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SYLLABUS FOR JEE (Main) – 2020

(a) Syllabus for paper -1 (B.E./B.Tech.) – Mathematics, Physics and Chemistry:


MATHEMATICS UNIT 8 : LIMIT, CONTINUITY AND
UNIT 1 : SETS, RELATIONS AND FUNCTIONS: DIFFERENTIABILITY
Sets and their representation; Union, intersection and Real – valued functions, algebra of functions,
complement of sets and their algebraic properties; polynomials, rational, trigonometric, logarithmic and
Power set; Relation, Types of relations, equivalence exponential functions, inverse functions. Graphs of
Relations, functions;. one-one, into and onto functions, simple functions. Limits, continuity and
Composition of functions. differentiability. Differentiation of the sum, difference,
product and quotient of two functions. Differentiation
UNIT 2 : COMPLEX NUMBERS AND QUADRATIC of trigonometric, inverse trigonometric, logarithmetic,
EQUATIONS: exponential, composite and implicit functions;
Complex numbers as ordered pairs of reals, derivatives of order upto two. Rolle’s and Lagrange’s
Representation of complex numbers in the form a+ib Mean Value Theorems. Applications of derivatives:
and their representation in a plane, Argand diagram, Rate of change of quantities, monotonic – increasing
algebra of complex numbers, modulus and argument and decreasing functions, Maxima and minima of
(or amplitude) of a complex numbers, square root of a functions of one variable, tangents and normals.
complex number, triangle inequality, Quadratic
equations in a real and complex number system and their UNIT 9 : INTEGRAL CALCULUS:
solutions. Relation between roots and co-efficients, Integrals as an anti – derivative. Fundamental integrals
nature of roots, formation of quadratic equations with involving algebraic, trigonometric, exponential and
given roots. logarithmic functions. Integration by substitution, by
parts and by partial fractions. Integration using
UNIT 3 : MATRICES AND DETERMINANTS: trigonometric identities.
Matrices, algebra of matrices, types of matrices,
determinants and matrices of order two and three. Evaluation of simple integrals of the type
    
Properties of determinants, evaluation of determinants,  dx  dx  dx  dx dx
area of triangle using determinants. Adjoint and

 ,
2 
,  2 ,  ,  2 ,


x  a  x  a  a − x  a − x  ax + bx + c
2 2 2 2 2 2
evaluation of inverse of a square matrix using
determinants and elementary transformations, Test of

 dx 
( px + q)dx  ( px + q)dx


,  2 ,
ax + bx + c  ax + bx + c  ax 2 + bx + c
consistency in two or three variables using determinants  2

and matrices.



a 2  x 2 dx  x 2 − a 2 dx
UNIT 4 : PERMUTATIONS AND COMBINATIONS:
Fundamental principle of counting, permutation as an
Integral as limit of a sum. Fundamental Theorem of
arrangement and combination as selection, Meaning
Calculus. Properties of definite integrals. Evaluation
of P(n,r) and C(n,r), simple applications.
of definite integrals, determining areas of the regions
bounded by simple curves in standard form.
UNIT 5 : MATHEMATICALINDUCTION:
Principle of Mathematical Induction and its simple
UNIT 10 : DIFFERENTIAL EQUATIONS:
applications.
Ordinary differential equations, their order and degree.
Formation of differential equations. Solutions of
UNIT 6 : BINOMIAL THEOREM AND ITS SIMPLE differential equations by method of separation of
APPLICATIONS: variables, solution of homogeneous an linear
Binomial theorem for a positive integral index, general differential equations of the type:
term and middle term, properties of Binomial
dy
coefficients and simple applications. + p ( x) y = q ( x)
dx
UNIT 7 : SEQUENCES AND SERIES: UNIT 11 : CO-ORDINATE GEOMETRY:
Arithmetic and Geometric progressions, insertion of Cartesian system of rectangular co-ordinates 10 in a
arithmetic, geometric means between two given plane, distance fomula, section formula, locus and its
numbers. Relation between A.M. and G.M. Sum upto equation, translation of axes, slope of a line, parallel
n terms of special series: S n, S n2, Sn3. Arithmetico- and perpendicular lines, intercepts of line on the
Geometric progression. coordinate axes.
Straight lines PHYSICS
Various forms of equations of line, intersection of The syllabus contains two sections–A and B. Section–A
lines, angles between two lines, conditions for pertains to the theory Part having 80% weightage, while
concurrence of three lines, distance of a point from a Section-B contains Practical Component (Experimental
line, equations of internal and external bisectors of
Skills) having 20% weightage.
angles between two lines, coordinates of centroid,
orthocentre and circumcentre of a triangle, equation
of family of lines passing through the point of SECTION-A
intersection of two lines. UNIT 1 : PHYSICS AND MEASUREMENT
Physics, technology and society, S I units,
Circles, conic sections Fundamental and derived units. Least count, accuracy
Standard form of equation of a circle, general form of and precision of measuring instruments, Errors in
the equation of a circle, its radius and centre, equation measurement, Dimensions of Physical quantities,
of a circle when the end points of a diameter are given, dimensional analysis and its applications.
points of intersection of a line and a circle with the
centre at the origin and condition for a line to be UNIT 2 : KINEMATICS
tangent to a circle, equation of tangent. Sections Frame of reference. Motion in a straight line: Position-
of cones, equations of conic sections (parabola, ellipse time graph, speed and velocity. Uniform and non-
and hyperbola) in standard forms, condition for y= uniform motion, average speed and instantaneous
mx + c to be a tangent and point (s) of tangency. velocity Uniformly accelerated motion, velocity-time,
position-time graphs, relations for uniformly
UNIT 12 : THREE DIMENSIONAL GEOMETRY: accelerated motion. Scalars and Vectors, Vector
Coordinates of a point in space, distance between two addition and Subtraction, Zero Vector, Scalar and
points, section formula, direction ratios and direction Vector products, Unit Vectors, Resolution of a Vector.
cosines, angle between two intersecting lines. Skew Relative Velocity, Motion in a plane, Projectile Motion,
lines, the shortest distance between them and its Uniform Circular Motion.
equation. Equation of a line and a plane in different
forms, intersecting of a line and a plane, coplanar lines. UNIT 3 : LAWS OF MOTION
Force and Inertia, Newton’s First law of motion;
UNIT 13 : VECTOR ALGEBRA Momentum, Newton’s Second Law of motion;
Vectors and scalars, addition of vectors, components Impulse; Newton’s Third Law of motion. Law of
of a vector in two dimensions and three dimensional conservation of linear momentum and its applications,
space, scalar and vector products, scalar and vectors Equilibrium of concurrent forces.
triple product.
Static and Kinetic friction, laws of friction, rolling
Friction.
UNIT 14 : STATSTICS AND PROBABILITY:
Measures of Dispersion: Calculation of mean, medium,
Dynamics of uniform cicular motion: Centripetal force
mode of grouped and ungrouped data calculation of
and its applications.
standard deviation, variance and mean deviation for
grouped and ungrouped data.
UNIT 4 : WORK, ENERGY AND POWER
Probability: Probability of an event, addition and Work done by a constant force and a variable force;
multiplication theorems of probability, Baye’s theorem, kinetic and potential energies, workenergy theorem,
probability distribution of a random variate, Bernoulli power.
trails and Binomial distribution.
Potential energy of a spring, conservation of
mechanical energy, conservative and nonconservative
UNIT 15 : TRIGONOMETRY:
forces; Elastic and inelastic collisions in one and two
Trigonometrical identities and equations,
dimensions.
Trigonometrical functions, Inverse trigonometrical
Functions and their properties. Heights and Distances.
UNIT 5 : ROTATIONAL MOTION
Centre of mass of a two-particle system, centre of
UNIT 16 : MATHEMATICAL REASONING:
mass of a rigid body; Basic concepts of rotational
Statements, logical operations and, or, implies, implied
motion; moment of a force, torque, angular momentum,
by, if and only if. Understanding of tautology,
conservation of angular momentum and its
contradiction, converse and contrapositive.
applications; moment of inertia, radius of gyration.
Values of moments of inertia for simple geometrical
objects, parallel and perpendicular axes theorems and UNIT 11 : ELECTROSTATICS
their applications. Rigid body rotation, equations of Electric charges: Conservation of charge, Coulomb’s
rotational motion. law-forces between two point charges, forces between
multiple charges; superposition principle and
UNIT 6 : GRAVITATION continuous charge distribution.
The universal law of gravitation. Acceleration due to
gravity and its variation with altitude and depth. Electric field: Electric field due to a point charge, Electric
Kepler’s laws of planetary motion. Gravitational Field lines, Electric dipole, Electric field due to a dipole,
potential energy; gravitational potential. Escape Torque on a dipole in a uniform electric field.
velocity. Orbital velocity of a satellite. Geo-stationary
satellites. Electric flux, Gauss’s law and its applications to find
field due to infinitely long uniformly charged straight
UNIT 7 : PROPERTIES OF SOLIDS AND LIQUIDS wire, uniformly charged infinite plane sheet and
Elastic behaviour, Stress-strain relationship, Hooke’s uniformly charged thin spherical shell. Electric
Law, Young’s modulus, bulk modulus, modulus of potential and its calculation for a point charge , electric
rigidity. Pressure due to a fluid column; Pascal’law dipole and system of charges; Equipotential surfaces,
and its applications. Viscosity, Stoke’law, terminal Electrical potential energy of a system of two point
velocity, streamline and turbulent flow, Reynolds Charges in an electrostatic field.
number. Bernoulli’s principle and its applications. Conductors and insulators, Dielectrics and electric
Surface energy and surface tension, angle of contact, Polarization, capacitor, combination of capacitor in
application of surface tension – drops, bubbles and Series and in parallel, capacitance of a parallel plate
capillary rise. Heat, temperature, thermal expansion; capacitor with and without dielectric medium between
specific heat capacity, calorimetry; change of state, the plates, Energy stored in a capacitor.
latent heat. Heat transfer-conduction, convection and
radiation, Newton’s law of cooling. UNIT 12 : CURRENT ELECTRICITY
Electric current, Drift velocity, Ohm’s law, Electrical
UNIT 8 : THERMODYNAMICS Resistance, Resistances of different materials, V-I
Thermal equilibrium, zeroth law of thermodynamics, characteristics of Ohmic and nonohmic conductors,
concept of temperature. Heat, work and internal Electrical energy and power, Electrical resistivity,
energy. First law of thermodynamics. Second law of Colour code for resistors; Temperature dependence
thermodynamics: reversible and irreversible processes. of resistance.
Carnot engine and its efficiency.
Electric Cell and its Internal resistance, potential
UNIT 9 : KINETIC THEORY OF GASES Difference and emf of a cell, combination of cells in
Equation of state of a perfect gas, work done on series and in parallel. Kirchhoff’s laws and their
compressing a gas. Kinetic theory of gases- applications. Wheatstone bridge, Metre bridge.
assumptions, concept of pressure. Kinetic energy and Potentiometer-principle and its applications.
temperature: rms speed of gas molecules; Degree of
freedom, Law of equipartition of energy, applications UNIT 13 : MAGNETIC EFFECTS OF CURRENT AND
to specific heat capacities of gases; Mean free path, MAGNETISM
Avagadro’s number. Biot-Savart law and its application to current carrying
circular loop. Ampere’s law and its applications to
UNIT 10 : OSCILLATIONS AND WAVES infinitely long current carrying straight wire and
Periodic motion-period, frequency, displacement as a solenoid. Force on a moving charge in uniform
Function of time. Period functions. Simple harmonic magnetic and electric fields. Cyclotron.
motion (S.H.M.) and its equation; phase; oscillations
of a spring-restoring force and force constant; energy Force on a current-carrying conductor in a uniform
in S.H.M. –kinetic and potential energies; Simple magnetic field. Force between two parallel current-
pendulum – derivation of expression for its time period; carrying conductors-definition of ampere. Torque
Free, forced and damped oscillations, resonance. experienced by a current loop in uniform magnetic
field; Moving coil galavanometer, its current sensitivity
Wave motion. Longitudinal and transverse waves, and conversion to ammeter and voltmeter.
Speed of a wave. Displacement relation for a
Progressive wave. Principle of superposition of waves, Current loop as a magnetic dipole and its magnetic
Reflection of waves, Standing waves in strings and dipole moment. Bar magnet as an equivalent solenoid,
organ pipes, fundamental mode and harmonics, Beats, magnetic field lines; Earth’s magnetic field and
Doppler effect in sound. magnetic elements. Para-, dia- and ferro- magnetic
substances.
Magnetic susceptibility and permeability, Hysteresis, UNIT 19 : ELECTRONIC DEVICES
Electromagnets and permanent magnets. Semiconductors; semiconductor diode: I-V
characteristics in forward and reverse bias; diode as a
UNIT 14 : ELECTROMAGNETIC INDUCTION AND rectifier; I-V characteristics of LED, photodiode, solar
ALTERNATING CURRENTS cell and Zener diode; Zener diode as a voltage
Electromagnetic induction; Faraday’s law, induced emf regulator. Junction transistor, transistor action,
and current; Lenz’s law, Eddy currents. Self and mutual characteristics of a transistor; transistor as an amplifier
inductance. Alternating currents, peak and rms value (common emitter configuration) and oscillator. Logic
of alternating current/ voltage; reactance and gates (OR,AND,NOT,NAND and NOR). Transistor
impedance; LCR series circuit, resonance; Quality as a switch.
factor, power in AC circuits, wattless current. AC
generator and transformer. UNIT 20 : COMMUNICATION SYSTEMS
Propagation of electromagnetic waves in the
UNIT 15 : ELECTROMAGNETIC WAVES atmosphere; Sky and space wave propagation, Need
Electromagnetic waves and their characteristics. for modulation, Amplitude and Frequency
Transverse nature of electromagnetic waves. Modulation, Bandwidth of signals, Bandwidth of
Transmission medium, Basic Elements of a
Electromagnetic spectrum (radio waves, microwaves, Communication System (Block Diagram only).
infrared, visible, ultraviolet, Xrays, gamma rays).
Applications of e.m. waves. SECTION-B
UNIT 21 : EXPERIMENTAL SKILLS
UNIT 16 : OPTICS Familiarity with the basic approach and observations
Reflection and refraction of light at plane and spherical of the experiments and activities:
surfaces, mirror formula, Total internal reflection and 1. Vernier calipers-its use to measure internal and
its applications, Deviation and Dispersion of light by external diameter amd depth of a vessal.
a prism, Lens Formula, Magnification, Power of a Lens,
Combination of thin lenses in contact, Microscope 2. Screw gauge-its use to determine thickness/
and Astronomical Telescope (reflecting and refracting) diameter of thin sheet/wire.
and their magnifyingpowers.
Waveoptics: wavefront and Huygen’s principle, Laws 3. Simple pendulum-dissipation of energy by
of reflection and refraction using Huygen’s principle. plotting a graph between square of amplitude and
Interference, Young’s double slit experiment and time.
expression for fringe width, coherent sources and
sustained interference of light. Diffraction due to a 4. MetreScale-mass of a given object by principle
single slit, width of central maximum. Resolving power Of moments.
of microscopes and astronomical telescopes,
Polarisation, plane polarized light; Brewster’s law, uses 5. Young’s modulus of elasticity of the material of a
of plane polarized light and Polaroids. metallic wire.

UNIT 17 : DUAL NATURE OF MATTER AND 6. Surface tension of water by capillary rise and effect
RADIATION of detergents
Dual nature of radiation. Photoelectric effect, Hertz
and Lenard’s observations; Einstein’s photoelectric 7. Co-efficient of Viscosity of a given viscous liquid
equation; particle nature of light. Matter waves-wave by measuring terminal velocity of a given spherical
nature of particle, de Broglie relation. Davission-Germer body.
experiment.
8. Plotting a cooling curve for the relationship
between the temperature of a hot body and time.
UNIT 18 : ATOMS AND NUCLEI
Alpha-particle scattering experiment; Rutherford’s
9. Speed of sound in air at room temperature using
Model of atom; Bohr model, energy levels, hydrogen
a resonance tube.
spectrum. Composition and size of nucleus, atomic
masses, isotopes, isobars; isotones. Radioactivity-
10. Specific heat capacity of a given (i) solid and (ii)
alpha, beta and gamma particles/rays and their
liquid by method of mixtures.
properties; radioactive decay law. Mass-energy
relation, mass defect; binding energy per nucleon and
11. Resistivity of the material of a given wire using
its variation with mass number, nuclear fission and
metre bridge.
fusion.
12. Resistance of a given wire using Ohm’s law.

13. Potentiometer-
(i) Comparison of emf of two primary cells.
(ii) Determination of internal resistance of a cell.
14. Resistance and figure of merit of a galvanometer Absolute scale of temperature; Ideal gas equation;
by half deflection method. Kinetic theory of gases (only postulates); Concept of
average, root mean square and most probable
15. Focal length of: velocities; Real gases, deviation from Ideal behaviour,
(i) Convex mirror compressibility factor and van der Waals equation.
(ii) Concave mirror, and
(iii) convex lens Liquid State:
using parallax method. Properties of liquids-vapour pressure, viscosity and
surface tension and effect of temperature on them
16. Plot of angle of deviation vs angle of incidence (qualitative treatment only).
for a triangular prism.
Solid State:
17. Refractive index of a glass slab using a travelling Classification of solids: molecular, ionic, covalent and
Microscope. metallic solids, amorphous and crystalline solids
(elementary idea); Bragg’s Law and its applications;
18. Characteristic curves of a p-n junction diode in Unit cell and lattices, packing in solids (fcc, bcc and
forward and reverse bias. Hcp lattices), voids, calculations involving unit cell
parameters, imperfection in solids; Electrical and
19. Characteristics curves of a Zener diode and finding magnetic properties.
Reverse break down voltage.
UNIT 3 : ATOMIC STRUCTURE
20. Characteristic curves of a transistor and finding Thomson and Rutherford atomic models and their
Current gain and voltage gain. limitations; Nature of electromagnetic radiation,
photoelectric effect; Spectrum of hydrogen atom, Bohr
21. Identification of Diode, LED, Transistor, IC, model of hydrogen atom –its postulates, derivation of
Resistor, Capacitor from mixed collection of such the relations for energy of the electron and radii of the
Items. different orbits, limitations of Bohr’s model; Dual
nature of matter, de-Broglie’s relationship. Heisenberg
22. Using multimeter to: uncertainty principle. Elementary ideas of quantum
(i) Identify base of a transistor mechanic, quantum mechanical model of atom. its
(ii) Distinguish between npn and pnp type important features. Concept of atomic orbitals as one
transistor
electron wave functions; Variation of  and  with r
2
(iii) See the unidirectional flow of current in case
of a diode and an LED. for 1s and 2s orbitals; various quantum numbers
(iv) Check the correctness or otherwise of a given (principle, angular momentum and magnetic quantum
electronic component (diode, transistor or IC). numbers) and their significance; shapes of s, p and d
-orbitals, electron spin and spin quantum number;
CHEMISTRY Rules for filling electrons in orbitals-aufbau principle,
SECTION: A Pauli’s exclusion principle and Hund’s rule, electronic
PHYSICAL CHEMISTRY configuration of elements, extra stability of half-filled
and completely filled orbitals.
UNIT 1 : SOME BASIC CONCEPTS IN CHEMISTRY
Matter and its nature, Dalton’s atomic theory; Concept
of atom, molecule, element and compound; Physical UNIT 4 : CHEMICAL BONDING AND MOLECULAR
quantities and their measurements in Chemistry, STRUCTURE
precision and accuracy, significant figures, S.I. Units, Kossel-Lewis approach to chemical bond formation,
dimensional analysis; Laws of chemical combination; concept of ionic and covalent bonds.
Atomic and molecular masses, mole concept, molar
mass, percentage composition, empirical and Ionic Bonding: Formation of ionic bonds, factors
molecular formulae; Chemical equations and affecting the formation of ionic bonds; calculation of
stoichiometry. lattice enthalpy.

UNIT 2 : STATES OF MATTER Covalent Bonding: Concept of electronegativity,


Classification of matter into solid, liquid and gaseous Fajan’s rule, dipole moment; Valence Shell Electron
states. Pair Repulsion (VSEPR) theory and shapes of simple
Molecules.
Gaseous state:
Measurable properties of gases; Gas laws – Boyle’s Quantum mechanical approach to covalent
law, Charle’slaw, Graham’s law of diffusion,Avogadro’s bonding:
law, Dalton’s law of partial pressure; Concept of Valence bond theory-Its important features, concept
of hybridization involving s, p and d orbitals; Ionic equilibrium: Weak and strong electrolytes,
Resonance. ionization of electrolytes, various concepts of acids
and bases (Arrhenius, Brönsted – Lowry and Lewis)
Molecular Orbital Theory – Its important features, and their ionization, acid – base equilibria (including
LCAOs, types of molecular orbitals (bonding, multistage ionization) and ionization constants,
antibonding), sigma and pi-bonds, molecular orbital ionization of water, pH scale, common ion effect,
electronic configurations of homonuclear diatomic hydrolysis of salts and pH of their solutions, solubility
molecules, concept of bond order, bond length and of sparingly soluble salts and solubility products,
bond energy. buffer solutions.

Elementry idea of metallic bonding. Hydrogen UNIT 8 : REDOX REACTIONS AND


bonding and its applications. ELECTROCHEMISTRY
Electronic concepts of oxidation and reduction, redox
UNIT 5 : CHEMICAL THERMODYNAMICS reactions, oxidation number, rules for assigning
oxidation number, balancing of redox reactions.
Fundamentals of thermodynamics: System and
surroundings, extensive and intensive properties, Electronic and metallic conduction, conductance in
state functions, types of processes. electrolytic solutions, molar conductivities and their
variation with concentration: Kohlrausch’s law and
First law of thermodynamics- Concept of work, heat its applications.
internal energy and enthalpy. heat capacity, molar heat
capacity; Hess’s law of constant heat summation; Electrochemical cells – Electrolytic and Galvanic cells,
Enthalpies of bond dissociation, combustion, different types of electrodes, electrode potentials
Formation, atomization, sublimation, phase transition, including standard electrode potential, half - cell and
hydration, ionization and solution. cell reactions, emf of a Galvanic cell and its
measurement; Nernst equation and its applications
Second law of thermodynamics; Spontaneity of Relationship between cell potential and Gibbs' energy
processes; ΔS of the universe and ΔG of the system change; Dry cell and lead accumulator; Fuel cells.
as criteria for spontaneity, ΔG˚ (Standard Gibbs energy
change) and equilibrium constant. UNIT 9 :CHEMICAL KINETICS
Rate of a chemical reaction, factors affecting the rate
UNIT 6 : SOLUTIONS of reactions: concentration, temperature, pressure and
Different methods for expressing concentration of catalyst; elementary and complex reactions, order and
solution- molality, molarity, mole fraction, percentage molecularity of reactions. rate law, rate constant and
(by volume and mass both), vapour pressure of its units, differential and integral forms of zero and
solutions and Raoult’s law – Ideal and non-ideal first order reactions, their characteristics and half –
solutions, vapour pressure – composition, plots for lives, effect of temperature on rate of reactions-
ideal and non-ideal solutions; Colligative properties Arrhenius theory, activation energy and its
of dilute solutions- relative lowering of vapour calculation, collision theory of bimolecular gaseous
pressure, depression of freezing point, elevation of reactions (no derivation).
boiling point and osmotic pressure; Determination of
UNIT 10 : SURFACE CHEMISTRY
molecular mass using colligative properties; Abnormal
value of molar mass, van’t Hoff factor and its Adsorption- Physisorption and chemisorption and
significance. their characteristics, factors affecting adsorption of
gases on solids - Freundlich and.Langmuir adsorption
isotherms, adsorption from solutions.
UNIT 7 : EQUILIBRIUM
Meaning of equilibrium, concept of dynamic
Catalysis- Homogeneous and heterogeneous, activity
equilibrium.
and selectivity of solid catalysts, enzyme catalysis
and its mechanism.
Equilibria involving physical processes:Solid-liquid
liquid – gas and solid –gas equilibria, Henry’s law,
general characteristics of equilibrium involving physical Colloidal state- distinction among true solutions,
processes, colloids and suspensions, classification of colloids -
Iyophilic, lyophobic: multimolecular, macromolecular
Equilibria involving chemical processes: Law of and associated colloids (micelles), preparation and
chemical equilibrium, equilibrium constants (Kp and properties of colloids - Tyndall effect, Brownian
Kc) and their significance, significance of ΔG and ΔG˚ movement, electrophoresis. dialysis. coagulation and
in chemical equilibria, factors affecting equilibrium flocculation; Emulsions and their characteristics.
concentration, pressure, temperature, effect of catalyst;
Le Chatelier’s principle.
SECTION - B Group- 14
INORGANIC CHEMISTRY Tendency for catenation: Structure, properties and
uses of Allotropes and oxides of carbon, silicon
UNIT 11 : CLASSIFICATION OF ELEMENTS AND tetrachloride, silicates, zeolites and silicones.
PERIODICITY IN PROPERTIES
Group- 15
Modem periodic law and present form of the periodic
Properties and uses of nitrogen and phosphorus;
table, s.p, d and f block elements, periodic trends in
Allotrophic forms of phosphorus; Preparation,
properties of elements atomic and ionic radii, ionization
properties, structure and uses of ammonia, nitric acid,
enthalpy; electron gain enthalpy. valence, oxidation
Phosphine and phosphorus halids, (PCL3 PCL5);
states and chemical reactivity.
Structures of oxides and oxoacids of nitrogen and
phosphorus.
UNIT 12 : GENERAL PRINCIPLES AND PROCESSES
OF ISOLATION OF METALS Group- 16
Modes of occurrence of elements in nature, minerals, Preparation, properties, structures and uses of ozone;
ores; Steps involved in the extraction of metals - Allotropic forms of sulphur; Preparation, properties,
concentration, reduction (chemical and electrolytic structures and uses of sulphuric acid (including its
methods) and relining with special reference to the industrial preparation); Structures of oxoacids of
extraction of Al, Cu, Zn and Fe; Thermodynamic and sulphur.
electrochemical principles involved in the extraction
of metals. Group- 17
Preparation, properties and uses of hydrochloric acid;
Trends in the acidic nature of hydrogen halides;
UNIT 13 : HYDROGEN Structures of Interhalogen. compounds and oxides and
Position of hydrogen in periodic table, isotopes, oxoacids of halogens.
preparation, properties and uses of hydrogen;
Physical and chemical properties of water and heavy Group- 18
water; Structure, preparation, reactions and uses of Occurrence and uses of noble gases; Structures of
hydrogen peroxide; Classification of hydrides – ionic, fluorides and oxides of xenon.
covalent and interstitial; Hydrogen as a fuel.

UNIT 14 : BLOCK ELEMENTS (ALKALI AND UNIT 16 : d - and f - BLOCK ELEMENTS


ALKALINE EARTH METALS) Transition Elements
Group - 1 and 2 Elements General introduction, electronic configuration,
occurrence and characteristics, general trends in
General introduction, electronic configuration and properties of the first row transition elements –
general trends in physical and chemical properties of physical properties, ionization enthalpy, oxidation
elements, anomalous properties of the first element of states, atomic radii, colour, catalytic behaviour,
each group, diagonal relationships. magnetic properties, complex formation, interstitial
compounds, alloy formation; Preparation, properties
Preparation and properties of some important and uses of K2 Cr2 O7 and KMnO4.
compounds - sodium carbonate and sodium hydroxide
and sodium hydrogen carbonate; Industrial uses of
Inner Transition Elements
Lime, limestone, Plaster of Paris and cement; Biological
significance of Na, K, Mg and Ca. Lanthanoids - Electronic configuration, oxidation
states and lanthanoid contraction.
UNIT 15 : P-BLOCK ELEMENTS Actinoids – Electronic configuration and oxidation
Group - 13 to Group 18 Elements states.
General introduction: Electronic configuration and
general trends in physical and chemica1properties of UNIT 17 : CO-ORDINATION COMPOUNDS
elements across the periods and down the groups; Introduction to co-ordination compounds, Werner's
unique behaviour of the first element in each group. theory; ligands, co-ordination number, denticity,
chelation; IUPAC nomenclature of mononuclear co-
Groupwise study of the p block elements ordination compounds, isomerism; Bonding-Valence
Group- 13 bond approach and basic ideas Of Crystal field theory,
Preparation, properties and uses of boron and colour and magnetic properties; Importance of co-
aluminium; Structure, properties and uses of borax, ordination compounds (in qualitative analysis,
boric acid, diborane, boron trifluoride, aluminium extraction of metals and in biological systems).
chloride and alums.
UNIT 18 : ENVIRONMENTAL CHEMISTRY Electronic displacement in a covalent bond
-Inductive effect, electromeric effect, resonance and
Environmental pollution- Atmosphere, water and soil. hyperconjugation.

Atmospheric pollution – Tropospheric and Common types of organic reactions- Substitution,


Stratospheric addition, elimination and rearrangement.

Tropospheric pollutants-Gaseous pollutants:Oxides UNIT 21 : HYDROCARBONS


of carbon, nitrogen and sulphur, hydrocarbons; their Classification, isomerism, IUPAC nomenclature,
sources, harmful effects and prevention; Green house general methods of preparation, properties and
effect and Global warming; Acid rain; reactions.

Particulate pollutants: Smoke, dust, smog, fumes, Alkanes – Conformations; Sawhorse and Newman
mist; their sources, harmfull effects and prevention. projections (of ethane); Mechanism of halogenation of
alkanes.
Stratospheric pollution- Formation and breakdown of
ozone, depletion of ozone layer - its mechanism and Alkenes - Geometrical isomerism; Mechanism of
effects. electrophilic addition; addition of hydrogen, halogens,
water, hydrogen halides (Markownikoff’s and peroxide
Water Pollution - Major pollutants such as, effect); Ozonolysis and polymerization.
Pathogens, organic wastes and chemical pollutants;
their harmful effects and prevention. Alkynes- Acidic character; Addition of hydrogen,
halogens, water and hydrogen halides; Polymerization.
Soil pollution – Major pollutants such as; Pesticides
(insecticides, herbicides and fungicides), their harmful Aromatic hydrocarbons- Nomenclature, benzene-
effects and prevention. structure and aromaticity; Mechanism of electrophilic
substitution; halogenation, nitration, Friedel - Craft's
Strategies to control environmental pollution. alkylation and acylation, directive influence of
functional group in mono-substituted benzene.
SECTION – C
ORGANIC CHEMISTRY UNIT 22 : ORGANIC COMPOUNDS CONTAINING
UNIT 19 : PURIFICATION AND HALOGENS
CHARACTERISATION OF ORGANIC General methods- of preparation, properties and
COMPOUNDS reactions; Nature of C-X bond; Mechanisms of
substitution reactions.
Purification – Crystallization, sublimation, distillation,
differential extraction and chromatography - principles Uses; Environmental effects of chloroform, iodoform
and their applications. freons and DDT.

Qualitative analysis - Detection of nitrogen, sulphur, UNIT 23 : ORGANIC COMPOUNDS CONTAINING


phosphorus and halogens. OXYGEN
General methods of preparation, properties, reactions
Quantitative analysis (basic principles only) – and uses.
Estimation of carbon, hydrogen, nitrogen, halogens,
sulphur, phosphorus. ALCOHOLS, PHENOLS AND ETHERS
Alcohols: Identification of primary, secondary and
Calculations of empirical Formulae and molecular tertiary alcohols; mechanism of dehydration.
formulae; Numerical problems in organic quantitative
analysis. Phenols: Acidic nature, electrophilic substitution
reactions; halogenation, nitration and sulphonation,
Reimer- Tiemann reaction.
UNIT 20 : SOME BASIC PRINCIPLES OF ORGANIC
CHEMISTRY Ethers: Structure.
Tetravalency of carbon; Shapes of simple molecules-
hybridization (s and p); Classification of organic Aldehyde and Ketones: Nature of carbonyl
compounds based on functional groups; and those group; Nucleophilic addition to >C=0 group, relative
containing halogens, oxygen, nitrogen and sulphur; reactivities of aldehydes and ketones; Important
Homologous series; Isomerism - structural and reactions such as - Nucleophilic addition reactions
stereoisomerism. (addition of HCN, NH, and its derivatives), Grignard
reagent; oxidation; reduction (Wolff Kishner and
Nomenclature (Trivial and IUPAC) Clemmensen); acidity of α-hydrogen, aldol
Covalent bond fission - Homolytic and heterolytic: condensation, Cannizzaro reaction, Haloform reaction;
free radicals, carbocations and carbanions; stability
of carbocations and free radicals, eleetrophiles and
nucleophiles.

Chemical tests to distinguish between aldehydes and


Ketones. functional groups: hydroxyl (alcoholic and phenolic),
carbonyl (aldehyde and ketone), carboxyl and amino
CARBOXYLICACIDS groups in organic compounds.
Acidic strength and factors affecting it.

UNIT 24 : ORGANIC COMPOUNDS CONTAINING • Chemistry involved in the preparation of the


NITROGEN following:
General methods of preparation, properties. reactions Inorganic compounds: Mohr's salt. potash alum.
and uses. Organic compounds: Acetanilide. pnitroacetanilide.
Amines: Nomenclature. classification, structure. basic aniline yellow. iodoform.
character and identification of primary. secondary and
• Chemistry involved in the titrimetric excercises -
tertiary amines and their basic character.
Acids bases and the use of indicators. oxalic-acid vs
Diazonium Salts: Importance in synthetic organic KMnO4 Mohr's salt vs KMnO4.
chemistry. • Chemical principles involved in the qualitative salt
analysis:

UNIT 25 : POLYMERS Cations - Pb2+, Cu2+, Al3+, Fe3+, Zn2+, Ni2+,


General introduction and classification of polymers,
general methods of polymerization-addition and Ca2+, Ba2+, Mg2+, NH +4 .
condensation, copolymerization;
Anions - CO32 − ,S2 − ,SO24 − , NO3− , NO−2 , Cl–, Br–, I–.
Natural and synthetic rubber and vulcanization; some (Insoluble salts excluded).
important polymers with emphasis on their monomer • Chemical principles involved in the following
and uses - polythene. nylon. polyester and batelite. experiments:
1. Enthalpy of solution of CuSO4
2. Enthalpy of neutralization of strong acid and strong
UNIT 26 : BIOMOLECULES
General introduction and importance of biomolecules. base.
3. Preparation of lyophilic and lyophobic sols.
CARBOHYDRATES - Classification: aldoses and 4. Kinetic study of reaction of iodide ion with hydrogen
ketoses: monosaccharides (glucose and fructose) and peroxide at room temperature.
constituent monosoccharides of oligosacchorides
(sucrose, lactose and maltose).

PROTEINS - Elementary Idea of α-amino acids,


peptide bond, polypeptides; Proteins: primary,
secondary, tertiary and quaternary structure
(qualitative idea only), denaturation of proteins,
enzymes.

VITAMINS - Classification and functions.

NUCLEIC ACIDS – Chemical constitution of DNA and


RNA.

Biological functions of nucleic acids.

UNIT 27 : CHEMISTRY IN EVERYDAY LIFE

Chemicals in medicines – Analgesics, tranquilizers,


antiseptics, disinfectants, antimicrobials, antifertility
drugs, antibiotics, antacids, antihistamins - their
meaning and common examples.

Chemicals in food - Preservatives, artificial sweetening


agents - common examples.

Cleansing agents - Soaps and detergents, cleansing


action.
UNIT 28: PRINCIPLES RELATED TO PRACTICAL
CHEMISTRY
• Detection of extra elements (N,S, halogens) in
organic compounds; Detection of the following

SYLLABUS FOR APTITUDE TEST B.ARCH/B.PLANNING


Part - I Awareness of persons, places. Buildings. Materials.)
Objects, Texture related to Architecture and
build-environment. Visualising three dimensional
objects from two dimensional drawings. Visualising.
different sides of three dimensional objects. Analytical
Reasoning Mental Ability (Visual, Numerical and
Verbal).

Part – II Three dimensional - perception:


Understanding and appreciation of scale and
proportion of objects, building forms and elements, colour
texture, harmony and contrast. Design and drawing of
geometrical or abstract shapes and patterns in pencil.
Transformation of forms both 2 D and 3 D union,
subtraction, rotation, development of surfaces and
volumes. Generation of Plan, elevations and 3 D views of
objects. Creating two dimensional and three dimensional
compositions using given shapes and forms.

Sketching of scenes and activities from memory of


urbanscape (public space. market, festivals, street scenes.
monuments, recreational spaces etc.), landscape (river
fronts. jungles. gardens, tre es. plants etc.) and rural life.

Note: Candidates are advised to bring pencils, own geometry


box set, erasers and colour pencils and crayons for
the Aptitude Test.

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