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Once equilibrium is
achieved, the
amount of each
reactant and product
remains constant.
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• Examples:
N2(g) + 3H2(g) ⇄ 2NH3(g); Kc = [NH 3 ] 2
[N 2 ][H 2 ] 3
SAMPLE EXERCISE 15.1 Writing Equilibrium-Constant Expressions Equilibrium Can Be Reached from Either
Write the equilibrium expression for Kc for the following reactions:
Direction
PRACTICE EXERCISE
Write the equilibrium-constant expression, Kc for
Kc, the final ratio of [NO2]2 to [N2O4], reaches a
constant no matter what the initial concentrations of
NO2 and N2O4 are (with const T).
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What Does the Value of K Mean? What Does the Value of K Mean?
• If K >> 1, the reaction • If K >> 1, the reaction
is product-favored; is product-favored;
product predominates product predominates
at equilibrium. at equilibrium.
• If K << 1, the reaction is
reactant-favored;
reactant predominates
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at equilibrium. 16
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At equilibrium, the mixture is found to contain 1.580 mole of HI. Kc =
[HI] 2
=
(0.316)
= 57
(a) What are the concentrations of H2, I2 and HI at equilibrium? (b) [H 2 ][I 2 ] ( 0.042 ) 2
Calculate the equilibrium constant Kc. 17 18
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2x
55.6 7.46 • Knowing Kc and the initial concentrations, we can
( 0.100 - x
determine the concentrations of components at
2 x 0.746 - 7.46 x ; 9.46 x 0.746
equilibrium.
x 0.0789 ;
[H 2 ] [I 2 ] 0.0211 M; [HI] 0.158 M
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Equilibrium constant is used to predict the direction of What does the reaction quotient tell us?
net reaction
• For a reaction of known Kc value, the direction of net reaction If Qc = Kc, the reaction is at equilibrium;
can be predicted by calculating the reaction quotient, Qc.
If Qc < Kc, the reaction is not at equilibrium and
• Qc is called the reaction quotient, where for a reaction such
as:
there’s a net forward reaction;
[C] c [ D] d
• aA + bB ⇄ cC + dD; Q c If Qc > Kc, the reaction is not at equilibrium and
[A] a [ B] b
• Qc has the same expression as Kc , but there’s a net reaction in the opposite direction.
• Qc is calculated using concentrations that are not necessarily
at equilibrium.
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Reactions that shift right when pressure increases Reaction that shifts left when pressure increases,
and shift left when pressure decreases but shifts right when pressure decreases
Consider the reaction: Consider the reaction: PCl5(g) ⇄ PCl3(g) + Cl2(g);
2SO2(g) + O2(g) ⇄ 2SO3(g),
1. The total moles of gas decreases as reaction proceeds in the 1. Forward reaction results in more gas molecules.
forward direction. 2. Pressure increases as reaction proceeds towards equilibrium.
2. If pressure is increased by decreasing the volume 3. If mixture is compressed, pressure increases, and reverse
(compression), a forward reaction occurs to reduce the reaction occurs to reduce pressure;
stress. 4. If volume expands and pressure drops, forward reaction
3. Reactions that result in fewer moles of gas favor high occurs to compensate.
pressure conditions. 5. This type of reactions favors low pressure condition
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[ H 3O ][OH ]
Keq
[ H 2O ]
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[H+] will be use to calculate [OH-] of the solution. 52
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Solubility Equilibrium
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