Narayana IIT Academy 11-01-20_Jr.

IIT-N-CHAINA/N-120_Jee-Adv_2015-P1_WAT-24_Q’P
CHEMISTRY Max Marks: 88
SECTION – I
(SINGLE INTEGER ANSWER TYPE)
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer, 0 if not attempted and 0 in all other cases.
21.

What is the value of x in the above reaction

22.

23.

The number of possible monobromo products is (excluding stereoisomers) :

24.

Double bond equivalent (degree of Unsaturation) of (A) is :

25.
Total number of geometrical isomer is :
26. The number of sp 2  sp 2 sigma bonds in the compound given below is :

27.

Jr.IIT-N-CHAINA/N-120 Page 7
The roots of education are bitter, but the fruit is sweet.
Narayana IIT Academy 11-01-20_Jr.IIT-N-CHAINA/N-120_Jee-Adv_2015-P1_WAT-24_Q’P

28. Total number of RMgX are consumed in the following reaction

SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
29.

The ether when treated with HI products:

A) B)

C) D)

30. Which of the following reactions will give good yield of ether?
A)

B)

C)

D)

Jr.IIT-N-CHAINA/N-120 Page 8
The roots of education are bitter, but the fruit is sweet.
Narayana IIT Academy 11-01-20_Jr.IIT-N-CHAINA/N-120_Jee-Adv_2015-P1_WAT-24_Q’P
31. In which of the following reaction 2o alcohol is obtained as a product ?

A) B)

C) D)

32. Possible products at place (B)

B)
A)

C) D)

33. Which of the following compounds will not form alkane on reaction with Grignard reagent?
A) CH3CH 2OH B) CH3CHO C) CH 3COCH 3 D) CH3CO2CH 3
34. Which of the following will not form between methyl butanoate and 2 mole of CH3 MgBr after
hydrolysis is :
A) C3 H7COCH 3 B) C3 H 7C  OH   CH 3 2 C) C3 H7CHOHCH3 D) C3 H 7COCH  CH 3 2
35. Which of the following statements are not correct?
A) Chlorobenzene is more reactive than benzene towards electrophilic subsititution reactions
B) C  Cl bond in chlorobenzene is less polar than in CH3Cl
C)Chlorobenzene is less reactive than CH3Cl towards nucleophilic substitution reactions
D) In chlorobenzene further substitution take place at meta position

Jr.IIT-N-CHAINA/N-120 Page 9
The roots of education are bitter, but the fruit is sweet.
Narayana IIT Academy 11-01-20_Jr.IIT-N-CHAINA/N-120_Jee-Adv_2015-P1_WAT-24_Q’P
36. Which of the following aryl halides will react with sodamide / liquid ammonia leading to sustitution
via bezyne mechanism

A) B) C) D)

37. Which of the following reactions are not feasible?

A)

B)

C)

D)

Jr.IIT-N-CHAINA/N-120 Page 10
The roots of education are bitter, but the fruit is sweet.
Narayana IIT Academy 11-01-20_Jr.IIT-N-CHAINA/N-120_Jee-Adv_2015-P1_WAT-24_Q’P
38. Write the product of the following reactions.

A) B) C) D)

SECTION - III
(MATRIX MATCHING ANSWER TYPE)
This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and four statements (P, Q, R, S
& T) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II.
For example, if for a given question, statement B matches with the statements given in Q and R, then for the particular question
darken the bubbles corresponding to Q and R in the OMR sheet. For each correct matching will be awarded +2 marks ONLY and
0 if not attempted and -1 in all other cases.
39. Matching the column I and II. (Matrix)

Column (I) Column (II)

Reactant Product
(a) (p)

(b) (q)

(c) (r)

(d) (s)

Jr.IIT-N-CHAINA/N-120 Page 11
The roots of education are bitter, but the fruit is sweet.
Narayana IIT Academy 11-01-20_Jr.IIT-N-CHAINA/N-120_Jee-Adv_2015-P1_WAT-24_Q’P
40. Matching the column I and II. (Matrix)
Column (I) Column (II)
Reaction Reaction Condition
(a) (p) 368 K

(b) (q) Room

Temperature

(c) (r) 443 K

(d) (s) 300 atm, 623 K

Jr.IIT-N-CHAINA/N-120 Page 12
The roots of education are bitter, but the fruit is sweet.