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L
ow cost carbon negative SNG (substitute
Figure 1. Carbon negative SNG scheme
natural gas) produced from co-gasified S Boiler feed water 150 bar
(source GL Noble Denton Ltd)
waste, biomass and coal, and CO2
decarbonised at source prior to injection into
the gas transmission system, will assist in
decarbonising downstream gas users – power, COS H2S Syngas HICOM CO2
removal
heat, transport and industry – at no cost to hydrolysis removal storage methanation (Timmins)
businesses and consumers, without alteration
to their existing use of energy, provided that 70 bar
carbon negative SNG is cost competitive with 80% waste
fossil natural gas. & biomass BGL Gas cooling
NG import Drying
20% coal gasifier and cleaning Steam
S
Particularly attractive is the integration of
SNG production technology initially
N2 CCGT
developed by British Gas Corporation
storage
and the UK government as part of a plan to
supply the whole of UK gas demand by SNG SNG
(when North Sea gas ran out) with BGL multi- O2 Site power
storage ASU
fuel co-gasification (as demonstrated by the
Electrical SNG
SVZ company operating what was once export export
Europe’s largest lignite to town gas 60 bar
production plant, at Schwarze Pumpe in
former E. Germany), together with the
Timmins CCS concept.* The cost per unit energy of carbon negative produce ‘green’ hydrogen, oxygen and heat for
The basic idea (Figure 1) is to use high SNG is estimated to be between 1/10th and low cost demand management and energy
efficiency slagging co-gasification to produce 1/15th of the ‘whole system’ cost of wind storage (see Figure 2).
carbon negative synthetic natural gas with power, and produces lower emissions than For the main carbon negative SNG scheme
CCS. The low cost carbon negative SNG, with wind when emissions from fossil fuel back up discussed here, the following results have been
gas storage, and natural gas back up, is used in are taken into account. obtained:
a conventional natural gas fired combined cycle The carbon negative SNG scheme can also Plant scale: 1.0 to 1.5 million tonnes per
plant with no loss of efficiency or operational be extended to include integrated electrolysis, annum of nominally 50% mixed wastes, 30%
flexibility. powered by low cost excess wind ‘lopping’, to biomass and 20% coal by mass.
*This article draws on the presentation given by Dr Williams at the IChemE Gasification Conference in Cagliari, Sardinia, May 2012. It also follows on from the article on
Timmins CCS published in the January 2013 edition of Modern Power Systems.
Timmins CCS is a generic CO2 separation scheme for any gas flow above 10 bar pressure, using rearranged standard gas processing plant. In the Timmins CCS scheme
the whole plant operates at high pressure, thus avoiding de-pressurisation and re-pressurisation costs, and producing high purity high pressure liquid CO2. Timmins CCS may
be integrated into a wide variety of power generation, gas processing, reforming, urea and petrochemical plants where it is desired to separate CO2 as a high purity, high
pressure liquid.
Three different schemes, based on three different fuels, using the Timmins CCS process for gas turbine power generation, are currently being developed:
Waste, biomass and coal: co-gasification with CCS to produce carbon negative SNG (as described in the present article), currently, the most advanced development of
Timmins CCS.
Coal: IGCC with CCS and a hydrogen fired CCGT. This was the topic of the January 2013 article in MPS. An update is planned, reporting on the latest results, which are
greatly improved relative to those published previously.
Natural gas: partial oxidation (POX) with autothermal reforming with a dual fuel high-hydrogen syngas/natural gas fired CCGT. Energy is recovered from the hot gases
produced by the POX reactor in an expansion turbine prior to further reforming, CCS and the CCGT. The additional energy recovered by the expander turbine offsets the
energy losses in the reforming stages.
generation at around 25% net efficiency is hazardous waste stream contains an average of
expensive and inefficient. In comparison the 10 GJ/tonne of thermochemical energy, the
British Gas originated SNG scheme with avoided cost of landfill tax is an effective £-8/GJ
Timmins CCS can produce carbon negative fuel subsidy. This can be used to offset the
SNG, which is a storable and dispatchable typical UK cost of coal and biomass at around
energy commodity, at 76.75% net efficiency, ie £3.0 to 3.50/GJ. Using an average 50:30:20
three times more ‘bang for your buck’. waste, biomass, coal (by mass) fuel mix as a
Due to the far higher net energy efficiency, basis, combined with processing of hazardous
the capital cost per unit output energy of a air pollution control residues produced in
waste gasification plant is lower than for a waste incinerators, it is possible to devise a net
waste incinerator. negative cost fuel mix with nearly 55%
Around 34% of a waste incinerator’s mass biogenic carbon content.
throughput is produced as solid, liquid and
gaseous emissions requiring expensive flue gas A strong case in the UK, EU and Figure 8. BGL gasifier in China, during
clean up, and secondary hazardous or leachable elsewhere construction (source GL Noble Denton Ltd,
waste processing and disposal operations. Our analysis shows that under a range of Zemag GmbH)
Coal and waste are both dirty hydrocarbon feasible policy scenarios, during the period
fuels. High temperature oxygen blown ‘clean 2012 to 2030, a carbon negative SNG plant in The UK CCS cost reduction task force
coal’ slagging gasification technology, UK, with a fuel input of around 1.0 to 1.5 million recently reported that by 2030 the cost of
designed to co-vitrify the heavy metal and tonnes pa (660 to 1000 MWt fuel input) of power generation with “conventional” CCS
minerals in low grade coal or lignite is equally mixed fuels will produce carbon negative SNG might feasibly be reduced from around
applicable to waste processing, and massively at a cost of around 40 to 45 p/therm, based on £160/MWh to around £100/MWh base load
reduces the secondary waste processing a 20 year payback period and 8% weighted (8000 hours pa), the cost of sequestered carbon
problems associated with waste incineration. aggregated cost of capital. reduced from around £150/tonne to about
Indeed the BGL slagging gasifier can utilise the The cost of carbon negative SNG in the UK £50/tonne, and the rate of CO2 capture
hazardous air pollution control residues case includes the avoided cost of UK landfill increased from 85% to 90%.
produced by waste incinerators as a flux to tax, the avoided cost of the UK carbon floor Over the same period, and using the same
promote slag formation. price, and a substantial developer’s risk assumptions as the task force, the cost of
As already noted, the BGL gasifier at SVZ premium, but excludes the additional revenue power generation from carbon negative SNG
Schwarze Pumpe (Figure 7) was granted full from the Renewable Heat Incentive (RHI) until would reduce from £55/MWh to £40/MWh, the
environmental certification in 1998 to co-gasify 2031, currently 104 p/therm for 54.6% biogenic cost of sequestered carbon would reduce from
up to 85% mixed hazardous and non-hazardous carbon content SNG. £15/tonne to £3/tonne, with the equivalent of
wastes, and 15% coal, and was approved by The current open market wholesale price of 110% CO2 capture rate. Even allowing for
UNEP in 2006 for the highly efficient (99.99%) natural gas in the UK is around 65 p/therm. optimism bias, and discounting any benefit
permanent destruction of persistent organic This is expected to increase to around 70 from the RHI, there is a strong case to be made
pollutants. Hazardous heavy metals are p/therm by 2015, and then gradually decrease for developing carbon negative SNG in the UK,
immobilised in a certified non-leaching vitrified from the mid 2020s onwards. There is and elsewhere in the EU.
recyclate. considerable debate about the long-term price There is also a strong case to be made for
Coal to SNG is not economic in Europe or trajectory for gas in EU and UK. It depends on, developing low cost carbon negative SNG with
USA due to the low price ‘spread’ per unit among other things, the rate at which Timmins CCS in a number of countries (eg,
energy between coal and natural gas being conventional gas is supplemented by USA, China, S Korea, Japan as well as in the
insufficient to cover the capital cost of an SNG unconventional gas, and the impact this has on EU) as a means of economically supplementing
plant. SNG developments are proceeding apace long-run oil-indexed gas prices. Informal advice natural gas resources, addressing the problem
in China due to the large ‘spread’ between the from parties associated with shale gas of ever increasing production of hazardous and
low cost of stranded coal assets in western development in the UK suggests that a non-hazardous wastes, and reducing
China, and the high cost of gas on the eastern technically and financially robust scheme, atmospheric emissions. The specific
China seaboard. Gas pipelines are the lowest which is cost competitive with the long-term circumstances of each country would of course
CAPEX method of bulk energy transmission. price trajectory for gas of around 40 to 45 need to be taken into account when developing
There is already experience with BGL and SNG p/therm, is considered to be ‘bankable’. any particular scheme. MPS