MSDS - ITD Cem PDF

ITD CEMENTATION INDIA LIMITED
INDEX - MSDS
Sr. Available in
Product Name (Alphabetically) MSDS No. Revision No / Date Page No.
No. Language
1 Acetylene EHS / 2018 / MSDS - 01 R-0 / 30.03.2018 English 3
2 Asphalt EHS / 2018 / MSDS - 02 R-0 / 30.03.2018 English 7
3 Admixture EHS / 2018 / MSDS - 03 R-0 / 30.03.2018 English 11
4 Araldite EHS / 2018 / MSDS - 04 R-0 / 30.03.2018 English 14
5 Bentonite EHS / 2018 / MSDS - 05 R-0 / 30.03.2018 English 18
6 Bleaching Powder EHS / 2018 / MSDS - 06 R-0 / 30.03.2018 English 20
7 Bitumen EHS / 2018 / MSDS - 07 R-0 / 30.03.2018 English 23
8 Carbolic Acid EHS / 2018 / MSDS - 08 R-0 / 30.03.2018 English 27
9 Curing Compound EHS / 2018 / MSDS - 09 R-0 / 30.03.2018 English 30
10 Dendrite EHS / 2018 / MSDS - 10 R-0 / 30.03.2018 English 32
11 Ecodet EHS / 2018 / MSDS - 11 R-0 / 30.03.2018 English 36
12 Engine Oil-20W40 EHS / 2018 / MSDS - 12 R-0 / 30.03.2018 English 39
13 Electric Delay Detonator EHS / 2018 / MSDS - 13 R-0 / 30.03.2018 English 41
14 Engine Oil-15W40 EHS / 2018 / MSDS - 14 R-0 / 30.03.2018 English 43
15 Grease EHS / 2018 / MSDS - 15 R-0 / 30.03.2018 English 46
16 Grouting Chemicals EHS / 2018 / MSDS - 16 R-0 / 30.03.2018 English 48
17 HSD - High Speed Diesel EHS / 2018 / MSDS - 17 R-0 / 30.03.2018 English 50
18 Hydraulic Oil EHS / 2018 / MSDS - 18 R-0 / 30.03.2018 English 53
19 Inhibitor Solutions EHS / 2018 / MSDS - 19 R-0 / 30.03.2018 English 55
20 Lime EHS / 2018 / MSDS - 20 R-0 / 30.03.2018 English 57
Page 1 of 2
INDEX - MSDS
Sr. Available in
Product Name (Alphabetically) MSDS No. Revision No / Date Page No.
No. Language
21 LPG EHS / 2018 / MSDS - 21 R-0 / 30.03.2018 English 60
22 Oil Paints EHS / 2018 / MSDS - 22 R-0 / 30.03.2018 English 62
23 Oxygen EHS / 2018 / MSDS - 23 R-0 / 30.03.2018 English 66
24 Phenol EHS / 2018 / MSDS - 24 R-0 / 30.03.2018 English 69
25 Petrol EHS / 2018 / MSDS - 25 R-0 / 30.03.2018 English 72
26 Plastic Paints EHS / 2018 / MSDS - 26 R-0 / 30.03.2018 English 74
27 Polymer EHS / 2018 / MSDS - 27 R-0 / 30.03.2018 English 76
28 Portland Cement EHS / 2018 / MSDS - 28 R-0 / 30.03.2018 English 79
29 Ready Mix Concrete EHS / 2018 / MSDS - 29 R-0 / 30.03.2018 English 82
30 Superpower 80 EHS / 2018 / MSDS - 30 R-0 / 30.03.2018 English 85
31 Sulphuric Acid EHS / 2018 / MSDS - 31 R-0 / 30.03.2018 English 87
32 Superpower 90 EHS / 2018 / MSDS - 32 R-0 / 30.03.2018 English 92
33 Solarcord EHS / 2018 / MSDS - 33 R-0 / 30.03.2018 English 95
34 Thinner EHS / 2018 / MSDS - 34 R-0 / 30.03.2018 English 97
35 Welding Electrode ( Arc) EHS / 2018 / MSDS - 35 R-0 / 30.03.2018 English 100
Page 2 of 2
Material Safety Data Sheet - (MSDS) EHS / 2018 / MSDS - 01
PROJECT NAME / CODE: ............................................................................... DEPT. : .......................................

Section:1 Product & Company Identification:
● PRODUCT NAME: ACETYLENE (Other means of identification- Acetylene, ethine, ethyne, narcylene)
● Manufacturer's Name & Address:

T-7, MIDC, Industrial Area
Taloja, Mumbai, Maharashtra - 401208
● Emergency Contact No.:+9122 27410822

Section:2 Composition: (Information of Ingredients)
Acetylene, dissolved (Main constituent)- 100%
Section:3 Hazard Identification:
● Route of Entry:  Eye contact □

□  Inhalation □ Ingestion □
 Skin Contact
1. EXTREMELY FLAMMABLE GAS
2. MAY REACT EXPLOSIVELY EVEN IN THE ABSENCE OF AIR AT ELEVATED PRESSURE AND/OR TEMPERATURE
● Hazard
3. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
Statement :
4. MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION
5. MAY FORM EXPLOSIVE MIXTURES WITH AIR
1. Do not handle until all safety precautions have been read and understood
2. Keep away from Heat, Open flames, Sparks, Hot surfaces. - No smoking
3. Use and store only outdoors or in a well-ventilated place
4. Leaking gas fire: Do not extinguish, unless leak can be stopped safely
5. Eliminate all ignition sources if safe to do so
● Precautionary 6. Dispose of contents/container in accordance with container Supplier/owner instructions
statements : 7. Use a back flow preventive device in the piping
8. Fusible plugs in the top, bottom, or valve melt at 98 °C to 107 °C (208 °F to 224 °F). Do not discharge at pressures above 15
psig (103 kPa) 9.Close valve after each
use and when empty
10. Never put cylinders into unventilated areas of passenger vehicles
11. Protect from sunlight when ambient temperature exceeds 52°C (125°F)
Section:4 First Aid Measures:
The liquid may cause frostbite. For exposure to liquid, immediately warm frostbite area with warm water not to exceed 105°F
(41°C). Water temperature should be tolerable to normal skin. Maintain skin warming for at least 15 minutes or until normal
● Skin Contact :
coloring and sensation have returned to the affected area. In case of massive exposure, remove clothing while showering with
warm water. Seek medical evaluation and treatment as soon as possible.
Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and
● Eye Contact : away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an
ophthalmologist immediately.. Get immediate medical attention.
Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep
● Inhalation :
victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.
● Ingestion :Ingestion is not considered a potential route of exposure.
Section:5 Fire Fighting Measures:

● Flammable: □ Yes □ No
● Fire Extinguishers: Type: Water, Foam Quantity :As Adequate
● Sand Buckets Nos : As Adequate
● Fire Hydrant System
□
 Yes □ No
Fire hazard EXTREMELY FLAMMABLE GAS. If venting or leaking gas catches fire, do not extinguish flames. Flammable vapors may
spread from leak, creating an explosive reignition hazard. Vapors can be ignited by pilot lights, other flames, smoking, sparks,
heaters, electrical equipment, static discharge, or other ignition sources at locations distant from product handling point.
Explosive atmospheres may linger. Before entering an area, especially a confined area, check the atmosphere with an
appropriate device.

Issued on: Mar 2018 Revised on: .....................
Revision : 0 Page 1 of 4
Explosion 
hazard
PROJECT NAME / CODE: ...............................................................................
EXTREMELY FLAMMABLE GAS . Forms explosive mixtures with air and oxidizing agents.
Reactivity
Firefighting Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA) and protective clothing.
instructions Immediately cool containers with water from maximum distance. Stop flow of gas if safe to do so, while continuing cooling water
spray. Remove ignition sources if safe to do so. Remove containers from area of fire if safe to do so.
Protection
during Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.
firefighting
Special
protective
equipment for Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fighters.
fire fighters
Specific a. Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat radiation may cause gas containers
methods to rupture. Cool endangered containers with water spray jet from a protected position. Prevent water used in emergency cases
from entering sewers and drainage systems
b. Stop flow of product if safe to do so
c. Use water spray or fog to knock down fire fumes if possible
d. Continue water spray from protected position until container stays cool.
Other Acetylene containers are provided with pressure relief devices designed to vent contents when
information exposed to elevated temperature.
Section:6 Accidental Release Measures:
Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in user’s equipment,be certain to
●General
purge piping with inert gas prior to attempting repairs. If leak is in container or container valve,contact the appropriate
measures :
emergency telephone number listed.
●Environmental Prevent waste from contaminating the surrounding environment. Prevent soil and water pollution. Dispose of contents/container
precautions : in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.
Section:7 Handling & Storage:

1. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only non-sparking
tools. Use only explosion-proof equipment.
2. Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from physical damage; do not drag,
roll, slide or drop. While moving cylinder, always keep in place removable valve cover. Never attempt to lift a cylinder by its cap;
the cap is intended solely to protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand truck,
● Handling etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver, pry bar) into cap openings; doing so may
measures: damage the valve and cause a leak. Use an adjustable strap wrench to remove over-tight or rusted caps. Slowly open the
valve. If the valve is hard to open, discontinue use and contact your supplier. Close the container valve after each use; keep
closed even when empty. Never apply flame or localized heat directly to any part of the container. High temperatures may
damage the container and could cause the pressure relief device to fail prematurely, venting the container contents.
Store only where temperature will not exceed 125°F (52°C). Post “No Smoking/No Open Flames” signs in storage and use
areas. There must be no sources of ignition. Separate packages and protect against potential fire and/or explosion damage
following appropriate codes
● Storage
Conditions Always secure containers upright to keep them from falling or being knocked over. Install valve protection cap, if provided,
firmly in place by hand when the container is not in use. Store full and empty containers separately. Use a first-in, first-out
inventory system to prevent storing full containers for long periods.
OTHER When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be
PRECAUTIONS encountered. Never work on a pressurized system. Use a back flow preventive device in the
FOR HANDLING, piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak
STORAGE, AND occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with
USE all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may
become part of an electrical circuit.
Storage area Acetylene trailers are designed and intended for outdoor use. Acetylene storage in excess of 2.500 cu ft (70.79 cubic meters) is
prohibited in buildings and other occupancies.

Section:8 Exposure Control / PPE:
Specific Engineering Control (Such as Ventilation, enclosed process)
□ Mask □
 Respirator □ Glove
 □ Visor
□
 Goggles □
 Footwear □
 Overall □ Others
An explosion-proof local exhaust system or a mechanical system is acceptable if it can prevent oxygen deficiency and keep
●Appropriate hazardous fumes and gases below all applicable exposure limits in the worker's breathing area. During welding, ensure that
engineering there is adequate ventilation to keep worker exposure below applicable limits for fumes, gases, and other by-products of
controls: welding. Do not breathe fumes or gases. Short-term overexposure to fumes may cause dizziness, nausea, and dryness or
irritation of the nose, throat, and eyes, or may cause other similar discomfort.
●Eye protection: Wear safety glasses with side shields.
As needed for welding, wear hand, head, and body protection to help prevent injury from radiation and sparks. (See ANSI
●Skin and body
Z49.1.) At a minimum, this includes welder’s gloves and protective goggles, and may include arm protectors, aprons, hats, and
protection:
shoulder protection as well as substantial clothing.
●Respiratory
When workplace conditions warrant respirator use. Use an air-supplied or air-purifying cartridge if the action level is exceeded.
protection:
Ensure that the respirator has the appropriate protection factor for the exposure level. If cartridge type respirators are used, the
cartridge must be appropriate for the chemical exposure. For emergencies or instances with unknown exposure levels, use a
self-contained breathing
apparatus (SCBA).
●Thermal hazard
protection: Wear cold insulating gloves when transfilling or breaking transfer connections.
●Environmental
Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for
exposure
specific methods for waste gas treatment.
controls:
●Other Consider the use of flame resistant anti-static safety clothing. Wear leather safety gloves and
information: safety shoes when handling cylinders.
Section:9 Physical & Chemical Properties:

Appearance : Colorless, odorless gas.
Molecular mass : 26 g/mol
Color : Colorless.
Odor : Garlic like. Poor warning properties at low concentrations.
● Data relevant to
safety Method : Boiling point : -84 °C (-119.2°F)
Flash point : -17 °C (1.4°F)
Critical temperature : 36 °C (97°F)
Auto-ignition temperature : 305 °C (581°F) Flammability
(solid, gas) : 2.5 - 100 vol %
Section:10 Stability & Reactivity:
● Reactivity: No reactivity hazard other than the effects described in sub-sections below.
● Chemical
Dissolved in a solvent supported in a porous mass. Stable under recommended handling and storage conditions
stability:
● Possibility of
May react explosively even in the absence of air. May decompose violently at high temperature and/or pressure or in the
hazardous
presence of a catalyst. Can form explosive mixture with air. May react violently with oxidants.
reactions:
● Conditions to High temperature. High pressure. Keep away from heat/sparks/open flames/hot surfaces. – No
avoid: smoking.
● Incompatible Forms explosive acetylides with copper, silver and mercury. Do not use alloys containing more than
materials: 65% copper. Air, Oxidizer. Do not use alloys containing more than 43% silver.
●Hazardous Thermal decomposition or burning may produce carbon monoxide, carbon dioxide, and hydrogen. The welding and cutting
decomposition process may form reaction products such as carbon monoxide and carbon dioxide. Other decomposition products of normal
products: operation originate from the volatilization, reaction, or oxidation of the material being worked.
Section:11 Toxicological Information:

● Effects: No Acute:No Chronic: No
Inhalation : Not Classified
● Carcinogen
Status:
Eye Contact : Not Classified

Section:12 Ecological Information:
● Environmental
No known ecological damage caused by this product.
Summary:
Section:13 Disposal Considerations:
● Waste Dispose of contents/container in accordance with local/regional/national/international

: regulations. Contact supplier for any special requirements.
Section:14 Transport Informations:

● UN Number : UN1001 Acetylene, dissolved, 2.1
Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is
aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before
transporting product containers:
● Emergency
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured.
Response Guide :
- Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided)
is correctly fitted.
- Ensure valve protection device (where provided) is correctly fitted.
Section:15 Regulatory Information:
Sudden release of pressure hazard
Reactive hazard
Fire hazard
Section:16 Other Information:
NFPA health hazard : Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials.
NFPA fire hazard : Will rapidly or completely vaporize at normal pressure and temperature, or is readily dispersed in air and will burn readily.
NFPA reactivity : Normally unstable and readily undergo violent decomposition but do not detonate. Also: may react violently with water or may
form potentially explosive mixtures with water.
Assesed By:
Name: .................................................................. Date: ..............................................................

PROJECT NAME / CODE: ............................................................................... DEPT. : ..................................

● PRODUCT NAME: ASPHALT (Pitch, Paving Asphalt for Road Constructions)
● Manufacturer's Name & Address: T-7, MIDC, Industrial Area


Asphalt and Hydrogen Sulfide

□  Inhalation □ Ingestion □
 Skin Contact
Hot material can cause severe eye and skin burns on contact. Hydrogen sulfide from heated material can accumulate in vapor space of tanks and containers.
● Hazard Contact between heated material and water can cause a violent eruption. Fumes from heated material can cause irritation to the eyes, skin, and respiratory
Statement : system,
and can increase susceptibility to sunburn.
1. Eyes : Hot material can cause burns to the eyes. Mists, vapors or fumes from this material can cause eye irritation with tearing, redness, or a stinging or
burning feeling.
2. Skin : Hot material can cause burns to the skin. May cause skin irritation with redness, an itching or burning feeling, and swelling of the skin. Exposure to
sunlight and to asphalt vapors may amplify tendency for sunburns. Skin contact may cause harmful effects in other parts of the body.
● Potential health 3. Ingestion : Contact with hot material may cause burns. If swallowed at ambient temperatures, no significant adverse health effects are anticipated. If
Effect : swallowed in large quantities, this material can obstruct the intestine.
4. Inhalation : No significant adverse health effects are expected to occur upon short-termexposure to this product at ambient temperatures. Asphalt fumes
have been associated with irritation of eyes nose and throat. Also, lower respiratory effects have been reported. Hydrogen sulfide (H2S) can evolve when this
product is
stored or handled at elevated temperatures. H2S can cause respiratory irritation and hypoxia. At low concentrations, H2S has an odor of rotten eggs. At higher
concentrations, H2S odor is not apparent. DO NOT use odor as an indicator of exposure to H2S.
Cool skin rapidly with cold water after contact with molten material. Take off all contaminated clothing immediately. Wash off with soap and water but do not
● Skin Contact : attempt to remove asphalt that adheres to skin before obtaining medical assistance. Wash contaminated clothing before re-use. If symptoms persist, seek
medical attention immediately.
● Eye Contact : Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, seek medical attention.
● Inhalation : Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Seek medical attention immediately.
Do NOT induce vomiting. Seek medical attention immediately. Clean mouth with water and drink afterwards plenty of water. If a person vomits when lying on his
● Ingestion :
back, place him in the recovery position.
Remove from exposure, lie down. Take off all contaminated clothing immediately. When symptoms persist or in all cases of doubt seek medical advice. Never
● General advice :
give anything by mouth to an unconscious person.

● Fire Extinguishers: Water, Foam,
Type: DCP Quantity : As Adequate
□
 Yes □ No
Suitable
extinguishing
media SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, or Halon.
LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers.

Specific hazards
during
PROJECTfire fighting
NAMEIsolate
/ CODE: ...............................................................................
area around container involved in fire. Cool tanks, shells, and containersexposed to fire and excessive heat with water. For massive fires the use of
unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank
to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied
fire fighting foam.
Further Vapors may form explosive mixture with air. Flammable vapor production at ambient temperature in the open is expected to be minimal unless the oil is heated
information above its flash point. When heated above flash point and mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in
confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back.
ACTIVATE FACILITY'S SPILL CONTINGENCY OR EMERGENCY RESPONSE PLAN. Evacuate nonessential personnel and remove or secure all ignition
sources. Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas.
●Personal
Response and cleanup crews must be properly trained and must utilize proper protective equipment.
precautions :
Soak up condensate with inert absorbent material and collect in ventilated waste container for disposal.
Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush
●Environmental
down sewer or drainage systems, unless system is designed and permitted to handle such material. Authorities should be notified if reportable quantity release
precautions :
occurs.

● Handling
Use only in well-ventilated areas.
measures:
● Advice on Do not smoke near areas where material is handled or stored. The product should only be used in areas where electrical classification meets the product rating
protection against for this product, i.e. intrinsically safe. Use only in area provided with appropriate exhaust ventilation. Vapors may form explosive mixtures with air.
fire and explosion:
● Requirements Product is generally transported and stored hot (typically at temperatures above 110oF and below 350°F). Handle as a combustible liquid. Keep away from
for storage heat, sparks, and open flame! Electrical equipment should be approved for classified area. Bond and ground containers during product transfer to reduce the
areas and possibility
containers of static-initiated fire or explosion.
● Advice on
common storage Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers. Keep containers closed and clearly labeled.
Emptyproduct containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition.
Store in a well-ventilated area. Avoid storage near incompatible materials. The cleaning of tanks previously containing this product should follow API
Recommended Practice. Hydrogen sulfide may accumulate in tanks and bulk transport compartments. Consider appropriate respiratory protection Stand
upwind. Avoid vapors when opening hatches and dome covers. Confined spaces should be ventilated prior to entry.

□
 Mask □
 □ Visor
□ Goggles □
 Footwear □
●Engineering Engineering controls are normally required when handling hot materials. Use process enclosures, local exhaust ventilation, or other controls to maintain
measures: airborne levels. Ensure that an emergency eye wash station and safety shower is located near the work-station.
Use a full-face shield and chemical safety goggles if handling heated material. With product at ambient temperatures, safety glasses equipped with side shields
●Eye protection:
are recommended as minimum protection in industrial settings. An eye wash station immediately available to the work area.
When handling product at elevated temperatures, use long-cuffed leather or heatresistant gloves. When product is at ambient temperatures, use gloves
●Hand protection:
constructed of chemical resistant materials such as heavy nitrile rubber if frequent or prolonged contact is expected.

●Respiratory
protection:
PROJECT NAMEContaminant air concentrations determine the level of respiratory protection required. Use only NIOSH-approved respiratory equipment within the limits of the
/ CODE: ...............................................................................
protection factors for that equipment. Use supplied air respirators when H2S concentrations are expected to exceed applicable workplace exposure levels. Do
not use air purifying respiratory equipment when considering elevated H2S concentrations. Respiratory equipment must be selected on the basis of the
maximum expected air concentration.
●Skin and body Use insulated, heat-resistant clothing when handling heated material. Use a fullbody
protection: heat-resistant or internally cooled suit when work conditions dictate.
●Hygiene
measures: Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. DO NOT use gasoline, kerosene, solvents, or
harsh abrasive skin cleaners to clean skin. Prevent skin contact when handling heated material. Use insulated, heat-resistant clothing when handling heated
material. Use a full-body heat-resistant or internally cooled suit when work conditions dictate

Form : Solid form, viscous liquid when heated
Appearance : Brown to black
Odor : Characteristic sour, tar-like odor
Flash point : > 218 °C (> 424 °F)
Thermal decomposition : No decomposition if stored and applied as directed.

Lower explosive limit : 0.9 % (V)
Upper explosive limit : 7 % (V)
● Data relevant to pH : Not applicable
safety Method :
Freezing point : No data available
Boiling point : 343 °C (649 °F)
Vapor Pressure : No data available
Density : 0.9 – 1.05 g/mL

Viscosity, kinematic : No data available
Percent Volatiles : Negligible volatility
Stable under normal conditions of use; however, incompatible with strong acids and strong oxidizers. Keep away from oxidizing agents, and acidic or alkaline
● Hazardous
products. Do not allow molten products to contact water or liquids as this can cause violent eruptions. Hydrogen Sulfide from the product can react with iron in
Reaction:
asphalt storage tank to form iron sulfide, a pyrophoric (a material which ignites spontaneously in air below 130°F) material.
● Conditions to
Heat, flames and sparks.
avoid:
● Incompatible
Strong acids and oxidizing agents
materials:
In case of fire hazardous decomposition products may be produced such as: Carbon oxides Hydrogen sulfide and other sulfur-containing gases can evolve from
●Hazardous
this product particularly at elevated temperatures. No decomposition products in case of appropriate storage / handling / transport.
decomposition
products:
Thermal decomposition : No decomposition if stored and applied as directed.

● Effects: Yes Acute:No Chronic: Yes
OSHA : This product, Asphalt may contain trace amounts of benzene a chemical known to cause cancer.
Skin irritation : Result: Mild skin irritation, Prolonged skin contact may cause skin irritation and/or dermatitis.
● Carcinogen
Status: Eye irritation : Result: Mild eye irritation, Contact with eyes may cause irritation.
Further information : Certain preparations of this material are classified as carcinogenic by OSHA, NTP,
or IARC.
● Environmental This product is estimated to have a slow rate of biodegradation. This product is not expected to bioaccumulate through food chains in the environment. Analysis
Summary: for ecological effects has not been conducted on this product. Spills into water ways may be harmful to organisms and bottom feeders.

● Waste : Recover as much spilled material as possible for reuse or recycling. Disposal of waste material must be conducted in accordance with State regulations.

● UN Number : UN3257, Class-9
● Emergency
Not Available
Response Guide :

Moderate skin irritant
Moderate eye irritant
Toxic by inhalation.
Possible carcinogen.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only
as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification.
Assesed By:
Name: .................................................................. Date: ..............................................................

PROJECT NAME / CODE: ............................................................................... DEPT. : .................................

● PRODUCT NAME: ADMIXTURE - Sikament 511

Sika India Pvt. Ltd. Street/postbox : 620, Diamond Harbour Road
Town/City and Post Code: Kolkata - 700034
● Emergency Contact No.:+913324472448, Telefax : +913324688688

Aqueous solution of modified Sulphonated naphthalene formaldehyde, Carbohydrate and surfactant

□  Inhalation □
 Ingestion □
 Skin Contact
Experience on humans
When skin contact: May cause irritation.
When eyes contact: May cause irritation.
When inhalation: May cause irritation.
When swallowed: May cause health disorders.
In case of contact with skin wash off immediately with soap and water
● Skin Contact :
Consult a doctor if skin irritation persists.
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water.
● Eye Contact :
Summon a doctor immediately.
● Inhalation : In the event of symptoms take medical treatment.
Do not induce vomiting.

● Ingestion : Summon a doctor immediately.
General instructions: In any case show the physician the Safety Data Sheet

● Fire Extinguishers: Type: ABC & DCP Quantity : As Adequate
□ Yes □
 No
Suitable extinguishing media: compatible with all usual extinguishing media. Exposure hazard arising from the product, its combustion products or
resulting gases
In the event of fire the following can be released:

Carbon monoxide (CO)
Carbondioxide (CO2)
Nitrogen oxides (NOx)
Additional information
Fire residues and contaminated firefighting medium must be disposed of in accordance with the local regulations.
Collect contaminated firefighting water separately, must not be discharged into the drains.

Ensure adequate ventilation.
●Personal
Use personal protective clothing.
precautions :
Use breathing apparatus if exposed to vapours/dust/aerosol.
●Environmental Do not allow to enter drains or waterways In case of entry into waterways, soil or drains, inform the
precautions: responsible authorities.
●Procedures for Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder).
cleaning up: When picked up, treat material as prescribed under heading "Disposal".

● Handling Instructions for safe handling See chapter 8 / Personal protective equipment.
measures: Instructions for fire and explosion protection Not applicable.
● Storage Requirements for storage rooms and containers: Keep container tightly closed and dry in a cool, well-ventilated place
Combined storage instructions: Keep away from food, beverages and animal feedstocks.
Additional information regarding storage:
Protect from frost.
Protect from heat and direct sunlight
Protect from atmospheric moisture and water

□ Mask □ Respirator □ Glove

 □ Visor
□
 Goggles □
 Footwear □ Overall □ Others
PPEs : General protective and hygiene measures:
Take care for sufficient ventilation or exhaust on the workshop place.
Avoid contact with eyes and skin
Remove soiled or soaked clothing immediately.
Do not eat, drink or smoke during work time.
Wash hands before breaks and after work.

Physical state : liquid
● Appearance : Colour : Dark brown
Odour : characteristic
Boiling point > 100 °C
Flash point : not applicable
● Data relevant to
safety Method : Solubility in water miscible
pH value at 27°C : Around 8.5

● Reactivity: No hazardous reactions when stored and handled according to prescribed instructions.
● Chemical Thermal decomposition and hazardous decomposition products

stability: No decomposition if used as prescribed

● Effects: Not Immediate Acute:No Chronic: No
When skin contact: May cause irritation.
● Carcinogen When eyes contact: May cause irritation.
Status: When inhalation: May cause irritation.
When swallowed: May cause health disorders.

● Environmental
Do not allow to enter waste water drain, waterways or soil.
Summary:

Product Recommendations:
Must be disposed of in a special waste disposal unit in accordancewith the corresponding regulations.
● Waste :
Packaging Recommendations:
Completely emptied packaging can be given for recycling. Packaging that cannot be cleaned should be disposed of as product
waste
● UN Number : Not regulated
● Emergency
No dangerous goods.
Response Guide :
The product does not require a hazard warning label in accordance with EC directives/the relevant national laws.
The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our
most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to any use and processing.
Assesed By:
Name: .................................................................. Date: ..............................................................

PROJECT NAME / CODE: ............................................................................... DEPT. : ..................................

● PRODUCT NAME: ARALDITE
● Manufacturer's Name & Address: Light

Hall B-wing, Saki Vihar Road, Andheri (East), Mumbai, Maharashtra 400072
● Emergency Contact No.:+91 22 4287 5100
This material is considered hazardous by the OSHA Hazard Communication Standard
Bisphenol A epoxy resin ( 30 - 60 %)
barium sulphate, natural ( 30 - 60 %)
Butanedioldiglycidyl ether (1 - 3%)
triglycidyl isocyanurate (1 - 3%)

 Ingestion □
 Skin Contact
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment
as required.Wear protective gloves. Wear eye or face protection. Avoid release to the environment. Avoid breathing vapor. Wash hands thoroughly
after handling. Contaminated work clothing should not be allowed out of the workplace. Collect spillage. IF exposed or concerned: Get medical
attention.
IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash
occurs: Get medical attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
attention. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with
● Skin Contact : water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact
● Eye Contact :
lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical
● Inhalation : attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation
of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical
surveillance
for 48 hours.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not
● Ingestion : induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does
not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

□ Yes □ No
● Flammable:

□ Yes □ No
Specific hazards arising from the chemical: In a fire or if heated, a pressure increase will occur and the container may burst.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary
● For non-
and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide
emergency :
adequate ventilation. Wear appropriate respirator when ventilation is
personnel :
inadequate. Put on appropriate personal protective equipment.
● For emergency If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable
responders: materials. See also the information in "For non-emergency personnel".
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if
●Environmental
the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the
precautions:
environment if released in large quantities. Collect spillage.
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
●Methods and basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage
materials for with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal
containment and according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent
cleaning up: material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13
for waste disposal

● Protective Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not
measures: be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle
until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Avoid release to the environment. If during normal
use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty
containers retain productresidue and can be hazardous. Do not reuse container.
● Advice on Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should
general wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before
occupational entering eating areas. See also Section 8 for additional
hygiene information on hygiene measures.
● Conditions for Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-
safe storage, ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly
including any closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent
incompatibilities: leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.


 □ Visor
□
 Goggles □
Engineering
Controls : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering
controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Environmental Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of
exposure environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment
controls : will be necessary to reduce emissions to acceptable levels.
Hygiene Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at
measures: the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated
work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the workstation location.
Eye/face Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid
protection: exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash
goggles.
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any
glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and
should be approved by a specialist before handling this product.
Other skin Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the
protection: risks involved and should be approved by a specialist before handling this product.
Respiratory Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is
protection: necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

● pH Value : Not Applicable ● Boiling Point: More than 93 degree celcius
● Odour and Appearance : Mild

● Flammability : Not availble
● Reactivity: No specific test data related to reactivity available for this product or its ingredients.
● Chemical
The product is stable.
stability:
● Possibility of
hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reactions:
● Conditions to
No specific data.
avoid:

● Effects: Immediate Acute:Yes Chronic: No
● Carcinogen Once sensitized, a severe allergic reaction may occur when subsequently exposed to
Status: very low levels.No known significant effects or critical hazards.
● Environmental
No known significant effects or critical hazards.
Summary:
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-
● Waste : products should at all times comply with the requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and nonrecyclable
products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant
with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be
considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been
● Container : cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff
and contact with soil, waterways, drains and sewers. Disposal should be in accordance
with applicable regional, national and local laws and regulations.

● Emergency
Cool exposed containers with water. Firefighters are to wear Full Bunker Gear and Self Contained Breathing Apparatus (SCBA).
Response Guide :
This product does not contain nor is it manufactured with ozone depleting substances.
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all the information required by the Controlled Products Regulations
Assesed By:
Name: .................................................................. Date: ..............................................................

PROJECT NAME / CODE: ............................................................................... DEPT. : .......................................

● PRODUCT NAME: BENTONITE
● Manufacturer's Name & Address: D-4,

Ground Floor, No 001-003, Shairyas Apartment Flat, Sarvodaya Parshwanth Nagar, Nahur, Mulund West, Mulund West, Mumbai, Maharashtra
400080
● Emergency Contact No.:022 2564 5776

Montmorillonite (Bentonite)-100%
● Route of Entry: □ Absorption □ Inhalation □ Ingestion □

 Skin Contact
Absorption: Not Applicable
Inhalation: Not Applicable
Ingestion: Not Applicable
Skin Contact: Skin irritation
Note : Aqueous solutions or powders that become wet render surfaces extremely slippery.

● Skin Contact : Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
● Eye Contact :
Cold water may be used. WARM water MUST be used. Get medical attention.
● Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.
● Ingestion : If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or
waistband.

● Flammable: □ Yes □
 No
● Fire Extinguishers: Type: Not required
● Sand Buckets Nos : Not required

□ Yes □
 No
● Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and dispose of according to local and regional authority requirements
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a
●Large Spill:
concentration level above TLV. Check TLV on the MSDS and with local authorities.

PROJECT
● Handling NAME
Do/not
CODE: ...............................................................................
breathe dust. Avoid contact with eyes. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable
Precautions : respiratory equipment. If you feel unwell, seek medical attention and show the label when possible.
● Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area

□ Mask □
 □ Visor
□
 Goggles □
Engineering Engineering measures to reduce Use local exhaust if dusting occurs. Natural ventilation is adequate in exposure: absence of
Controls : dusts.
Personal a. Dust safety masks are recommended where concentration of total dust is more than 10 mg/m3.
protection b. Hand protection: Rubber gloves.
equipment c. Eyes protection: Safety glasses with side-shields. Do not wear contact lenses.
Respiratory d. Skin and body protection: Chemical resistant apron or protective suit if splashing or repeated contact with solution is likely.
protection:
Hygiene Wash hands before breaks and at the end of workday. Handle in accordance with good industrial hygiene and safety practice.
measures:
● pH Value : Not Applicable ● Boiling Point:
● Odour and Appearance : Colourless Gas
● Flammability : 9.6
● Chemical
Not Applicable
Stability:
Stability: Product is stable, no hazardous polymerization will occur.

● Stability and
Materials to avoid: Oxidizing agents may cause exothermic reactions.
Reactivity:
Hazardous decomposition products: Thermal decomposition may produce: nitrogen oxides (NOx), carbon oxides.

Chronic Effects on Humans: Causes damage to the following organs: lungs. Other
Toxic Effects on Humans:
● Carcinogen
Hazardous in case of inhalation.
Status:
Slightly hazardous in case of skin contact (irritant), of ingestion.

● Environmental Ecotoxicity: Not available.
Summary: Toxicity of the Products of Biodegradation: The products of degradation are as toxic as the original product.

● Waste : Can be used for landfiling

Identification: Not applicable.
Special Provisions for Transport: Not applicable.

This product is not a hazardous article and need to be considered as non-hazardous.
Not available
Assesed By:
Name: .................................................................. Date: ..............................................................

PROJECT NAME / CODE: ............................................................................... DEPT. : .....................................

● PRODUCT NAME: BLEACHING POWDER ( Chemical Name- Calcium Hypo Chlorite )
● Manufacturer's Name & Address: Shriram Bleaching Powder

Muncipal Building, New Bardan Ln, Vadgadi, Masjid Bandar West, Masjid Bandar, Mumbai, Maharashtra - 400003
● Emergency Contact No.: Ph : 022 2342 4110

Type of application: Inorganic compound As a
mixture with lime and calcium chloride, it is marketed as chlorine powder or bleach powder for water treatment and as a bleaching agent. This
compound is relatively stable and has greater available chlorine than sodium hypochlorite (liquid bleach). It is a white solid, although commercial
samples appear yellow.
● Route of Entry: □ Eye

contact □
Inhalation □ Ingestion □
 Skin Contact
Inhalation/Skin absorption/Ingestion
Skin Contact : Remove contaminated clothing and wash affected area with sufficient quantity of water for 15-20 minutes &
obtain medical advice immediately
Eye Contact : Immediately flush eyes thoroughly for at least 15 minutes with running water. Hold eyelids open during flushing. If
Effects of irritation persists, repeat flushing. Seek medical attention.
Exposure/
Symptoms Inhalation: Move the victim to fresh air, obtain medical attention .In case of respiratory failure provide artificial respiration
Ingestion: Have victim rinse mouth thoroughly with water & drink plenty of water to dilute the material in stomach. If
spontaneous vomiting occurs, make victim lean forward with head down to avoid breathing in of vomitus, rinse mouth and
administer more water. Obtain medical attention immediately. Further Medical Advice Seek medical attention
(IMMEDIATE MEDICAL ATTENTION REQUIRED)
INHALATION : Remove victim to fresh air, give artificial respiration if breathing has stopped, Oxygen if breathing is labored.
Emergency INGESTION : Wash our mouth thoroughly with water. Give conscious victim plenty of water to drink.
Treatment CONTACT : Eyes : Irrigate immediately with plenty of water for at least 15 min.
Skin : Remove contaminated clothing and flood affected skin with water for at least 15 min.

(IMMEDIATE MEDICAL ATTENTION REQUIRED)
Remove victim to fresh air, give artificial respiration if breathing has stopped.
● Exposure : Wash our mouth thoroughly with water. Give conscious victim plenty of water to drink.
Eyes : Irrigate immediately with plenty of water for at least 15 min.
Skin : Remove contaminated clothing and flood affected skin with water for at least 15 min.

● Fire Extinguishers: Type: Water Quantity : As Adequate
□ Yes □
 No
Fire Extinguishing Media: Water Spray
Fire hazard due to chemical reaction with combustible materials. A powerful oxydizer. Deflagration occurs in contact with combustible substances. In
contact with acid or acid fumes, it emits highly toxic fumes and explodes. It will react with water and steam to produce toxic and corrosive fumes. It
can react vigorously with reducing materials. Readily ignites with combustible/organic materials.

Do not touch spilled material. Prevent it entering sewers. Dry manual lifting of the spilled material is suggested.
● Spillage :
● Personal Avoid generation of dust. Avoid Eyes & Skin Contact. Avoid Inhalation. Avoid Ingestion. Wear appropriate personal protective
Precautions: equipments.
●Environmental
Prevent contamination of soil and water. Prevent from spreading or entering into sewers or confined spaces.
Precautions :

● Handling : Store in a well ventilated area. Keep containers closed. Keep away from heat, sparks and flames. Use only with adequate
ventilation. Avoid generating dust & breathing vapour. Avoid contact with eyes, skin or clothing..
● Storage Store in tightly closed containers in a cool, dry & well-ventilated place. Keep away from sunlight and combustible materials.
requirements : Always keep the bag on wooden pallets.
Protect against physical damage. Store in cool dry well ventilated place away from combustible materials. Drums may rupture
from exposure to heat. Particularly if chlorine content is high. Avoid storage for prolonged periods, particularly at summer
temperatures

□
 Mask □ Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
●General
Chemical goggles, Rubber gloves, Self contained breathing apparatus in case of fire or enclosed spaces
Precautions

● pH Value : 11.5 (5% solution) ● Boiling Point: 315 °C
● Odour and Appearance : Powder, White solid with odour of chlorine Chlorine Content Min. 35% m/m
● Flammability : Not applicable

● Chemical Stability: Normally unstable (losses available chlorine by 2% on heating above 100 °C)
● Conditions to avoid: Excessive heat and moisture. Acids, organic compounds, metal oxides, ammonia, urea & amines etc.
Air : Releases chlorine gas.

Water ; A risk of explosion or toxic gas formation
● Reactivity Acids : Highly reactive with a risk of explosion & toxic gas formation
Alkalis : Reactive
Hazardous Decomposition Products : Nascent Oxygen, Chlorine, Calcium chlorate

● Effects: short term Acute: Not immediate Chronic: Internal Body parts
● Routes of Entry
In contact with skin: Solution can cause chemical burns
In contact with eyes: Dust can cause eye irritation
Inhalation : Dust may irritate nose, throat & upper respiratory tract
Ingestion: May cause burns to the mouth & digestive tract

Bio - Accumulation : Not determined
Biodegradability : This material is inorganic and does not subject to biodegradation.
● Environmental
Toxicity : Non-toxic
Summary:
Mobility : No
Behaviour in Sewage: Improves sewage quality

Untreated waste must never be discharged directly in to sewers.
● Waste : Review National/Regional Regulations.
Packing materials gets contaminated & can be disposed off by appropriate methods in accordance with National / Regional
● Container :
requirement.
UN No. & Symbols 2208, “ Oxidizing Substance”

● UN Number : EC No: 231-908-7
Road /Rail Transport : Not Known
Air Transport: Not Known
● Emergency Transport only in accordance with following regulation with Road & Rail Transport.
Response Guide :

Danger Symbol
Risk Phrases R40/R20/R22 : Harmful: possible risk of irreversible effects if swallowed.

R36 : Irritating to eyes
R8: Contact with combustible material may cause fire.
R50/53 : Very toxic to aquatic organisms, may cause long term adverse effects
R31: Contact with acid liberates toxic gas
R34: Causes burns
Safety Phrases S2: Keep out of the reach of children.

S24/25: Avoid contact with skin and eyes.
S23: Do not breathe gas/fumes/vapour/spray.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately and show the label where possible
S61: Avoid release to the environment

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The
information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process unless specified in the text
Assesed By:
Name: .................................................................. Date: ..............................................................

PROJECT NAME / CODE: ............................................................................... DEPT. : ....................................

● PRODUCT NAME: BITUMEN
● Manufacturer's Name & Address: Tiki Tar Industries

Village Road, Bhandup West, Mumbai, Maharashtra 400078
● Emergency Contact No.: Ph : 022 4126 6666

Bitumens ( 90 - 100 %)
Organo-sulphur compounds (4-5 %)
● Route of Entry: □
 Eye contact □Inhalation □ Ingestion □
 Skin Contact
Inhalation: May cause respiratory tract irritation. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and in extreme cases, loss of consciousness.
Inhalation may cause central nervous system effects. Hydrogen sulphide may be released and collect in the vapor
Effects of space of process vessels and storage tanks. In high doses hydrogen sulphide may produce pulmonary edema and
Exposure/ respiratory depression or paralysis.
Symptoms
Skin : May cause skin irritation.
Eyes : May cause eye irritation.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

● Move to fresh air.
● Artificial respiration and/or oxygen may be necessary.
● If inhaled :
● Seek medical advice.
● In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothingand shoes.
● In case of skin
● Wash skin thoroughly with soap and water or use recognized skin cleanser.
contact :
● Wash clothing before reuse.
● Remove contact lenses.

● In case of eye
● Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
contact :
● Obtain medical attention.
● Rinse mouth with water.

● DO NOT induce vomiting unless directed to do so by a physician or poison control center.
● If swallowed :
● Never give anything by mouth to an unconscious person.
● Most important
symptoms
and effects, both ● First aider needs to protect himself.
acute and
delayed

Revision : 0 Page 1 of 4 Page 1 of 4
□ Yes □ No
● Flammable:
● Fire Extinguishers: Type: Water, Foam Quantity : As Adequate

□
 Yes □ No
● Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
● Unsuitable extinguishing media : No information available.
● Specific hazards during firefighting : Cool closed containers exposed to fire with water spray.
● Hazardous combustion products : Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), hydrogen sulphide (H2S),
smoke and irritating vapours as products of incomplete combustion.
● Further information : Prevent fire extinguishing water from contaminating surface water or the ground water system.
Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary.

● Personal
● Use personal protective equipment.
precautions,
● Ensure adequate ventilation.
protective
● Evacuate personnel to safe areas.
equipment and
● Material can create slippery conditions.
emergency
procedures :
● Environmental
If the product contaminates rivers and lakes or drains inform respective authorities.
precautions:
● Prevent further leakage or spillage if safe to do so.

●Methods and ● Remove all sources of ignition.
materials for ● Soak up with inert absorbent material.
containment and ● Non-sparking tools should be used.
cleaning up : ● Ensure adequate ventilation.
● Contact the proper local authorities.
●For personal protection;

Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease
should not be employed in any process in which this mixture is being used.
●Smoking, eating and drinking should be prohibited in the application area.
● Advice on safe ●Use only with adequate ventilation.
handling : ●In case of insufficient ventilation, wear suitable respiratory equipment.
●Avoid contact with skin, eyes and clothing.
●Do not ingest.
●Keep away from heat and sources of ignition.
●Keep container closed when not in use.
●Store in original container.

●Containers which are opened must be carefully resealed and
● Storage ●kept upright to prevent leakage.
requirements : ●Keep in a dry, cool and well-ventilated place.
●Keep in properly labelled containers.
●To maintain product quality, do not store in heat or direct sunlight.

□
 Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
●Engineering No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne
measures contaminants.
Respiratory protection: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure
assessment demonstrates that exposures are within recommended exposure guidelines.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Eye protection : Wear face-shield and protective suit for abnormal processing problems. Ensure that eyewash stations
●Personal and safety showers are close to the workstation location.
protective
equipment Skin and body protection : Choose body protection in relation to its type, to the concentration and amount of
dangerous substances, and to the specific work-place.
Protective measures : Wash contaminated clothing before re-use.
Hygiene measures : Remove and wash contaminated clothing and gloves, including the inside, before re-use.Wash
face, hands and any exposed skin thoroughly after handling.
● pH Value : No data available ● Boiling Point: 230 - 1,000 °C (446 - 1,832 °F)
Tarry odour. "Rotten egg" if H2S present, but odour is an unreliable warning, since it may deaden the sense
● Odour and Appearance :
of smell.
Low fire hazard. This material must be heated before ignition will occur. Hydrogen sulphide may be released if the
● Flammability :
product is overheated.

● Possibility of hazardous reactions: Hazardous polymerisation does not occur. Stable under normal conditions.
● Conditions to avoid:No data available,

Incompatible materials: Reactive with oxidising agents.
● Hazardous
May release COx, NOx, SOx, H2S, smoke and irritating vapours
decomposition
when heated to decomposition.
products

● Effects: short term Acute: Toxicity Chronic: Internal Body parts
Acute oral toxicity : No data available
Acute inhalation toxicity : No data available
Acute dermal toxicity : No data available
Toxicity to fish , Toxicity to daphnia and other aquatic invertebrates : Remarks: No data available
● Environmental
Summary:
Toxicity to algae, Toxicity to bacteria: Remarks: No data available

●The product should not be allowed to enter drains, water courses or the soil.
●Offer surplus and non-recyclable solutions to a licensed disposal company.
●Waste must be classified and labelled prior to recycling or disposal.
● Waste :
●Send to a licensed waste management company.
●Dispose of as hazardous waste in compliance with local and national regulations.
●Dispose of product residue in accordance with the instructions of the person responsible for waste disposal.

● UN Number : Not Available
● Emergency Not regulated as a dangerous good,

Response Guide :

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the
CPR.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication
Assesed By:
Name: .................................................................. Date: ..............................................................

PROJECT NAME / CODE: ............................................................................... DEPT. : ...........................

● PRODUCT NAME: CARBOLIC ACID (Codes/Label: Poison Class 6)

SHIV CHEMICALS
Near Reva Township, Sanala Road,, Morbi, Gujarat, India - 363641
● Emergency Contact No.: Ph : +91-9825417789, +91-9687620226

Contains not less than 89.0% Phenol
Phenol: ORAL (LD50): Acute: 317 mg/kg, 270 mg/kg, DERMAL (LD50)
AFFECTS CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEYS. The major hazard of Carbolic acid is its ability to penetrate the skin rapidly,
particularly when liquid, causing severe injury which can be fatal. It has also strong corrosive effect on body tissue causing severe chemical burns.

● Route of Entry: □ Absorption □ Inhalation □
 Ingestion □
 Skin Contact
Hazard Statement:
1. Toxic if swallowed.
2. Toxic in contact with skin.
3. Toxic if inhaled.
4. Causes severe skin burns and eye damage.
5. Suspected of causing genetic defects.
6. May cause damage to organs through prolonged or repeated exposure. Affected organs: kidney, liver, skin and nervous system.
Precautionary statements:
1. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
2. Use respiratory protection and other personal protective equipment as required.
Wash face, hands and any exposed skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
● Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Cold water may be used. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and
● Skin Contact:
shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes
before reuse. Get medical attention immediately.
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is
difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous
● Inhalation:
to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek
immediate medical attention.
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.
● Ingestion: If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or
waistband.

● Fire Extinguishers: Type: All Quantity : As Adequate
□ Yes □ No
Fire Hazards in Presence of Various Substances:
Flammable
PROJECTin NAME
presence/ CODE:
of open flames and sparks, of heat. Non-flammable in presence of shocks.
...............................................................................
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:

SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards:

Phenol + nitrides results in heat and flammable gas generation. Phenol + mineral oxdizing acids results in fire. Phenol +
calcium hypochlorite is an exothermic reaction producing toxic fumes which may ignite.

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call
for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the
MSDS and with local authorities.

Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire
risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust.
● Handling : Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical
advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as
oxidizing agents, acids.
● Storage Air Sensitive. Sensitive to light. Store in light-resistant containers. Moisture sensitive. Keep container tightly closed. Keep
requirements : container in a cool, well-ventilated area.

□
 Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
●Engineering
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below
Controls:
the exposure limit.
●Personal
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Protection:
●Personal
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
Protection in
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
Case of a Large
product.
Spill:
● pH Value : Not available ● Boiling Point: 182°C
Distinct, aromatic, somewhat sickening sweet and

● Odour and Appearance : acrid
Colour less to light pink
Easily soluble in methanol, diethyl ether. Soluble in cold water, acetone. Solubility in water: 1g/15 ml water. Soluble in benzene.
Very soluble in alcohol, chloroform, glycerol, petroleum, carbon disulfide, volatile and fixed oils, aqueous alkali hydroxides,
● Solubility :
carbon tetrachloride, acetic acid, liquid sulfur dioxide. Almost insoluble in petroleum ether. Miscible in acetone. Sparingly soluble
in mineral oil.

PROJECT
● NAME
Stability: The / CODE:
product is stable...............................................................................
Conditions of Instability: Heat, ignition sources (flames, sparks), light, incompatible materials
Corrosivity: Extremely corrosive in presence of copper. Slightly corrosive in presence of stainless steel(304), of stainless steel(316). Noncorrosive in
presence of glass, of aluminum.
Reactivity: Air and light sensitive. Prone to redden on exposure to light and air. Incompatible with aluminum chloride, peroxydisulfuirc acid,
acetaldehyde, sodium nitrite, boron trifluoride diethyl ether + 1,3-butadiene, isocyanates, nitrides, mineral oxidizing acids, calcium hypochlorite,
halogens, formaldehyde, metals and alloys, lead, zinc, magnesium and their alloys, plastics, rubber, coatings, sodium nitrate + trifluoroacetic acid.
Phenol + isocyanates results in heat generation, and violent polymerization.
Phenol + 1,3-butadiene and boron trifluoride diethyl ether complex results in intense exothermic reaction. Phenol +
acetaldehyde resultes in violent condensation.
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Chronic Effects on Humans: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: kidneys, liver, central nervous
system (CNS).
Other Toxic Effects on Humans: Very hazardous in case of skin contact (corrosive, irritant), of ingestion, . Hazardous in case of skin contact
(sensitizer, permeator), of eye contact (corrosive), of inhalation (lung corrosive)
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
● Waste : Waste must be disposed of in accordance with federal, state and local environmental control regulations

DOT Classification: CLASS 6.1: Poisonous material.
● UN Number :
Identification: : Phenol, solid UNNA: 1671 PG: II
● Emergency
Not Available
Response Guide :

May cause sensitization by skin contact.
Harmful to aquatic organisms.
Keep locked up and out of the reach of children.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: CURING COMPOUND : AT-CURE WR350 (Water Based Curing Compound)

TADO ADDITIVES MFG PVT. LTD.
BD-64, Sector I
Salt Lake City, Kolkata 700064
West Bengal, India
● Emergency Contact No.:+91 33 40017313 / +91 33 23587377

Aqueous solution of silicates and lithium
● Route of Entry: □ Eye contact □ Inhalation □ Ingestion □ Skin Contact

The product does not contain any substances classified as hazardous under current regulations.
● Skin Contact : Wash skin thoroughly with soap and water. Contaminated clothing should be washed or drycleaned before re-use.
● Eye Contact : Immediately flood the eye with plenty of water for at least 10 minutes, holding the eye open. Obtain medical attention urgently.
Unlikely to occur. However provide symptomatic.

● Inhalation :
Medical treatment if required.
● Ingestion : Wash out mouth with water. Do not induce vomiting. Obtain medical attention.

 No
● Fire Extinguishers: Type: Quantity :
● Sand Buckets Nos :
□ Yes □
 No
●Personal
Wear appropriate protective clothing.
precautions :
●Environmental
Precautions and Try to prevent the material from entering drains or water cources.
Clean-up Methods :
Small spillages may be flushed with large quantities of water. Contain and absorb using earth, sand or other
●Spillages :
inert material. Transfer into suitable containers for recovery or disposal.

● Handling
Avoid contact with eyes, skin and clothing.
measures:
● Storage
Storage area should be cool & dry out of direct sunlight.

□
 Mask □ Respirator □ Glove
 □ Visor
□
 Goggles □
 Footwear □


● Engineering
PROJECT
Control NAMEUse
Measures
of the basic
/ CODE: principles of Industrial Hygiene will enable this material to be used safely.
...............................................................................
● Respiratory
Use Mask.
Protection
● Hand Protection The nature of the work in hand will determine the choice of gloves.
● Eye Protection Wear safety glasses if risks of accidental contamination are possible during application.

Physical State : Liquid
Color : Pinkish Red
Odour : Odourless
● Data relevant to pH : 6-8 Approx.
safety Method : Flash Point °C : Not applicable
Solubility-Water : Completely soluble
Specific Gravity : 1.01 ± 0.02
● Stability : Stable under normal conditions.
● Conditions to
Protect from frost
avoid :
● Materials to avoid
Oxidising agents. Mineral acids. Alkalis.
:

Acute toxicity : Low order of acute toxicity.

● Carcinogen
Eye irritation : May cause slight transient irritation.
Status:
Skin irritation : Frequent or prolonged skin contact may cause some local short term skin irritation.

● Environmental The product will dissolve rapidly in water.
Summary: The product is expected to be readily biodegradable.

Arrange for disposal via a licensed waste contractor.PROTECTION CAP IN PLACE for proper disposal.
● Waste : Dispose of containers with care. Empty packaging

● UN Number : Not Assigned
● Emergency
IT IS ABSOLUTELY SAFE TO CARRY THE MATERIAL BY ROAD, RAIL & AIR TRANSPORT
Response Guide :
Risk Phrases : None assigned

Safety Phrases : None assigned

This MSDS summarises our best knowledge of the health and safety hazard information of the product and how to safely handle and use the product in
the workplace. Each user should read this MSDS and consider the information in the context of how the product will be handled and used in the workplace
including in conjunction with other products.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: DENDRITE

Chandras’ Chemical Ent. Pvt. Ltd., P – 35, C. I. T Road, olkata - 700014
● Emergency Contact No.:+91 33 22177933, 22658195 / 6286 / 6287

This material is considered hazardous by the OSHA Hazard Communication Standard
Polychloroprene ( 12 – 14 %)
Aliphatic solvent ( 25 – 35 %)
Aromatic Solvent (50 – 65 %)

Eye contact □
Inhalation □

Ingestion □
Skin Contact
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective
equipment as required.Wear protective gloves. Wear eye or face protection. Avoid release to the environment. Avoid breathing vapor.
Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Collect spillage. IF
exposed or concerned: Get medical attention.
IF ON SKIN: Mild irritation occur . Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing
before reuse. If skin irritation or rash occurs: Get medical attention.
IF IN EYES: Pain & redness . Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical
● Skin Contact :
attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any
● Eye Contact :
contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.If not breathing, if breathing is
● Inhalation :irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. I
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities
● Ingestion :
of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel.

□ Yes □ No
For Large Fires: Use foam or water fog. Keep drum cool by spraying with water
For Small Fires: Use carbon dioxide, dry chemical powder, foam, sand, earth or water fog. Do not use water jets

● For non-
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep
emergency :
unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material.
personnel :
● For emergency
If specialised clothing is required to deal with the spillage
responders:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant
●Environmental
authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material.
precautions:
May be harmful to the environment if released in large quantities. Collect spillage.
●Methods and
materials for Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers,
containment and water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.
cleaning up:

● Protective 1. Put on appropriate personal protective equipment . Persons with a history of skin sensitization problems should not
measures: be employed in any process in which this product is used.
2.Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist.
3. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with
adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use.
● Advice on Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed.
general Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and
occupational protective equipment before entering eating areas.
hygiene
● Conditions for Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and
safe storage, well-ventilated area, away from incompatible materials . Containers that have been opened must be carefully resealed
including any and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid
incompatibilities: environmental contamination.


 □ Visor
□
 Goggles □
Engineering
Controls : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Environmental Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements
exposure of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the
controls : process equipment will be necessary to reduce emissions to acceptable levels.

Hygiene Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the
measures:
PROJECT NAME / CODE:
lavatory and at...............................................................................
the end of the working period. Appropriate techniques should be used to remove potentially
contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is
protection: necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection
should be worn, unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when
handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by
the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the
case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this product.
Other skin Appropriate footwear and any additional skin protection measures should be selected based on the task being
protection: performed and the risks involved and should be approved by a specialist before handling this product.
Respiratory Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment
protection: indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards
of the product and the safe working limits of the selected respirator.

● pH Value : Not Applicable ● Boiling Point: 4 to 8 Degree Celcius
● Odour and Appearance : Tan coloured liquid

● Flammability : Yes
● Stability : Stable at ambient temperature in a sealed container.
● Conditions to
No decomposition if used according to specifications.
Avoid :
● Materials to
Nucleophils, Oxidizing agents, Reducing agents, Alkalis
Avoid :
● Hazardous
Decomposition None, if storage and handling is done according to specification.
Product :
● Effects: Immediate Acute:Yes Chronic: No
● Carcinogen Oral rat LD50: 5800 mg/kg; Inhalation rat LC50: 50,100mg/m3; Irritation eye rabbit, Standard Draize, 20 mg severe;
Status: investigated as a tumorigen, mutagen, reproductive effector.
● Environmental
Not allowed to use on water
Summary:

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and
● Waste : any by-products should at all times comply with the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements. Waste should not be disposed of untreated to the sewer
unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible.
Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and
● Container : contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional,
national and local laws and regulations.

IMDG Class: III
UN No. 1133
● UN Number :
Packaging group: II
● Emergency Cool exposed containers with water. Firefighters are to wear Full Bunker Gear and Self Contained Breathing
Response Guide : Apparatus (SCBA).

This product does not contain nor is it manufactured with ozone depleting substances.
Health Rating: 2 - Moderate
Flammability Rating: 3 - Severe (Flammable)
Reactivity Rating: 0 - None
Contact Rating: 3 - Severe
This data is based on our present knowledge. However, it shall not constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship. Variations can occur in application and users are advised to conduct their own test
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: ECODET (NONEL) CORRECT SHIPPING NAME: DETONATOR ASSEMBLIES, NON-ELECTRIC
ECONOMIC EXPLOSIVES LIMITED
11, Zade Layout, Bharat Nagar, Amravati Road, Nagpur – 440 033 (M.S.), Ph: 0712-2561000 / 2560010, Fax : 0712-2560202
Works : Village Sawanga, Tahsil & Districts, Nagpur (M.S.), India , Ph: 07118-256553
● Emergency Contact No.: 07118-256553, 0712-2561000 / 2560010
Base charge of Pentaerythritol Tetranitrate (PETN) and a priming charge typically consisting of lead azide, lead styphnate and aluminium
powder with a length of tubing with a dusting of PETN and aluminium powder adhering to the internal surface. A pyrotechnic delay
element may also be present
Chemical Entity : Pentaerythritol Tetranitrate (PETN) and Aluminium Powder
USES : Initiators for explosive charges.
Appearance, Odour : Metal Tubes, closed at one end and capped at the other with a length of coloured or opaque plastic tubing.
Solubility : Insoluble in water
Reactivity : Detonation can occur from impact, friction or excessive heating
Shelf life : To be used within one year of date of manufacture.
Temp.Range : To be used between -5°c to 50°c
Storage temp. : Not to exceed 60°c
● Route of Entry: □ Absorption □ Inhalation □

 Ingestion □
 Skin Contact
Swallowed : Swallowing the PETN core may result in nausea, vomiting and mild gastric irritating
Test firing of detonators in poorly ventilated areas can cause presence of lead fume in air. Exposure to lead fume over
Inhalation:
a period of time can potentially result in lead poisoning-toxic effects noted below.
Eye Contact: Not applicable
Skin Contact: Not irritating to the skin.
Long terms exposure to low concentrations of lead may result in altered haemoglobin breakdown, kidney damage,
Chronic Effects:
anaemia and central and peripheral nervous system damage
● Skin Contact : Not applicable
● Eye Contact : Not applicable
● Inhalation :Remove victim from exposure. Seek medical advice if effects persist.
● Ingestion :Remove victim from exposure. Seek medical advice if effects persist.
● Advice to
Doctor: Treat symptomatically.

□ Yes □ No
Material
 Safety Data Sheet - (MSDS) EHS / 2018 / MSDS - 11
● Leak & Spill
Shut off all possible sources of ignition. Collect and seal in labelled packages for disposal. Handle with care.
Measures :
● Fire / Explosion Hazards: Explosive. Severe detonation hazard when exposed to heat. In case of small fire where the actual detonators
are not involved and are remote from fire, carefully remove the detonators to a safe distance.
Where explosives are involved in fire evacuate area immediately and allow fire to burn, DO NOT attempt to fight fire. Toxic fumes
containing lead will be produced.

● Storage and Transport
UN NO:0360. Classified as a 1.1B (Explosive). Dangerous substance for the purpose of transport. Refer to relevant regulations for
storage and transport requirements.
Explosives should not normally be carried on the same vehicle with dangerous goods of other classes, however exemptions may apply.
Store in a clean, dry magazine suitably licenced for IMCO Class 1.1B explosives. Handle with care. Do not subject materials to impact,
sparks or any form of heating.

□
 Glove □ Visor
□
 Goggles □
 Footwear □
Engineering Controls : Natural ventilation should be adequate under normal use conditions.
Personal Protection : Avoid eye contact and repeated or prolonged skin contact with the PETN core. Were overalls, safety glasses and
impervious gloves. Always wash hands before smoking, eating,drinking or using the toilet.
● pH Value : Not Applicable ● Boiling Point: Not Applicable
● Odour and Appearance : Not Applicable
● Flammability : Explosive material. Avoid all ignition sources.
EXPOSURE STANDARDS
No value assigned for this specific material by the local Regulatory Bodies.
However, Exposure Standard for a product of detonation :

TWA ,ppm, mg/m3
Lead, inorganic dusts - 0.15
and fumes (as Pb)
TWA-the Time-Weighted Average airborne concentrations over an eight hour working day, for a five day working week over an entire life.
These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric contamination should be
kept to as low lable as is workable Exposure Standards should not be used as fine dividing lines between safe and dangerous
concentration of chemicals. They are not a measure of relative toxicity.

● Chemical Stability: Aluminium Powder, Lead Azide, Lead Styphnate and Pentaerythritol Tentranitrate (PETN)
Uses : Initiators for explosive charges.
● Conditions to avoid: Explosive material. Detonation can occur from heavy impact.

● Effects: Long term Acute: Not immediate Chronic: Internal Body parts
● Carcinogen Status: Long term exposure to lead has resulted in kidney damage, anaemia and central nervous system and peripheral
nervous system damage.
Appearance, Odour : Metal Tubes, closed at one end and capped at the other with a length of coloured or opaque plastic tubing.
Reactivity : Detonation can occur from impact, friction or excessive heating
Shelf life : To be used within one year of date of manufacture.
Temp.Range : To be used between -5°c to 50°c
Storage temp. : Not to exceed 60°c
ACUTE EFFECTS
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms
may arise if the product is mishandled.

● Environmental Summary: All atmospheric contamination should be kept to as low level as is workable. Exposure Standards should not
be used as fine dividing lines between safe and dangerous concentrations of chemicals. They are no a measure of relatively toxicity

For small quantities :Place in a blast hole and explode during blasting. Large quantities to be disposed off in
● Waste :
conjunction with the relevant State Dangerous Goods Branch & Economic Explosives Limited.
Large quantities to be disposed off in conjunction with the relevant State Dangerous Goods Branch & Economic
● Container :
Explosives Limited.
● UN Number : U.N. NO. : 0360 CLASS: 1.1 B Explosives, HAZCHEM : E
● Emergency Shut off all possible sources of ignition. Clear area of all unprotected personnel. Wear protective equipment to prevent
Response Guide : skin and eye contact. If contamination of sewers or waterways has occurred advise local emergency services.

The Explosives Rules,1983 were framed to regulate the manufacture, possession, sale, use, transportation, importation etc. of condensed
explosives.
The SAFETY DATA SHEET summarizes at the date of issue our best knowledge of health and safety hazard information of the product,
and in particular how to safely handle and use the product in the workplace. Since Economic Explosives Limited cannot anticipate or
control the conditions under which the product may be used, each user must, prior to usage, review this SAFETY DATA SHEET in the
context of how the user intends to handle and use the product in the workplace.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact Economic
Explosives Limited.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: Engine Oil - 15W40

Gulf Oil Corporation Limited, IN Centre, 12th Road, Marol, Andheri (East), Mumbai- 400 093
● Emergency Contact No.:+91 22 66487777
This product is not considered to be hazardous but contains hazardous components.
Zinc alkyl dithiophosphate : 1-2%
Olefine sulphide : 0.5 - 1 %
Alkyl phenol : 0.1 - 0.15 %
● Route of Entry: □ Absorption □ Inhalation □ Ingestion □ Skin Contact

Skin Contact: Skin irritation leading to dematitis may occur upon prolonged or repeated contact.

Remove affected clothing and wash all exposed skin area with mild soap and water followed by warm water rinse.
● Skin Contact :
Seek medical attention if irritation develops
● Eye Contact : Rinse immediately with plenty of water. Seek medical attention if irritation develops.
● Inhalation :As sure fresh air breathing. Obtain medical attention if breathing difficulty persists.
● Ingestion :DO NOT INDUCE VOMITING. Seek medical attention immediately

● Others If there is any suspicion of aspiration into the lungs either directly or as a result of vomiting, obtain medical advice.
:
● Fire Extinguishers: Type: ABC & Foam Quantity : As Adequate
□ Yes □ No
Clean up any spills as soon as possible, using an absorbent material to collect it. Collect spills and put it into
● Leak & Spill
appropriated container. Use suitable disposal containers. Recover the cleaning water for disposal. Spill area may be
Measures :
slippery.
● Fire / Explosion
No reaction to Fire & Explosion
Hazards:

● Handling Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work.
Equipment:
● Storage and Keep container closed when not in use. Keep only in the original container in a cool,well ventilated place. Keep at
Transport temperature not exceeding 45°C.


 □ Visor
□
 Goggles □
Engineering
Controls : Use only intrinsically safe electrical equipment approved for use in classified areas.
Personal Eye Protection: Safety glasses

Protection : Hand protection : Gloves constructed of nitrile, neoprene, or PVC are recommended. Consult manufacturer
specifications for further information.
Skin and body protection : No special clothing/skin protection equipment is recommended under normal conditions
of use.
Respiratory protection : No special respiratory protection equipment is recommended under normal conditions of use
with adequate ventilation.
Industrial hygiene : Provide local exhaust or general room ventilation to minimize dust and/or vapour concentrations.
When using, do not eat, drink or smoke. Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
● pH Value : Not Applicable ● Boiling Point: 550 Degree Celcius
● Odour and Appearance : Characteristic
● Flammability : 228
● Chemical
Stable
Stability:
● Conditions to
Open flame. Sparks. Overheating
avoid:
● Effects: No Acute:No Chronic: No
● Carcinogen
Not listed as a carcinogen or potential carcinogen by the NTP, IARC, and OSHA.
Status:
● Environmental
Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment
Summary:

● Waste : Dispose in a safe manner in accordance with local/national regulations. Dispose of this material and its container at
hazardous or special waste collection point. S29/ 56 : Do not empty into drains, dispose of this material and its
● Container : container to hazardous or special waste collection point.


Do not empty into drains ; dispose of this material and its container in a safe way. S29/56 : Do not empty into drains, dispose of this
material and its container to hazardous or special waste collection point. S59 : Refer to manufacturer/supplier for information on
recovery/recycling. S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.
R36/38 : Irritating to eyes and skin. R38 : Irritating to skin. R50/53 : Very toxic to aquatic organisms, may cause long term adverse effects
in the aquatic environment. R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 :
Possible risk of impaired fertility. For specific or detailed technical data for this product, please contact your local sales representative
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: SUPREME ALUMINIUM LONG DELAY ELECTRIC DETONATORS.
ECONOMIC EXPLOSIVES LIMITED
11, Zade Layout, Bharat Nagar, Amravati Road, Nagpur – 440 033 (M.S.), Ph: 0712-2561000 / 2560010, Fax : 0712-2560202
Hazardous Ingredients: Base charge of Pentaerythritol Tentranitrate (PETN) and a priming charge typically consisting of lead azide, lead
styphnate and aluminium powder
● Route of Entry: □ Absorption □ Inhalation □ Ingestion □

 Skin Contact
Inhalation: Test firing of detonators in poorly ventilated areas can cause presence of lead fume in air. Exposure to lead fume
Ingestion: over a period of time can potentially result in lead poisoning.
Skin Contact: Not Applicable
If irritation occurs seek medical advice.
● Skin Contact : Not Applicable
● Eye Contact : Not Applicable
● Inhalation :Remove victim from exposure. Seek medical advice if effects persist
● Ingestion :Not Applicable
● Others Advice to Doctor - Treat symptomatically
:
□ Yes □ No
● Leak & Spill Shut off all possible sources of ignition. Collect and seal in labelled containers. In the case of a transport accident
Measures : notify the state police, State Explosive Inspector and Economic Explosives Limited.
● Fire / Explosion Hazards: Explosive. Severe detonation hazard when exposed to heat. In case of small fire where the actual detonators
are not involved and are remote from fire, carefully remove the detonators to a safe distance.
Where explosives are involved in fire evacuate area immediately and allow fire to burn, DO NOT attempt to fight fire. Toxic fumes
containing lead will be produced.

● Handling Equipment: Storage and Transport
UN No: 0030. Classified as a 1.1B (EXPLOSIVES) Dangerous Substance for the purpose of transport. Refer to relevant regulations for
Explosives shall not normally be carried on the same vehicle with dangerous gods of other classes, however exemptions may apply.
Store in a clean, dry magazine suitably licenced for IMCO Class 1.1B explosives. Handle with care. Do not subject materials to impact
sparks or any from of heating.

□
 Glove □ Visor
□
 Goggles □
 Footwear □
Engineering Controls : When test firing, ensure ventilation is adequate to maintain air concentrations below exposure standard.
Personal Protection : No specific safety equipment necessary. Containment of charge within packaging prevents exposure, When test
firing, use with adequate ventilation. Always wash hands before smoking, eating, drinking or using the toilet.
● Conditions to avoid: Explosive material. Avoid all ignition sources.

● Carcinogen Status: Chronic effects: Long term exposure to low concentrations of lead (by any route) may result in blood effects,
anaemia, central and peripheral nervous system damage, gastrointestinal disturbances, renal injury, foetotoxicity, developmental
deficiencies in neonates and children, and testicular damage including decreased sperm count.
Reproductive toxicity : May damage fertility or the unborn child.
Exposure to explosive charge material unlikely. The main hazard is the possibility of exposure to lead fumes when test firing detonators in
a poorly ventilated area. The effects of lead poisoning may not be appartent immediately but significant absorption over a period of time
may produce adverse effects as noted earlier due to accumulation of lead in the body.


● Waste : For small quantities :Place in a blast hole and explode during blasting
● Container :
Explosives Limited.
● UN Number : 0030, Class : 1.1 B Explosive, Hazchem: E

explosives.

Long Delay Detonators are designed for use in underground mining for driving shafts and tunnels, blasting raises and sinking shafts. In
many cases they are used for stopeing in metal mines, trenching and other blasting applications. The longer delay period allows sufficient
rock movement before firing the next shot.
EXPOSURE STANDARDS: No value assigned for this specific material by the local Regulatory Bodies. However, Exposure Standard for
a product of detonation :
TWA ppm mg/m3 , Lead, inorganic dusts - 0.15, and fumes (as Pb)
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: Engine Oil - 20W40

Zinc alkyl dithiophosphate : < 0.6 %
Sodium Sulfonate : < 0.2 %
Alkyl phenol : < 0.2
Polyolefin polyamine succinimide, : <1%
HOB Calcium branched chain alkyl polyol phenate sulphide : < 0.5 %
Calcium long chain alkaryl sulphonate: < 0.3 %
● Route of Entry: □ Absorption □ Inhalation □ Ingestion □

 Skin Contact

● Skin Contact :
● Inhalation : As sure fresh air breathing. Obtain medical attention if breathing difficulty persists.
● Ingestion : DO NOT INDUCE VOMITING. Seek medical attention immediately

:
□ Yes □ No
● Leak & Spill
Measures :
slippery.
Hazards:

PROJECT
● Handling NAME / CODE: ...............................................................................
Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work.
Equipment:


 □ Visor
□
 Goggles □
Engineering
Controls : Use only intrinsically safe electrical equipment approved for use in classified areas.
Personal Eye Protection: Safety glasses

Skin and body protection : No special clothing/skin protection equipment is recommended under normal
conditions of use.
Respiratory protection : No special respiratory protection equipment is recommended under normal conditions of
use with adequate ventilation.
When using, do not eat, drink or smoke. Emergency eye wash fountains and safety showers should be available in
the immediate vicinity of any potential exposure.
● Odour and Appearance : Characteristic Mild
● Flammability : 228
● Chemical
Stable
Stability:
● Conditions to
avoid:
R38 : Irritating to skin.
R41 : Risk of serious damage to eyes.
R43 : May cause sensitization by skin contact.
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

● Effects: May cause respiratory irritation
following prolonged or repeated inhalation of Acute:No Chronic: No
excessive oil mist and vapours.
● Carcinogen
Status:
● Environmental
Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment
Summary:

hazardous or special waste collection point. S29/ 56 : Do not empty into drains, dispose of this material and its
● Container : container to hazardous or special waste collection point.


Contains : - Calcium long chain alkaryl sulphonate. May produce an allergic reaction.

To the best of our knowledge and belief, the information and recommendations provided in this MSDS are correct.We make no warranty
whatsoever, expressed or implied of merchantability or fitness for the particular purpose, regarding the accuracy of such data or the
results to be obtained from the use thereof. We do not assume any liability for consequences of the uses of this information since it may
be applied under conditions beyond our control or knowledge. The information is furnished on the condition that the recipients shall make
their own decision as to safety and suitability of the material for their purposes. We will not be responsible for damages of any nature
resulting from the use or reliance upon the information and recommendations. If you have purchased this product for supply to a third
party, it is your duty to pass on to that third party the information given in this Data Sheet. If the third party is not an employer it is his duty
to pass the information given in the Data Sheet to the employer of whoever uses or handles this product. It is an employer's duty to advise
and instruct his employees handling this product (and others who may be affected) , of any hazards described in the Data Sheet and of
any precautions which should be taken to ensure safe handling of the product. The contents and format of this MSDS are in accordance
with EEC Commission Directive 93/112/EEC.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: GREASE

● Emergency Contact No.: 022 66487777

This product is not considered to be hazardous and does not contain hazardous components at or above regulated limits.Chemical
classification.
Highly refined mineral base oils ( PCA-content < 3% -IP 346), Soap thickener and performance additives.
● Route of Entry: □ Absorption □ Inhalation □

 Ingestion □ Skin Contact
Absorption: Not expected to present a significant absouption contact hazard under anticipated conditions of normal use.
Inhalation: Not expected to present a significant inhalation hazard under anticipated mconditions of normal use.
Ingestion: Not expected to present a significant ingestion hazard under anticipated conditions of normal use
Skin Contact: Not expected to present a significant skin contact hazard under anticipated conditions of normal use.

● Skin Contact :
● Inhalation :As sure fresh air breathing. Obtain medical attention if breathing difficulty persists.
● Ingestion :DO NOT INDUCE VOMITING. Seek medical attention immediately

:

● Fire Extinguishers: Type: Foam, Dry Chemical Powder and ABC ( Adequate nos.)
● Sand Buckets Nos : As Adequate F.E Quantity As Adequate

:
□ Yes □ No
● Leak & Spill
Measures :
slippery.
Issue warning: “ FLAMMABLE”. Eliminate all sources of ignition.
Hazards:

● Handling
Equipment:

□ Mask □ Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
Personal Respiratory protection : No special respiratory protection equipment is recommended under normal conditions of use
Protection : with adequate ventilation.
Hand protection : Use neoprene or rubber gloves
Hand protection : Use neoprene or rubber gloves
Eye protection : Safety glasses.
● pH Value : Not Applicable ● Boiling Point: NA
● Flammability : 200 degree celcius
● Chemical
Stable
Stability:
● Conditions to
avoid:

● Effects: May cause respiratory irritation
following prolonged or repeated inhalation of Acute: Not expected to be toxic Chronic: No
excessive oil mist and vapours.
● Carcinogen Status: No data available. The ingredients used in this preparation have not been listed in the US National Toxicology
Program ( NTP) nor have they been classified by the International Agency for Research on Cancer ( IARC) as carcinogenic or probably
carcinogenic to humans.
● Environmental Summary: Adverse effects to the environment are not expected from this product

● Waste : Dispose in a safe manner in accordance with local/national regulations
● Container : Large quantities to be disposed off in conjunction with the relevant State rules and regulations.
● Emergency
Shut off all possible sources of ignition. Clear area of all unprotected personnel.
Response Guide :
Not classified as hazardous in accordance with OSHA 29 CFR 1910.1200

To the best of our knowledge and belief, the information and recommendations provided in this MSDS are correct.We make no warranty
whatsoever, expressed or implied of merchantability or fitness for the particular purpose, regarding the accuracy of such data or the
results to be obtained from the use thereof. We do not assume any liability for consequences of the uses of this information since it may
be applied under conditions beyond our control or knowledge.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: CEBEX 100 ( FOSROC)
Fosroc Chemicals (India) Pvt. Ltd.
Head Office: 111/3, Hafeeza Chamber II Floor,
K H Road, PBNo. 2744, Bangalore - 560027
● Emergency Contact No.: +91 80-22240018/120
Chemical Classification: Aqueous dispersion of a polymer based on Styrene-Butadiene
SILICA SAND (60-100%)
CALCIUM LIGNOSULPHONATE POWDER (10-30%)
ALUMINIUM POWDER (STABILIZED)(< 1%)

Absorption □
Inhalation □

Ingestion □

Skin Contact
HUMAN HEALTH: Dust or splashes from the mixture may cause permanent eye damage. Dust may irritate throat and respiratory system and
cause coughing.
Dust has an irritating effect on moist skin. Prolonged contact with wet cement/mixture may cause burns. Frequent inhalation of dust over a long
period of time increases the risk of developing lung diseases
Do not rub eye. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids
● Eye Contact :
widely. If irritation persists: Continue flushing during transport to hospital. Bring these instructions.
Move injured person into fresh air and keep person calm under observation. If uncomfortable: Seek hospital and bring these
● Inhalation :
instructions.
Immediately rinse mouth and drink plenty of water or milk. Keep person under observation. Do not induce vomiting. If
● Ingestion :
vomiting occurs,keep head low. Transport immediately to hospital and bring along these instructions.
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation persists
● Skin Contact :
after washing.
● Fire Extinguishers: Type: Water and ABC ( Adequate nos.)
● Sand Buckets Nos : As Adequate F.E Quantity As :Adequate

□ Yes □
 No
● Leak & Spill For waste disposal, Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into closed
Measures : container.
Not a fully flammable item
Hazards:
● Handling Observe good chemical hygiene practices. Avoid spread of dust. Avoid inhalation of dust. Avoid contact with eyes and
Equipment: prolonged skin contact. Mechanical ventilation may be required. Change contaminated clothing.
To be stored out of reach of children in its original packaging in a dry place. The product contains less than 2 mg chromate/kg
● Storage and
dry cement, and this limit will not be exceeded for 12 months from the packing date stated on the packaging. Seal opened
Transport
containers and use up as soon as possible
□ Mask □ Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
Personal RESPIRATORY EQUIPMENT:
Protection :
PROJECT NAME Dust mask/respirator,
/ CODE: Use respiratory equipment with particle filter, type P2. (EN 149)
...............................................................................
HAND PROTECTION
Wear protective gloves. PVC or rubber gloves are recommended. The most suitable glove must be chosen in consultation
with the gloves. Supplier, who can inform about the breakthrough time of the glove material. If signs of wear and tear are
noticed then the gloves should be
replaced.
EYE PROTECTION
Wear goggles/face shield. (conform EN 166)
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact.
HYGIENE MEASURES
Change contaminated clothing. When using do not eat, drink or smoke.
APPEARANCE: Powder, dust
COLOUR : Silver
ODOUR: Slight odour
SOLUBILITY : Insoluble in water
RELATIVE DENSITY : 1.3 (bulk)
● Chemical Stable under normal temperature conditions. When stored under humid conditions, the chromate neutralization will decrease.
Stability: This product contains a chromate reducing agent to reduce the risk of allergic dermatitis causes by chromium (VI). This
product has a shelf life. If not stored in accordance with packaging instructions (sealed and dry), there is an increased risk of
the presence of hexavalent chromate leading to an increased risk of an allergic reaction. The product will harden into a hard
mass in contact with water and moisture.
● Conditions to
Water, moisture
avoid:
INHALATION: Dust may irritate throat and respiratory system and cause coughing.
INGESTION: Not likely, due to the form of the product. Ingestion may cause severe irritation of the mouth, the oesophagus and the
gastrointestinal tract.
SKIN CONTACT: Dust has an irritating effect on moist skin. Prolonged contact with wet cement/mixture may cause burns.
EYE CONTACT: Dust or splashes from the mixture may cause permanent eye damage. Immediate first aid is necessary.
SPECIFIC EFFECTS: Frequent inhalation of dust over a long period of time increases the risk of developing lung diseases.
ECOTOXICITY: The product is not expected to be hazardous to the environment.
MOBILITY: The product is not volatile but may be spread by dust-raising handling.
DEGRADABILITY: The product is not biodegradable.
Dispose of waste and residues in accordance with local authority requirements. Note that fully cured material is not
● Waste :
considered as hazardous waste.
● Container : Waste from residue can be considered
● Emergency The product is not covered by international regulation on the transport of dangerous goods. No transport warning sign
Response Guide : required.
This material and its container must be disposed of as hazardous waste.
Classification and Labelling of Substances and Preparations Dangerous for Supply.
Safety Data Sheets for Substances and Preparations.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: Diesel Oil / HSD
BPCL, Bharat Bhavan , Currimbhoy road, Mumbai.
● Emergency Contact No.:022 22713000,1800222725
Naphthalene 1-5 %, Xyene 1- 5 %, Nonane 0.75- 1 %, Trimethylbenzene 0.75- 1 %

 Ingestion □
 Skin Contact
Inhalation: Vapours or mists from this material can irritate the nose, throat, lungs and can cause signs and symtoms of nervous system
depression .
Ingestion: Harmful of fatal if swallowed. Do NOT induce vomiting. This material can irritate the mouth, throat, stomach and cause nausea,
vomiting, diarrhea and restlessness. Aspiration hazard if liquid is inhaled into lungs, particularly from vomiting after ingestion.
Skin Contact: Skin irritation leading to dematitis may occur upon prolonged or repeated contact. Liquid mau be absorbed through the skin in
toxic amounts if large areas of skin are repeatedly exposed. Long term repeaed skin contact may cause skin cancer.
Hazards : Combustible Liquid, Toxic by ingestion, Severe skin irritant, Moderate eye irritant, Possible Cancer Hazard.

Take off all contaminated clothing imediately. Was off immediately with soap and plenty of water. If skin irritation persists,
● Skin Contact :
seek medical attention.
Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye
● Eye Contact :
irritation persists, seek medical attention.
Move to fresh air. Give oxygen. If breathing is irregular or stopped, administer artificial respiration. Seek medical attention
● Inhalation :
immediately.
Do Not induce vomiting. Ingestion may results in nausea, vomiting, diarrhea and restlessness. Aspiration may cause
● Ingestion :
pulmonary edema and pneumonitis. Seek medical attention immediately.
● Others
Advice to Doctor - Treat symptomatically
:
□ Yes □ No
Consider wind direction, stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers etc. to
contain spill areas. Spills may infiltrate subsurface soil and groundwater, professional assistance maybe necessary to
● Leak & Spill determine the extent of subsurface impact.
Measures : Steps to be taken Shut off leak, if safe to do so, .Keep non-involved people away from spill site. Eliminate all sources of
ignition. Prevent spill entering in to sewers, for Major spillage contact Emergency services
Waste Disposal method: N.A.
Hydrocarbon liquids including this product can act as a non-conductive flammable liquid (or static accumulators), and
may form ignitable vapor-air mixtures in storage tanks or other containers. Precautions to prevent static-initated fire or
explosion during transfer, storage or handling, include but are not limited to these examples:
● Fire / Explosion (1) Ground and bond containers during product transfers. Grounding and bonding may not be adequate protection to
Hazards: prevent ignition or explosion of hydrocarbon liquids and vapors that are static accumulators.
(2) Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that can exist
when higher flash point material (such as fuel oil or diesel) is loaded into tanks previously containing low flash point
products (such gasoline or naphtha).

PROJECT
● Handling NAME / CODE:
Keep ...............................................................................
away from fire, sparks and heated surfaces. No smoking near areas where material is stored or handled. The
Equipment: product should only be stored and handled in areas with intrinsically safe electrical classification.
● Storage and Keep away from food, drink and animal feed. Incompatible with oxidizing agents.
Transport Incompatible with acids.
□
 Mask □ Respirator □ Glove
 □ Visor
□
 Goggles □
 Footwear □
Engineering
Use only intrinsically safe electrical equipment approved for use in classified areas.
Controls :
Personal Eye Protection: Safety glasses with side-shield.
Skin and body protection : If needed to prevent skin contact, chemical protective clothing such as of DuPont
TyChem®, Saranex or equivalent recommended based on degree of exposure. The resistance of specific material may
vary from product to product as well as with degree of exposure.
● pH Value : Not Applicable ● Boiling Point: 160 °C (320 °F)
● Odour and Appearance : Characteristic petroleum (kerosene) odor
Carbon monoxide, carbon dioxide and noncombusted hydrocarbons (smoke).
● Chemical Diesel exhaust particulates may be a lung hazard.
Stability: Thermal decomposition : No decomposition if stored and applied as directed. No decomposition if used as directed.
Hazardous reactions : Keep away from oxidizing agents, and acidic or alkaline products.
● Conditions to Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources. Keep away from strong
avoid: oxidizers.
● Effects: Long term Acute:Immediate Chronic: Internal Body parts
NTP : Naphthalene . IARC : Naphthalene
Skin irritation : Irritating to skin.
Eye irritation : Irritating to eyes.

● Carcinogen
Status:
Further information : Studies have shown that similar products produce skin cancer or skin tumors in laboratory animals
following repeated applications without washing or removal. The significance of this finding to human exposure has not
been determined. Other studies with active skin carcinogens have shown that washing the animal's skin with soap and
water between applications reduced tumor formation.
● Environmental Keep out of sewers, drainage areas, and waterways. Report spills and releases, as applicable, under Federal and State
Summary: regulations.
● Waste : Consult federal, state and local waste regulations to determine appropriate waste characterization of material and
● Container : allowable disposal methods.
● UN Number : UN 1202
Fire extinguishing media: Foam, Carbon dioxide, Dry Chemical Powder. Water may be used to cool fire-exposed
containers.
● Emergency
Special procedure: Shut off leak, if safe to do so, .Keep non-involved people away from spill site. Eliminate all sources of
Response Guide :
ignition.
Unusual hazards: it will spread along the ground and collect in sewers

PROJECTTONAME
RELEASE / CODE: ...............................................................................
THE ENVIROMENT: Definition of hazardous substances contains a “petroleum exclusion” clause which exempts crude oil.
Fractions of crude oil, and products (both finished and intermediate) from the crude oil refining process and any indigenous components of
such from the CERCLA Section 103 reporting requirements. However, other federal reporting requirements, as well as the Clean Water Act
may still apply.
Further information. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the
text.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: Hydraulic Oil
● Manufacturer's Name & Address: Gulf Oil Corporation Limited, IN Centre, 12th Road, Marol, Andheri (East), Mumbai- 400 093

Zinc dialkyl dithiophosphate : 1-2%
Long-chain alkenyl succinimide : < 0.1 %
Alkyl phenol : 0.1 - 0.15 %
Calcium alkaryl sulphonate : < 0.05 %
Alkylated diphenylamines : < 0.05 %
Dithiophosphoric acid ester : < 0.1 %
Sterically hindered phenol : < 0.25 %
● Route of Entry: □ Absorption □ Inhalation □ Ingestion □ Skin Contact


Remove affected clothing and wash all exposed skin area with mild soap and water followed by warm water rinse. Seek
● Skin Contact :
medical attention if irritation develop.
● Inhalation : As sure fresh air breathing. Obtain medical attention if breathing difficulty persists.
● Ingestion : DO NOT INDUCE VOMITING. Seek medical attention immediately

:
□ Yes □ No
● Leak & Spill Clean up any spills as soon as possible, using an absorbent material to collect it. Collect spills and put it into appropriated
Measures : container. Use suitable disposal containers. Recover the cleaning water for disposal. Spill area may be slippery.
Hazards:
● Handling
Equipment:


 □ Visor
□
 Goggles □
Engineering
Use only intrinsically safe electrical equipment approved for use in classified areas.
Controls :
Personal Eye Protection: Safety glasses Hand
Protection : protection : Gloves constructed of nitrile, neoprene, or PVC are recommended. Consult manufacturer specifications for
further information.
Skin and body protection : No special clothing/skin protection equipment is recommended under normal conditions of
use.
Respiratory protection : No special respiratory protection equipment is recommended under normal conditions of use
with adequate ventilation.
● Flammability : 130 to 280
● Chemical
Stable
Stability:
● Conditions to
avoid:
● Effects: No Acute:No No Chronic: No
● Carcinogen
Status:
● Environmental
No such specific risk to environment
Summary:
hazardous or special waste collection point. S29/ 56 : Do not empty into drains, dispose of this material and its container
● Container : to hazardous or special waste collection point.

● Emergency Cool exposed containers with water. Firefighters are to wear Full Bunker Gear and Self Contained Breathing Apparatus
Response Guide : (SCBA).
Do not empty into drains ; dispose of this material and its container in a safe way. S29/56 : Do not empty into drains, dispose of this material
and its container to hazardous or special waste collection point. S59 : Refer to manufacturer/supplier for information on recovery/recycling.
S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.

R36/38 : Irritating to eyes and skin. R38 : Irritating to skin. R50/53 : Very toxic to aquatic organisms, may cause long term adverse effects in
the aquatic environment. R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 :
Possible risk of impaired fertility.
For specific or detailed technical data for this product, please contact your local sales representative.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: INHIBITOR SOLUTION (IS)

Patil Bhuvan, Netaji Subhash road, Mulund - West, Mumbai - 400080
● Emergency Contact No.:+91 22 25681148, 25681078

This product contains no hazardous materials.
Compositions are ; Caustic soda, Sodium Nitate, Borax, Solphonated polymer , Benzotriazole and Dichlorophen

Physical / Chemical Hazards: Toxic, Irritating to eyes and skin
Environment hazrds: Toxic to wildlife and fish
Human health hazards: Toxic if swallowed

Irritation and redness of skin. Soreness on prolonged contact , wash with soap and water. Remove contaminated
● Skin Contact :
clothing.
● Eye Contact : Irritating to eyes. Immediately rinse eye with sterile water for 10 minutes. If more seek medical advice.
● Inhalation :No unknown ill effects
Toxic if swallowed, May cause nausea, hedache, dizziness, weakness and short breath. In severe cases may cause
● Ingestion :
fatal.

 No
● Fire Extinguishers: Type: Water or Foam Quantity : As Adequate
● Sand Buckets Nos : Not required
□ Yes □
 No
●Personal Wear full protective equipment- gloves, eye/ face protection and overalls
precautions : Ensure sufficient air supply
●Environmental Do not allow to enter drains or waterways In case of entry into waterways, soil or drains, inform the
precautions: responsible authorities.
Small spillage should be flushed with water to a foul drain. Large spillage should be used with absorbent material
●Procedures for
(e.g. sand, sawdust, general-purpose binder). When picked up, treat material as prescribed under heading
cleaning up:
"Disposal".
● Handling
Avoid direct contact with product. Before eating, drinking or smoking wash hands with soap and water
measures:
● Storage Store above 10 C . Do not freeze. Ensure that the container is firmly secure when not in use.


 □ Visor
□
 Goggles □
 Footwear □
Long term : 8 Hrs
Exposure Limits : Short term: 15 Mins
Not applicable unless aerosol formation possible, in which case appropriate respiratory protection must be worn.
PPEs :
Common PPEs i.e Overall, boots, rubber hand gloves applicable.

Physical state : liquid Solution
● Appearance : Colour : Straw Coloured
Odour : None
● Stability: Stable under normal conditions
● Reactivity: Avoid temprature extreamsand reacts with acids
● Chemical
Decomposition generates oxides of carbon ( CO and CO2) and nitrogen (Nox)
stability:

● Carcinogen Oral: Sodium nitrite Toxic

Status: Eye: irritant

● Environmental Sastainable and biodegradable .
Summary: Toxic to aquatic life

● Methods of Small quantity can be disposed of via foul drain. Larger quantities should be handled by a licensed contractor in
Disposal : accordance with waste disposal regulations.
● Packaging Plastic drums will be collected by supplier for recycling, Damaged containers should be destroyed by cutting up or
Disposal : incinerations. Empty containers must not be used for poratble water.

● UN Number : 3287
● Emergency
No dangerous goods for transportation
Response Guide :
Toxic if swallowed, Avoid release to the environment.
Reference: The carriage of Goods by Road and Rail Regulations.

The control of substances Hazards to Health regulations
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: LIME (Chemical Name: Calcium Hydroxide)

Phoenix Industries Pvt. Ltd. 243, Udyog Bhavan, Sonawala Road, Goregaon (E),
Mumbai - 400 063
● Emergency Contact No.: Ph : (022) 4044 1111
Type of application: Hydrated Lime, Industrial Hydrate
Calcium hydroxide >85 1305-62-0

● Route of Entry: □ Absorption □Inhalation □
 Ingestion □
 Skin Contact
Overview: Hydrated lime is an odorless white or grayish-white granular powder. Contact can cause irritation to eyes, skin, respiratory
system, and gastrointestinal tract. Contact may aggravate disorders of eyes, skin, gastrointestinal tract, and respiratory system.
Eyes: Can cause severe irritation or burning of eyes, including permanent damage.
Skin: Can cause severe irritation or burning of skin, especially in the presence of moisture.
Ingestion: Can cause severe irritation or burning of gastrointestinal tract if swallowed.
Inhalation: Can cause severe irritation of the respiratory system. Long-term exposure may cause permanent
damage.
Irritant: Eyes, mucous membranes, moist skin, respiratory tract.
Flammability: This product is not flammable or combustible
Explosive: This product is not explosive in dust form
Reactivity: May react violently with strong acids producing heat and possible steam explosion in confined
space
Inhalation: Acute: irritation, sore throat, cough, sneezing. Chronic: persistent coughing and breathing
problems. Long-term exposure to silica can cause a chronic lung disorder, silicosis.
Eyes: Acute: severe irritation, intense tearing, burns. Chronic: possible blindness when exposure is
prolonged.
● Health Effects:
Skin: Acute: removes natural skin oils, blotches, itching and superficial burns in case of sweating.
Chronic: no known effects.
Ingestion: Acute: sore throat, stomach aches, cramps, diarrhea, vomiting. Chronic: no known effects.
Inhalation: Move victim to fresh air. Seek medical attention if necessary. If breathing has stopped, give
artificial respiration.
Eyes: Immediately flush eyes with large amounts of water for at least 15 minutes. Pull back the eyelid
to make sure all the lime dust has been washed out. Seek medical attention immediately. Do
not rub eyes.
● Treatments: :
Skin: Flush exposed area with large amounts of water. Seek medical attention immediately.
Ingestion: Give large quantities of water or fruit juice. Do not induce vomiting. Seed medical attention
immediately. Never give anything by mouth if victim is rapidly losing consciousness or is
unconscious or convulsing.

□ Yes □ No
● Flammable:

□ Yes □ No
Flash point: Non-flammable
Autoignition temperature: Non-flammable
Inflammability limits: None
Explosion risk: None by itself, but heat produced by reaction with strong acids can generate steam and pressure
Hazardous combustion products: Decomposes to produce calcium oxide (CaO), which can react with water to produce steam and
pressure
Extinguishing media: Use dry chemical fire extinguisher. Do not use water or halogenated compounds, except that large amounts of water
may be used to deluge small quantities of hydrated lime. Use appropriate extinguishing media for surrounding fire conditions.
Fire fighting instructions: Keep personnel away from and upwind of fire. Wear full fire-fighting and respiratory protection (self-contained
breathing apparatus).

Individual and collective precautions: Avoid creating conditions which release dust – use mechanical
ventilation to remove dust from work spaces:
Avoid inhalation of dust: Wear respiratory protection Dust Mask
Cleaning methods for spills: Use personal protective equipment (eyes, skin and inhalation, see
● Personal Section 8). Use dry methods (vacuuming, sweeping) to collect spilled materials. Avoid generating dust. For large spills,
precautions : evacuate area downwind of clean-up area operations to minimize dust exposure. For small spills, store spilled materials in
dry, sealed plastic or metal containers. Dust residue on surfaces may be washed with water.
Precautions for the protection of the environment: May not be released into surface waters without controls
(increases pH)
Waste Disposal: Dispose according to environmental regulations

● Handling : In open air or in ventilated places, avoid skin and eye contact, avoid creating airborne dust
● Storage Store in dry places sheltered from humidity. Keep away from acids and incompatible substances
requirements : Keep out of reach of children

□
 Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
●Respiratory
Wear Dust Mask.
protection:
●Hand protection Use clean dry gloves
Eye protection (chemical goggles, safety glasses and/or face shield) should be worn where there is a risk of hydrated lime
●Eye protection
exposure. Contact lenses should not be worn when working with lime products
Cover body with suitable clothes (long sleeves shirts and trousers). Use over the ankle waterproof caustic resistant
●Skin protection:
footwear

● pH Value : 12.4 in saturated water ● Boiling Point: 2850°C
solution at 25 Celcius
● Odour and Appearance : Odorless, white powder
● Flammability : Non- Flammable

● Stability: Stable products, not very soluble.
Decomposition temperature: 580oC, forms calcium oxide (CaO) and water
Reactivity: Reacts with acids to form calcium salts while generating heat.
Reacts with carbon dioxide in air to form calcium carbonate.
Conditions to avoid: Vicinity of incompatible materials

● Incompatible materials: Acids; reactive fluoridated, brominated or phosphorous compounds; aluminum (may form hydrogen gas),
reactive powdered metals; organic acid anhydrides; nitro-organic compounds; interhalogenated compounds.

Toxicity: No reported Carcinogenicity, Reproductive Effects, Teratogenicity or Mutagenicity.
Irritancy: Can cause severe irritation of eyes, skin, respiratory tract and gastrointestinal tract.
Chronic Exposure: Inhalation of silica can cause a chronic lung disorder, silicosis.
Alkaline substance that increases pH to a maximum of 12.4 in a saturated water solution at 25o C
Calcium hydroxide gradually reacts with CO2 in air to form calcium carbonate (CaCO3)
Calcium carbonate is ecologically neutral
Uncontrolled spillage in surface waters should be avoided since the increase pH could be detrimental to fish
Harmful to aquatic life in high concentration
● Waste : Dispose according to environmental regulations

● UN Number : Not Applicable
● Emergency
Not Applicable
Response Guide :
Risk Phrases: Risk of serious damage to the eyes, Keep out of reach of children
Safety Phrases: Keep storage container away from humidity, Avoid contact with skin and eyes. In case of contact with eyes, rinse
immediately with water for at least 15 minutes
Hydrated lime can be removed from objects (such as vehicles) using rags dampened with dilute vinegar. After
applying dilute vinegar, vehicles (especially chrome surfaces) must be washed with water.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: LIQUEFIED PETROLEUM GAS ( Shipping Name : Petroleum Gasses Liquefied)

● Emergency Contact No.: 022 22713000,1800222725

HAZARDOUS INGREDIENTS : C.A.S.NO.
Propane : 74-98-6 3
Butane : 106-97-8
Propylene : 115-07-1
● Route of Entry: □ Absorption □ Inhalation □ Ingestion □

 Skin Contact
Autoignition Temperature o C : 466.1 Propane, 405 Butane
Explosion sensitivity to impact : May explode.
Explosion sensitivity to static Electricity : May explode
Hazardous Combustion Products : Emits CO, CO2
Hazardous Polymerization : Will not occur

● Skin Contact : Remove the wetted clothes & wash the affected area with plenty of water.
● Eye Contact : Flush with plenty of water for 15 mins. Seek medical aid immediately.
● Inhalation : If inhaled, remove the victim to fresh air area. Provide artificial resuscitation.
● Ingestion : Not Applicable
● Others None
:
● Fire Extinguishers: Type: DCP /ABC Quantity : Adequate
● Sand Buckets Nos :2
□
 Yes □ No
● Leak & Spill
Shut off leaks if without risk. Warn everybody that air mixture is explosive.
Measures :
Personal Precautions : Do not enter any area where liquefied petroleum gas has been spilled unless tests have shown that it is safe to do
so.
Environmental Precautions: The danger of widespread formation of explosive LPG/Air mixtures should be taken
into account. Accidental ignition could result in massive explosion.
Small spills: DO NOT extinguish the fire unless the leakage can be stopped immediately. Once the fire has been extinguished and all
spills have been stopped, ventilate the area.
Large spills: Stop the source if it can be done without risk. Contain the leaking liquid, with sand or earth, or disperse with special water/fog
spray nozzle. Allow to evaporate. Restrict access to the area until completion of the clean-up procedure. Ventilate the area using forced-
draught if necessary. All electrical equipment must be flameproof.

a. Cylinders containing liquefied petroleum gas should only be handled and stored in the vertical position.
b. Cylinders should never been rolled.
c. Do not allow cylinders to slide or come into contact with sharp edges and they should be handled carefully.
d. Ensure that cylinders are stored away from oxidants.
e. Comply with local legislation..

□
 Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
● pH Value : Not Applicable ● Boiling Point: > - 40 degree celcius
● Odour and Appearance : Colourless gas with an unpleasant odour
● Chemical Stability: Stable
● Conditions to avoid: No reaction with common materials but may react with oxidising materials.

● Effects: Long term Acute: Yes Chronic: No
● Carcinogen Status: Severe cold burns can result in carcinoma
Eye : Liquid in eyes will cause tissue damage. Vapour may cause irritation.
Inhalation : May cause headaches, drowsiness and dizziness. Excessive exposure may cause unconsciousness or even death, due to
asphyxiation (refers to vapour not liquid).
Skin: Liquid may cause frostbite, tissue damage, blisters and wounds.
Ingestion: Due to product form, ingestion is considered highly unlikely.

● Environmental Summary: Vapourised liquefied petroleum gas is heavier than air, and can cause pockets of oxygen-depleted
atmosphere in low-lying areas. It does not pose a hazard to the ecology, unless the gas/air is ignited.

● Waste : Allow gas to burn under control.
● Container : The disposal of cylinders must only be handled by the gas supplier.

UN/ID no. UN1075
Proper shipping name: Petroleum gases, liquefied
● UN Number : Hazard Class : 2.1
Special Provisions : T50
Description : UN1075, Petroleum gases, liquefied, 2.1
● Emergency
Shut off all possible sources of ignition. Clear area of all unprotected personnel.
Response Guide :

LPG is classified as a hazardous substance under Indian regulations. Its storage and handling is covered by various pieces of
legislation.
Avoid contact with oxidisers. Olefinic impurities may lead to narcotic effect or it may act as a simple asphyxiant. A very dangerous hazard
when exposed to heat or flame. If fire is big, keep surrounding areas cool by spraying water.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: PAINT ( Water Base)

BERGER PAINTS INDIA LIMITED, 14 & 15 SWARNAMOYEE ROAD
P.O. BOTANIC GARDEN, Howrah – 711103
● Emergency Contact No.: 91-33-2668-4706 - 09

Naphtha (petroleum)
Hydrodesulphurized heavy
Benzene
● Route of Entry:
 Absorption □
 Eye Contact □ Skin Contact
a. Flammable liquid and vapor.
b. May cause an allergic skin reaction.
c. Suspected of causing cancer.
d. May cause drowsiness or dizziness.
e. Causes damage to organs through prolonged or repeated exposure. (central nervous system (CNS))
f. Toxic to aquatic life with long lasting effects.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any
● Eye Contact :
contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still
present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing
is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous
● Inhalation :
to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center
or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly
● Skin Contact : with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event
of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink.
Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by
● Ingestion : medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical
attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
● Flammable: □
 Yes □ No
DCP,
● Fire Extinguishers: As adequate
Type: CO2,Foam Quantity :
● Sand Buckets Nos : As adequate
□ Yes □ No


Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst,
PROJECT
Specific NAME
hazards / CODE:with
arising ...............................................................................
the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is
from the chemical toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or drain.
Decomposition products may include the following materials:
Hazardous thermal carbon dioxide
decomposition products carbon monoxide
metal oxide/oxides
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action
Special protective actions
shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can
for fire-fighters
be done without risk. Use water spray to keep fire-exposed containers cool.
Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep
● For non-
unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition
emergency
sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear
personnel :
appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
● For emergency If specialized clothing is required to deal with the spillage i.e for suitable and unsuitable materials and also can be refer
responders : "For nonemergency personnel".
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant
● Environmental
authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May
precautions :
be harmful to the environment if released in large quantities. Collect spillage.
Methods and materials for containment and cleaning up
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with
●Small spill water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach
release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g.
●Large spill
sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled
product.

● Protective Put on appropriate personal protective equipment . Persons with a history of skin sensitization problems should not be
measures : employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unlessadequately ventilated. Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be
hazardous. Do not reuse container.
● Advice on
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers
general
should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective
occupational
equipment before entering eating areas.
hygiene. :
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected
● Conditions for
from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and
safe storage,
drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and
including any
sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent
incompatibilities :
leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

□
 Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
●Appropriate Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep
engineering worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need
controls to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
●Environmental Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of
exposure environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process
controls equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the
●Hygiene lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated
measures: clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before
reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary
●Eye/face
to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn,
protection:
unless the assessment indicates a higher degree of protection: safety glasses with sideshields
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove
●Hand protection manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time
( Skin): to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be
accurately estimated.
Personal protective equipment for the body should be selected based on the task being performed and the risks involved
●Body Skin and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity,
Protection wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static
overalls, boots and gloves.
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification.
●Respiratory
Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other
protection:
important aspects of use.

● pH Value : 8.5 – 9.0 ● Boiling Point: Not Applicable
● Odour and Appearance : Mild odour and Viscous liquid ● Flash Point: 26°C (78,8°F)
● Reactivity : No specific test data related to reactivity available for this product or its ingredients.
● Chemical stability: The product is stable.
● Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
● Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
● Incompatible materials: Reactive or with the following materials oxidizing
● Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

PROJECT
● NAMEsignificant
Effects: No known / CODE:effects
...............................................................................
or
Acute: Not immediate Chronic: Skin reaction
critical hazards.
● Carcinogen Status: No toxicity data are available for this product.

● Environmental
No known significant effects or critical hazards.
Summary:
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal
contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all
● Disposal Waste authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when
: recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product
residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do
not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.

● UN Number : Not Prepared
● Emergency Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons
Response Guide : transporting the product know what to do in the event of an accident or spillage.

Not Listed

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: OXYGEN

T-7, MIDC, Industrial Area

Oxygen (99.9 to 100%)
● Route of Entry: □ Eye contact □ Inhalation □ Ingestion □ Skin Contact

● Skin Contact : Adverse effects not anticipated.
● Eye Contact : Adverse effects not anticipated

High concentrations of oxygen (greater than 75%) causes symptoms of hyperoxia which included cramps,
nausea, dizziness, hypothermia, ambylopia, respiration difficulties, bradycardia, fainting spells and convulsions capable of
● Inhalation :
leading to death. The property is that of hyperoxia which leads to pneumonia. Concentrations between 25 and 75% present a
risk of inflammation of organic matter in the body.
● Ingestion : Adverse effects not anticipated.
Experience on humans
Elevated oxygen levels may result in cough and other pulmonary changes. High concentrations of oxygen (greater than 75%) causes symptoms
of hyperoxia which included cramps, nausea, dizziness,hypothermia, ambylopia, respiration difficulties, bradycardia, fainting spells and
convulsions capable of leading to death. Nonflammable. Oxidizer, will accelerate combustion
Remove contaminated clothing and flush affected areas with lukewarm water. If irritation persists, seek medical
● Skin Contact :
attention.
Never introduce ointment or oil into the eyes without medical advice. If pain is present, refer the victim to an
● Eye Contact :
ophthalmologist for treatment and follow up.
PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO
OXYGEN. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING
● Inhalation : APPARATUS. Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick
removal from the contaminated area is most important. Further treatment should be symptomatic and
supportive. Inform the treating physician that the patient could be experiencing hyperoxia.
● Ingestion : Ingestion is not anticipated.

 No
● Fire Extinguishers: Type: Water Quantity :
● Sand Buckets Nos :
□ Yes □
 No
FIRE AND EXPLOSION HAZARDS:
High oxygen concentrations vigorously accelerate combustion.
EXTINGUISHING MEDIA:
Water spray to keep cylinders cool. Extinguishing agent appropriate for the combustible material.
FIRE FIGHTING INSTRUCTIONS:

If possible, stop the flow of oxygen which is supporting the fire.

Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in user’s equipment,be certain to
●Personal
purge piping with inert gas prior to attempting repairs. If leak is in container or container valve,contact the appropriate
precautions :
emergency telephone number listed.

● Handling 1. Oxygen should not be used as a substitute for compressed air in pneumatic equipment since this type generally contains
measures: flammable lubricants.
2. Do not attempt to repair, adjust or in any other way modify the operation of these vessels. If there is a malfunction or other
type of operations problem with the vessel, contact the vendor / supplier.
3. Never carry a compressed gas cylinder or a container of a gas in cryogenic liquid form in an enclosed space such as a car
trunk, van or station wagon. A leak can result in a fire, explosion, asphyxiation or a toxic exposure.
● Storage Store in cool, dry, well-ventilated area away from heavily trafficked areas and emergency exits. Do not allow the temperature
where cylinders are stored to exceed 130o
F (54oC).
Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty
cylinders should be segregated. Use a "first in-first out" inventory system to prevent full cylinders being stored
for excessive periods of time. Post "NO SMOKING OR OPEN FLAMES" signs in the storage area or use area.
There should be no sources of ignition in the storage or use area.

 □ Visor
□
 Goggles □
 Footwear □
PPEs : ENGINEERING CONTROLS:
Use local exhaust to prevent accumulation of high concentrations that increase the oxygen level in air to more
than 25%.
EYE/FACE PROTECTION:
Safety goggles or glasses as appropriate for the job.
SKIN PROTECTION:
Protective gloves made of any suitable material appropriate for the job.
OTHER/GENERAL PROTECTION:
Safety shoes, safety shower.
Physical state (gas, liquid, solid) : Gas
Vapor pressure : Above critical temp.
Vapor density (Air = 1) : 1.11
Evaporation point : Not Available
Boiling point : -297.3 oF to -182.9 oC

● Data relevant to Freezing point : -361.8 oF : -218.8 oC
safety Method : pH : Not Applicable
Specific gravity at STP : Not Available
Oil/water partition coefficient : Not Available

Solubility (H20) : Slightly soluble
Odor threshold : Not Applicable
Odor and appearance : Colorless, odorless gas
● Reactivity: All flammable materials
● Chemical
Stable
stability:

Inhalation : Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of
breathing. Poisoning began in dogs 36 hours after inhalation of pure oxygen at atmospheric pressure. Distress was seen
within 48 hours and death within 60 hours.
● Carcinogen
Eye Contact : The incompletely developed retinal circulation is more susceptible to toxic levels of oxygen. In premature
Status:
infants, arterial oxygen tension above 150 mm Hg may cause retrolental fibroplasia. Permanent
blindness may occur several months later. One case of severe retinal damage in an adult was reported.
An individual suffering from myasthenia gravis developed irreversible retinal atrophy after breathing
80% oxygen for 150 days.

● Environmental Will not bioconcentrate.
Summary: Does not contain ozone depleting chemica

Do not attempt to dispose of residual waste or unused quantities. Return in the shipping container
● Waste : PROPERLY LABELED WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN
PLACE for proper disposal.

● UN Number : UN1072, Proper shipping name: Oxygen, compressed
● Emergency
No PPEs required.
Response Guide :

This product does not contain any chemicals which are subject to the reporting requirements of the Act.
Acute Health Hazard : No
Chronic Health Hazard : No
Fire Hazard : Yes
Sudden Release of Pressure Hazard :Yes
Reactive Hazard : No

Contact with combustible material may cause fire
Contents under pressure
Keep at temperatures below 52°C / 125°F
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: PHENOL (Codes/Label : Poison Class 6)

SHIV CHEMICALS
Near Reva Township, Sanala Road,, Morbi, Gujarat, India - 363641
● Emergency Contact No.: Ph : +91-9825417789, +91-9687620226

Phenol: ORAL (LD50): Acute: 317 mg/kg, 270 mg/kg. DERMAL (LD50)
AFFECTS CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEYS. The major hazard of phenol is its ability to penetrate the skin rapidly,
particularly when liquid, causing severe injury which can be fatal. Phenol also has a strong corrosive effect on body tissue causing
severe chemical burns.
● Route of Entry: □ Absorption □Inhalation □
 Ingestion □
 Skin Contact
Potential Acute Health Effects:
Very hazardous in case of skin contact (corrosive, irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in
case of skin contact (sensitizer, permeator). The amount of tissue damage depends on length of contact. Eye contact can
result in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce
irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can
produce lung damage, choking, unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and
itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
The substance may be toxic to kidneys, liver, central nervous system (CNS). Repeated or prolonged exposure to the substance can
produce target organs damage. Exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can
produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung
damage. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many
human organs.
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least
● Eye Contact:
15 minutes. Cold water may be used. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
● Skin Contact: clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention immediately.
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband.
If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation.
● Inhalation:
WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled
material is toxic, infectious or corrosive. Seek immediate medical attention.
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
● Ingestion: unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
□ Yes □ No

Fire Hazards in Presence of Various Substances:
Flammable
PROJECTin NAME
presence/ CODE:
of open flames and sparks, of heat. Non-flammable in presence of shocks.
...............................................................................
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:

SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards:

Phenol + nitrides results in heat and flammable gas generation. Phenol + mineral oxdizing acids results in fire. Phenol +
calcium hypochlorite is an exothermic reaction producing toxic fumes which may ignite.
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call
for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the
MSDS and with local authorities.
Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers
pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest.
● Handling : Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin
and eyes. Keep away from incompatibles such as oxidizing agents, acids.
● Storage Air Sensitive. Sensitive to light. Store in light-resistant containers. Moisture sensitive. Keep container tightly closed.
requirements : Keep container in a cool, well-ventilated area.

□
 Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
●Engineering
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
Controls:
airborne contaminants below the exposure limit.
●Personal Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or
Protection: equivalent. Gloves.
●Personal
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be
Protection in
used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
Case of a Large
BEFORE handling this product.
Spill:
● pH Value : Not available ● Boiling Point: 182°C
Distinct, aromatic, somewhat sickening sweet and

● Odour and Appearance : acrid
Colour less to light pink
Easily soluble in methanol, diethyl ether. Soluble in cold water, acetone. Solubility in water: 1g/15 ml water. Soluble
in benzene. Very soluble in alcohol, chloroform, glycerol, petroleum, carbon disulfide, volatile and fixed oils, aqueous
● Solubility :
alkali hydroxides, carbon tetrachloride, acetic acid, liquid sulfur dioxide. Almost insoluble in petroleum ether. Miscible
in acetone. Sparingly soluble in mineral oil.

PROJECT
● NAME
Stability: The / CODE:
product is stable...............................................................................
Conditions of Instability: Heat, ignition sources (flames, sparks), light, incompatible materials
Corrosivity: Extremely corrosive in presence of copper. Slightly corrosive in presence of stainless steel(304), of stainless steel(316).
Noncorrosive in presence of glass, of aluminum.
Reactivity: Air and light sensitive. Prone to redden on exposure to light and air. Incompatible with aluminum chloride, peroxydisulfuirc
acid, acetaldehyde, sodium nitrite, boron trifluoride diethyl ether + 1,3-butadiene, isocyanates, nitrides, mineral oxidizing acids, calcium
hypochlorite, halogens, formaldehyde, metals and alloys, lead, zinc, magnesium and their alloys, plastics, rubber, coatings, sodium
nitrate + trifluoroacetic acid. Phenol + isocyanates results in heat generation, and violent polymerization.
Phenol + 1,3-butadiene and boron trifluoride diethyl ether complex results in intense exothermic reaction. Phenol +
acetaldehyde resultes in violent condensation.
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Chronic Effects on Humans: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: kidneys, liver, central
nervous system (CNS).
Other Toxic Effects on Humans: Very hazardous in case of skin contact (corrosive, irritant), of ingestion, . Hazardous in case of skin
contact (sensitizer, permeator), of eye contact (corrosive), of inhalation (lung corrosive)
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation
products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
● Waste : Waste must be disposed of in accordance with federal, state and local environmental control regulations

DOT Classification: CLASS 6.1: Poisonous material.
● UN Number :
Identification: : Phenol, solid UNNA: 1671 PG: II
● Emergency
Not Available
Response Guide :

May cause sensitization by skin contact.
Harmful to aquatic organisms.
Keep locked up and out of the reach of children.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: PETROL (Shipping name: Gasoline, Petrol)

● Emergency Contact No.: 022 22713000,1800222725

Chemical classification: Flammable liquid
Formula: mixture of hydrocarbons

excessive inhalation Vapors cause rapid breathing, excitability, staggering, headache ,fatigue ,nausea and
Inhalation:
vomiting, dizziness, drowsiness, narcosis convulsions, coma,
Ingestion: May be Skin ingestion
Skin Contact: Skin-dryness, cracking, irritation eyes watering, stinging and inflammation.

● Skin Contact : in case of contact with Skin flush with fresh water, remove containment clothing.
● Eye Contact : Not Applicable
in case of excessive inhalation move the victim to fresh air, If problem in breathing give artificial respiration; give
● Inhalation :
oxygen. obtain medical assistance
● Ingestion :Give water to conscious victim to drink; do not induce vomiting.
● Others Emergency treatment: in case of contact with Skin flush with fresh water, remove containment clothing, in case of
: excessive inhalation move the victim to fresh air, obtain medical assistance.

Foam, Carbon dioxide, Dry Chemical Powder.
● Fire Extinguishers: Type:
Water may be used to cool fire-exposed containers.
● Sand Buckets Nos : As Adequate F.E Quantity As Adequate
:
□ Yes □ No
Shut off leak, if safe to do so, .Keep non-involved people away from spill site.
● Leak & Spill
Eliminate all sources of ignition. Prevent spill entering in to sewers, for Major spillage contact
Measures :
Emergency services
● Fire / Explosion Hazards: Issue warning: “ FLAMMABLE”. Eliminate all sources of ignition.
Unusual hazards: Vapor heavier than Air it will spread along the ground and collect in sewers
● Handling Equipment: eliminate all sources of ignition at storage, ensure good ventilation, ground and bond the containners

□
 Glove □ Visor
□
 Goggles □
 Footwear □
● pH Value : Not Applicable ● Boiling Point: 30 to 215 C
● Odour and Appearance : Characteristic odor
● Chemical Stability: Gasoline is complex mixture of hydrocarbons .It’s exact composition depends on the source of
crude oil from which it is produced and the refining methods used
● Conditions to avoid: Explosive material. Avoid all ignition sources.

● Carcinogen Status: on fire it will liberate some amount carbon monoxide, Nitrogen oxide. and other aromatic hydrocarbons. Vapor
heavier than Air it will spread along the ground and collect in sewers

● Environmental Summary: All atmospheric contamination should be kept to as low level as is workable. Exposure Standards should
not be used as fine dividing lines between safe and dangerous concentrations of chemicals. They are no a measure of relatively
toxicity
● Waste : For small quantities :Place in a blast hole and explode during blasting
● Container :
Explosives Limited.
● UN Number : 0030, Class : 1.1 B Explosive, Hazchem: E
Shut off all possible sources of ignition. Clear area of all unprotected personnel. Wear protective equipment to
● Emergency
prevent skin and eye contact. If contamination of sewers or waterways has occurred advise local emergency
Response Guide :
services.
Regulated identification Shipping name: Gasoline, Petrol
Codes/Label: Hazchem code: class 3
Hazardous waste ID No: N.A.
Explosion sensitivity to impact: not sensitive to Mechanical Impact

Explosion sensitivity to static electricity: For vapors sensitivity exist
Hazardous Combustion Products: carbon monoxide, Nitrogen oxide. and other aromatic hydrocarbons
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: PAINT ( Water Base)

BERGER PAINTS INDIA LIMITED, 14 & 15 SWARNAMOYEE ROAD
P.O. BOTANIC GARDEN, Howrah – 711103
● Emergency Contact No.: 91-33-2668-4706 - 09

Type of application: Paint thinning and equipment cleaning
Polymer 50 % Max.
Ethylene Glycol (EG) 15% Max.
Texanol Ester Alcohol 10% Max.
Preservatives 5% Max
● Route of Entry:
□ Absorption □ Inhalation □
 Eye Contact □
 Skin Contact
Inhalation : Vapor or mist can irritate the nose, throat and lungs and cause headache & nausea.
Skin Contact : Irritating to skin upon repeated or prolonged contact.
Eye Contact : Moderately irritating to eyes.

● Inhalation : Move subject to fresh air.
● Eye & Skin Flush eyes with a large amount of water for at least 15 minutes. See a physician, if irritation persists. Wash
Contact : affected skin areas with soap and water.
If swallowed, dilute by giving two glasses of water or drink. See a physician. Never give anything by mouth to an
● Ingestion :
unconscious person.
 No
● Fire Extinguishers: Type: NA Quantity : NA
● Sand Buckets Nos : NA
□ Yes □
 No
Steps to be taken in case material is released or spilled Keep spectators away. Floor may be slippery, use care to
● Personal avoid falling. Dike and contain spill with inert material (e.g. sand, earth). Transfer liquid to containers for recovery
precautions : or disposal and solid diking material to separate containers for disposal. Keep spills and cleaning run-offs out of
municipal sewers and open bodies of water

● Precautionary
Labeling : Keep from freezing — product may coagulate.
Max. 60°C/140°F
● Storage Temp. :
Min. 10°C/34°F

□
 Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
●Ventilation Type Mechanical, local exhausts ventilation at point of contaminated release.
●Respiratory
Wear suitable respirator where exposure limits are exceeded.
Protection
●Protective
Thin rubber gloves
Gloves:
●Eye protection Chemical Splash goggles.

● pH Value : 8.5 – 9.0 ● Boiling Point: Variable
● Odour and Appearance : Mild odour and Viscous liquid

● Chemical Stability: Stable
● Conditions to avoid: Temperature above 150°C

● Carcinogen Status: No toxicity data are available for this product. The effect of over exposure based on information about similar
materials.

● Environmental
No experimental data of the product available.
Summary:
Incinerate the liquid and the contaminated diking material at permitted facility according to local, state and Federal
● Waste :
regulations.
● UN Number : Not Prepared
● Emergency
This is a water based composition and does not pose fire hazards or explosion hazards to the carrier.
Response Guide :
Contact us for the latest information.

Does not contain Titanium dioxide and inorganic filler. Contains metallic pigments
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: POLYMER
STAR DRILLING FLUIDS
307, Avior Building, Nirmal Galaxy, LBS Marg, Mulund West
Mumbai-400080
Identification of the preparation: Anionic water-soluble polymer.
● Route of Entry: □ Absorption □ Inhalation □ Ingestion □

 Skin Contact
Skin Contact: Not Applicable
Note : Aqueous solutions or powders that become wet render surfaces extremely slippery.
● Skin Contact : Wash with water and soap as a precaution. In case of persistent skin irritation, consult a physician.
Rinse thoroughly with plenty of water, also under the eyelids. In case of persistent eye irritation, consult a
● Eye Contact :
physician.
● Inhalation : Move to fresh air.
● Ingestion : The product is not considered toxic based on studies on laboratory animals.

● Fire Extinguishers: Water, Water Spray, Foam, Carbon dioxide (CO2), Dry powder.
Type:
□ Yes □
 No
Special fire-fighting precautions: Aqueous solutions or powders that become wet render surfaces extremely slippery.

PROJECT
● Personal NAME / CODE: ...............................................................................
No special precautions required.
precautions:
●Environmental
Do not contaminate water.
precautions:
● Methods for Do not flush with water. Clean up promptly by scoop or vacuum. Keep in suitable and closed containers for
cleaning up: disposal. After cleaning, flush away traces with water.

● Handling : Avoid contact with skin and eyes. Avoid dust formation. Do not breathe dust. Wash hands before breaks and at the
end of work day.
● Storage: Keep in a dry, cool place (0-35°C).

□ Mask □
 □ Visor
□
 Goggles □
Engineering Engineering measures to reduce Use local exhaust if dusting occurs. Natural ventilation is adequate in exposure:
Controls : absence of dusts.
Personal a. Dust safety masks are recommended where concentration of total dust is more than 10 mg/m3.
protection b. Hand protection: Rubber gloves.
equipment c. Eyes protection: Safety glasses with side-shields. Do not wear contact lenses.
Respiratory d. Skin and body protection: Chemical resistant apron or protective suit if splashing or repeated contact with
protection: solution is likely.
Hygiene Wash hands before breaks and at the end of workday. Handle in accordance with good industrial hygiene and
measures: safety practice.
● pH Value : Not Applicable ● Boiling Point:
● Odour and Appearance : Colourless Gas
● Flammability : 9.6
Form: Granular solid
Colour : White
Odour : NoneStable
pH: 4 - 9 @ 5 g/l for product series.
Melting point (°C): Not applicable.
● Chemical
Flash Point (°C): Not applicable.
Stability:
Auto Ignition Temperature (°C): Not applicable.
Vapour Pressure (mm Hg): Not applicable.
Bulk density: 0.7 - 0.9 g/cm3
Water solubility: soluble.
Brookfield Viscosity (mPa.s): 1100 - 1400 @ 5.0 g/L.
Stability: Product is stable, no hazardous polymerization will occur.

● Stability and
Materials to avoid: Oxidizing agents may cause exothermic reactions.
Reactivity:
Hazardous decomposition products: Thermal decomposition may produce: nitrogen oxides (NOx), carbon oxides.

Acute Toxicity: Oral: LD 50 / oral / rat > 5000 mg/kg. Chronic: No
• Dermal: The results of testing on rabbits showed this material to be non-toxic even at high dose levels.
• Inhalation: The product is not expected to be toxic by inhalation.
Irritation to
• Skin: The results of testing on rabbits showed this material to be non-irritating to the skin.
● Carcinogen • Eyes: Testing conducted according to the Draize technique showed the material produces no corneal or iridial
Status: effects and only slight transitory conjuctival effects similar to those which all granular materials have on
conjuctivae.
Sensitization: The results of testing on guinea pigs showed this material to be non-sensitizing.
Chronic toxicity: A two-year feeding study on rats did not reveal adverse health effects. A one-year feeding study
on dogs did not reveal adverse health effects.

Ecotoxicity • Fish: LC50 /Danio rerio/96h > 100 mg/L (OCDE 203)
• Algae: IC50/Scenedesmus subspicatus/72h> 100 mg/L (OCDE 201)
● Environmental
• Daphnia: EC/Daphnia magna/48 h > 100 mg/L (OCDE 202)
Summary:
Hydrolyze: Not expected to hydrolyse. Biodegradation: Not readily biodegradable Log Pow: 0 Bioaccumulation:
None

● Waste : Waste from residues / unused products: In accordance with local and national regulation
Contaminated packaging: Rinse empty containers with water and use the rinse water to prepare the working
● Container :
solution. Can be landfilled or incinerated, when in compliance with local regulations.
Not classified as dangerous in the meaning of transport regulations.

This product is not a hazardous article and need not to be labelled according to EC-Directives as amended.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal
and release, and is not to be considered as a warranty or quality specification. The information relates only to the specific material
designated andmay be valid for such material used in combination with any other materials or in any process unless specified in the
text.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: Portland Cement Raw Materials
ACC LTD, Gagal Cement Works, ACC LTD.
Product Codes: Portland Cement Type I, IA, II, III, IV, V, White Cement. CSA Type 10, 20, 30, 40, & 50. This MSDS covers many products.
Individual constituents will vary.
● Emergency Contact No.: Emergency Information: (CHEMTREC),

Health Transportation

Chemical Family: Chemical compounds. Calcium silicate components and other calcium compounds containing iron and aluminum make up
the majority of this product.
Chemical Name and Synonyms: Portland cement. Portland cement is also known as hydraulic cement.
Component (%):
Tri-calcium silicate (20-70) , Di-calcium silicate (10-60), Tetra-calcium- alumino-ferrrite (5-15), Calcium sulfate (2-10)
Tri-calcium Aluminate (1-15), Magnesium oxide (0-4), Nuisance Dusts, Crystalline Silica (Quartz) * (0-1%), Hexavalent Chromium (measured
as chromic acid and chromates)

 Ingestion □
 Skin Contact
●Effects resulting
Exposure to airborne dust may cause immediate or delayed irritation or inflammation.Eye contact with larger amounts of
from eye contact:
dry powder or splashes of wet Portland cement may cause effects ranging from moderate eye irritation to chemical burns
and blindness. Such exposures require immediate first aid (see section IV) and medical attention to prevent significant
damage to the eye.
from skin contact: Discomfort or pain cannot be relied upon to alert a person to a hazardous skin exposure. Consequently, the only effective
means of avoiding skin injury or illness involves minimizing skin contact, particularly contact with wet cement. Exposed
persons may not feel discomfort until hours after the exposure has ended and significant injury has occurred. Exposure to
dry Portland cement may cause drying of the skin with consequent mild irritation or more significant effects attributable to
aggravation of other conditions. Dry portland cement contacting wet skin or exposure to moist or wet portland cement
may cause more severe skin effects including thickening, cracking or fissuring of the skin. Prolonged exposure can cause
severe skin damage in the form of (caustic) chemical burns. Some individuals may exhibit an allergic response (e.g.,
allergic contact dermatitis) upon exposure to portland cement, possibly due to trace amounts of chromium. The response
may appear in a variety of forms ranging from a mild rash to severe skin ulcers. Persons already sensitized may react to
the first contact with the product. Other persons may experience this effect after years of contact with portland cement
products.
●Effects resulting Portland cement contains small amounts of free crystalline silica. Prolonged exposure to respirable free crystalline silica
from inhalation: can aggravate other lung conditions and cause silicosis, a disabling and potentially fatal lung disease and/or other
diseases. Risk of injury or disease depends on duration and degree of exposure. (Also see “Carcinogenic potential”
below.) Exposure to Portland cement may cause irritation to the moist mucous membranes of the nose, throat, and upper
respiratory system. It may also leave unpleasant deposits in the nose.
Although small quantities of dust are not known to be harmful, ill effects are possible if larger quantities are consumed.
from ingestion:
Portland cement should not be eaten.
• Carcinogenic
NTP, OSHA, or IARC has not listed Portland cement as a carcinogen. It may, however, contain trace amounts of
potential:
substances listed as carcinogens by these organizations. Crystalline silica, which is present in Portland cement in small
amounts, has been listed by IARC and NTP as a known human carcinogen (Group I) through inhalation. Hexavelant
chromium is listed by IARC, EPA, NTP and OSHA as Group I known carcinogen by inhalation.

Wash skin with cool water and pH-neutral soap or a mild detergent. Seek medical treatment in all cases of prolonged
● Skin Contact : exposure to wet cement, wet cement mixtures, wet concrete liquids from fresh cement products, or prolonged wet skin
exposure to dry cement.
Immediately flush eyes thoroughly with water. Continue flushing eye for at least 15 minutes, including under lids, to
● Eye Contact :
remove all particles. Call physician immediately.
Remove to fresh air. Seek medical help if coughing or other symptoms do not subside. (Inhalation of gross amounts of
● Inhalation :
portland cement requires immediate medical attention).
● Ingestion : Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately.
● Others
Advice to Doctor - Treat symptomatically
:
 No
● Fire Extinguishers: Type: Not Required Quantity : NA
● Sand Buckets Nos : Not Required
□ Yes □
 No
● Collect dry material using a scoop. Avoid actions that cause dust to become airborne. Avoid inhalation of dust and contact with skin. Wear
appropriate personal protective equipment as described in Section VIII.
Scrape up wet material and place in an appropriate container. Allow the material to “dry” before disposal. Do not attempt to wash portland
cement down drains.
Dispose of waste material according to local, state, and federal regulations.
● Keep portland cement dry until used. Normal temperatures and pressures do not affect the material. Promptly remove dusty clothing or
clothing which is wet with cement fluids and launder before reuse. Wash thoroughly after exposure to dust or wet cement mixtures or fluids.

□
 Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
Skin Protection: Prevention is essential to avoiding potentially severe skin injury. Avoid contact with unhardened wet portland cement
products. If contact occurs, promptly wash affected area with soap and water. Where prolonged exposure to unhardened portland cement
products might occur, wear impervious clothing and gloves to prevent skin contact. Where required, wear sturdy boots that are impervious to
water to eliminate foot and ankle exposure. Do not rely on barrier creams; barrier creams should not be used in place of impervious gloves
and clothing. Periodically wash areas contacted by dry portland cement or wet cement or concrete with a pH neutral soap. Wash again at
the end of the work. If irritation occurs, immediately wash the affected area and seek treatment. If clothing becomes saturated with wet
concrete, it should be removed and replaced with clean, dry clothing.
Respiratory protection: Avoid actions that cause dust to become airborne. Use local or general ventilation to control exposures below
applicable exposure limits.
Ventilation: Use local exhaust or general dilution ventilation to control exposure within applicable limits.
Eye Protection: In conditions where user may be exposed to splashes or puffs of cement, wear safety glasses with side shields or goggles.
In extremely dusty or unpredictable environments, wear unvented or indirectly vented goggles to avoid eye irritation or injury. Contact lenses
should not be worn when working with portland cement or fresh cement products.

● pH Value : 12 to 13 in Water ● Boiling Point: Not Applicable
● Odour and Appearance : No distinct odour
None. (Although portland cement poses no fire-related hazards, a self-contained breathing apparatus is recommended to
● Flammability :
limit exposure to combustion products when fighting any fire.)

PROJECT NAME
Stability: Stable. / CODE: ...............................................................................
Incompatibility:Wet portland cement is alkaline. As such it is incompatible with acids, ammonium salts, and aluminum metal.
Conditions to avoid: Unintentional contact with water.
Hazardous decomposition: Will not spontaneously occur. Adding water produces (caustic) calcium hydroxide as a result of hydration.
Hazardous polymerization: Will not occur.

● Effects: Portland cement qualifies as a
“hazardous substance” with delayed health Acute: Not immediate Chronic: Internal Body parts
effects
● Carcinogen Status: Portland cement is considered to be a hazardous material under the Hazardous Product Act as defined by the
Controlled Products Regulations (Class E - Corrosive Material) and is therefore subject to the labeling and MSDS requirements of the
Workplace Hazardous Materials Information System (WHMIS).

● Environmental Summary: No recognized unusual toxicity to plants or animals

For small quantities :Place in a blast hole and explode during blastingDispose of waste material according to local, state,
● Waste : and federal regulations. (Since portland cement is stable, uncontaminated material may be saved for future use.)
Dispose of bags in an approved landfill or incinerator.
Hazardous materials description/proper shipping name: Portland cement is not hazardous
Hazard class: Not applicable
● Data : Identification class: Not applicable
Required label text: Not applicable
Hazardous substances/reportable quantities (RQ): Not applicable
Collect dry material using a scoop. Avoid actions that cause dust to become airborne. Avoid inhalation of dust and
● Emergency contact with skin. Wear appropriate personal protective equipment as described in Section VIII.
Response Guide : Scrape up wet material and place in an appropriate container. Allow the material to “dry” before disposal. Do not attempt
to wash portland cement down drains.
Portland cement is considered a “hazardous chemical” under this regulation, and should be part of any hazard communication program.

Portland Cement is the principal ingredient in concrete, which is used worldwide as the main building block of infrastructure construction as
well as for commercial and residential structures.
Air toxics, also referred to as hazardous air pollutants (HAPs), are those pollutants that are known or suspected to cause cancer or other
serious health effects. Portland cement manufacturing is an energy intensive process in which cement is made by grinding and heating a
mixture of raw materials such as limestone, clay, sand, and iron ore in a rotary kiln. The kiln is a large furnace that is fueled by coal, oil, gas,
coke and/or various waste materials. The product (called clinker) from the kiln is cooled, ground, and then mixed with a small amount of
gypsum to produce portland cement.
The main source of air toxics emissions from a portland cement plant is the kiln. Emissions originate from the burning of fuels and heating of
feed materials. Air toxics are also emitted from the grinding, cooling, and materials handling steps in the manufacturing process. Pollutants
regulated under this rule are particulate matter, organic HAP, metals through the control of particulate matter, mercury, acid gases, and
dioxin/furan.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: READY MIX CONCRETE
(Also Known as Concrete Ready Mix, Portland Cement Concrete, Ready Mix Stucco, Ready Mix Grout, Ready Mix, Concrete,
Freshly Mixed Concrete, Colloidal Concrete, Permeable Concrete, Shotcrete, Gunite, Colored Concrete, Flowable Fill, Roller-
Compacted Concrete, Fiber Reinforced Concrete)
● Manufacturer's Name & Address: UltraTech Cement

B Wing, 2nd Floor, Ahura Centre, Mahakali Caves Road, Andheri (East), Mumbai, Maharashtra 400093
● Emergency Contact No.: 070656 63772

Aggregate (crushed stone, sand, gravel, expanded shale) Quartz (crystalline silica)- 60-95%
Hydraulic Cement(s) Portland and/or Slag Cement- 3-20%
Pozzolan ( Artificial Fly Ash & Silica Fume) - 0-11%
Water- 6-13%

● Route of Entry:
□ Absorption □Inhalation □ Ingestion □
 Skin Contact
a. Skin corrosion/irritation
b. Serious eye damage/eye irritation
c. Carcinogenicity
d. Specific target organ toxicity, single exposure
e. Specific target organ toxicity, repeated exposure

Dusts from hardened product may irritate the mouth, nose, throat and lungs. Remove person to fresh air. Dust in
● Inhalation:
throat and nasal passages should clear spontaneously. Contact a physician if irritation persists or later develops.
Immediately flush eye(s) with plenty of clean water for at least 15 minutes, while holding the eyelid(s) open.
● Eye Contact : Occasionally lift the eyelid(s) to ensure thorough rinsing. Beyond flushing, do not attempt to remove material from
eye(s). Contact a physician if irritation persists or later develops.
● Skin contact: Wash off with soap and plenty of water. Remove contaminated clothing. Contact physician if irritation persists
If person is conscious do not induce vomiting. Give large quantity of water and get medical attention. Never attempt
● Swallowed:
to make an unconscious person drink.
Most important symptoms and effects, both acute and delayed

Contact with wet product may result in chemical (caustic) burns and eye injury which may be progressive and could cause blindness.
Wet product may result in chemical burns to the skin. Dust may irritate the skin and respiratory tract. Breathing silica-containing dust for
prolonged periods in the workplace can cause lung damage and a lung disease called silicosis. Symptoms of silicosis may include (but
are not limited to) shortness of breath, difficulty breathing with or without exertion; coughing; diminished work capacity; diminished chest
expansion; reduction of lung volume; right heart enlargement and/or failure.
Indication of any immediate medical attention and special treatment needed

Not all individuals with silicosis will exhibit symptoms of the disease. However, silicosis can be progressive, and symptoms can appear
at any time, even years after exposures have ceased. Persons with silicosis have an increased risk of pulmonary tuberculosis infection.

□ Yes □
● Flammable:  No
● Fire Extinguishers: Type: NA Quantity : NA
● Sand Buckets Nos : NA
□ Yes □
 No
The presence of this material in a fire does not hinder the use of any standard extinguishing medium. Use extinguishing medium for
surrounding fire.

● Personal precautions, protective equipment and emergency procedures
Avoid contact with skin. Wear appropriate protective equipment as described.
● Environmentalprecautions
Prevent further leakage or spillage. Do not let product enter drainage systems where it can harden and clog flow.
● Methods and materials for containment and cleaning up

Scrape wet concrete and place in container. Allow material to dry or solidify before disposal.

● Handling : Respirable crystalline silica-containing dust may be generated during processing, handling, and storage. Use all
appropriate measures of dust control or suppression and Personal Protective Equipment (PPE).
● Storage Keep container tightly closed in a dry and well-ventilated place.

requirements :

□ Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □
●Engineering Minimize splashing through concrete discharge flow rates. While cutting, crushing or grinding hardened concrete,
Measures minimize dust generation through suppression and ventilation methods.
Eye/face protection
Wear appropriate protective eyeglasses or chemical safety goggles as described for eye and face protection
regulations.
Skin protection
Waterproof gloves, rubber boots, and clothing sufficient to protect skin from contact with wet product should be worn.
Clothing saturated from contact with wet product should be removed promptly to prevent continued contact with skin.
●Personal
After working with product, workers should clean their skin with soap and water. Clean clothing should be worn after
protective
showering.
equipment:
Respiratoryprotection
Not required when working with wet product. Activities that generate dust from hardened dry product require the use
of approved dust respirator for the exposure circumstances involved
Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment
must be avoided.
● pH Value : 12 - 13 ● Boiling Point: NA
Odorless, Semi-fluid, flowable paste
● Odour and Appearance :
Color: Usually grey :

● Reactivity : Not reactive under normal use.
● Chemical stability : Stable under recommended storage conditions.
● Possibility of hazardous reactions: No data available
● Conditions to avoid : Exposure to moisture.
● Incompatiblematerials : Unhardened concrete is alkaline and is incompatible with acids, ammonium salts and aluminum metals.
Portland cement dissolves in hydrofluoric acid and produces silicon tetrafluoride gas. Portland cement reacts with water to form silicates
which in turn react with powerful oxidizers such as fluorine, boron triflouride, chlorine triflouride, manganese triflouride and oxygen
diflouride.

Skin corrosion/irritation: Causes severe skin burns
Serious eye damage/eye irritation: Causes serious eye damage
Specific target organ toxicity - single exposure: May cause respiratory irritation
Specific target organ toxicity - repeated exposure: May causes damage to organs (lungs, respiratory system) through prolonged or
repeated exposure (inhalation)
● Environmental
No Data Available
Summary:

Material can be retained until it hardens, and then disposed of as solid waste. Place contaminated materials in
appropriate containers and dispose of in a manner consistent with applicable federal, state, and local regulations.
● Waste : Prevent from entering drainage, sewer systems, and unintended bodies of water. It is the responsibility of the user to
determine, at the time of disposal, whether product meets criteria for hazardous waste. Product uses,
transformations, mixture and processes, may render the resulting material hazardous.
● UN Number : Not Regulated
● Emergency Transport only in accordance with following regulation with Road Transport.
Response Guide :

This product contains a chemical (crystalline silica, chromium, cobalt, nickel) known to cause cancer.

This information only concerns the above mentioned and do not need to be valid if used with other products or in any process. The
information is to our best present knowledge, correct and complete and is given in good faith but without warranty. It remains the
user’s own responsibility to make sure that the information is appropriate and complete for his special use of this product.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: SUPERPOWER 80
SOLAR INDUSTRIES INDIA LIMITED
11, Zade Layout, Bharat Nagar, Amravati Road, Nagpur – 440 033 (M.S.)
Ph:0712-2561000 / 2560010, Fax : 0712-2560202
Works : Village Chakdoh, Tahsil Katol, Districts, Nagpur (M.S.), India
Ph: 07118- 256655, 256656 E-mail: solar @solarexplosives.com
● Emergency Contact No.: Ph:0712-2561000 / 2560010, 07118- 256655 / 256656
Hazardous Ingredients : Ammonium nitrate ( Very High ), S.Nitrate, Inert materials, Sodium perchlorate, Cellulose, starch & other oxygen,
Negative materials, Other inorganic oxidizers, Aluminium powder and Stabilisers- (Low Quantities)
USES : Mining, tunnelling and general blasting where energetic water-resistant explosive is required
● Route of Entry: □ Absorption □

 Inhalation □
 Ingestion □
 Skin Contact
Health Effect: No adverse health effects expected if the product is handled in accordance with this safety data sheet. Symptoms that may
arise if the product is mishandled.
Swallowed: Swallowing of contents can result in nausea, vomiting and mild gastric irritation.
Inhalation: No hazard due to low vapour pressure at ambient temperature.
Eyes: Packaging normally prevents contact, however contents are a moderate eye irritant.
Skin Contact: Packaging normally prevents contact, however contents may cause mild irritation on repeated or prolonged contact.

Wipe material from skin, then wash contaminated skin with plenty of soap and water. Remove contaminated clothing and
● Skin Contact :
wash before reuse. If irritation occurs, seek medical advice.
Immediately irrigate with copious quantities of water for atleast 15 minutes. Eyelids should be held open. Seek immediate
● Eye Contact :
medical assistance.
● Inhalation : Not Applicable
● Ingestion : Not Applicable
● Swallowed Rinse mouth with water. Give plenty of water to drink. Seek medical assistance
:● Advice to Doctor Treat symptomatically as for exposure to nitrates. Over exposure may lead to methaemoglobinaemia. Nitrates can have a
: smooth muscle relaxant effect, which can result in hypertension
□ Yes □ No
● Leak & Spill Clear area of all unprotected personnel. Shut off all ignition sources. In case of a transport accident notify local police and
Measures : SOLAR INDUSTRIES INDIA LIMITED.
● Fire / Explosion Hazards: Explosive. In case of a small fire, if actual explosive is not burning, carefully remove as much explosive as possible to
a safe distance. However, if explosive is burning, evacuate area immediately. Do not fight fire. Decomposes on heating emitting irritating while
fumes of nitrous oxide and ammonium nitrate mist. Brown fumes indicate the presence of toxic oxides of nitrogen.
● Handling and Storage : Classified as 1.1D (EXPLOSIVE). Dangerous substance for the purpose of transport. Refer to relevant regulations for
Explosives should not be loaded with dangerous goods of other classes. Store cases in a well ventilated magazines. Do not subject the product to
impact, friction between hard surfaces or to any form of heating.

□
 Glove □ Visor
□
 Goggles □
 Footwear □
Personal Protection : Avoid repeated and prolonged skin contact. Wear overalls, Safety Shoes and Safety Goggles. Always wash hands before
smoking, eating, drinking or using the toilet Avoid repeated and prolonged skin contact. Wear overalls, Safety Shoes and Safety Goggles. Always
wash hands before smoking, eating, drinking or using the toilet.
● Appearance, odour : Grey to Greyish mixture cartridged in plastic sausages with metal clips at both ends. Mild odour.
● Reactivity : Detonation may occur from heavy impact or excessive heating, particularly under confinement.

● Carcinogen Status: The components in the proportions present are not considered to represent a hazard under conditions of good occupational
work practice.
Under untreated circumstances over exposure to nitrates may lead to methaemoglobinaemia.
Oral LD50 (rat) : 2217 mg/kg – ammonium nitrate

● Environmental Summary: All atmospheric contamination should be kept to as low level as is workable. Exposure Standards should not be used
as fine dividing lines between safe and dangerous concentrations of chemicals. They are no a measure of relatively toxicity

Small quantities of damaged or deteriorated material may be destroyed by inclusion in a blast hole containing good explosives
For large quantities of damaged or deteriorated explosives notify SOLAR INDUSTRIES INDIA LIMITED .
● Waste :
For small quantities :Place in a blast hole and explode during blasting

● UN Number : U.N.NO. : 0241 CLASS : 1.1 D EXPLOSIVE , HAZCHEM : E
● Emergency Shut off all possible sources of ignition. Clear area of all unprotected personnel. Wear protective equipment to prevent skin
Response Guide : and eye contact. If contamination of sewers or waterways has occurred advise local emergency services.

explosives.
The process of deterioration of this material is a gradual crystallization of the composition, generally starting from the outside and moving towards
the center. After prolonged storage a slight crusty shell begins to be apparent before the cartridges are squeezed. The product should be test fired
before use
Manufacturer cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this MSDS
in the context of how the user intends to handle and use the product in the workplace.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: SULPHURIC ACID
Acid Industries.
2, Dev Daya Nagar Society Rd, Shivai Nagar, Thane West, Thane, Maharashtra 400606
● Emergency Contact No.: Ph : 098330 74988
Sulfuric acid is classified for physicochemical hazards and specified as dangerous
Recommended use:
Fertiliser manufacture, battery acid, metal treatment, pH control, acid leaching.
The Extreme Health Hazards Associated with Sulfuric Acid. Concentrated sulfuric acid is extremely corrosive and can cause
serious burns when not handled properly. ... If ingested, this chemical may cause internal burns, irreversible organ damage,
and possibly death .
● Route of Entry: □ Absorption □Inhalation □ Ingestion □

 Skin Contact
Sulfuric acid (98% solution) is classified as hazardous and specified in the NOHSC of Designated Hazardous Substances.
Risk Phrases
1.Toxic by inhalation and if swallowed.
2. Causes severe burns
3. Irritating to eyes, respiratory system and skin.
4. Risk of serious damage to the eyes.
5. Danger of serious damage to health by prolonged exposure.
6. May cause cancer by inhalation.
Safety Phrases
1. Keep locked and out of reach of children.
2. When using do not smoke.
3. Do not breathe fumes, vapour or mist
4. Avoid contact with skin and eyes.
5. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
6. Take off immediately all contaminated clothing.
7. After contact with skin, wash immediately with plenty of water.
8. Do not empty into drains.
9. Never add water to this product.
10. Wear suitable protective clothing, gloves and eye/face protection.
11. In case of fire and/or explosion do not breathe fumes.
12. In case of accident or if you feel unwell seek medical attention immediately (show the label where possible).
SULFURIC ACID (98% SOLUTION) IS CORROSIVE ON CONTACT AND POISONOUS BY INGESTION AND INHALATION OF ITS VAPOUR.
FIRST AID ATTENTION MUST BE GIVEN AS URGENTLY AS POSSIBLE AS OUTLINED BELOW. ALL SUSPECTED SULFURIC ACID BURNS
SHOULD RECEIVE MEDICAL ATTENTION. TRAINING ON HANDLING SULFURIC ACID INCIDENTS USING THIS MSDS SHOULD BE
PROVIDED BEFORE ANY SULFURIC ACID (98% SOLUTION) HANDLING OR USE COMMENCES.

First Aid Facilities:
PROJECT
First NAMEequipment,
aid procedures, / CODE: medication
...............................................................................
and training for the treatment of burns with sulfuric acid should be in place BEFORE the
use commences. Company physician, occupational health nurse and first aid personnel should be aware of the nearest hospitals which
are familiar with the treatment of sulfuric acid burns.
1. Equipment and medication in place should be:
2. Safety shower and eyewash stations immediately accessible in the workplace;
3. Eye-wash bottle;
4. Personal protective equipment for use by first aid personnel;
5. Fresh, clean cool drinking water;
6. Oxygen;
7. thermal blankets for treating patients for shock.
Do not give anything by mouth if victim is losing consciousness, or is unconscious, or convulsing. If victim is
● Swallowed : conscious, rinse mouth thoroughly with water immediately and give water or milk to drink.
DO NOT induce vomiting. Seek urgent medical assistance.
Persons with potential eye exposure should not wear contact lenses. Immediately irrigate with copious
● Eye Contact :
quantities of water, while holding eyelids open, for at least 15 minutes. Seek urgent medical assistance.
Rescuer should wear appropriate personal protection to avoid skin contamination skin and breathing sulfuric
acid fumes or mist. Remove affected persons from exposure. Allow affected person to assume most comfortable
position and keep warm. Keep at rest until fully recovered. If breathing is laboured, or affected person is cyanotic
● Inhalation :
(blue), ensure airways are clear and have a qualified person give oxygen through a
face-mask. If breathing has stopped apply expired air resuscitation immediately. If the affected person suffers
cardiac arrest commence cardio-pulmonary resuscitation immediately. Seek urgent medical attention.
● Skin First aid personnel must avoid contact with this chemical. Wear protective gloves when assisting patient. DO
NOT USE HOT WATER. Immediately wash affected areas with copious amounts of water. Remove all
contaminated clothing and launder before re-use. DO NOT apply creams or ointments.
Seek urgent medical assistance.
Personal Protection By First Aid Personnel
First aid personnel providing first aid treatment to a patient exposed to sulfuric acid (98% solution) should observe the following
precautions for their own personal protection:
1· Avoid contact with contaminated skin, clothing and equipment by wearing protective gloves to prevent contact of sulfuric acid with
skin
2· Wear chemical goggles as a minimum level of eye protection to prevent splashes of sulfuric acid entering eyes;
3· Avoid inhalation of sulfuric acid (98% solution) fumes or mist during rescue in contaminate areas by wearing suitable respiratory
protection;
4· Respiratory protection suggested is: an air supplied breathing apparatus, or positive pressure self-contained breathing apparatus.

 No
● Fire Extinguishers: Type: NA Quantity :
□ Yes □
 No
Product flammability:
Sulfuric acid is non-flammable and non-combustible. However, on contact with most metals, it will liberate hydrogen gas, which is
flammable and (when confined) explosive. Sulfuric acid is an oxyacid with a good oxidizing ability – therefore, contact with cellulose
based products (e.g., paper and cotton), organic solvents and other organic materials may lead to liberation of large quantities of heat.
Suitable extinguishing media

Water fog (or if unavailable, fine water spray), foam, dry chemical powder, or carbon dioxide.
Special protective precautions and equipment for fire fighters

Wear full body protective clothing with breathing apparatus. Prevent spillage from entering drains or waterways. Consider evacuation.
Use water to control fire and cool adjacent area and fire exposed sulfuric acid storage containers. Avoid direct water impingement on
strong acid since this creates heat increasing toxic fume evolution. Do not approach sulfuric acid containers suspected to be hot.
If safe and practicable to do so remove sulfuric acid containers from path of fire. Equipment should be thoroughly decontaminated after
use. Wear self-contained breathing apparatus with a full-face piece operated in pressure-demand or positive
pressure mode.

PROJECT NAME / CODE:
Small Leaks: ...............................................................................
Sulfuric acid fumes: Increase ventilation and allow fumes to vent to a safe area. If possible contain the surface
area of a spill by bunding with sand, earth or vermiculite. Do NOT use sawdust. Dilute spill with water, then
neutralise with lime or soda ash to pH 6 to 10. Prevent run-off into drains and waterways.
● Personal
precautions : Large Leaks
Sulfuric acid fumes: Use water fog to dampen cloud of sulfuric acid (98% solution) fumes and reduce vapours. Do
not spray water directly on the leak or sulfuric acid container. Sulfuric acid liquid: If possible contain the surface
area of a spill by bunding with sand, earth or vermiculite. Do NOT use sawdust. Use water fog to dampen sulfuric
acid fumes and reduce vapours. Prevent run-off into drains and waterways.
● Emergency The hazardous nature of sulfuric acid requires emergency and spill procedures to be effective to avoid both human
Procedure: and environmental exposure. Hazardous conditions may result if material is managed improperly. Make plans in
advance to handle possible emergencies, including obtaining stocks of absorbent materials. Always wear
recommended personal protective equipment and respiratory protection. Good ventilation is necessary. Sulfuric acid
dissolves very readily in water, giving off large quantities of heat. Avoid direct water contact with sulfuric acid leaks.

● Handling :
1. Regulated dangerous goods as Class 8 Corrosive. Proper protective clothing must be worn that encapsulates
the body including the face. A safety shower and eyewash should be available. Do not breathe vapour or mist.
2. Avoid contact with skin, eyes and clothing.
3. Do not add water to sulfuric acid – this may generate spitting and splashing of acid. In dilution process, sulfuric
acid should be added to plenty of water.
4. Do not smoke anywhere near the storage and handling of sulfuric acid (98% solution) or associated pipework
and equipment.
5. Do not touch damaged containers or spilled material unless wearing appropriate personal protective
equipment.
6. Change and wash clothing, and personal protective equipment if contaminated, or before storing and/or reusing.
Wash hands and face thoroughly after handling and before work breaks, eating, drinking, smoking and
using toilet facilities.
● Storage 1. Ensure sulfuric acid in bulk is stored and handled in accordance with Indian legislation. The storage and handling
requirements : of corrosive substances. Ensure adequate ventilation to keep airborne concentration below exposure standard.
Where necessary, use local exhaust ventilation in conjunction with canister respirator, or as appropriate, self
contained breathing apparatus.
2. Store away from strong alkalis, hypochlorites, cyanides, organic and combustible materials.
3. Sulfuric acid is highly corrosive to most metals. Many plastics (except for Teflon - PTFE) do not resist sulfuric
acid.
□
 Mask □
 Respirator □
 Glove □ Visor
□
 Goggles □
 Footwear □

 Material Safety Data Sheet - (MSDS) EHS / 2018 / MSDS - 31
●Engineering Handle sulfuric acid (98% solution) within closed systems whenever possible. Provide adequate ventilation
Measures
PROJECT NAME particularly
/ CODE: at ...............................................................................
low level.
●Personal
protective Whenever the risk of exposure exists, such as tanker loading/unloading procedures, non-routine operations
equipment and emergency circumstances, the following personal protection measure are recommended:
Respiratory protection:
Supplied air or full face mask and filter respirator self contained breathing apparatus may be required if
working with sulfuric acid (98% solution) or if decomposition fumes exits, for prolonged periods.
Hand protection:
PVC or butyl rubber gauntlet-type gloves.
Eye protection:
Chemical splash goggles (gas tight type preferred) and full face shield.
Skin protection:
PVC overalls or jacket and pants and butyl rubber Wellington boots.

● pH Value : 10% solution < 1. ● Boiling Point: 335°C at 101·3 kPa.
● Odour and Appearance : Hygroscopic, viscous clear to brownish liquid.

● Flammability : Not Applicable
● Chemical Stability: Stable at ambient conditions of use and storage.
● Conditions to avoid: Sulfuric acid reacts violently with water, alkalis and most organic materials to liberate large quantities of heat.
Dilute acid on contact with most metals, will liberate hydrogen gas, which is flammable and (when confined) explosive.
Sulfuric acid can react with most metals generating flammable hydrogen gas. Most plastics do not resist concentrated sulfuric acid
greater than 50 to 60% strength.
Releases sulfur dioxide at extremely high temperatures.

● Hazardous reactions:
Sulfuric acid reacts vigorously, violently or explosively with many organic and inorganic chemicals including water, acrylonitrile, alkali
solutions, carbides, chlorates, fulminates, nitrates, perchlorates, permanganates, picrates, metal acetylides or carbides,
epichlorohydrin, aniline, ethylenediamine, alcohols with strong hydrogen peroxide, chlorosulfonic acid, cyclopentadiene, hydrofluoric
acid, nitromethane, 4- nitrotoluene, phosphorus (iii) oxide, potassium, sodium, ethylene glycol, isoprene, styrene. Acetaldehyde and
allyl chloride may polymerise violently in the presence of sulfuric acid . Hazardous gases such as hydrogen cyanide, hydrogen sulfide,
and acetylene, are evolved when sulfuric acid contacts cyanide, sulfides and carbides, respectively.

● Effects: Long term Acute: Destructive Chronic: Internal Body parts
● Carcinogen Status: The International Agency for Research on Cancer (IARC) has concluded that there is sufficient evidence that
occupational exposure to strong inorganic mists containing sulfuric acid is carcinogenic to humans (Group 1)*. Many studies have
reported an excess of cancer of larynx, and to a lesser extent, the lungs, in a variety of processes involving the use of strong inorganic
acids including sulfuric acid. Throughout these studies, sulfuric acid mists were the most common exposure, and in two studies, the
number of cancers increased as exposure increased.
Skin: Highly corrosive to skin. Causes severe burns leading to necrosis and scarring. The severity of injury depends
on the concentration of sulfuric acid (98% solution) and the duration of exposure.
Eye: Corrosive to eyes. Contact may cause corneal burns. Permanent eye damage including loss of sight may occur. Sulfuric acid mists
and aerosols are expected to be very irritating.
Swallowed:
Can kill if swallowed. Will cause severe damage to the mucous membranes. May cause nausea, vomiting, abdominal pain and severe
burns to the mouth, throat, stomach and gastrointestinal tract. LD50 (Oral, rat) = 2,140 mg/kg.

Ecotoxicity:
Sulfuric acid is slightly to moderately toxic to aquatic life. Large discharges into the environment may contribute to lowering of water pH
and be fatal to aquatic life and soil micro-organisms.
Mobility:
Sulfuric acid is soluble in water and has high mobility in soil. During transport through the soil, sulfuric acid will dissolve some of the
soil material; in particular, the carbonate based materials. The acid will be neutralised to some degree with adsorption of the proton
also occurring on clay materials. However, significant amounts of acid are expected to remain for transport down towards the ground
water table. Upon reaching the ground water table, the acid will continue to move, now in the direction of the ground water flow. Lime
addition may be required to rectify low pH resulting from sulfuric acid spillages.

Due to its inherent properties, hazardous conditions may result if material is managed improperly. Dispose of
● Waste : all contained and neutralised spill residue in accordance with Department of the Environment requirements.
● Container : As required under the Indian Legislation, treat empty containers as filled containers.
● UN Number :
1830
● Emergency Transport only in accordance with regulation of Road & Rail Transport.
Response Guide :

Licensing is required for this chemical in some States and Territories
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: SUPERPOWER 90
SOLAR INDUSTRIES INDIA LIMITED
11, Zade Layout, Bharat Nagar, Amravati Road, Nagpur – 440 033 (M.S.)
Ph:0712-2561000 / 2560010, Fax : 0712-2560202
Works : Village Chakdoh, Tahsil Katol, Districts, Nagpur (M.S.), India
Ph: 07118- 256655, 256656 E-mail: solar @solarexplosives.com
● Emergency Contact No.: Ph:0712-2561000 / 2560010, 07118- 256655 / 256656

Hazardous Ingredients: Ammonium nitrate ( Very High ), S.Nitrate, Inert materials, Sodium perchlorate, Cellulose, starch & other oxygen,
Negative materials, Other inorganic oxidizers, Aluminium powder and Stabilisers- (Low Quantities)

 Ingestion □
 Skin Contact
Health Effect: No adverse health effects expected if the product is handled in accordance with this safety data sheet. Symptoms
that may arise if the product is mishandled.
Swallowed:
Swallowing of contents can result in nausea, vomiting and mild gastric irritation.
Inhalation:
No hazard due to low vapour pressure at ambient temperature.
Eyes:
Packaging normally prevents contact, however contents are a moderate eye irritant.
Skin Contact:
Packaging normally prevents contact, however contents may cause mild irritation on repeated or prolonged contact.

Wipe material from skin, then wash contaminated skin with plenty of soap and water. Remove contaminated clothing
● Skin Contact :
and wash before reuse. If irritation occurs, seek medical advice.
Immediately irrigate with copious quantities of water for atleast 15 minutes. Eyelids should be held open. Seek
● Eye Contact :
immediate medical assistance.
● Inhalation :Not Applicable
● Ingestion :Not Applicable
● Swallowed Rinse mouth with water. Give plenty of water to drink. Seek medical assistance
:
● Advice to Doctor Treat symptomatically as for exposure to nitrates. Over exposure may lead to methaemoglobinaemia. Nitrates can
: have a smooth muscle relaxant effect, which can result in hypertension

□ Yes □ No

Material
 Safety Data Sheet - (MSDS) EHS / 2018 / MSDS - 32
● Leak & Spill Clear area of all unprotected personnel. Shut off all ignition sources. In case of a transport accident notify local police
Measures : and SOLAR INDUSTRIES INDIA LIMITED.
● Fire / Explosion Hazards: Explosive. In case of a small fire, if actual explosive is not burning, carefully remove as much explosive as
possible to a safe distance. However, if explosive is burning, evacuate area immediately. Do not fight fire. Decomposes on heating
emitting irritating while fumes of nitrous oxide and ammonium nitrate mist. Brown fumes indicate the presence of toxic oxides of nitrogen.

● Handling and Storage : Classified as 1.1D (EXPLOSIVE). Dangerous substance for the purpose of transport. Refer to relevant
regulations for storage and transport requirements.
Explosives should not be loaded with dangerous goods of other classes. Store cases in a well ventilated magazines. Do not subject the
product to impact, friction between hard surfaces or to any form of heating.

□
 Glove □ Visor
□
 Goggles □
 Footwear □
Personal Protection : Avoid repeated and prolonged skin contact. Wear overalls, Safety Shoes and Safety Goggles. Always wash hands
before smoking, eating, drinking or using the toilet Avoid repeated and prolonged skin contact. Wear overalls, Safety Shoes and Safety
Goggles. Always wash hands before smoking, eating, drinking or using the toilet.

● Appearance, odour : Grey to Greyish mixture cartridged in plastic sausages with metal clips at both
ends. Mild odour.
● Reactivity : Detonation may occur from heavy impact or excessive heating, particularly under confinement.

● Carcinogen Status: The components in the proportions present are not considered to represent a hazard under conditions of good
occupational work practice.
Under untreated circumstances over exposure to nitrates may lead to methaemoglobinaemia.
Oral LD50 (rat) : 2217 mg/kg – ammonium nitrate


Small quantities of damaged or deteriorated material may be destroyed by inclusion in a blast hole containing good
explosives
● Waste :
For small quantities :Place in a blast hole and explode during blasting.

● UN Number : 1.1D (EXPLOSIVE)

The Explosives Rules,1983 were framed to regulate the manufacture, possession, sale, use, transportation, importation etc. of
condensed explosives.

The process of deterioration of this material is a gradual crystallization of the composition, generally starting from the outside and moving
towards the center. After prolonged storage a slight crusty shell begins to be apparent before the cartridges are squeezed. The product
should be test fired before use
Manufacturer cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review
this MSDS in the context of how the user intends to handle and use the product in the workplace
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: SOLARCORD CORRECT SHIPPING NAME: DETONATING CORD
ECONOMIC EXPLOSIVES LIMITED, 11, Zade Layout, Bharat Nagar, Amravati Road, Nagpur – 440 033 (M.S.), Ph: 0712-2561000 / 2560010, Fax
: 0712-2560202
Cords consist of continuous PETN explosive core enclosed in plastic tapes, fibres, and a plastic sleeve.
Chemical Entity : Pentaerythritol Tetranitrate (PETN)
USES : Detonating cord for initiating charges
● Route of Entry: □ Absorption □ Inhalation □

Swallowed : Swallowing the PETN core may result in nausea, vomiting and mild gastric irritating
Inhalation: Not an inhalation hazard
Eye Contact: Exposure to the PETN core may result in mild eye irritation. The core can cause physical irritation to the eyes.
Skin Contact: The PETN core may be a milk skin sensitiser. The packaged Material is not irritating to skin.
Long term exposure to lead has resulted in kidney damage, anaemia and central nervous system and peripheral nervous
Chronic Effects:
system damage.
● Skin Contact : Wash contaminated skin with plenty of soap and water. If irritation occurs, seek medical advice
● Eye Contact : Irrigate with copious quantities of water for 15 minutes. In all cases of eye contamination it is a sensible precaution to seek medical ad
● Inhalation : Not Applicable
● Ingestion : Rinse mouth with water. Give plenty of water to drink. If vomiting occurs give further water. Seek medical advice
● Advice to Treat symptomatically. Where ingestion of the PETN core has occurred blood pressure may be lowered due to vasodilatory
Doctor: effects of the material. Treat as for exposure to nitrates.
□ Yes □ No
● Leak & Spill
Shut off all possible sources of ignition. Collect and seal in labelled packages for disposal. Handle with care.
Measures :
● Fire / Explosion Hazards: High Explosives. Severe explosion hazard when exposed to heat. In case of small fire where actual exposure is not
burning. Carefully removes much explosive as possible to a safe distance. However, if explosive is burning evacuate area immediately. Do Not
fight fire. Under confined conditions toxic fume of oxides of nitrogen and Carbon monoxide will be present.

● Handling Equipment: Storage and Transport
UN NO:0065 Classified as a 1.1D (Explosive). Dangerous substance for the purpose of transport. Refer to relevant regulations for storage and
transport requirements.
Explosives should not normally be carried on the same vehicle with dangerous goods of other classes. Store cases in a well ventilation clean, dry
magazine suitably licenced for IMCO Class 1.1D Explosives. Protect ends of cords from contact with moisture or oil. Handle with care

□
 Glove □ Visor
□
 Goggles □
 Footwear □
Engineering Controls : Natural ventilation should be adequate under normal use conditions.
Personal Protection : Avoid eye contact and repeated or prolonged skin contact with the PETN core. Were overalls, safety glasses and impervious
gloves. Always wash hands before smoking, eating,drinking or using the toilet.
● Conditions to avoid: Explosive material. Detonation can occur from heavy impact.

● Carcinogen Status: Long term exposure to lead has resulted in kidney damage, anaemia and central nervous system and peripheral nervous
system damage.
● Environmental Summary: All atmospheric contamination should be kept to as low level as is workable. Exposure Standards should not be used
as fine dividing lines between safe and dangerous concentrations of chemicals. They are no a measure of relatively toxicity

Controlled incineration as for explosives. Large quantities to be disposed off in conjunction with the relevant State Dangerous
● Waste :
Goods Branch & Solar Explosives Limited.
Large quantities to be disposed off in conjunction with the relevant State Dangerous Goods Branch & Economic Explosives
● Container :
Limited.
● UN Number : UN NO:0065 Classified as a 1.1D (Explosive)
● Emergency Shut off all possible sources of ignition. Clear area of all unprotected personnel. Wear protective equipment to prevent skin and
Response Guide : eye contact. If contamination of sewers or waterways has occurred advise local emergency services.

explosives.
ACUTE EFFECTS
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms may arise
if the product is mishandled.
Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: THINNER

Grand Polycoats Co. Pvt. Ltd., 204, Siddharth Complex, R.C. Dutt Road, Baroda – 390 007
Gujarat (India)
● Emergency Contact No.: Ph : (0265)2300912/2340682
Type of application: Paint thinning and equipment cleaning
Xylene (mixture of Isomer) (40 – 50 %)
Butyl acetate (20 - 25 %)
Cellosolve acetate (20 - 25 %)
● Route of Entry: □ Absorption □Inhalation □ Ingestion □

 Skin Contact
Absorption: Harmful
Inhalation: Harmful by inhalation and in contact with skin.
Ingestion: Harmful to aquatic organism, may cause long term adverse effects
Skin Contact: Irritating to skin.
Remove contaminated clothing and shoe immediately. Wash with soap or mild detergent and large amounts of water
● Skin Contact : until no evidence of chemical remains, recognized skin cleanser may be used for cleaning large area. Apply skin
cream. Small splash can be cleaned off with cleaning emulsion or cooking oil.
Remove contaminated clothing and shoe immediately. Wash with soap or mild
detergent and large amounts of water until no evidence of chemical remains, recognized skin cleanser
● Eye Contact :
may be used for cleaning large area. Apply skin cream. Small splash can be cleaned off with cleaning
emulsion or cooking oil.
Remove from exposure area fresh air immediately, Keep person warm and at rest. If breathing is irregular perform
● Inhalation :artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give
nothing by mouth Treat symptomatically and supportively.
Do not induce vomiting. If vomiting occurs, keep head lower than hips to help prevent
● Ingestion :
aspiration. Get medical attention immediately
● Others- General In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an
unconscious person.
□ Yes □ No
Extinguishing media: Dry chemical powder, Foam or Carbon dioxide
Unsuitable extinguishing media: Water jet since water may cause the fire of a combustible material to spread. Do not allow run off water
and contaminants from fire fighting to enter drains or watercourses.
Hazardous combustion products: Thermal decomposition products may include toxic product of carbon and nitrogen. Decomposition
products may be hazardous to health. Avoid exposure and use breathing apparatus as appropriate.

● Personal Smoking, work causing sparks, welding or similar work near the area must be ceased immediately. Ventilate the area
precautions : and avoid breathing solvent vapours.
● Envionmental Do not allow the product to enter drains or water courses or soil.
Precautions:
●Method of Collect as much as possible in a clean container for (preferable reuse or disposal. Absorb the remainder with
cleaning up: absorbing media like Vermiculite, saw dust
● Handling : The usual precautions for handling chemicals should be observed. Areas of storage, preparation and application
should be ventilated to prevent the creation of flammable or explosive concentrations of vapor in air and avoid vapor
concentrations higher than the occupational exposure limits. Handle containers carefully to prevent damage and
spillage
Observe all federal, state and local regulations while storing this substance. Store away from incompatible substance
and source of ignition or fire.
Never use pressure to empty a container; containers are not pressure vessels.
The product may charge electrostatically. Always use earthing leads when pouring solvents and transferring product.
Operators should wear clothing, which does not generate static (at least 60% natural fiber) and antistatic footwear;
floors should be of conducting type.
● Storage Store in a dry, well-ventilated and cool place. Keep the container upright and tightly closed and away from source of
requirements : ignition, naked flames and foodstuff. Opened container should be resealed properly and stored properly.
Smoking, eating and drinking should be prohibited in all preparation and application areas.

□
 Glove □ Visor
□
 Goggles □
 Footwear □
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any
●Engineering vapor below occupational exposure limits suitable respiratory protection must be worn.
Measures
The workers must be instructed thoroughly. Provide adequate ventilation. If the general extraction is insufficient,
●Occupational efficient local exhaust must be provided. Work is whenever possible to be done in a spray booth or similar.
exposure controls
If working areas have insufficient ventilation, wear half or totally covering mask equipped with gas filter of type
A(brown), when grinding with particle filter of type P2. When spraying wear a combined filter Ap. In continuous and
●Respiratory prolonged work isolating protection(e.g hood with supply of fresh or compressed air) or motor driven fan protection is
protection: recommended.
Employee must wear appropriate protective gloves to prevent contact with this substance. Preferably use nitrile or
butyl rubber gloves or 4H, if the product comes into contact with skin, change the gloves immediately when the first
●Hand protection
sign of decomposition appear. Always contact supplier of gloves for information on the breakthrough time and for
recommendation of best quality of gloves.
●Eye protection Eyes must be protected when using spray application. Use appropriate spectacles
●Skin protection: When using spray application suitable protective clothing should be used.
●Engineering
The usual precautionary measures for handling chemicals should be observed. Good ventilation should be sufficient.
Measures

● pH Value : Not Applicable ● Boiling Point: 315 °C
● Odour and Appearance : Liquid, colorless and odour of solvent


● Chemical Stability: Stable under recommended storage and handling conditions. When exposed to high temperatures
may produce hazardous decomposition products such as carbon monoxide, carbon dioxide, oxides of nitrogen and smoke.
● Conditions to avoid: Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid
possible exothermic reactions.

● Carcinogen Status: Exposure to solvent vapor concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and
adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular
weakness, drowsiness and in extreme cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and
possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause
irritation and soreness with possible reversible damage.

● Environmental
Paint products must be handled carefully and they may not be allowed to enter drains, watercourse or soil.
Summary:

The waste is collected and disposed of in accordance with local regulations. Liquid waste must be transported to
● Waste :
facilities for collecting hazardous waste or to other similar place to be disposed of as hazardous waste.
● Container : Large quantities to be disposed off in conjunction with the relevant State rules and regulation.
UN No 1263 MFAG - Packing Group III

● UN Number :
Marine Pollutant Yes
Packing Group III
Response Guide : Proper Shipping Name Thinner

The following information is provided as a summary of the information contained in this MSDS.
Symbol (S)- Harmful , Contains: R Phrase and Flammable
Harmful: May Cause lung damaged if swallowed

Do not breath vapour/spray
Avoid contact with skin
Wear eye / face protection
Use only in well ventilated areas

Assesed By:
Name: .................................................................. Date: ..............................................................


● PRODUCT NAME: MILD STEEL COVERED ELECTRODES ( Application: Arc Welding )
ESAB INDIA LIMITED
Plot No.13, 3rd Main Road,
Industrial Estate, Ambattur,
Chennai - 600 058.
● Emergency Contact No.: Ph : +91 - 44 - 42281100
Aluminum Oxide, Calcium Carbonate, Iron, Mineral Silicates, Titanium Oxide , Zirconium Compounds , Manganese , Potassium
Titanate etc.

● Route of Entry:
□ Absorption □Inhalation □ Ingestion □
 Skin Contact
Emergency Overview:
Coated metal rods in varying colors. These products are normally not considered hazardous as shipped. Gloves should be worn when
handling to prevent contaminating hands with product dust. These products contain titanium dioxide which is possibly carcinogenic.
These products contain quartz, but normally not in an inhalable fraction. Quartz can cause silicosis and may cause cancer. Avoid eye
contact or inhalation of dust from these products. Skin contact is normally no hazard but should be avoided to prevent possible allergic
reactions.
Persons with a pacemaker should not go near welding or cutting operations until they have consulted their doctor and obtained
information from the manufacturer of the device.When these products are used in a welding process, the most important hazards are
heat, radiation, electric shock and welding fumes.
Heat: Spatter and melting metal can cause burn injuries and start fires.
Radiation: Arc rays can severely damage eyes or skin.
Electricity: Electric shock can kill.
Fumes: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or irritation of
the nose, throat or eyes. Chronic overexposure to welding fumes may affect pulmonary function. Overexposure to
manganese and manganese compounds above safe exposure limits can cause irreversible damage to the central
nervous system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, muscular
weakness, psychological disturbances and spastic gait.
If breathing has stopped, perform artificial respiration and obtain medical assistance immediately! If breathing is
● Inhalation: difficult, provide fresh air and call physician.
For radiation burns due to arc flash, see physician. To remove dusts or fumes flush with water for at least fifteen
● Eye Contact : minutes. If irritation persists, obtain medical assistance.
For skin burns from arc radiation, promptly flush with cold water. Get medical attention for burns or irritations that
● Skin contact:
persist. To remove dust or particles wash with mild soap and water.
Disconnect and turn off the power. Use a nonconductive material to pull victim away from contact with live parts or
● Electric shock: wires. If not breathing, begin artificial respiration, preferably mouth-to-mouth. If no detectable pulse, begin Cardio
Pulmonary Resuscitation (CPR). Immediately call a physician.
● General Move to fresh air and call for medical aid.

□ Yes □ No
● Flammable:

□ Yes □ No
No specific recommendations for welding consumables. Welding arcs and sparks can ignite combustible and flammable materials. Use
the extinguishing media recommended for the burning materials and fire situation. Wear self-contained breathing apparatus as fumes
or vapors may be harmful.
● Personal Solid objects may be picked up and placed into a container. Liquids or pastes should be scooped up and placed
precautions : into a container. Wear proper protective equipment while handling these materials. Do not discard as refuse.

● Handling : Handle with care to avoid stings and cuts. Wear gloves when handling welding consumables. Avoid exposure to
dust. Do not ingest.
Some individuals can develop an allergic reaction to certain materials. Retain all warning and identity labels.
Storage: Keep separate from chemical substances like acids and strong bases, which could cause chemical
reactions.
● Storage Store in a dry, well-ventilated and cool place. Keep the container upright and tightly closed and away from source
requirements : of ignition, naked flames and foodstuff. Opened container should be resealed properly and stored properly.
Smoking, eating and drinking should be prohibited in all preparation and application areas.

□
 Glove □ Visor
□
 Goggles □
 Footwear □
Ensure sufficient ventilation, local exhaust, or both, to keep welding fumes and gases from breathing zone and
●Engineering general area. Keep working place and protective clothing clean and dry. Train welders to avoid contact with live
Measures electrical parts and insulate conductive parts. Check condition of protective clothing and equipment on a regular
basis.
Use respirator or air supplied respirator when welding or brazing in a confined space, or where local exhaust or
●Personal
ventilation is not sufficient to keep exposure values within safe limits. Use special care when welding painted or
protective
coated steels since hazardous substances from the coating may be emitted. Wear hand, head, eyes, ear and body
equipment:
protection like welders gloves, helmet or face shield with filter lens, safety boots, apron, arm and shoulder
protection. Keep protective clothing clean and dry.

● pH Value : Not Applicable ● Boiling Point: >1300°C/>2300°F
● Odour and Appearance : Solid, non-volatile with varying color

● Stability: These products are stable under normal conditions.
● Conditions to avoid: Contact with chemical substances like acids or strong bases could cause generation of gas.

Inhalation of welding fumes and gases can be dangerous to your health. Classification of welding fumes is difficult because of varying
base materials, coatings, air contamination and processes. The International Agency for Research on Cancer has classified welding
fumes as possibly carcinogenic to humans
● Acute toxicity: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or
irritation of the nose, throat or eyes.
● Chronic toxicity: Overexposure to welding fumes may affect pulmonary function. Overexposure to manganese and manganese
compounds above safe exposure limits can cause irreversible damage to the central nervous system, including the brain, symptoms of
which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances and spastic gait. Prolonged
inhalation of titanium dioxide above safe exposure limits can cause cancer. Inhalable quartz is a respiratory carcinogen; however, the
process of welding converts crystalline quartz to the
amorphous form which is not considered to be a carcinogen.

Welding consumables and materials could degrade/weather into components originating from the consumables or
● Environmental
from the materials used in the welding process. Avoid exposure to conditions that could lead to accumulation in
Summary:
soils or groundwater.

Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full
● Waste :
compliance with federal and local regulations. Use recycling procedures if available.
● Container : No international regulations or restrictions are applicable.
● UN Number : Not Available
Response Guide :

Read and understand the manufacturer's instructions, your employer's safety practices and the health and safety instructions on the
label. Observe any federal and local regulations. Take precautions when welding and protect yourself and others.
WARNING: Welding fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate
ventilation.
ELECTRIC SHOCK can kill.
ARC RAYS and SPARKS can injure eyes and burn skin.
Wear correct hand, head, eye and body protection.

Assesed By:
Name: .................................................................. Date: ..............................................................


MSDS - ITD Cem PDF

Caricato da

Informazioni sul documento

Titolo originale

Copyright

Formati disponibili

Condividi questo documento

Condividi o incorpora il documento

Opzioni di condivisione

Hai trovato utile questo documento?

Questo contenuto è inappropriato?

Copyright:

Formati disponibili

MSDS - ITD Cem PDF

Caricato da

Copyright:

Formati disponibili

ITD CEMENTATION INDIA LIMITED

1 Acetylene EHS / 2018 / MSDS - 01 R-0 / 30.03.2018 English 3

2 Asphalt EHS / 2018 / MSDS - 02 R-0 / 30.03.2018 English 7

3 Admixture EHS / 2018 / MSDS - 03 R-0 / 30.03.2018 English 11

4 Araldite EHS / 2018 / MSDS - 04 R-0 / 30.03.2018 English 14

5 Bentonite EHS / 2018 / MSDS - 05 R-0 / 30.03.2018 English 18

6 Bleaching Powder EHS / 2018 / MSDS - 06 R-0 / 30.03.2018 English 20

7 Bitumen EHS / 2018 / MSDS - 07 R-0 / 30.03.2018 English 23

8 Carbolic Acid EHS / 2018 / MSDS - 08 R-0 / 30.03.2018 English 27

9 Curing Compound EHS / 2018 / MSDS - 09 R-0 / 30.03.2018 English 30

10 Dendrite EHS / 2018 / MSDS - 10 R-0 / 30.03.2018 English 32

11 Ecodet EHS / 2018 / MSDS - 11 R-0 / 30.03.2018 English 36

12 Engine Oil-20W40 EHS / 2018 / MSDS - 12 R-0 / 30.03.2018 English 39

13 Electric Delay Detonator EHS / 2018 / MSDS - 13 R-0 / 30.03.2018 English 41

14 Engine Oil-15W40 EHS / 2018 / MSDS - 14 R-0 / 30.03.2018 English 43

15 Grease EHS / 2018 / MSDS - 15 R-0 / 30.03.2018 English 46

16 Grouting Chemicals EHS / 2018 / MSDS - 16 R-0 / 30.03.2018 English 48

18 Hydraulic Oil EHS / 2018 / MSDS - 18 R-0 / 30.03.2018 English 53

19 Inhibitor Solutions EHS / 2018 / MSDS - 19 R-0 / 30.03.2018 English 55

20 Lime EHS / 2018 / MSDS - 20 R-0 / 30.03.2018 English 57

21 LPG EHS / 2018 / MSDS - 21 R-0 / 30.03.2018 English 60

22 Oil Paints EHS / 2018 / MSDS - 22 R-0 / 30.03.2018 English 62

23 Oxygen EHS / 2018 / MSDS - 23 R-0 / 30.03.2018 English 66

24 Phenol EHS / 2018 / MSDS - 24 R-0 / 30.03.2018 English 69

25 Petrol EHS / 2018 / MSDS - 25 R-0 / 30.03.2018 English 72

26 Plastic Paints EHS / 2018 / MSDS - 26 R-0 / 30.03.2018 English 74

27 Polymer EHS / 2018 / MSDS - 27 R-0 / 30.03.2018 English 76

28 Portland Cement EHS / 2018 / MSDS - 28 R-0 / 30.03.2018 English 79

29 Ready Mix Concrete EHS / 2018 / MSDS - 29 R-0 / 30.03.2018 English 82

30 Superpower 80 EHS / 2018 / MSDS - 30 R-0 / 30.03.2018 English 85

31 Sulphuric Acid EHS / 2018 / MSDS - 31 R-0 / 30.03.2018 English 87

32 Superpower 90 EHS / 2018 / MSDS - 32 R-0 / 30.03.2018 English 92

33 Solarcord EHS / 2018 / MSDS - 33 R-0 / 30.03.2018 English 95

34 Thinner EHS / 2018 / MSDS - 34 R-0 / 30.03.2018 English 97

Material Safety Data Sheet - (MSDS) EHS / 2018 / MSDS - 01

PROJECT NAME / CODE: ............................................................................... DEPT. : .......................................

● Manufacturer's Name & Address:

● Emergency Contact No.:+9122 27410822

Section:3 Hazard Identification:

● Route of Entry:  Eye contact □

● Ingestion :Ingestion is not considered a potential route of exposure.

Section:5 Fire Fighting Measures:

Section:6 Accidental Release Measures:

Section:7 Handling & Storage:

Issued on: Mar 2018 Revised on: .....................

●Eye protection: Wear safety glasses with side shields.

Section:9 Physical & Chemical Properties:

Section:10 Stability & Reactivity:

Section:11 Toxicological Information:

Issued on: Mar 2018 Revised on: .....................

Section:13 Disposal Considerations:

● Waste Dispose of contents/container in accordance with local/regional/national/international

Section:14 Transport Informations:

Name: .................................................................. Date: ..............................................................

Issued on: Mar 2018 Revised on: .....................

Material Safety Data Sheet - (MSDS) EHS / 2018 / MSDS - 02

PROJECT NAME / CODE: ............................................................................... DEPT. : ..................................

● Manufacturer's Name & Address: T-7, MIDC, Industrial Area

● Emergency Contact No.:+9122 27410822

Section:3 Hazard Identification:

● Route of Entry:  Eye contact □

Section:4 First Aid Measures:

Section:5 Fire Fighting Measures: