Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Advanced Date: 14-05-19
Time: 09:00 AM to 12:00 Noon 2013_P1 Max.Marks:180
KEY SHEET

PHYSICS
1 B 2 C 3 D 4 D 5 B

6 B 7 C 8 D 9 C 10 D

11 C 12 BD 13 ABC 14 AC 15 ABCD

16 1 17 5 18 5 19 2 20 2

CHEMISTRY
21 C 22 C 23 D 24 D 25 A

26 C 27 A 28 A 29 A 30 A

31 ABD 32 BCD 33 BCD 34 ABCD 35 BC

36 5 37 4 38 1 39 4 40 3

MATHS
41 B 42 A 43 C 44 B 45 A

46 B 47 D 48 A 49 D 50 D

51 AC 52 BCD 53 ABC 54 AD 55 AD

56 6 57 5 58 6 59 9 60 2
Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
SOLUTIONS
PHYSICS
9
1. Least court  LC   1 MSD  1VSD  0.05mm   0.05 mm  0.005cm
10
Reading of scale = Diameter = MSR + n (Least count) – zero error
 1.8  6   0.005  4   0.005  cm
D  1.81cm
2. Assertion is false but reason is true.
The twinkling of a star is due to refraction of light from the star through the
atmosphere of earth. As the conditions of the refracting medium are not stationary, star
light has to travel through fluctuating masses of air in motion with changing
conditions of temperature, temperature gradients etc. Therefore, the apparent position
of the star fluctuates. This gives rise to the twinkling effect of star.
B
l1
2
L M
 l
1

com 2

A C
3.
 AM  0

l1 l
T2 sin   T3 1 sin 
2 2
T1  T2  T3

V1 M2 40
4.    10  3.16
V2 M1 4
KA t 1
5. Q  
 K
6. Both assertion and reason are true but reason is not the correct explanation of
assertion.
According to Lenz’s law, induced emf are in a direction such as to attempt to maintain
the original magnetic flux when a change occurs. When the switch is opened, the
sudden drop in the magnetic field in the circuit induces an emf in a direction that
attempts to keep the original current flowing. This can cause a spark as the current
bridges the air gap between the poles of the switch. (The spark is more likely in
circuits with large inductance)

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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
7. At highest point,
Apply LCLM.
2h
Separation  v .
g
8. Assertion is false but reason is true.
Time period of a simple pendulum is inversely proportional to the square root of
  2h  
g. i.e.T  1/ g . At mountain top, the value of g decreases  g '  g  1    . Hence
  R 
the value of T increases i.e., the pendulum will take longer time to complete one
vibration. This shows that the pendulum clock will become slow. Hence the pendulum
clock will lose time on the mountain top.

9. Both assertion and reason are true but reason in not the correct explanation of
assertion.
When frequency of alternating current is increased, the effective resistance of the
inductance coil increases  X L   L  2 fL . Current in the circuit containing inductor

V V
is given by I   . As inductive resistance of the inductor increases, current
X L 2 fL
in the circuit decreases.
 
10. x   2  1 t
 1 
T
11. P  2 2 f 2 A2  s,  
s
12. In situation (i), mass C is moving towards right with velocity v. A and B are at rest. In
situation (ii), which is just after the collision of C and A,C stops and A acquires a
velocity v . When A starts moving towards right, the spring suffers a compression due
to which B also starts moving towards right. The compression of the spring continues
till there is relative velocity between A and B. Once this velocity becomes zero, both
A and B move with the same velocity v ' and the spring is in a state of maximum
compression
Applying momentum conversation is situations (ii) and (iii),
v
mv  mv ' mv '  v ' 
2
 KE of the system is situation (iii) is
1 '2 1 2 2 mv 2
mv  mv '  mv ' 
2 2 4
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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
Applying energy conversation, we get
1 2 1 1 1
mv  mv '2  mv '2  Kx 2
2 2 2 2
m
Solve to get x  v
2K

13. Force diagram on both the block is as shown in figure.

4
a1   4m / s 2 (left wards)
1
18  4
a2   11m / s 2 (right wards)
2
 a1  15m / s 2
14. If ‘q’ is positive and small displacement is along line joining, a  d
If ‘q’ is negative and small displacement is along line perpendicular to the line joining the two
charges, then a   d . In these two cases, ‘q’ is in SHM.
A 0 A
15. C1  , C2  0
2d d

Charge on plate B1'  Charge on plate B2  Q

1. Now if only S1 is closed then charge on plate C will still be zero
 Charge on plate B2  0
 Total charge  Q is on plate B1'
  Q amount of charge will flow through S1 so as to form a capacitor C1 .
2. Similarly, if only S 2 is closed Q amount of charges will flow through S 2
 In both of above cases Charge of amount Q (sign is not taken) is flown

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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A

Now, If S1 and S 2 both are closed, let the distribution charges on the capacitors are
 q  Q  q
Now  0
C1 C2
Q
 q
3
  Q / 3 amount of charge is flown through S1 and  Q  Q / 3 , i.e., 2Q / 3 amount
of charge is flown through S 2
Q
Charges on outer surfaces are equal and is equal to .
2
16. Slope of graph for any metal is h / e  constant.
N N 1
17. N  t /0T  ;T  5Mins
2 N0 8
18. FBD of m w.r.t. wedge

Relative acceleration along the inclined plane

ma cos   mg sin 
ar 
m
 a cos   g sin 
 3  1
 
 10 3    10  
 2   2
 10m / s 2
2s 2 1 1
t   s
ar 10 5
19. For a plane refracting surface, the lateral magnification is 1.
20. u  5 gR
v 2  u 2  2 gh   5 gR   2 gR
 3gR
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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
v2
ar   3g
R
ar  g
 a  ar2  at2  g 10

CHEMISTRY
21. Conceptual
H 3C H H 3C
OH OTs

22.
23. Conceptual
24. E2 Reaction
25. Conceptual
COOH

CHO
CH 3
26.
27. Conceptual
28. Friedel Crafts Alkylation Reaction
29. Conceptual
30. Ionic character PbCl2 > PbCl4
31.  HCN  OH 
CN   H 2O 
0.1  x x x
1014 x2

Ka 0.1  x
x  10 2
32. Option (A) is wrong because ‘b’ in trans position w.r.t. ‘a’.
33. LiAlH4 reduces both ester and ketone group
34. A,B,C and D are correct
760  740 1
35.   nH 2O  37  nice  200  37  163
740 nH 2O

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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
1
 ΔT f  2   1000 K
37  18
 2000  0
Tf   C
 37  18 
150 0
36. λ A  5 A0
6
37. Conceptual
38. XeOF4 ; Square pyramidal, one lp on xenon atom.
39. K 2  CoF6  , K3 CoF6  , K3  Fe(CN ) 6 
40. Conceptual
MATHS
41. Let any point on the second line be   ,2 ,3 
A1,1,1


0 B ,2,3

6 6
cos   ,sin  
42 42
1
 OAB   OA OB sin 
2
1 6
 3 14   6
2 42
Or 2
So B is  2,4,6
42. The point of intersection of diagonals,
i.e., 1,1 , lies on the circumcircle.

I
1,1
720
R

Hence,
I  2 R sin 720
sin 360
R 0
 cos 720
2sin 72

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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
2 2
Therefore, the locus is  x  1   y  1  cos 2 72 0 . Hence
x 2  y 2  2 x  2 y  1  sin 2 720  0
43. a 2 x 2  ax  1 is clearly positive for all real values of x . Area under consideration.
1


A   a 2 x 2  ax  1 dx 
0

a2 a
  1
3 2
1

 2a 2  3a  6
6

1  3 9 18 
  2  a2  a    6  
6  2 16  16 
2
1  3 39 
  2 a    , which is clearly minimum
6  4 8 
3
For a  
4
44. If A, B, C represent events that the student is successful in tests I , II , III , respectively.
Then the probability that the student is successful is
P  A  B  C '   A  B ' C    A  B  C  
 P  A  B  C '  P  A  B ' C   P  A  B  C 
 P  A P  B  P  C '  P  A P  B ' P  C   P  A P  B P  C 
[ A, B, C are independent events]
 1 1 1
 pq  1    p 1  q  pq
 2 2 2
1 1
 pq  p  pq
2 2
1
  pq  p
2
1 1
 p 1  q  
2 2
 p 1  q   1
45. u 2  2u  2  0  u 1 i


 x   n   x    n
 
n n
 cot   1  1  i     cot   1  1  i  

2i
 cot   1  x

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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
n n


 cos   i sin     cos   i sin  
sin n  2i
2i sin n

sin n  2i
sin n

sin n 
46. Conceptual
dy y 2dy dx
47.   
dx 2 x y x
 log y  log x  cosnt  y 2  Cx, this passes through  2,1 if C  1/ 2. Thus y 2  1/ 2 x which
2

represents a parabola with focus 1/ 8, 0  .

  2 k  1   2k  1 
48. tan 1  
1   2k  1 2k  1 
49. For real roots
 (4) 2  4(2  1)(2  1)  0

 (2  1)2  4
  2  2  1  2
1 3
 
2 2
 Integral values of  are 0 and 1

Hence, the greatest integer value of   1

50. In an isosceles triangle ABC in which AB=AC, the median and bisector from ‘A’ must
be same line
 Reason ‘R’ is true
uv
Now AD 
2
and AD 
2

4 
1 2 2
u  v  2 u v cos  
1
 1  1  2 cos  
4
 AD  cos  / 2
51. Plane P1 contains the line

 
r  iˆ  ˆj  kˆ   iˆ  ˆj  kˆ , hence contains the
point iˆ  ˆj  kˆ and is normal to vector iˆ  ˆj .  
Hence, equation of plane is

   
r  iˆ  ˆj  kˆ . iˆ  ˆj  0 
Or x y2

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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
Plane P2 contains the line

 
r  iˆ  ˆj  kˆ   iˆ  ˆj  kˆ and point ĵ
Hence, equation of plane is
x  0 y 1 z  0
1 0 11 1 0  0
1 1 1
Or x  2y  z  2
If  is the acute angle between P1 and P2 , then
  
n1.n2
cos     

iˆ  ˆj . iˆ  2 ˆj  kˆ 
n1 n2 2. 6

3 3
 
2. 6 2
3 
  cos 1 
2 6
As L is contained in P2    0
52. Since f is defined on  0,  .
Therefore, 2a 2  a  1  0 which is true as D  0
Also 3a 2  4a  1  0
 3a  1 a  1  0  a  1/ 3 or a  1 (1)
As f is increasing hence
  
f 2a 2  a  1  f 3a 2  4a  1 
 2a 2  a  1  3a 2  4a  1
 0  a 2  5a
 a  a  5  0   0,5 (2)
From (1) and (2), we get
Hence, a  0,1/ 3  1,5 .
Therefore, possible integers are  2,3, 4
53. Let the three – digit number be xyz . According to given condition, we have
y 2  xz (1)
2  y  2  x  z (2)
100 x  10 y  z  792  100 z  10 y  x
 xz8 (3)
Squaring (2) and (3), and substracting, w have
2
4 xz  4  y  2  64 (4)
2
 y 2   y  2  16 [Using (1)]
 y3
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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
 x  z  10 [Using (2)]
 x  9, z  1
Hence, the number is 931  7 2  19 .
T T
54. B T
AB   BT AT BT    BT AT B  BT AB if A is symmetric. Therefore, BT AB is
symmetric if A is symmetric.
T

Also, BT AB   BT AT B  BT   A B   BT AT B  
T
Therefore, B AB if A is skew – symmetric if A is skew – symmetric
55.

h 1

x
x

x 2  h 2  1;
1 3 2 3
Volume, V 
3
6
4
x h
2
h 1  h2  
1
For V '  h  0  h   Vmax  1/ 3
3
 
56. 
2V  V  iˆ  2 ˆj  2iˆ  kˆ    (i)

Or    
2V . iˆ  2 ˆj  0  2iˆ  kˆ . iˆ  2 ˆj 

Or 
2V . iˆ  2 ˆj  2 
 2
Or 
V . iˆ  2 ˆj  1 
2 2
Or V . iˆ  2 ˆj cos 2   1

(  is the angle between V and iˆ  2 ˆj )
2
Or V 5 1  sin 2   1  
2 2
Or V 5sin 2   5 V  1 (ii)
From Eq. (i), we have
  2 2
2V  V  iˆ  2 ˆj    2iˆ  kˆ
2  2
Or 4 V  V  iˆ  2 ˆj  5  
2 2 2
Or 4 V  V . iˆ  2 ˆj sin 2   5

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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
2 2
Or 4 V  5 V sin 2   5
2 2
Or 4 V  5V 1 5
2
Or 9V  6

Or 3V  6
 6 m
 m6
57. The number of ways of drawing 7 balls (second draws) 10 C7
For each set of 7 balls of the second draw, 3 must be common to the set of 5 balls of
the first draw, i.e., 2 other balls can be drawn in 3 C2 ways.
Thus, for each set of 7 balls of the second draw, there are 7 C3  3 C2 ways of making
the first draw so that there are 3 balls common.
Hence, the probability of having three balls in common is
7
C3  3 C2 5
10

C7 12
58. 1  2 x  5x 2

 10 x 3  11 C0 11 C1 x 11 C2 x 2  ........  1  a1 x  a2 x 2  ......
n  n  1
 a1  n  2 and a2   2n  5
2
Given that a12  2a2
  n  2 2  n  n  1  4n  10
 n2  4n  4  n 2  5n  10
 n6
2
 k  k  1  k  k  1
59.  2   2
 1980
 
k  k  1  k  k  1 
  1  1980
2  2 
  
k  k  1 k 2  k  2  1980  4
  k  1 k  k  1 k  2  8.9.10.11
 k 1 8  k9
60.  OS1  ae  6, OC  b  let 
Also, CS1  a
1
Area of OCS1   OS1    OC   3b
2
1
 Semi – perimeter of OCS1   OS1  OC  CS1 
2
1
  6  a  b (i)
2
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Sri Chaitanya IIT Academy 14-05-19_Sr. ICON ALL_JEE-ADV(2013_P1)_GTA-11_Key & Sol’s_Code-A
 In radius of OCS1  1
3b
Or  1 or 5b  6  a (ii)
1/ 2 6  a  b
Also, b 2  a 2  a 2e2  a 2  36 (iii)
So, from (iii),
25b 2  36  12a  a 2
 
Or 25 a 2  36  36  a 2  12a
2a  a  78  0
13
Or a  , 6
2
13 5
 a and b  .
2 2

Sec: Sr. ICON ALL Page 13