UNITY PUBLIC SCHOOL

KOTTUR

TEST - 4
Name: Roll No: Class: Max Time: 3 Hrs
Date: Subject: CHEMISTRY Max Marks: 70

General Instructions
(a) All questions are compulsory.
(b) Section A: Q.no. 1 to 20 are very short answer questions (objective type) and carry 1 mark each.
(c) Section B: Q.no. 21 to 27 are short answer questions and carry 2 marks each.
(d) Section C: Q.no. 28 to 34 are long answer questions and carry 3 marks each.
(e) Section D: Q.no. 35 to 37 are also long answer questions and carry 5 marks each.
(f) There is no overall choice. However an internal choice has been provided in two questions of two
marks, two questions of three marks and all the three questions of five marks weightage. You have to
attempt only one of the choices in such questions.
(g) Use log tables if necessary, use of calculators is not allowed.

SECTION A
1 Two liquids A and B boil at 145 °C and 190 °C respectively. Which of them has 1
a higher vapour pressure at 80 °C?
2 Considering the formation, breaking and strength of hydrogen bond, predict 1
which of the following mixtures will show a positive deviation from Raoult’s
law?
(a) Methanol and acetone.
(b) Chloroform and acetone.
(c) Nitric acid and water.
(d) Phenol and aniline.
3 Which of the following statements is false? 1
(a) Two different solutions of sucrose of same molality prepared in different
solvents will have the same depression in freezing point.
(b) The osmotic pressure of a solution is given by the equation ∏ = CRT
(where C is the molarity of the solution).
(c) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of
barium chloride, potassium chloride, acetic acid and sucrose is
BaCl2 > KCl > CH3COOH > sucrose.
(d) According to Raoult’s law, the vapour pressure exerted by a volatile
component of a solution is directly proportional to its mole fraction in the
solution.
4 Maximum amount of a solid solute that can be dissolved in a specified amount 1
of a given liquid solvent does not depend upon ____________.
5 In the following question a statement of assertion followed by a statement of 1
reason is given. Choose the correct answer out of the following choices.
(a) Assertion and reason both are correct statements and reason is correct
explanation for assertion.
(b) Assertion and reason both are correct statements but reason is not correct
explanation for assertion.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion and reason both are incorrect statements.
(e) Assertion is wrong statement but reason is correct statement.
Assertion: When a solution is separated from the pure solvent by a
 semipermeable membrane, the solvent molecules pass through it from pure
solvent side to the solution side.
Reason: Diffusion of solvent occurs from a region of high concentration
solution to a region of low concentration solution.
6 Calculate the overall order of a reaction which has the rate expression 1
(a) Rate = k [A]1/2 [B]3/2 (b) Rate = k [A]3/2 [B]–1
7 Which of the following is affected by catalyst? 1
(a) ∆H (b) ∆S(c) ∆G (d) Ea
8 Consider Fig. and mark the correct option. 1
(a) Activation energy of forward reaction is E1 + E2 and product is less stable
than reactant.
(b) Activation energy of forward reaction is E1 + E2 and product is more stable
than reactant.

(c) Activation energy of both forward and backward reaction is E1 + E2 and

reactant is more stable than product.
(d) Activation energy of backward reaction is E1 and product is more stable
than reactant.

9 In the following questions a statement of assertion followed by a statement of 1

reason is given. Choose the correct answer out of the following choices.
(a) Both assertion and reason are correct and the reason is correct explanation
of assertion.
(b) Both assertion and reason are correct but reason does not explain
assertion.
(c) Assertion is correct but reason is incorrect.
(d) Both assertion and reason are incorrect.
(e) Assertion is incorrect but reason is correct.
Assertion: Order and molecularity are same.
Reason: Order is determined experimentally and molecularity is the sum of the
stoichiometric coefficient of rate determining elementary step.

10 If activation energy for forward reaction (Ea)f = 150 kJ and (Ea)b is 260 kJ, DH 1
of reaction = _________.
11 Write the IUPAC name of 1

12 Acetophenone when reacted with base C2H5—ONa, yields a stable product: 1

13 The product formed by the reaction of an aldehyde with a primary amine is 1
(a) Carboxylic acid (b) Aromatic acid (c) Schiff’s base (d) Ketone
14 In the following questions a statement of assertion followed by a statement of 1
reason is given. Choose the correct answer out of the following choices.
(a) Assertion and reason both are correct and reason is correct explanation of
assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct but reason is wrong statement.
(d) Assertion is wrong but reason is correct statement.
(e) Assertion and reason both are correct statements but reason is not correct
explanation of assertion.
Assertion: The α-hydrogen atom in carbonyl compounds is less acidic.
Reason: The anion formed after the loss of a-hydrogen atom is resonance
stabilised.

15 Formic acid does not undergo HVZ reaction because it does not have 1
_______________.
16 Arrange the following compounds in increasing order of solubility in water: 1
C6H5NH2, (C2H5)2NH, C2H5NH2
17 The reaction of p–Toluidine with CHCl3 and KOH gives. 1

18 4-Nitrotoluene is treated with bromine to get P. ‘P’ is reduced with Sn/HCl to 1

get compound ‘Q’. ‘Q’ is diazotised and the product is treated with phosphinic
acid to get compound ‘R’. ‘R’ is oxidised with alkaline KMnO4 to get ‘S’.
Compound ‘S’ is
(a) 2-Bromo-4-hydroxy benzoic acid (b) 2-Bromo benzoic acid
(c) 3-Bromo benzoic acid (d) 4-Bromo benzoic acid

19 In the following questions a statement of assertion followed by a statement of 1

reason is given. Choose the correct answer out of the following choices.
(a) Assertion and reason both are correct and reason is correct explanation of
assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct but reason is wrong statement.
(d) Assertion is wrong but reason is correct statement.
(e) Assertion and reason both are correct statements but reason is not correct
explanation of assertion.
Assertion: Acetanilide is less basic than aniline.
Reason: Acetylation of aniline results in decrease of electron density on
nitrogen.
20 The pKb of N, N-Dimethyl aniline is _________ than aniline. 1
 SECTION B
21 The vapour pressure of pure benzene at a certain temperature is 0.85 bar. A 2
non-volatile, non-electrolyte solid weighing 0.5 g is added to 39.0 g of
benzene (molar mass 78 g mol–1). Vapour pressure of the solution, then, is
0.845 bar. What is the molar mass of the solid substance?
22 An aqueous solution of solidum chloride freezes below 273 K. Explain the 2
lowering in freezing points of water with the help of a suitable diagram.

23 For a chemical reaction R → P, the variation in the concentration (R) vs. time 2
(t) plot is given as:

(i) Predict the order of the reaction.

(ii) What is the slope of the curve?

24 Why is acetic acid stronger than phenol whereas formic acid is stronger than 2
acetic acid?
25 Write chemical equations to illustrate each of the following reactions: 2
(i) Acylation reaction (ii) Rosenmund reduction
26 How will you bring about the following conversions? 2
(i) Nitrobenzene to Phenol.
(ii) Aniline to Chlorobenzene.
27 A primary amine, RNH2 can be reacted with CH3—X to get secondary amine. 2
R—NHCH3 but the only disadvantage is that 3° amine and quaternary
ammonium salts are also obtained as side products. Can you suggest a
method where RNH2 forms only 2° amine?
SECTION C
28 What would be the molar mass of a compound if 6.21 g of it dissolved in 24.0 3
g of chloroform forms a solution that has a boiling point of 68.04 °C. The
boiling point of pure chloroform is 61.7 °C and the boiling point elevation
constant, Kb for chloroform is 3.63 °C/m.
29 3
3.9 g of Benzoic acid dissolved in 49 g of benzene shows a depression in
freezing point of 1.62 K. Calculate the van’t Hoff factor and predict the nature
of solute (associated or dissociated). (Given; Molar mass of benzoic acid = 122
g mol–1, Kf for benzene = 4.9 K kg mol–1)
30 The reaction, N2(g) + O2(g) 2NO(g) 3
contributes to air pollution whenever a fuel is burnt in air at a high
temperature. At 1500 K, equilibrium constant K for it is 1.0 × 10–5. Suppose in
 a case [N2] = 0.80 mol L–1 and [O2] = 0.20 mol L–1 before any reaction occurs.
Calculate the equilibrium concentrations of the reactants and the product after
the mixture has been heated to 1500 K.
31 The following data were obtained during the first order thermal decomposition 3
of N2O5 (g) at constant volume:

Calculate the rate constant.

32 What happens when: 3

(i) An aqueous solution of sodium acetate is electrolysed?
(ii) Calcium acetate is dry distilled?
(iii) S odium benzoate is heated with soda lime?
33 How are the following conversions carried out ? 3
(i) E thylcyanide to ethanoic acid
(ii) Butan-1-ol to butanoic acid
(iii) Benzoic acid to m-bromobenzoic acid.
34 i) Stating the necessary reaction conditions write chemical reaction 3
equations to obtain the following: Chlorobenzene from aniline.
(ii) Identify A and B in the following:

ii)
SECTION D
35 (a) Define the following terms: 5
(i) Azeotrope (ii) Osmotic pressure (iii) Colligative properties
(b) Calculate the molarity of 9.8% (w/w) solution of H2SO4 if the density of the
solution is 1.02 g mL–1 (Molar mass of H2SO4 = 98 g mol–1)
(OR)
(a) Explain the following:
(i) Henry’s law about dissolution of a gas in a liquid.
(ii) Boiling point elevation constant for a solvent.
(b) A solution of glycerol (C3H8O3) in water was prepared by dissolving some
glycerol in 500 g of water. This solution has a boiling point of 100.42 °C. What
mass of glycerol was dissolved to make this solution? (Kb for water = 0.512 K
kg mol–1)
36 (a) Write the products of the following reactions: 5
 (b) Which acid of each pair shown here would you expect to be stronger?

(OR)
(a) Account for the following:
(i) CH3CHO is more reactive than CH3COCH3 towards reaction with HCN.
(ii) Carboxylic acid is a stronger acid than phenol.
(b) Write the chemical equations to illustrate the following name reactions:
(i) Wolff-Kishner reduction
(ii) Aldol condensation
(iii) Cannizzaro reaction

37 (a) Write the structures of main products when aniline reacts with the 5
following reagents:
(i) Br2 water (ii) HCl iii) (CH3CO)2O/pyridine
(b) Arrange the following in the increasing order of their boiling point:
C2H5NH2, C2H5OH, (CH3)3N
(c) Give a simple chemical test to distinguish between the following pair of
compounds:
(CH3)2NH and (CH3)3N
(OR)
(a) Illustrate the following reactions giving suitable example in each case:
(i) Hoffmann's Bromamide degradation reaction,
(ii) Diazotization
(iii) Gabriel phthalimide synthesis.
(b) Distinguish between the following pairs of compounds:
(i) Aniline and N-methyl aniline
(ii) (CH3)2 NH and (CH2)3N.
 BLUE PRINT

LESSON 1 2 3 5 TOTAL

ALDEHYDE 5 2 2 5 20

AMINES 5 2 1 5 17

SOLUTION 5 2 2 5 20

CHEMICAL 13
5 1 2
KINETICS

TOTAL 20 14 21 15 70