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Water Pollution:
Impact of Pollutants and New Promising Techniques in
Purification Process
Ramandeep Singh Gambhir1*, Vinod Kapoor2, Ashutosh Nirola3, Raman Sohi4 and
Vikram Bansal4
1
Department of Public Health Dentistry, 2 Department of Oral and Maxillofacial Surgery,
Gian Sagar Dental College and Hospital, Rajpura, India
3
Department of Periodontology, Laxmi Bai Dental College and Research Centre,
Patiala, India
4
Department of Public Health Dentistry, M.M. College of Dental Sciences and Research,
Mullana, Ambala, India
KEYWORDS Water Pollution. Wastes. Water Treatment. New Techniques. Pure Water
ABSTRACT Water is a critical resource in the lives of people who both benefit from its use and who are harmed by
its misuse and unpredictability (flooding, droughts, salinity, acidity, and degraded quality). Water is a finite and
vulnerable resource. Consequently, consumption of polluted water puts lives and livelihoods at risk because water has
no substitute. There are many ways in which water intended for human consumption can get polluted. These include
wastes from industries like mining and construction, food processing, radioactive wastes from power generating
industries, domestic and agricultural wastes and by various microbiological agents. Nowadays, water is being purified by
various methods but research is being conducted to look for more reliable and cheaper methods that can purify water
at an affordable cost. Various techniques have been developed like utilizing rechargeable polymer beads, seeds of
Moringa Oleifera tree, aerobic granular sludge technology, resin based treatment and two-pronged water treatment
technology.
The earliest recorded attempts to find or living with HIV/AIDS (UNICEF 2011). Almost 1
generate pure water date back to 2000 B.C. Early billion people lack access to safe and improved
Sanskrit writings outlined methods for purifying water supply. More than 50 countries still report
water (Early Water Treatment 2009). These cholera to WHO (World Health Organization).
methods ranged from boiling or placing hot metal Millions are exposed to unsafe levels of naturally-
instruments in water before drinking it to filtering occurring arsenic and fluoride in drinking water
that water through crude sand or charcoal filters. which leads to cancer and tooth/skeletal damage.
These writings suggest that the major motive in An estimated 260 million people are infected with
purifying water was to provide better tasting schistosomiasis (WHO 2004). 1.3 million people
drinking water. It was assumed that good tasting die of malaria each year, 90% of whom are
water was also clean. People did not yet connect children under 5. Impoverished slum dwellers in
impure water with disease nor did they have the Angola draw drinking water from the local river
technology necessary to recognize tasteless yet where their sewage is dumped. Farmers on the
harmful organisms and sediments in water. lower reaches of the Colorado River struggle
Although various techniques have been deve- because water has been diverted to cities like
loped in order to purify water so that it can be Las Vegas and Los Angeles. In large parts of
made safe and wholesome but large scale Africa, more than 60 percent of city dwellers are
purification involves lot of finances. Research in fact slum dwellers. For many of them, water
is being conducted worldwide in order to develop comes not from faucets inside their shacks but
newer methods which can be used to purify from water tankers or standpipes, neither of which
water and that too at an affordable cost. is reliable as a water source. Open sewers
The main objectives of this study is to increase the risk of water-borne diseases (UN
highlight the impact of various water pollutants works 2010).
which have rendered the water unsuitable for
drinking and other domestic purposes and to HUMAN ACTIVITIES RESPONSIBLE
enumerate new and affordable techniques which FOR WATER POLLUTION
can be used to purify water for various purposes.
Virtually all human activities produce some
Facts and Figures Related to Water Pollution kind of environmental disturbance that contami-
nate surrounding waters. Eating (body wastes),
Disease spreads by consumption of polluted gardening (pesticide and sediment runoff) and
water. It has been estimated that 50,000 people many other activities create byproducts that can
die daily world-wide as a result of water-related find their way into the water cycle. For conveni-
diseases (Nevondo and Cloete 1999). A large ence, we can assign the large majority of sources
number of people in developing countries lack of water pollution to three broad categories of
access to adequate water supply. In South Africa, waste (Mc Kinney and Schoch 2003).
it has been estimated that more than 12 million a. Industrial
people do not have access to an adequate b. Agricultural and
supply of potable water (Nevondo and Cloete c. Domestic wastes
1999). Polluted water also contains viruses,
bacteria, intestinal parasites and other harmful a. Industrial Wastes
microorganisms, which can cause waterborne
diseases such as diarrhea, dysentery, and Wastes from industry serve as major
typhoid. Due to water pollution, the entire eco- sources for all water pollutants. Many major
system gets disturbed. Unsafe drinking water, industries contribute significantly to water
along with poor sanitation and hygiene, are the pollution, but some of the important are the (i)
main contributors to an estimated 4 billion cases manufacturing (ii) power-generating (iii) mining
of diarrhoeal disease annually, causing more than and construction, and (iv) food processing
1.5 million deaths, mostly among children under industries (Mc Kinney and Schoch 2003).
5 years of age (WHO 2005). Contaminated Manufacturing industries like chemical, oil
drinking water is also a major source of hepatitis, refining, steel etc. contribute many of the most
typhoid and opportunistic infections that attack highly toxic pollutants, including a variety of
the immuno-compromised, especially persons organic chemicals and heavy metals (Mc Kinney
WATER POLLUTING AGENTS AND NEW PURIFICATION TECHNIQUES 105
contained in washing powders affect the health trypanosomiasis (tse-tse fly-borne) and
of all forms of life in the water. onchocerciasis (black fly-borne)
(Obasohan et al. 2010).
Micro-organisms Causing Water Pollution
NEW TECHNIQUES IN WATER
There are various micro-biological agents PURIFICATION PROCESS
which can also cause water pollution if drinking
water gets contaminated with these agents. The 1. Point-of-use Water Purification Using
pathogenic agents involved include bacteria, Rechargeable Polymer Beads
viruses and protozoa which may cause diseases
that vary in severity from mild gastroenteritis to ‘Halo-pure’ is one such enabling technical
severe and sometime fatal diarrhoea, dysentery, advance in the development of an entirely new
hepatitis or typhoid fever (WHO 1996). Most of biocidal medium in the form of chlorine-
them are widely distributed throughout the rechargeable polystyrene beads that is based
world. Faecal contamination of drinking water is on patented chemistry inventions from the
only one of several faeco-oral mechanisms by Department of Chemistry at Auburn University
which they can be transmitted from one person (Dunk et al. 2005). The discoveries were natural
to another or, in some cases, from animals to but creative outcome of a series of studies,
people. covering more than a decade of research, focused
Most of the mortality and morbidity on stabilizing chlorine on water insoluble,
associated with water related disease especially synthetic polymer surfaces.
in developing countries is due directly or The fundamental principles of the
indirectly to infectious agents which infect man technology are deceptively simple to under-
through:- stand, although their incorporation into a reliably
1) Ingesting pathogenic bacteria, viruses reproducible and practical medium for water
or parasites (protozoans and helminthes) sanitation has taken years of intense effort and
in water polluted by human or animal research. Porous polystyrene beads are similar
faeces or urine. Diseases in this to those used for water softener resin beds, are
category include cholera (Cholera modified chemically so as to be able to bind
vibrio), shigellosis (dysentery caused chlorine or bromine reversibly in its oxidative
by Shigella spp.), typhoid (Samonella form. All that is required is enough free chlorine
typhi), paratyphoid (Samonella to surround the binding site. Almost no free
paratyphi), diarrhea (Escherichia coli), chlorine is released when the beads are placed
hepatitis (Hepatitis virus) and into the water flow. Typical levels range from
poliomyelitis (Polio virus) (Obasohan et 0.05 ppm to 0.20 ppm free available chlorine. This
al. 2010). is not enough to kill anything without lengthy
2) Diseases associated with scarcity of incubation. Hence, the swift efficacy of Halo-
water for personal hygiene (bathing, pure depends on intimate contact between the
hand washing), laundering clothes and microbes and the bound halogen on the polymer.
cleaning of cooking utensils. In this What you have, then, is a solid surface,
category of diseases are scabies, yaws, effectively biocidal on contact to contaminants
skin ulcers, conjunctivitis and trachoma in the water and repeatedly rechargeable when
(Obasohan et al. 2010). periodically exposed to free halogen. In this way,
3) Diseases associated with ingestion or a powerful antimicrobial component can be
penetration of human skin by infective introduced into a water purifier that will not run
forms that require a snail, fish or other out of steam, and have to be discarded. Instead,
aquatic hosts. Examples include schisto- it can have its power regularly and conveniently
somiasis, clonorchiasis and paragoni- “topped up” by the user. Organisms make
miasis (Obasohan et al. 2010). contact with the display of chlorine, for example,
4) Diseases from being bitten by insect on the surface of the beads, and pick up enough
vector which breeds in or around water. halogen to inactivate them in short order. Those
They include malaria, dengue, yellow not killed within seconds suffer a near-death
fever, filariasis (mosquito-borne); experience, and succumb quickly in the product
WATER POLLUTING AGENTS AND NEW PURIFICATION TECHNIQUES 107
water as the adherent chlorine slowly damages be prepared fresh each time. In general, 1 seed
the organism to the point of fatal consequences kernel will treat 1 liter (1.056 qt) of water.
(Dunk et al. 2005). Dosage Rates: Low turbidity NTU
The technology holds the promise of (Nephelometric Turbidity Units) <50 1 seed per
reducing the impact of water borne diseases 4 liters (4.225 qt) water
throughout the developing world. Its widespread Medium Turbidity: NTU 50-150 1 seed per 2
use could contribute to the realization of UN liters (2.112 qt) water
goals for access to safe water for all by 2015. High Turbidity: NTU 150-250 1 seed per 1
And it could do so without resort to the massive liter (1.056 qt) water
infrastructure investments that are needed to Extreme Turbidity: NTU >250 2 seeds per 1
reach this goal using more conventional centra- liter (1.056 qt) water
lized sanitation and distribution approaches
(Dunk et al. 2005). 3. Water Purification Using Aerobic Granular
Sludge Technology
2. Water Treatment Using the Seeds of the
Moringa oleifera Tree With the new aerobic granular sludge
technology, aerobic (thus oxygen using) bac-
Using natural materials to clarify water is a terial granules are formed in the water that is to
technique that has been practiced for centuries be purified. The great advantage of these
and of all the materials that have been used, seeds granules is that they sink quickly and that all the
of the Moringa have been found to be one of the required biological purifying processes occur
most effective. Studies have been conducted within these granules (Delft University of
since the early 1970’s to test the effectiveness of Technology 2006).
Moringa seeds for treating water (Paterniani et al. The technology, therefore, offers important
2010). These studies have confirmed that the advantages when compared to conventional
seeds are highly effective in removing suspended water purification processes. For example, all the
particles from water with medium to high levels of processes can occur in one reactor. Moreover,
turbidity (Moringa seeds are less effective at there is no need to use large re-sinking tanks,
treating water with low levels of turbidity). such as those used for conventional purification.
Moringa oleifera seeds treat water on two Such large tanks are needed for this because the
levels, acting both as a coagulant and an antimi- bacteria clusters that are formed take much longer
crobial agent. It is generally accepted that time to sink than the aerobic granule sludge.
Moringa works as a coagulant due to positively The aerobic granular sludge technology is
charged, water-soluble proteins, which bind with very promising, and has been nominated for the
negatively charged particles (silt, clay, bacteria, Dutch Process Innovation Award. The techno-
toxins, etc) allowing the resulting “flocs” to settle logy is now in the commercialisation phase. In
to the bottom or be removed by filtration. The the coming years, further research will be
antimicrobial aspects of Moringa continue to be continued. Testing of this purification method
researched. Findings support recombinant is being done on a larger scale. The first
proteins both removing microorganisms by installations are already in use in the industrial
coagulation as well as acting directly as growth sector (Delft University of Technology 2006).
inhibitors of the microorganisms. While there is
ongoing research being conducted on the nature 4. Resin Based Treatment for Colour and
and characteristics of these components, it is Organic Impurities Removal
accepted that treatments with Moringa solutions
will remove 90-99.9% of the impurities in water The rapid industrialization during the last
(Paterniani et al. 2010). few decades has resulted in tremendous increase
Solutions of Moringa seeds for water in demand of water for industries. A large
treatment may be prepared from seed kernels or quantity of water used is ultimately discharged
from the solid residue left over after oil extraction into water bodies and land as waste water from
(presscake). Moringa seeds, seed kernels or various unit operations related to various
dried presscake can be stored for long periods industrial processes, and is responsible for their
but Moringa solutions for treating water should pollution (Kumar and Bhatia 2007). Attempts
108 RAMANDEEP SINGH GAMBHIR, VINOD KAPOOR, ASHUTOSH NIROLA ET AL.
have been made to prevent the adverse aesthetic everyone will have access to clean and pure
effects associated with industrial waste water water and that too at an affordable cost.
discharges by accelerating the removal of colour
during treatment of the variety of industrial ACKNOWLEDGEMENTS
wastes. Colour removal is also important if the
water has to be made suitable for drinking I would like to thank all my co-authors for
purpose because many times underground water rendering me the required support needed to
comes with colour and this colour has to be complete the article. This work should be
removed prior to drinking. attributed to Gian Sagar Dental College and
Among the manufacturing operations, the Hospital, Ramnagar, Rajpura.
textile dyeing and finishing industries are directly
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