Part B: Determining the acetic acid content of Datu Puti vinegar

Table 2: Data gathered on determination of Datu Puti’s acetic acid content for trials 1, 2 and 3

Trial 1 Trial 2 Trial 3

Volume of Vinegar
12.5 mL 12.5 mL 12.5 mL
used
Volume of Aliquot
10.0 mL 10.0 mL 10.0 mL
used
Initial Burette
0.00 mL 0.00 mL 0.00 mL
Volume
Final Burette Volume 8.50 mL 8.30 mL 8.00 mL
Volume of NaOH
8.50 mL 8.30 mL 8.00 mL
used
Average Volume of
8.267 mL
NaOH used
Molarity of NaOH
0.05 M 0.05 M 0.05 M
solution
Molarity of Acetic
0.0425 M 0.0415 M 0.04 M
Acid in Vinegar
Average Molarity of
Acetic Acid in 0.0413 M
Vinegar
Percent (w/v) Acetic
5.105% 4.984% 4.804%
Acid
Average percent
4.9643%
(w/v) Acetic Acid

A. Solving the Moles of NaOH

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
M = 𝑙𝑖𝑡𝑒𝑟𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑁𝑎𝑂𝐻
0.1 M = 0.5 𝐿

(0.1 mol/L) (0.5L) = moles of NaOH

moles of NaOH = 0.05 mol NaOH

B. Solving the Molarity of Acetic Acid

Trial 1
Moles = (volume in liter) (Molarity)

= (0.0085L) (0.05mol/L)
= 0.000425 mol

Number of mole for NaOH = 0.000425 mol

Number of mole for NaOH = Number of mole for CH3COOH
Therefore, the number of mole for CH3COOH = 0.000425 mol

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
Molarity for CH3COOH = 𝑙𝑖𝑡𝑒𝑟𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

0.000425 mol
= 0.01𝐿

= 0.0425 M

Trial 2

Moles = (volume in liter) (Molarity)

= (0.0083L) (0.05mol/L)
= 0.000415 mol

Number of mole for NaOH = 0.000415 mol

Number of mole for NaOH = Number of mole for CH3COOH
Therefore, the number of mole for CH3COOH = 0.000415 mol

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
Molarity for CH3COOH = 𝑙𝑖𝑡𝑒𝑟𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

0.000415 mol
= 0.01𝐿

= 0.0415 M

Trial 3

Moles = (volume in liter) (Molarity)

= (0.0080L) (0.05mol/L)
= 0.0004 mol

Number of mole for NaOH = 0.0004 mol

Number of mole for NaOH = Number of mole for CH3COOH
 Therefore, the number of mole for CH3COOH = 0.0004 mol

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
Molarity for CH3COOH = 𝑙𝑖𝑡𝑒𝑟𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

0.000415 mol
= 0.01𝐿

= 0.04 M

C. Percent Acetic Acid

Weight of CH3COOH = (Volume of NaOH used) (Molarity of NaOH) (Molar mass of

CH3COOH) (Equivalence Factor)

Trial 1
0.05𝑚𝑜𝑙 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 60.052𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻 250
Weight of CH3COOH = 0.0085L NaOH x x x x
𝐿 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 10

Weight of CH3COOH = 0.6381g CH3COOH

𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑎𝑐𝑒𝑡𝑖𝑐 𝑎𝑐𝑖𝑑
% 𝑤 ⁄𝑣 = 𝑥 100
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑣𝑖𝑛𝑒𝑔𝑎𝑟

0.6381𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻

= 𝑥 100
12.5𝑚𝐿 𝑣𝑖𝑛𝑒𝑔𝑎𝑟

= 5.1048%

Trial 2
0.05𝑚𝑜𝑙 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 60.052𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻 250
Weight of CH3COOH = 0.0083L NaOH x x x x
𝐿 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 10

Weight of CH3COOH = 0.6230g CH3COOH

0.6230𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻
% 𝑤 ⁄𝑣 = 𝑥 100
12.5𝑚𝐿 𝑣𝑖𝑛𝑒𝑔𝑎𝑟

= 4.984%

Trial 3
0.05𝑚𝑜𝑙 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 60.052𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻 250
Weight of CH3COOH = 0.0080L NaOH x x x x
𝐿 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 10

Weight of CH3COOH = 0.60052g CH3COOH

 0.60052𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻
% 𝑤 ⁄𝑣 = 𝑥 100
12.5𝑚𝐿 𝑣𝑖𝑛𝑒𝑔𝑎𝑟

= 4.804%

Part C: Determining the acetic acid content of Sukang Paombong (Nipa Palm vinegar)
Trial 1 Trial 2 Trial 3
Volume of Vinegar
12.5 mL 12.5 mL 12.5 mL
used
Volume of Aliquot
10.0 mL 10.0 mL 10.0 mL
used
Initial Burette
0.00 mL 0.00 mL 0.00 mL
Volume
Final Burette Volume 3.90 mL 3.70 mL 3.85 mL
Volume of NaOH
3.90 mL 3.70 mL 3.85 mL
used
Average Volume of
3.8167mL
NaOH used
Molarity of NaOH
0.1 M 0.1 M 0.1 M
solution
Molarity of Acetic
0.039 M 0.037 M 0.0385 M
Acid in Vinegar
Average Molarity of
Acetic Acid in 0.03817 M
Vinegar
Percent (w/v) Acetic
4.684% 4.444% 4.624%
Acid
Average percent
4.584%
(w/v) Acetic Acid

A. Solving the Molarity of Acetic Acid

Trial 1

Moles = (volume in liter) (Molarity)

= (0.0039L) (0.1mol/L)
= 0.00039 mol

Number of mole for NaOH = 0.00039 mol

Number of mole for NaOH = Number of mole for CH3COOH
Therefore, the number of mole for CH3COOH = 0.00039 mol
 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
Molarity for CH3COOH = 𝑙𝑖𝑡𝑒𝑟𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

0.00039 mol
= 0.01𝐿

= 0.039 M

Trial 2

Moles = (volume in liter) (Molarity)

= (0.0037L) (0.1mol/L)
= 0.00037 mol

Number of mole for NaOH = 0.00037 mol

Number of mole for NaOH = Number of mole for CH3COOH
Therefore, the number of mole for CH3COOH = 0.00037 mol

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
Molarity for CH3COOH = 𝑙𝑖𝑡𝑒𝑟𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

0.00037 mol
=
0.01𝐿

= 0.037 M

Trial 3

Moles = (volume in liter) (Molarity)

= (0.00385L) (0.1mol/L)
= 0.000385 mol

Number of mole for NaOH = 0.000385 mol

Number of mole for NaOH = Number of mole for CH3COOH
Therefore, the number of mole for CH3COOH = 0.000385 mol

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
Molarity for CH3COOH = 𝑙𝑖𝑡𝑒𝑟𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

0.000385 mol
= 0.01𝐿

= 0.0385 M
 B. Percent Acetic Acid

Weight of CH3COOH = (Volume of NaOH used) (Molarity of NaOH) (Molar mass of

CH3COOH) (Equivalence Factor)

Trial 1
Trial 1
0.1𝑚𝑜𝑙 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 60.052𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻 250
Weight of CH3COOH = 0.0039L NaOH x x x x
𝐿 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 10

Weight of CH3COOH = 0.5855g CH3COOH

𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑎𝑐𝑒𝑡𝑖𝑐 𝑎𝑐𝑖𝑑
% 𝑤 ⁄𝑣 = 𝑥 100
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑣𝑖𝑛𝑒𝑔𝑎𝑟

0.5855𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻

= 𝑥 100
12.5𝑚𝐿 𝑣𝑖𝑛𝑒𝑔𝑎𝑟

= 4.684%

Trial 2
0.1𝑚𝑜𝑙 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 60.052𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻 250
Weight of CH3COOH = 0.0037L NaOH x 𝐿 𝑁𝑎𝑂𝐻 x x x
1𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 10

Weight of CH3COOH = 0.5555g CH3COOH

0.5555𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻
% 𝑤 ⁄𝑣 = 𝑥 100
12.5𝑚𝐿 𝑣𝑖𝑛𝑒𝑔𝑎𝑟

= 4.444%

Trial 3
0.1𝑚𝑜𝑙 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 60.052𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻 250
Weight of CH3COOH = 0.00385L NaOH x 𝐿 𝑁𝑎𝑂𝐻 x x x
1𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝐶𝐻3 𝐶𝑂𝑂𝐻 10

Weight of CH3COOH = 0.5780g CH3COOH

0.60052𝑔 𝐶𝐻3 𝐶𝑂𝑂𝐻
% 𝑤 ⁄𝑣 = 𝑥 100
12.5𝑚𝐿 𝑣𝑖𝑛𝑒𝑔𝑎𝑟

= 4.624%