a circular region
having uniform magnetic field B perpendicular and into the plane of paper from point P as
shown in fig. R is the radius and O is the center of Circular region. If the line OP makes
20
an angle  with the direction of vo then the value of vo so that particle passes through O is
qBR
, then k is equal to
kmsin
Magnetic
field
x
x
x x x
x O x
x
vo  x
m, q p x x
5. A point charge q = 9 C is placed at a distance 3R from a

+ R
conducting sphere of Radius R. If the switch S is closed, q 3
R S
charge flowing through switch is _____  C
6. Two identical charged spheres are suspended by strings of equal length (spheres are
suspended from same point). The strings make an angle of 30° with each other. When
suspended in a liquid of density 800 kg/m3, the angle remains the same. What is
the dielectric constant of the liquid ? The density of the material of the spheres is 1600 kg/m3.
7. A conducting ring of mass 2kg and radius 0.5 m is placed on a

smooth horizontal plane. The plane of the ring is vertical to the
ground. The ring carries a current of 4 amp. A horizontal
magnetic field B = 1T is switched on at some instant. Then if the
rad
initial angular acceleration of the ring is K , then the value
sec 2
of K will be :
8. A particle of charge 1C and mass 1 kg starts moving from the origin under the action of an
1
electric field E  2iˆ and magnetic field B  10iˆ with a velocity of ĵ . (All units are in S.I.
2
3
system). Then the speed of the particle becomes m / sec after a time t. Then find t (in
2
sec.)
9. Two identical intersecting spheres having the same volume

charge density of magnitude  0 (in S.I. unit) opposite in nature
of charge, are shown in figure. Radius of spheres are 5cm. The
distance between the centres is 6cm. Then the magnitude of
E0
electric field in the shaded portion is , then E0 will to (In S.I.
100
unit)
21
10. A charged particle of mass m and charge q is projected on a Z

Bo
rough horizontal xy-plane surface with Z-axis in the vertically
upward direction. Both electric fields are acting in the region Eo
   Y
and given by E   Eo kˆ and B   Bo k respectively. The particle P(a,0,0)
Vo
 
enters into the field at (a, 0,0) with velocity V  v o j . The
particle starts moving into a circular path on the plane. If the
coefficient of friction between the particle and the plane is , X
then distance travelled by the particle when it comes to rest is
2
mVo
found to be where value of n is
nmg  qEo 
S
SEEC
CTTIIO
ONN--2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART– A
1. Which of the following reactions are correctly representing the product(s) ?
(a) O (b) OCH3 OCH3

C COONa (i) PhLi
N—H NaOH/Br2 (ii) H2O
Ph
C Cl (Major Product)
NH2
O
(c) O (d) O
14 1. AgOH
C–Cl 1. NaN3 NH2 CH3–CH=CH–C–OH CH3–CH=CH2
14 2. Br2/CCl4/
2. OH¯/H3O/
2. MeCHO and PhCHO will give different type of reaction with

(A) NaOI (B) KCN (C) MeMgBr (D) KOH, 
3. The given compounds can be distinguished by

CH3
H2C CH CH2 OH & H3C C CH3
OH
(a) Lucas reagent (b) Victor Meyer test (c) Iodoform test (d) Aqueous AgNO3
4.
O
N2
(i)  (i) SOCl2
(A) (B)
(ii) HOH (ii) NH2–NH2
(iii) NaNO2/HCl,
Which is / are correct statement(s) about the product (A), (B) and involved reactions ?
(A) Product (B) gives iso cyanide test.
(B) Product (A) is a carboxylic acid containing six carbon atoms.
(C) Rearrangement is the RDS during formation of (A) and during formation of (B) from
(A).
(D) Arndt Eistert, Curtius, Diazotisation reactions are involved in above interconversion.
22
5. Which of the following statements is / are true :

(A) Major part of energy needed for the heterolysis of C–X bond in SN1 reaction
mechanism is obtained by the solvation of X– by the polar protic solvent.
(B) Greater solvation of attacking nucleophile & poor solvation of transition state promotes
the reaction by SN2 mechanism.
(C) Increase in the no. of phenyl ring at C of C–X causes a shift in mechanism from SN2 to
SN1.
(D) Allyl & benzyl halides undergo SN2 reactions as they are primary halides which do not
give SN1 reaction.
6.
H3C CH CH2 Br 
(1) Li
(2) CuI
X 
Y
 2,7  dim ethyloc tan e
CH3
(a) X : H3C CH CH2 CuLi (b) H3C CH CH2 CuLi
X:
CH3
CH3 2
(c) Y : Br  CH2  CH2  CH2  CH  CH3 (d) Y : CH3  CH2  CH2  CH  CH2  Br
CH3 CH3
7. Which of the following compounds will not show mutarotation ?
(a) Methyl-  -D-glucopyranoside
(b) 4-O-  -D-glucopyranosyl-D-glucopyranose
(c)  -D-galactopyranose
(d)  -D-glucopyranosyl-  -D-fructofuranoside
8. CH3  CH  CH  CH3 

OsO4 / KIO4
(A) 
1. PhMgBr
2.H2O
(B)
(a) Compound (B) on oxidation with (CrO3 + H2SO4) gives a compound which gives 2, 4-
DNP test positive
(b) Compound (B) on reaction with Cerric ammonium nitrate gives red colouration
(c) Compound (B) gives iodoform test positive
(d) Compound (B) on oxidation with hot alkaline KMnO4 then neutralization gives Benzoic
acid
9. Correct statement(s) among the following is/are
(a) Formic acid gives positive test with Tollen’s reagent

(b) Benzaldehyde gives positive test with Fehling’s solution
O
(c)
OH gives positive test with Benedict’s solution
O O
(d)
H2N C NH C NH2 gives Biuret test positive
10. Which of the following statement(s) is/are incorrect
O O
C C O CH2 CH2 O
(a)
n is not the structure of terylene
23
O O
CH2 CH2 O C C O
(b)
n is not the structure of polymer PET
O O
O CH2 CH2 O C C
(c)
n is incorrect structure of Dacron
(d) Melamine is trimer of carbamide
PART – C
(Integer Type)
1. 4.6 g of a polyhydric alcohol was treated with an excess of methyl magnesium bromide to
produce
3.36 litre of CH4 at STP. Calculate number of –OH group present in the alcohol.
(molecular weight of alcohol = 92)
2. How many moles of Grignard reagent can react with one mole of following compound for
complete reaction .
14
Cl  CH2  CH2  S  CH2  CH3   Number of amines produced
NH
3. 3
Br
4. alc
.KOH

 Number of alkene produced
5.
Me
OH
Et
Ph 
HI
How many iodides are produced in more than 5% yield
6. PhCOOH 
Red P (limited)
Cl2
How many Cl atoms are present in the final major product
7.
O O
Ph   P(C15H11O2Cl)
HCl
Contains three aromatic rings
OH
Half of number of degree of unsaturation in P is ____
24
8. The number of chiral compounds produced upon monochlorination of 2-methylbutane is

____
9. In the following species, number of nucleophiles is _____

CH3 , NH3 , BF3 , BF4 , Cl , NH4 , AlCl4 , CH2, CN
10.
R number of products 

HCl
 
Br2 /CCl4
 P number of products
D D
Cold alkaline dil KMnO 4
Q number of products
Then the value of half of sum of P, Q and R is _____
S
SEEC
CTTIIO
ONN--3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
 sin x  1, 0  x    2  x ;  1 x  1
 2
1. Consider, and g(x)   and f(x)  
x  x  2  x ; 1 x  3
 [x]  cos(x  2),
 2
where [k] denotes greatest integer function of k. Identify the correct statement(s).
(A) lim g(f(x))  1 (B) lim g(f(g(x)))  0


x1 x 
2
f(g(x)) 1 g(f(x))
(c) lim  (D) lim 1
x2 f(x)  2 2 x 0  (f(x)  2)2 2
2. Which of the following functions are twice differentiable at x = 0?
(A) f(x)  x | x | (B) g(x)  [x 2 ] tan1 x  {x 2 } cot 1 x  [x 2 ] 
2
(C) h(x)  | sin2 x |

 4
 x cos
(D) h(x)   x 
1 ; x0
 0 ; x0
3. If (x)  f(x)  f(2a  x) and f "(x)  0, a  0, 0  x  2a then :

(A)  (x) increases in (a, 2a) (B)  (x) increases in (0, a)
(C)  (x) decreases in (0, a) (D)  (x) decreases in (a, 2a)
1 1
4. Let I   1  x dx and J   1  x dx , then correct statement is

0 1 x 0 1 x
(A) I  J  2 (B) I  J   (C) I  2   (D) J  4  
2 2
5. Let the function f(x) be thrice differentiable and satisfies f(f(x))  1  x for all

1
4 0
x  [0,1], If J   f(x)dx and f " , then which of the following is(are) true?
0
5
25
3 3
(A) f 1  f 2  1 (B) J  1
2
(C) f "(x)  0 has at least one root in x  1 , 3
4 4   (D) f ”(x) = 0 at least one root in
 
x  1, 4
2 5
6. f(x) 
[x]  1
{x}  1  2  
for f :  0, 5  1 , 3  , where [.] represents the greatest integer function and {.}
2 
represents the fractional part of x. Then which of the following is true?
(A) f(x) is injective discontinuous function. (B) f(x) is surjective non–differentiable
function

(C) min lim f(x), lim f(x)  f(1) .
x 1 x 1  (D) max (x values of point of discontinuity) =
f(1)
x
7. Suppose that f(x) is a differentiable invertible function, f(x)  0 and h(x)   f(t)dt. Given that
1
f(1)  f '(1)  1 and g(x) is inverse of f(x).,

Let G(x) = x2g(x) –xh(g(x)) x R . Which of the following are correct:
(A) G’(1) = 2 (B) G’(1) = 3 (C) G”(1) = 2 (D) G”(1) = 3
 tan1 x, | x | 
 4 . Which of the following is NOT correct?
8. Let f(x)  
  | x |,| x | 

2 4

(A) Range of f(x) is , tan1 
4  (B) f(x) is a many – one function
(C Number of solutions of the equation f(x) =  are 2 (D) f(x) is an odd function
4
9. Let f(x)  sin1(cos x) cos1(sin x)x  [0, 2] , then which of the following statement(s) is/are
correct?
(A) f(x) is continuous and differentiable in [0, 2]
(B) Range of f(x) is    ,  

2 2
 4 4
(C) x   is a point of global minima as well as local minima

(D)  f(x)dx  0
0
10. f : R  [ 1, ) and f(x)  ln([ sin 2x  cos 2x ])(where [.] is the greatest integer function.) Then,
(A) f(x) has range Z (B) f(x) is periodic with fundamental period
/4
(C) f(x) is invertible in  0,   (D) f(x) is into function
 4
26
PART – C
(Integer Type)
  1
n
e 1 1
1. If lim n exists and is equal to non–zero constant c, then find the value of
n n
12  c    .
2. Let f(x) = |x – 1| + sgn (sin x). If L and M denote the number of points on x  ( 1, ], where
f(x) is discontinuous and non–differentiable respectively, then find ( L + M).
[Note : sgn (x) denotes signum function of x]
3. Let f(x) be a differentiable function on R such that 2f(x  y)  f(x  y)  3f(x)  3f(y)  2xy for all
x, y  R . If f’(0) = 0, then find the value of f(3).
Let g(x)  ( | x |)2.e(5|x|) . If N1 denotes the number of values of  where g(x) is
2
4.
discontinuous x R , then find the value of N1 + N2 and N2 denotes the number of values of
 where g(x) is differentiable
5. Consider f(x)   5 
x  sin x
. If the number of points in (0, 20 ) where f(x) is non–derivable are
the different values of c of LMVT for the twice differentiable function g(x) i.e.,
g(b)  g(a)
g '(c)  for some c  (a, b) , then the minimum number of points where g” (x)
ba
vanishes is n. Find the value of  n  .
2
 x(x  1)(x  2) ; 0  x  n
6. Let f(x)   . If n N then find the least value of n for which f(x) has
 sin(x) ; n  x  2n
more points of minima than maxima in [0, 2n].
(x  1)dx
7. If  (x  x x  x) x(x  1)
 4 tan1[g(x)]  C , where C is an arbitrary constant of integration.
2
Find g (1).
x 2012  1dx and I   log 2  (logx 2)  dx, Then Find I  I

2 4 2
8. I1  
1/ 2
x 2014  1 2 2  x

ln 2 
 1 2
   
1/ n
 n 
9. If lim   sin r cos r   a , a, b N then find the least value of (a + b)
n  4n 4n  b
r 1
1
2 3/4 
10. Let f(x)  x 3  3x  x  1 . Find the value of   f(f(x)dx 
2 4  1/ 4 
27
ANSWERS
SR. NO PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE
1. B P120106 AC C122704 BD M110615
2. ABC P120111 AD C122705 BCD M113625
3. ABC P120115 B C1221803 AC M120604
4. AC P121424 AC C122802 BD M122802
5. BD P121424 AC C124603/02 ABCD M120616
6. AD P121420 BC C124606 ABD M120401/407
7. ACD P120104 AD C122901 AD M120311/22809
8. BC P120108 ABCD C122713 ACD M120325
9. ABC P120104 ACD C122821 BCD M120410
10. CD P120303 ABC C121701 BD M120322/310
1. 4 P120309 3 C121802 6 M110614
2 8 P121515 7 C124603 5 M120406/07
3. 7 P120110 2 C124510 9 M113629
4. 2 P120305 5 C124608 2 M113627
5. 3 P120216 2 C121802 5 M120616
6. 2 P120104 0 C122816 3 M120611
7. 4 P120307 5 C122713 2 M113801
8. 1 P120305 4 C122713 0 M120813
9. 2 P120406 4 C124606 5 M122801
10. 2 P120305 6 C124608 4 M122804
28
PAPER – 2
S
SEEC
CTTIIO
ONN–– 1
1:: P
PHHY
YSSIIC
CSS
PART – A
(Single Correct Choice Type)
and (D) out of which ONLY ONE is correct.
1. Amount of charge flown to earth through key K when it is

closed is
(a) 3 Q (b) – 3 Q
(c) 2 Q (d) – Q
2. Amount of heat generated in R when key it is shifted

from x to y (switch is at x for long time so C is fully
charged)
5 2
(a) 2C2 (b) C
2
9 2 7
(c) C (d) C 2
2 2
3. If plate area is A and separation is as given equivalent

capacitance between A and B is
d/2
0 A 3 0 A
(a) (b)
2d 4 2d
3 0 A 0 A
(c) (d)
2 d
4. Electric potential V as a function of x and y is given as V  a(x 2  y 2 ) . The E can be given

as
(a) E  2a[xiˆ  yj]
ˆ (b) E  2a[yiˆ  xj]
ˆ (c) E  2a[xiˆ  yj]
ˆ (d) E  a[xiˆ  yj]
ˆ
5. Magnetic field at the center of equilateral triangle of side

a carrying current i is
5  0i 7 0i
(a) (b)
3 a 2 a
4 0 i 9 0 i
(c) (d)
a 2 a
29
6. Charge on capacitor in steady state is :
(a) 4c (b) 6c (c) 10c (d) 16c
PART – A
Assertion – Reason Type
This section contains 3 questions numbered 7 to 9. Each question contains STATEMENT-1
(Assertion) and STATEMENT – 2 (Reason). Each question has 4 choices (a), (b), (c) and (d) out of
which ONLY ONE is correct.
7. STATEMENT 1: A conducting circular disc of radius R rotates about its own axis with
angular velocity  then no EMF is induced in the disc.
Because
STATEMENT 2: Centrifugal force is acted on free electrons when disc rotates.
(a) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1
(b) Statement-1 is True, Statement-2 is True ; Statement-2 is Not a correct explanation for
Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True.
8. STATEMENT 1: If current enclosed by a closed loop is zero, then magnetic field at all the
points of loop is zero.
Because
STATEMENT 2:  B.dl   i
C
0 enc
Statement-1
9. STATEMENT 1: An electric dipole is placed in an electric field whose direction is fixed but
magnitude varies with distance. It is possible that the dipole experiences
no net force but a torque.
Because
STATEMENT 2: An electric dipole is place at the centre of a sphere ; the electric field is
zero at every point of the sphere.
Statement-1
(Paragraph Type)
This section contains 2 paragraphs. Based upon the paragraphs 3 multiple choice questions
have to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
30
Paragraph for Question no. 10 to 12
Figure shows the circuit of a potentiometer. The length

of the potentiometer wire AB is 50 cm. The EMF E1 of
the battery is 4 V, having negligible internal resistance.
Value of R1 and R2 are 15 and 5 , respectively. When
both the keys are open, the null point is obtained at a
distance of 31.25 cm from A, but when both the keys are
closed, the balance length reduces to 5 cm only. Given
RAB  10
10. The EMF of the cell E2 is

(a) 1 V (b) 2 V (c) 3 V (d) 4 V
11. The internal resistance of the cell E2 is

(a) 4.5  (b) 5.5  (c) 6.5  (d) 7.5 
12. The balance length when key K2 is open and K1 is closed is given by
(a) 10.5 cm (b) 11.5 cm (c) 12.5 cm (d) 13.5 cm

A charge particle of charge 1 C and mass 10 gm is
moving with velocity 10 î m/s in horizontal plane
3
consisting of magnetic field 0.1kˆ T of width m and
2
electric field 0.1jˆ N/ C of width d. Particle enters the
magnetic field at t = 0 perpendicularly and follows the
path as shown in figure and strikes the wall AB
perpendicularly at A ' (neglect gravity).
13. The time t after which it strikes the wall

(a) 1.2 s (b) 0.97 s (c) 1.07 s (d) 1.98 s
14. The width d of electric field is

5 5
(a) 5 3 m (b) 3m (c) 10 3 m (d) 3m
2 4
15. Taking O as origin, y-coordinate of A’ will be

(a) 3.75 m (b) 0.50 m (c) 4.25 m (d) 3.25 m
PART - B
Matrix-Match Type
This section contains 2 questions. Each question contains statements given in two columns which
have to be matched. Statements (a, b, c, d) in Column I have to be matched with statements (p, q,
r, s) in Column II. The answer to these questions have to be appropriately bubbled as illustrated in
the following example. If the correct matches are a-p, a-s, b-q, b-r, c-p, c-q and d-s, then the
correctly bubbled 4 × 4 matrix should be as follows :
31
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
Match the conditions/expressions in Column I with statements in Column II and indicate

your answer by darkening the appropriate bubbles in the 4 × 4 matrix given in OMR
1.
Column – 1 Column - 2
(a) When a dielectric slab is gradually (P) Electric potential energy of system
inserted between plates of an isolated decreases
parallel plate capacitor
(b) When a dielectric slab is gradually (Q) Work done by eternal agent is positive
inserted between plates of a parallel plate
capacitor keeping battery connected
(c) When plates of parallel plate capacitor are (R) Work done by battery is positive
pulled apart keeping battery connected
(d) When plates of a parallel plate capacitor (S) Work done by eternal agent is negative
are pulled apart keeping its charge
constant
2.
Column – 1 Column - 2
(a) (P) 1 and 2 attract each other
(b) (Q) 1 and 2 repel each other
(c) (R) 1 and 2 do not exert any force on each other
(d) (S) Magnetic field at P due to 1 and 2 are perpendicular to

each other
(T) Magnetic fields at point P due to wire 1 and 2 are in same

direction
32
S
SEEC
CTTIIO
ONN--2
2:: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. Following interconversion was done by Saleha & Amol in ICL (International Chemical
Laboratory) New York.
HC  C – H  ?
 DC  C - CH2 – CH2 – OH
Saleha’s method : O
(i) CH3MgBr (1 eq.) followed by & NH4Cl
(ii) CH3MgBr (1 eq.) followed by DOD.
Amol's method:
(i) CH3MgBr (excess) (ii) CH2  Cl (1eq.)

|
CH2  Cl
(iii) Aq. KOH. (iv) D2O
Find out the correct statement(s) based on above formation.

(A) Saleha's method is correct & Amol's method is wrong
(B) Amol's method is correct & Saleha's method is wrong.
(C) Both the methods can give desired product but Amol's method is better.
(D) Director of ICL (international Chemical Laboratory) Vyom Kishor Burnwal fired on
Saleha's & Amol's because both applied the wrong method.
NH2
NaNO2  HCl
2.   x Major product ‘X’
(A) OH (B) OH
(C) OH (D) OH

3. CH2 (COOEt)2  (CH2 )3 Br2 
NaOEt
EtOH I 
H3O
  II is:
(A) (B)
(C) (D)
33
4. 
HBr
 Major product is
1eq., 40 C
(A) Br (B) Br
(C) (D)
Br
Br
5. Nylon-6 is prepared by linear condensation homopolymerization reaction of:

(A) caprolactum (B) hexamethylene diamine and adipic acid
(C) 6-aminohexanoic acid (D) acrylonitrile
6. Which gives 2 moles of HCHO, 1 mole of HCOOH and CO2 by HIO4
(A) H2C OH (B) HC O
HC OH HC OH
C O HC OH
H2C OH HC O
(C) H2C OH (D) All

( HC OH)2
HC O
PART – A
7. STATEMENT 1: NH2 – NH2 gives Prussian blue colour during Lassaigne test
(element detection test).
Because
STATEMENT 2: NaCN gives Prussian blue colour of Fe 4[Fe(CN6)]3 with FeSO4, FeCl3
Statement-1
CH3 – CH – CH2 – CH3

P eroxide
8. CH3 – CH = CH – CH3 + HX  X
STATEMENT 1: The stereochemistry of product is same whether HCl or HBr is used as
reactant.
Because
STATEMENT 2: The reaction mechanism with HCl and HBr are same in above conditions.
Statement-1
34
9. STATEMENT 1: Polybutadiene is an example of chain growth polymer

Because
STATEMENT 2: In chain growth polymers, the reactive particles may free radicals or ions
(cations or anions) to which monomers get added by a chain reaction.
Statement-1
(Paragraph Type)
Consider following   amino acids
Sr. Structure of   amino Pka1 Pka2

Name Abbreviation
No. acid (   COOH) (   NH3 )
H2C COOH
1. Glycine Gly 2.4 9.6
NH2
COOH
2. Valine Val 2.3 9.7
NH2
Ph COOH
3. Phenylalanine Phe 1.8 9.2
NH2
10. Structure of H-gly-phe-gly-OH is
(a) OH (b) O
O
NH
NH O H2N NH OH
O
O Ph
(c) O (d) O
O O
NH NH
H2N NH OH NH OH
O H2N O
11. For valine at pH = 6 which of the following will exist as major component.
(a) COOH (b) -

COO
NH2 NH2
(c) - (d) COOH
COO
+
+ NH3
NH3
35
12. What is the pl of the following amino acids ?

+
pka  8.95  NH3
+ OH pka  2.18

pka  10.79  H3N
O
(a) 3.22 (b) 9.87 (c) 5.6 (d) 6.49

 S
CrO
3

 P 
 Q  R
O3 KOH N2H4
Zn / H2 O EtONa
  U 
HBr NH
3
excess
V
 T
KOH H2 / Pd
 excess
13. Which of the following statement is correct about S ?

(a) It will not give yellow/orange or red colour with 2, 4-DNP
(b) It will give red colour with Cerric Ammonia Nitrate
(c) It will not give Fehling test
(d) It will give Bielstien test
14. Which of the following statement is correct about V ?

(a) It will not give mustard oil reaction
(b) It will not give carbylamines test or isocyanide test
(c) It is less basic than aniline
(d) It will give base soluble product with Hinsburg reagent
15. Which of the following reaction will be useful for conversion of R into S
(a) Clemmen’s reduction (b) Oppenauer oxidation
(c) Meerwin Pondorff Verely reduction (d) Tischenko reaction
PART - B
Matrix-Match Type
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s

1 Column I Column II
(A) O (P) Formation of six member
ring takes place

traces of KOH (A) (B) 
HCN LiAlH4 NaNO2
HCl (C)
36
(B) O (Q) Final product is Ketone


NH2OH
(A) 
H
(B)

(C) O O (R) Final product is

|| || HO
CH 3  C  CH 2  CH 2  CH 2  C  H  aldehyde
(D) (S) Final product formed will
react with 2,4–DNP


H

(A)

2. Column I Column II
(A) (P) Gives orange colour with Brady's
reagent (2,4-DNP)
O
(B) (Q) Gives haloform reaction
Cl
(C) O (R) Gives positive Beilstein's test
(D) Cl (S) Can give aldol reaction with dil.

NaOH
(T) Gives white ppt. with alcoholic

AgNO3
S
SEEC
CTTIIO
ONN--3
3:: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. Period of function f(x)  min{| x 2  (2n  1)x  n(n  1) | where n  3k  1,k  I} is equal to
(a) 5 (b) 6 (c) 2 (d) 3
2. If y  e x  e x then xy 2  (1/ 2)y1 is equal to

(a) y 
(b) x e x  e x
 (c) (1/ 4)y (d) xy
3. Let f(x) = ax +b, where a and b are integers. If f(f(0)) = 0 and f(f(f(4)) = 9, then the value of
f(f(f(f(10)))) is equal to
(a) 0 (b) 4 (c) 9 (d) 10
4. If a twice differentiable function satisfying a relation

 1
f(x 2 y)  x 2 f(y)  yf(x 2 )x,y  0 and f '(1)  1 then the value of f ''   is
 7
(a) 7 (b) 7/2 (c) 7/3 (d) 7/4
37
sin2x
5. If I   dx , then I equals
(3  4cos x)3
3 cos x  8 3  8cos x 3 cos x 3  8cos x
(a) C (b)  C (c) C (d) C
(3  4 cos x)2 16(3  4cos x)2 (3  4 cos x)2 16(3  4cos x)2
  x 
1  cos 2  , 1 x  2
  
6. The number of points where the function f(x)   and f(1) = 0 is
1  {x}, 0  x 1
| sin x |, 1  x  0
continuous but non-differentiable is/are (where [.] and {.} represent greatest integer and
fractional part functions, respectively)
(a) 0 (b) 1 (c) 2 (d) none of these
PART – A
7. STATEMENT 1: f is an even function, g and h are odd functions, all 3 being polynomials.
Given
f(1) = 0, f(2) = 1, f(3) = -5, g(1) = 1, g(-3) = 2, g(5) = 3, h(1) = 3, h(3) = 5
and
h(5) = 1. The value of f(g(h(1)))  g(h(f(3)))  h(f(g( 1))) is equal to zero.
Because
STATEMENT 2: If a polynomial function P(x) is odd then P(0) = 0.
(e) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1
(f) Statement-1 is True, Statement-2 is True ; Statement-2 is Not a correct explanation for
Statement-1
(g) Statement-1 is True, Statement-2 is False
(h) Statement-1 is False, Statement-2 is True.
8. Let p,q  R be such that the function f(x)  ln | x |  qx 2  px, x  0 has extreme values at x = -1 and
x=2
STATEMENT 1: f has local maximum at x = -1 and x = 2

Because
1 1
STATEMENT 2: p and q 
2 4
Statement-1
9. STATEMENT 1: Let L1 : f1(t)x  f2 (t)y  5 and L2 : g1(t)x  g2 (t)y  4 be two lines where
t  [0,1] and f1,f2 ,g1,g2 are continuous function. If f1(0) = g2(0) = f2(1) = g1(1)
= 2, f2(0) = g1(0) = 3 and f1(1) = g2(1) = 4 then both the lines must be
perpendicular for some t  [0,1]
Because
STATEMENT 2: If f(x) is a continuous function in [a, b] and f(a). f(b) < 0, then the equation
f(x) = 0 has a root in (a, b)
38
Statement-1
(Paragraph Type)

3x  a
Consider a function f(x)  which has greatest value equal to 3/2.
x2  3
10. The value of the constant number a is equal to

(a) 1 (b) 2 (c) 3 (d) 4
11. The minimum value of f(x) is equal to

          
(a) tan   (b) sin   (c) cos   (d) cot  
 3   6   3  2
12. If the equation f(x) = b has two distinct real roots then the number of integral values of b is
equal to
(a) 0 (b) 1 (c) 2 (d) 3
Consider f : R  R be a polynomial function whose degree is greater than 1 and atmost 4.

Also f is a one-one and onto function whose graph is symmetrical about A(4, 0) and f has
horizontal tangent at
x=4
2018

2010
f(x) dx is equal to
(a) – 4 (b) 0 (c) 4 (d) 8
14. The value of f 1(2)  f 1( 2) is equal to

(a) 0 (b) 2 (c) 4 (d) 8
15. If f '(10)  20 , then f '( 2) is equal to

(a) 4 (b) 8 (c) 20 (d) 32
PART - B
Matrix-Match Type
39
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s

1. Match Column I with statements in Column II
Column – I Column – I Column – II

g( x) cos x
dt
(A)
If f(x)  
0 1  t3
where g(x)  
0
(1  sint 2 ) dt , then the value of
(P) 3
f '(  / 2)
If f(x) is a non zero differentiable function such that
x
(B) (Q) 2
 f(t) dt  (f(x))
2
for all x, then f(2) equals
0
b
(C) If  (2  x  x 2 ) dx, is maximum then b is equal to (R) 1

0
 sin 2x b
(D) If lim   a  2   0 then (3a  b) has the value equal to (S) -1
x0  x 3
x 
2. Match Column I with statements in Column II
Column – I Column – I Column – II

The set of value of x satisfying the inequality   
(A) 1 + log2(sin x) + log2 (sin3x) > 0 in (0,  ) is / are (P)  6 , 4 
The set of values of x in (0,  ) in which f(x)  3 sinx  cosx is   

(B) (Q)  4 , 3 
decreasing is/are
Any point of extrema of the function g(x) = 6sin x – 4sin3x lies in   2 
(C)
interval
(R)  3 , 3 
1
 2 3  
2
 (sin(x )  x 3  1)dx lies in interval

5
(D) The value of definite integral (S)  3 , 4 
1
2
 2 
(T)  3 ,  
40
ANSWERS
SR. PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE

N
O
1. A P120118 D C111713 D M113422
2. C P120216 A C124520 C M114106
3. B P120115 B C124603 D M113412
4. A P121408 C C114708 A M113423
5. D P120302 A POLYMER B M113802
6. D P121512 A POLYMER B M113623
7. D P120305 D C124510 A M113420/21
8. D P120303 C C111708 A M120608
9. C P120113 A C111709 D M113616
10. A P121515 B C122906 C M120612
11. D P121515 C C122906 B M120608
12. C P121515 B C121704 B M120616
13. B P120305 C C122714 B M113410
14. B P120305 D C121601 D M113411
15. C P120305 B C124510 C M114101
1. A-PS, B- P120114 PQS, P, C121401/03/08 A-S, B- M113802/3423/
RS, C-PQ, PQS, PQS R, C-R, 3811/0611
D-Q D-Q
2. A-RS, B- P120302/306 PQS, QRT, C122001 A-P, B- M120609/611/
RS, C-RS, PS, RT ST, C- M113813
D-RT RT, D-R

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PHYSICS, CHEMISTRY & MATHEMATICS

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