CPP

IIT-JEE
Ch em i str y Batch : XI
MOLE CONCEPT

SOME BASIC CONCEPT AND MOLE CONCEPT

1. Match the following :

COLUMN – I COLUMN – II
A 52g of He P 13 atoms

B 52 moles of He Q 44.8 L
23
C 34 g of NH3 R 313.196  10 atoms
23
D 52 u of He S 78.299  10 atoms

2. Iron has a density of 7.86 g cm–3 and an atomic mass of 55.85 amu. The volume occupied by 1 mol of Fe is :
(A) 0.141 cm3 mol–1 (B) 7.11 cm3 mol–1 (C) 4.28 × 1024 cm3 mol–1 (D) 22.8 cm3 mol–1

3. The number of gram-molecules of oxygen in 6.02 × 1024 molecules of CO is :

(A) 10 (B) 5 (C) 1 (D) 0.5

4. The number of atoms present in 11.2 L of SO2 at S.T.P. is :

(A) 1.5 NA (B) 2 NA (C) NA (D) 4 NA

5. The volume (in litres) of CO2 liberated at STP when 10 g of 90% pure limestone is heated completely is :
(A) 22.4 (B) 2.24 (C) 20.16 (D) 2.016

6. Among the following the largest number of molecules is in :

(A) 28.0 g of CO2 (B) 46.0 g of CH3OH (C) 34.0 g of water (D) 54.0 g of N2O5

7. On being heated strongly, 2.76 g of Ag2CO3 (Ag = 108) yields a residue weighing :
(A) 2.16 g (B) 2.48 g (C) 2.32 g (D) 2.64 g

8. An electric bulb was filled with 100 cc of argon gas (At. mass = 40) at 25 °C and 1 atm pressure. The number of
atoms of argon present in the bulb is :
(A) 2.5 × 1021 (B) 3.3 × 1024 (C) 1.5 × 1024 (D) 6.02 × 1021

9. A certain gaseous mixture contains methane and sulphur dioxide in ratio of 1 : 8 by mass. The ratio of number
of molecules is :
(A) 1 : 8 (B) 1 : 2 (C) 1 : 1 (D) 2 : 1

10. The crystalline salt Na2SO4.xH2O on heating loses 55.9% of its weight. The formula of the crystalline salt is :
(A) Na2SO4.5H2O (B) Na2SO4.7H2O (C) Na2SO4.10H2O (D) Na2SO4.6H2O

11. A plant virus is found to consist of uniform cylindrical particles of 150 Å in diameter and 5000 Å long. The
specific volume of the virus is 0.75 cm3/g. If the virus is considered to be a single particle then its approximate
molecular weight is :
(A) 8 × 107 (B) 10.9 × 108 (C) 7 × 107 (D) 9 × 108

12. The vapour density of a mixture containing NO2 and N2O4 is 38.3 at 27°C. The mole of NO2 in 100 mole mixture
is :
(A) 35 mole (B) 36.5 mole (C) 40 mole (D) 33.48 mole

FIITJEE 1
13. The number of water molecules in 1 litre of water is :
(A) 18 (B) 18 × 1000 (C) NA (D) 55.55 NA

14. The number of moles of BaCO3 which contains 1.5 moles of oxygen atoms is :
(A) 0.5 (B) 1 (C) 3 (D) 6.02 × 1023

15. If NA is Avogadro’s number then number of valence electrons in 4.2 g of nitride ions (N3–) is :
(A) 2.4 NA (B) 4.2 NA (C) 1.6 NA (D) 3.2 NA

16. A quantity of aluminium has a mass of 54.0 g. What is the mass of the same number of magnesium atoms ?
(A) 12.1 g (B) 24.3 g (C) 48.6 g (D) 97.2 g

17. If the atomic weight of carbon is taken to be 6 amu, the value of the Avogadro constant will be :
(A) 12.04 × 1023 mol–1 (B) 3.01 × 1023 mol–1 (C) 1.5 × 1023 mol–1 (D) 6.02 × 1023 mol–1

18. The charge on 1 gram ion of Al3+ is :

1 1 1
(A) N A e coulomb (B)  N A e coulomb (C)  N A e coulomb (D) 3 × NAe coulomb
27 3 9

19. A gaseous mixture contains CO2(g) and N2O(g) in a 2 : 5 ratio by mass. The ratio of the number of molecules of
CO2(g) and N2O(g) is :
(A) 5 : 2 (B) 2 : 5 (C) 1 : 2 (D) 5 : 4

20. X and Y are two elements which form X2Y3 and X3Y4. If 0.20 mol of X2Y3 weighs 32.0 g and 0.4 mol of X3Y4
weighs 92.8 g, the atomic weights of X and Y are respectively.
(A) 16.0 and 56.0 (B) 8.0 and 28.0 (C) 56.0 and 16.0 (D) 28.0 and 8.0

21. The density of water at 4 °C is 1.0 × 103 kg m–3. The volume occupied by one molecule of water is approximately
:
(A) 3.0 × 10–23 mL (B) 6.0 × 10–22 mL (C) 3.0 × 10–21 mL (D) 9.0 × 10–23 mL

22. The relative abundance of two isotopes of atomic mass 85 and 87 is 75% and 25% respectively. The average
atomic mass of element is
(A) 75.5 (B) 85.5 (C) 40.0 (D) 86.0

23. The number of oxygen atoms in 0.2 mole of decahydrate sodium carbonate is
(A) 1.56 x 10 24 (B) 1.56 x 10 23 (C) 1.56 x 10 25 (D) 3. 12 x 10 24 .

24. The mass of carbon (II) oxide which contains 6.02 x 10 23 oxygen atom is
(A) 2.8 g (B) 28 g (C) 14 g (D) 1.4 g

25. The volume of a gas at 0C and 700 mm pressure is 760 cc. The no. of molecules present in this volume is
(A) 1.88 x 10 22 (B) 6.022 x 10 23 (C) 18.8 x 10 23 (D) 18.8 x 10 22

26. 1 mole of diatomic element X2 contains 34 and 40 moles of electron and neutron respectively. The isotopic
formula of the element is
74 37 40 40
(A) 34 X (B) 17 X (C) 34 X (D) 20 X

27. 6.022 × 1022 molecules of N2 at NTP will occupy a volume of :

(A) 22.4 litre (B) 2.24 litre (C) 6.02 litres (D) 6.02 ml

28. Molecular weight of a gas, 11.2 litres of which at STP weighs 14 g is :

(A) 14 (B) 28 (C) 14/11.2 (D) 14 × 11.2

29. Which of the following contains greatest number of oxygen atoms ?

(A) 1 g of O (B) 1 g of O2
(C) 1 g of O3 (D) all have the same no. of atoms

FIITJEE 2
30. Which of the following has the highest mass ?
1
(A) 1 g-atom of C (B) mole of CH4
2
(C) 10 mL of water (D) 3.011 × 1023 atoms of oxygen

31. 6.022 × 1022 molecules of N2 at NTP will occupy a volumeof :

(A) 22.4 litres (B) 2.24 litres (C) 6.02 litres (D) 6.02 mL

32. How many grams are contained in 1 gram-atom of Na?

1
(A) 13 g (B) 23 g (C) 1g (D) g
23

33. The wight of 350 mL of a diatomic gas at 0°C and 2 atm pressure is 1 g. The wt. of one atom is :
16 32
(A) (B) (C) 16 N (D) 32 N (N is the Av. const)
N N

34. 1 mole of compound contains 1 mole of C and 2 moles of O. The molecular weight of the compound is :
(A) 3 (B) 12 (C) 32 (D) 44

35. The total number of atoms of oxygen in 0.2 mol of Na2B4O7  10 H2O will be :
(A) 6.02 × 1023 (B) 1.02 × 1024 (C) 2.05 × 1024 (D) 2.05 × 1023

36. How many moles of electrons weigh one kilogram ?

1 6.022 1
(A) 6.022  1023 (B)  1031 (C)  1054 (D)  108
9.108 9.108 9.108  6.022

37. The number of atoms in 20 g of SO3 is approximately :

(A) 1 × 1023 (B) 1.5 × 1023 (C) 2 × 1023 (D) 6 × 1023

38. Which of the following contains the greatest mass of oxygen ?

(A) 0.1 mol O3 (B) 10 g O2 (C) 79 g KMnO4 (D) 10 g Na2CO3

39. The no. of mol. of the independent species present in one mole of potash alum
(A) 32 (B)16 (C) 38 (D) 64

40. A mixture of gas ''X'' (mol. wt. 16) and gas Y (mol. wt. 28) in the mole ratio a : b has a mean molecular weight
20. What would be mean molecular weight if the gases are mixed in the ratio b : a under identical conditions
(gases are non reacting).
(A) 24 (B) 20 (C) 26 (D) 40

41. An oxide of sulphur contains 50% of ‘S’. What will be its empirical formula :
(A) SO (B) SO2 (C) SO3 (D) S2O3

42. One litre of a gas at S.T.P. weighs 1.16 g. It can possibly be :

(A) C2H2 (B) CO (C) O2 (D) CH4

43. A certain compound has the molecular formula X4O6. If 10 gm of compound contains 5.62 g of X, the atomic
mass of X :
(A) 32 amu (B) 37 amu (C) 42 amu (D) 48 amu

44. An oxide of a metal (M) contains 60% by mass of metal. Metal (M) has relative mass of 24. The empirical
formula of the oxide is :
(A) M2O (B) MO (C) M2O3 (D) M3O

45. If 224 mL of a triatomic gas has a mass of 1 g at 273 K and 1 atm pressure, then the mass of one atom is :
(A) 8.30 × 10–23 g (B) 2.08 × 10–23 g (C) 5.53 × 10–23 g (D) 6.24 × 10–23 g

FIITJEE 3
46. How many molecules of an ideal gas are there in 1 mL of the gas if temperature is 27°C and pressure is 3 atm
?
(A) 8.15 × 1023 (B) 8.15 × 1020 (C) 7.34 × 1019 (D) 7.34 × 1022

47. If isotopic distribution of C-12 and C-14 is 98% and 2% respectively, then the number of C-14 atoms is 12 g of
carbon is :
(A) 1.032 × 1022 (B) 3.01 × 1022 (C) 5.88 × 1023 (D) 6.023 × 1023

48. If 0.25 g of a substance when vaporized displaced 50 cm3 of air at S.T.P. the gram molecular mass of the
substance will be :
(A) 50 g (B) 100 g (C) 112 g (D) 127.5 g

49. For the reaction, A + 2B  C, 5 moles of A and B moles of B will produce :

(A) 5 moles of C (B) 4 moles of C (C) 8 moles of C (D) 13 moles of C

50. The compound possess 8% sulphur by mass. The least molecular mass is :
(A) 200 (B) 400 (C) 155 (D) 355

51. The simplest formula of a compound containing 50% of element X (atomic mass = 10) and 50% of element
Y (atomic mass = 20) is :
(A) XY (B) X2Y (C) XY3 (D) X2Y3

52. The percentage of nitrogen in urea is about :

(A) 38.4 (B) 46.6 (C) 59.1 (D) 61.3

53. The weight of sulphuric acid needed for dissolving 3g magnesium carbonate is
(A) 3.5 g (B) 7.0 g (C) 1.7 g (D) 17.0 g

54. Two oxides of a metal contain 27.6% and 30% of oxygen respectively. If the formula of the 1st oxide is M3O4,
the formula of the 2nd oxide is :
(A) MO (B) M2O3 (C) MO2 (D) M3O2

55. The empirical formula of a compound is CH. Its molecular weight is 78. The molecular formula of compound
will be :
(A) C2H2 (B) C3H3 (C) C4H4
(D) C6H6

56. A compound was found to contain nitrogen and oxygen in the ratio nitrogen 28g and 80g of oxygen. The formula
of the compound is
(A) NO (B) N2O3 (C) N2O5 (D) N2O4

57. 10 ml of gaseous hydrocarbon on combustion gives 40 ml of CO2(g) and 50 ml of H2O (vapour). The hydrocarbon
is
(A) C4H5 (B) C8H10 (C) C4H8 (D) C4H10

58. The number of atoms present in 16 g of oxygen is :

(A) 6.02 × 10115 (B) 3.01 × 1023 (C) 3.01 × 1011.5 (D) 6.02 × 1023

59. The chief ore of manganese is an oxide known as pyrolusite, which is 36.8% O and 63.2% Mn by mass. Which
of the following oxides of manganese is pyrolusite? [At Wts: O = 16.00 amu; Mn = 54.94 amu]
(A)MnO (B)MnO2 (C)Mn2O3 (D) MnO3

60. In a reaction, 4 moles of electrons are transferred to one mole of HNO3. The possible product obtained due to the
reduction is
(A) 1.5 moles of N2 (B) 0.5 mole of N2O (C) 1 mole of NO2 (D) 1 mole of NH3

FIITJEE 4
61. There are two common oxides of S; one contains 50% O2 by weight and the other contains 60% O2 by weight.
The weights of sulphur that combine with 1 g of oxygen are in the ratio
(A) 1 : 1 (B) 2 : 1 (C) 2 : 3 (D) 3 : 2

62. 0.0833 mol of carbohydrate of empirical formula CH2O contains 1 g of Hydrogen. The molecular formula of the
carbohydrate is
(A) C5H10O5 (B) C3H4O3 (C) C12H22O11 (D) C6H12O6

63. The molecular formula of certain compound is M4O6. If 18.88 g of the compound contains 10 g of M, the atomic
mass of M is approximately
(A) 40 g (B) 54 g (C) 27 g (D) 12 g

PROBLEM BASED ON CHEMICAL EQUATION & CONCEPT OF LIMITING

REAGENT

64. 1.44 gram of Titanium (Ti) reacted with excess of O2 and produced x gram of non-stoichiometric compound
Ti1.44O. The value of x will be
(A) 2.77 g (B) 3.77 g (C) 1.77 g (D) 3.0 g

65. 8 gm sulphur are burnt to form SO2 which is then oxidised by chlorine to sulphate. The solution is now treated
with BaCl2 solution. The amount of BaSO4 precipitated in mol will be
(A) 0.25 mol (B) 0.30 mol (C) 0.50 mol (D) 0.75 mol

66. 5.00 moles of hydrogen gas, 3 moles of white phosphorus {P4(s)} and 12 moles of oxygen gas are taken in a
sealed flask and allowed to react as follws :
H2(g) + P4(s) + O2(g)  H3PO4
Determine the moles of ortho-phosphoric acid that can be produced, considering that the reaction occurs in
90% yield.
(A) 3 mol (B) 0.30 mol (C) 5 mol (D) 0.75 mol

67. An unknown compound contains 8% sulphur by mass. The least molecular weight of the compound and its
molecular weight if one molecule contains 4 atoms of S respectively are :
(A) 200, 400 (B) 300, 400 (C) 400, 1600 (D) 400, 1200

68. Equal masses of zinc and iodine are mixed together to form zinc iodide, ZnI2. Which is limiting reagent? What
percent of excess reactant taken will be left after the reaction ? (Zn = 65.4, I = 127)

69. Calculate the amount of ZnO produced (in gm) when 195 gm of ZnS reacts with 89.6 l O2 at 1 atm and 273 K.
ZnS + O2  ZnO + SO2

70. Commercial bronze, an alloy of Zn and Cu, reacts with hydrochloric acid as follows: (Zn = 65.37)
Zn(s) + 2HCl(aq)  ZnCl2(aq) + H2(g)
Copper does not react with HCl. When 0.507 g of bronze reacts with excess HCl, 0.0985 grams of ZnCl2 is
produced. The % by mass of Zn in bronze is closest to:
(A) 9.34% (B)19.34% (C)30.34% (D)69.66%

71. A fuel mixture of two liquids, hydrazine (N2H4) and dinitrogen tetraoxide (N2O4) ignite to form nitrogen gas and
water vapor. How many grams of nitrogen gas form when exactly 100.0 g N2H4 and 200.0 g of N2O4 are mixed?
(Assume the reaction goes to completion.)
(A) 662 g N2 (B)331 g N2 (C)183 g N2 (D)131 g N2

72. According to the following reaction the minimum quantity in gm of H2S needed to precipitate 63.5 gm of Cu2+
ions will be nearly Cu+2 + H2S  CuS + 2H+
(A) 63.5 gm (B) 31.75 gm (C) 34 gm (D) 20 gm

FIITJEE 5
73. The number of atoms present in 0.05 g of water is :
(A) 1.67 × 1023 (B) 1.67 × 1022 (C) 5.02 × 1021 (D) 1.67 × 1021

74. 4I– + Hg2+  HgI42–, 1 mole each of Hg2+ and I– will form HgI42– :
(A) 0.25 mole (B) 0.5 mole (C) 0.75 mole (D) 1 mole

75. When 1 L of CO2 is heated with graphite, the volume of the gases collected is 1.5 L. Calculate the number of
moles of CO produced at S.T.P.
1 28 1 14
(A) (B) (C) (D)
11.2 22.4 22.4 22.4

76. If a compound contains one sulphur atoms, four oxygen atoms and number of hydrogen atoms is half of oxygen
atoms, the vapour density will be :
(A) 98 (B) 49 (C) 24.5 (D) unpredictable

77. X g of Ag was dissolved in HNO2 and the solution was treated with excess of NaCl when 2.87 g of AgCl was
precipitated. The value of x is :
(A) 1.08 g (B) 2.16 g (C) 2.70 g (D) 1.62 g

78. What mass of barium chloride in grams would be enough to produce 14.35 g of AgCl ? (At. mass of Ba = 137;
Ag = 108)
(A) 10.4 g (B) 5.2 g (C) 15.6 g (D) 7.8 g

79. The weight of slaked lime necessary to decompose completely 1.07 g of ammonium chloride is :
(A) 0.74 g (B) 1.48 g (C) 7.4 g (D) 0.37 g

80. 32 g of sulphur is burnt with 6.02 × 1023 molecules of oxygen to produce a suffocating gas. The volume of
reactants would be . . . . . as products
(A) one-fourth (B) one-half (C) the same (D) three-fourth

81. 1 gram molecule of chlorine combines with a certain weight of a metal giving 111 g of its chloride. The
same weight of the metal displaced 2 g of hydrogen from an acid. The atomic weight of the metal (assuming
its valency to be 2) is :
(A) 40 (B) 20 (C) 80 (D) none of these

82. Calculate the volume of CO 2 produced by the combustion of 40 ml of acetone vapours in presence of
excess of oxygen
(A) 12 ml (B) 1.20 ml (C) 120 ml (D) 11.2 ml

83. The mass of nitrogen in 1 kg of ammonium nitrate is :

(A) 700 g (B) 3.5 × 10–1 kg (C) 350 g (D) 35 g

84. Which of the following will not have a mass of 10 g ?

(A) 0.1 mol of CaCO3 (B) 1.51 × 1023 Ca2+ ions (C) 0.016 mole of CO32– (D) 7.525 × 1023 Br atom

85. The mole percent of oxygen present in gaseous mixture containing 14.0 g nitrogen and 32 g oxygen is :
(A) 50 (B) 33.3 (C) 66.6 (D) 40

86. The number of molecules present in C drop of water with volume = 0.06 cc (density 1 g/cc) is approximately :
(A) 1021 (B) 2 × 1021 (C) 3 × 1021 (D) 4 × 1021

87. 1.6 g of sulphur was burnt in air to form SO2. The member of molecules of SO2 introduced into the air will be :
(A) 6.02 × 1023 (B) 3.01 × 1023 (C) 6.02 × 1022 (D) 3.01 × 1022

REDOX REACTION & BALANCING

88. In which of the following compounds, nitrogen has an oxidation state of –1?
(A) N2O (B) NO2– (C) NH2OH (D) N2H4

FIITJEE 6
89. The oxide that cannot act as a reducing agent is
(A) SO2 (B) NO2 (C) CO2 (D) ClO2

90. A mole of N2H4 loses 10 mol of electrons to form a new compound. Y Assuming that all the nitrogen appears in
the new compound, what is the oxidation state of nitrogen in Y ? (There is no change in the oxidation number
of hydrogen)
(A) –1 (B) –3 (C) +3 (D) +5

91. When copper is treated with a certain concentration of nitric acid, nitric oxide and nitrogen dioxide are liberated
in equal volumes according to the equation :
xCu  yHNO3  Cu(NO3 )2  NO  NO2  H2O
The coefficients x and y are
(A) 2 and 3 (B) 2 and 6 (C) 1 and 3 (D) 3 and 8

92. KBrO3 + 8H+  Br– + H2O ; The equivalent weight of BrO3– in the above reaction is (Br = 80) :
(A) 167 (B) 28 (C) 33 (D) 42

93. N2 + 3H2  2NH3

Molecular weights of NH3 and N2 are X1 and X2 their equivalent weights are Y1 and Y2 then Y1 - Y2 is :
 2X1 - X 2   2X1 - X 2 
(A)   (B)   (C) (3X1 – X2) (D) X1 – 3X2
 3   6 

94. Equivalent weight of MnO4– in acidic, neutral and basic media are in ratio of :
(A) 3 : 5 : 15 (B) 5 : 3 : 1 (C) 5 : 1 : 13 (D) 3 : 15 : 5

95. In the following reaction :

NO3–  As2S3  H2O  AsO3– 2–
4  NO  SO4  H


the equivalent weight of As2S3 (with molecular weight M) is

3M M M M
(A) (B) (C) (D)
28 4 24 28

96. 0.84 g of metal carbonates reacts with 40 ml of N/2 H2SO4. The equivalent weight of metal carbonate is :
(A) 84 g (B) 64 g (C) 42 g (D) 38 g

97. The equivalent weight of MnSO4 is half of its molecular weight when it is converted to :
(A) Mn2O3 (B) MnO2 (C) MnO4 (D) MnO42–

98. The equivalent weight of KMnO4 in neutral medium is (mol. wt = M) :

M M M
(A) (B) M (C) (D)
2 4 3

99. Equivalent weight of CuS when it undergoes the following change CuS  Cu2+ + SO2
M M M M
(A) (B) (C) (D)
2 3 4 6

100. The equivalent weight of an element is 4, its chloride has vapour density of 59.25 then the valency to he element
is :
(A) 4 (B) 3 (C) 2 (D) 1

101. 0.42 g of a metal forms 0.56 g of metal oxide. Its equivalent mass is :
(A) 12 (B) 24 (C) 48 (D) 72

FIITJEE 7
102. A metallic oxide contains 60% of the metal. The equivalent mass of the metal is :
(A) 12 (B) 24 (C) 48 (D) 72

103. When a metal is burnt, its mass increases by 50%. The equivalent mass of the metal is :
(A) 16 (B) 24 (C) 25.0 (D) 33.3

104. 9 gm of Al (at. Wt. = 27) will react completely with an acid to give :
(A) one mole of H2 (B) one half mole of H2 (C) one-third mole of H2 (D) none of these

105. How many gram of H3PO 4 would be needed to neutralise 100 gm of Mg (OH) 2 ?
(A) 66.7 gm (B) 252 gm (C) 112.6 gm (D) 168 gm

106. What weight of CuSO 4.5H2O must be taken to make 0.5 litre of 0.01 M Cu2+ ions solution ?
(A) 12.45 gm (B) 1.245 gm (C) 6.24 gm (D) 100 gm

EQUIVALENT CONCEPT

107. 2 grams of a gas mixture of CO and CO 2 on reaction with excess I 2O5 yield 2.54 grams of I 2. 7What would
be the weight % of CO in the original mixture ?
(A) 70.1 (B) 75.3 (C) 68.4 (D) 80.7

108. In an organic compound of molar mass greater than 100 containing only C, H and N, the percentage of C
is 6 times the percentage of H while the sum of the percentages of C and H is 1.5 times the percentage of
N. What is the least molar mass :
(A) 175 (B) 140 (C) 105 (D) 210

109. If an equal volume of 1 M KMnO4 and 1 M K2Cr2O7 solutions is allowed to oxidise Fe(II) to Fe(III) in an acidic
medium, then amount of Fe+2 oxidised will be :
(A) more by KMnO4 (B) more by K2Cr2O7
(C) equal in both the cases (D) cannot be determined

110. When 0.5 mol of BaCl2 is added to 0.2 mol of Na3PO4, the number of moles of Ba3(PO4)2 formed is :
(A) 0.10 (B) 0.20 (C) 0.40 (D) 0.15

111. Sulphuryl chloride, SO2Cl2, reacts with H2O to give mixture of H2SO4 and HCl. Aqueous solution of one mol
SO2Cl2 will be neutralised by :
(A) 3 mol of NaOH (B) 2 mol of Ca(OH)2 (C) Both (D) None

112. The number of moles of KMnO4 required to oxidise one mole of Fe C2 O4 in an acidic medium is
(A) 0.6 (B) 1.67 (C) 0.2 (D) 0.4

113. For reaction

Mx   MnO–4  MO3–  Mn2  (1/ 2)O2

if 1 mol of MnO4– MO3– + Mn2+ to MO3– , then the value of x in the reaction is :
(A) 5 (B) 3 (C) 2 (D) 1

114. A solution containing 2.68 × 10–3 mol of An+ requires 1.61 × 10–3 mol. of MnO4– for the conversion of An+ to
AO3– in acidic medium. What is the value of n ?
(A) 8 (B) 13 (C) 2 (D) 3

115. One gram of a variable alloy of lead and tin yielded on treatment with conc. HNO 3, filtration and heating
0.42 grams of SnO 2. If all the lead in one gram of alloy is converted into PbSO 4, what will be the weight of
PbSO 4 obtained ?
(A) 0.98 (B) 1 g (C) 1.07 g (D) 0.95 g

116. An iodide solution, ½ litre containing 0.664 grams of KI per litre, required 100 ml of a certain solution of
Ce4+ ion for complete reaction. What is the normality of the Ce 4+ solution ?
(A) 0.04 (B) 0.004 (C) 0.02 (D) none of these

FIITJEE 8
117. 0.7 g of a sample of Na2CO 3. x H2O were dissolved in water and the volume was made to 100 ml . 20 ml
of this solution required 19.8 ml of N/10 HCl for complete neutralization. The value of x is :
(A) 7 (B) 3 (C) 2 (D) 5

118. 34 g of hydrogen peroxide is present in 1120 ml of solution. This solution is called :

(A) 10 vol solution (B) 20 vol solution (C) 30 vol solution (D) 32 vol solution

119. Exactly 4.00 gm of a solution of H2SO 4 was diluted with water and excess BaCl 2 was added. The washed
and dried precipitate of BaSO 4 weighed 4.08 gm. Find the percent H2SO 4 in the original acid solution.
(A) 43.0 % (B) 4.3 % (C) 47 % (D) none

120. Number of moles of electrons taken up when 1 mole of NO 3– ions is reduced to 1 mole of NH2OH is :
(A) 2 (B) 4 (C) 5 (D) 6

121. What volume of chlorine at STP is required to liberate all the iodine from 200 ml of 0.2 M KI solution :
(A) 896 ml (B) 448 ml (C) 224 ml (D) 672 ml

122. The mass of precipitates produced when carbon dioxide is bubbled through 500 mL of 1 N Ca(OH)2 will be :
(A) 10 g (B) 20 g (C) 25 g (D) 50 g

123. In alkaline medium, KMnO4 reacts as follows: 2KMnO4 + 2KOH  2 K2MnO4 + H2O + O
Therefore, the equivalent mass of KMnO4 will be :
(A) 31.6 (B) 52.7 (C) 7.0 (D) 158.0

124.  Ca (PO ) + 6H O. Equivalent mass of H PO in this reaction is :

2H3PO4 + 3Ca(OH)2  3 4 2 2 3 4
(A) 98 (B) 49 (C) 32.66 (D) 24.5

125. 12 g of an alkaline earth metal gave 14.8 g of its nitride. Atomic mass of that metal is :
(A) 20 (B) 12 (C) 40 (D) 14.8

126. When one gram mole of KMnO 4 reacts with HCl, the volume of chlorine liberated at NTP will be :
(A) 11.2 litres (B) 22.4 litres (C) 44.8 litres (D) 56.0 litres

127. 8 g of sulphur is burnt to form SO 2 which is oxidised by Cl 2 water. The solution is treated with BaCl 2
solution. The amount of BaSO 4 precipitated is :
(A) 1 mole (B) 0.5 mole (C) 0.24 mole (D) 0.25 mole

128. 1 gram of a carbonate of a metal was dissolved in 25 ml of 1N HCl. The resulting liquid required 5 ml of N
NaOH for neutralization. The eq. wt. of metal carbonate is :
(A) 100 (B) 30 (C) 40 (D) 50

129. Sulphuryl chloride SO2Cl2 reacts with water to give a mixture of H2SO4 and HCl. How many moles of NaOH
would be needed to neutralize the solution formed by adding 1 mole of SO 2Cl 2 to excess of water :
(A) 1 (B) 3 (C) 2 (D) 4

130. 0.126 g of an acid requires 20 mL of 0.1 N NaOH for complete neutralisation. Eq. wt. of the acid is :
(A) 45 (B) 53 (C) 40 (D) 63

131. Equivalent mass of Na2S2O 3 in its reaction with I 2 is equal to :

(A) molar mass (B) molar mass/2 (C) molar mass/3 (D) molar mass/4

CONCENTRATION TERMS & TITRATION

132. What volume of 96 % H2SO 4 by weight solution (density 1.83 g/ml) is required to prepare 2.00 L of 3.00
M H2SO 4 solution ?
(A) 335 ml (B) 670 ml (C) 167.5 ml (D) none

133. A 5.0 mL solution of H2O2 liberates 1.27 g of iodine from an acidified KI solution. The percentage strength
of H2O2 is :
(A) 11.2 (B) 5.6 (C) 1.7 (D) 3.4

FIITJEE 9
134. A solution of KMnO 4 is reduced to MnO 2. The normality of solution is 0.6 N. The molarity is
(A) 1.8 M (B) 0.6 M (C) 0.2 M (D) 0.1 M

135. Hardness of water sample is 300 ppm CaCO 3. Hence its molarity is :
(A) 0.3 M (B) 0.030 M (C) 0.003 M (D) 0.0015 M

136. A 100 mL solution of KOH contains 10 milliequivalents of KOH. Calculate its strength in normality and grams/
litre.
(A) 5.1 g/lit (B) 5.6 g/lit (C) 4.6 g/lit (D) 3.6 g/lit

137. Calculate the normality of a solution of FeSO4. 7H2O containing 2.4 g/100 mL (Fe = 56, S = 32, O = 16, H =
1) which converts to ferric form in a reaction.
(A) 0.086 N (B) 2.886 N (C) 1.086 N (D) 0.076 N

138. The equivalent weight of KHC2O4 · H2C2O4 · 2H2O in a neutralisation reaction is :

(A) 127 (B) 84.6 (C) 254 (D) 232

139. In an experiment 50 ml of 0.1 M solution of a salt reacted with 25 ml of 0.1 M solution of sodium sulphite.
The half equation for the oxidation of sulphite ion is –
SO 32– (aq.) + H2O(l) SO 42– (aq.) + 2H+ (aq.) + 2e–
If the oxidation number of metal in the salt was 3, what would be the new oxidation number of metal ?
(A) 0 (B) 1 (C) 2 (D) 4

140. One mole of a mixture of CO and CO2 requires exactly 20 gram of NaOH in solution for complete conversion
of all the CO 2 into Na2CO 3. How many grams more of NaOH would it require for conversion into Na2CO 3 if
the mixture (one mole) is completely oxidized to CO 2 .
(A) 60 grams (B) 80 grams (C) 40 grams (D) 20 grams

141. 5 ml of N HCl, 20 ml N/2 H2SO 4 and 30 ml of N/3 HNO3 are mixed together and volume made to 1 litre. The
normality of resulting solution is :
(A) N/5 (B) N/10 (C) N/20 (D) N/40

142. 30 mL of a diabasic acid is neutralized by 15 mL of 0.2 N NaOH. The molarity of the acid is :
(A) 0.05 M (B) 0.2 M (C) 0.3 M (D) 0.4 M

143. Amount of phosphoric acid needed to neutralise 100 g of Mg(OH)2 is :

(A) 66.7 g (B) 112 g (C) 168 g (D) 252 g

144. The mass of pure H2SO4 required for neutralisation of 500 mL of 2M of NaOH is :
(A) 49 g (B) 98 g (C) 73.5 g (D) 24.5 g

145. Calculate the morarity of the resulting solution obtained by mixing 5 g NaOH with 200 mL M/4 NaOH (density =
1.05 g/cc)
(A) 0.55 (B) 0.4 (C) 0.8 (D) 0.88

146. Calculate the maximum volume of 0.3 M NaOH can be obtained from the solutions of one litre each of 0.5 M
NaOH volume and 0.25 M NaOH. Answer is :
(A) 1 L (B) 1.5 L (C) 1.25 L (D) 2 L

147. When the solution containing NaHCO3 and Na2CO3 is titrated using methyl orange indicator then which of
following statement is correct :
(A) eq. of NaOH = eq. of HCl (B) eq. of NaHCO3 + eq. of NaCO3 = eq. of HCl
1 1 1 1
(C) eq. of NaHCO3 + eq. of Na2CO2 = eq. of HCl (D) eq. of NaHCO3 + eq. of Na2CO3 = eq. of HCl
2 2 2 2

148. What will be the nature of resulting solution obtained by mixing 100 ml of each 0.5 N NaOH, N/5 HCl and N/10
H2SO4 together :
(A) acidic (B) neutral (C) alkaline (D) amphoteric

FIITJEE 10
149. What will be the normality of a solution obtained by mixing 0.45 N and 0.6 N NaOH in the ratio 2 : 1 by volume
:
(A) 0.4 N (B) 0.5 N (C) 0.05 N (D) 0.15 N

150. Which of the following is correct :

wt
(A) Mole = Molarity × V in L =
Mol. wt.
wt
(B) Millimole = Molarity × V in ml =  1000
Mol.wt.
(C) Mole and millimole of reactants reacts according to stoichimetric ratio of balanced chemical equation
(D) All

151. A bottle of H2O2 is labelled as 10 V H2O2.112 ml of this solution of H2O2 is titrated against 0.04 M acidified
solution of KMnO4. The volume of KMnO4 in litre is :
(A) 1L (B) 2 L (C) 3 L (D) 4 L

152. In the mixture of (NaHCO3 + Na2CO3), volume of HCl required is x mL with phenolphthalein indicator and then y
mL with methyl orange indicator in same titration. Hence, volume HCl for complete reaction of Na2CO3 is :
x
(A) 2x (B) y (C) (D) (y – x)
2

153. 10 mL of H2O2 solution (volume strength = x) requried 10 mL of N/0.56 MnO4– solution in acidic medium. Hence
x is :
(A) 0.56 (B) 5.6 (C) 0.1 (D) 10

154. What is the normality of 1 M solution of H3PO4 ?

(A) 0.5 N (B) 1 N (C) 2 N (D) 3 N

155. The normality of H2SO4 having 50 milliequivalent in 2 litre is :

(A) 0.25 (B) 0.025 (C) 2.5 (D) 25

156. The normality of FeSO4.7H2O solution containing 6.0 g / 250 ml is :

(A) 1 N (B) 0.0664 N (C) 0.0864 N (D) 0.0569 N

157. Normality of phosphoric acid solution (H3PO4 ) (sp. gr. 1.426) containing 60% by weight of pure H3 PO4 (P = 31)
is :
(A) 36.5 N (B) 3.65 N (C) 35.95 N (D) 35 N

158. The number of millimoles of solute contained in 10 ml of 0.125 M of Pb(NO3 )2 (Pb = 207; N = 14; O = 16) is :
(A) 2.2 (B) 2.15 (C) 3.15 (D) 1.25

159. An aqueous solution of urea (NH2CONH2) is 3.0 molal. The mole fraction of urea is :
(A) 0.33 (B) 0.25 (C) 0.66 (D) 0.05

160. 0.2 M H2SO4 (1 mL) is diluted to 1000 times of its initial volume. The final normality of H2SO4 ?
(A) 2 × 10–3 (B) 2 × 10–4 (C) 4 × 10–4 (D) 2 × 10–2

161. 0.2 mol of HCl and 0.1 mol of barium chloride is dissolved in water to produce a 500 mL solution. The molarity
of Cl– is :
(A) 0..06 M (B) 0.12 M (C) 0.09 M (D) 0.80 M

162. The density of 1 M solution of NaCl is 1.0585 g mL–1. The molality of the solution is :
(A) 1.0585 (B) 1.00 (C) 0.0585 (D) 0.10

163. H3PO4 is a tribasic acid and one of its salt is NaH2PO4. What volume of 1 M NaOH solution should be added t0
12 g of NaH2PO4 to convert it into Na3PO4 ?
(A) 100 mL (B) 200 mL (C) 80 mL (D) 300 mL

FIITJEE 11
164. The normality of a mixture obtained by mixing 100 mL of 0.2 M H2SO4 with 100 mL of 0.2 M NaOH is :
(A) 0.05 N (B) 0.1 N (C) 0.15 N (D) None of these

165. H3PO4 is a tribasic acid and one of its salt is NaH2PO4. What volume of 1 M NaOH solution should be added
to 12 g of NaH2PO4 to convert it into Na3PO4 ?
(A) 100 mL (B) 200 mL (C) 80 mL (D) 300 mL

166. Normality of 1% H2SO4 solution is nearly

(A) 2.5 (B) 0.1 (C) 0.2 (D) 1

167. The volume of water to be added to 200 mL of seminormal HCl solution to make it decinormal is :
(A) 200 mL (B) 400 mL (C) 600 mL (D) 800 mL

168. 0.2 g of a sample of H2O2 required 10 mL of N KMnO4 in a titration in the presence of H2SO4. Purity of H2O2 is :
(A) 25% (B) 85% (C) 65% (D) 95%

169. Mixture X = 0.02 mole of [CO(NH3)5SO4] Br and 0.02 mole of [Co(NH3)5Br]SO4 was prepared in 2 L solution.
1 L of mixture X + excess of AgNO3 solution  Y
1 L of mixture X + excess of Bacl2 solution  Z
Number of moles of Y and Z are :
(A) 0.01, 0.01 (B) 0.02, 0.01 (C) 0.01, 0.02 (D) 0.02, 0.02

170. Dissolving 120 g of urea (mol. vt. 60) in 1000 g of water gave a solution of density 1.15 g/mL.The molarity of the
solution is :
(A) 1.78 M (B) 2.00 M (C) 2.05 M (D) 2.22 M

171. The volume strength of 1.5 N H2O2 is :

(A) 4.8 (B) 8.4 (C) 3.0 (D) 8.0

172. The number of moles of KMnO4 that will be needed to react with one mole sulphite ion in acidic solution is :
2 3 4
(A) (B) (C) (D) 1
5 5 5

173. An aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 mL. The volume of 0.1 N NaOH required to
completely neutralize 10 mL of this solution is :
(A) 40 mL (B) 20 mL (C) 10 mL (D) 4 mL

174. Consider a titration of potassium dichromate solution with acidified Mohr’s salt solution using diphenylamine as
indicator. The number of moles of Mohr’s salt required per mole of dichromat is :
(A) 3 (B) 4 (C) 5 (D) 5

175. In the titration of certain H2SO4 solution, 60 mL of 5.0 M NaOH solution was used to completely neutralize 75
mL of the acid. The molarity of the acid solution may be expressed as :
5M 60mL 5M  75mL  2 75mL  2 60mL  75mL  2
(A) (B) (C) (D)
2  75mL 60mL 5.0M  60mL 5.0M

Subjective

176. Calculate the molality of 1.0 L solution of 93% H2SO4, (weight/volume). The density of the solution is 1.84 g/mL.

177. 8.0575 × 10–2 kg of Glaumber’s salt is dissolved in water to obtain 1 dm3 of solutionof density 1077.2 kg m–3.
Calculate the molarity and mole fraction of Na2SO4 in solution.

178. The density of a 3 M sodium thiosulphate solution (Na2S2O3) is 1.25 g per mL. Calculate (i) the percentage by
weight of sodium thiosulphate (ii) the molalities of Na+ and S2O32– ions.

FIITJEE 12
179. 4.08 g of a mixture of BaO and unknown carbonate MCO3 was heated strongly. The residue weighed 3.64 g.
This was dissolved in 100 mL of 1 N HCl. The excess acid required 16 mL of 2.25 N NaOH solution for complete
neutralization. Identify the metal M.

180. A 5.0 cm3 solution of H2O2 liberates 0.508 g of iodine form an acidicfied KI solution. Calculate the strength of
H2O2 solution in terms of volume strength at STP.

*****

Answer Key

1. A -S; B-R ; C -Q ; D-P 2. B 3. A 4. A 5. D 6. C 7. A 8. B

9. B 10. C 11. C 12. D 13. D 14. A 15. A 16. C 17. B 18. D
19. B 20. C 21. A 22. B 23. A 24. B 25. D 26. B 27. B 28. B
29. D 30. A 31. B 32. B 33. A 34. D 35. C 36. D 37. D 38. C
39. A 40. A 41. B 42. A 43. B 44. B 45. C 46. C 47. A 48. C
49. B 50. B 51. B 52. B 53. A 54. B 55. D 56. C 57. D 58. D
59. B 60. B 61. D 62. D 63. C 64. C 65. A 66. A 67. C 68. I 2 0.74
69. 163 grm 70. A 71. D 72. C 73. C 74. A 75. C 76. B 77. B
78. A 79. A 80. B 81. A 82. C 83. C 84. C 85. C 86. B 87. D
88. C 89. C 90. C 91. B 92. B 93. B 94. A 95. D 96. C 97. B
98. D 99. D 100. B 101. B 102. A 103. A 104. B 105. C 106. B 107. C
108. B 109. B 110. A 111. B 112. A 113. C 114. C 115. A 116. C 117. C
118. A 119. A 120. D 121. B 122. C 123. D 124. C 125. C 126. D 127. D
128. D 129. D 130. D 131. A 132. A 133. D 134. C 135. C 136. B 137. A
138. B 139. C 140. A 141. D 142. A 143. C 144. B 145. D 146. C 147. B
148. C 149. B 150. D 151. A 152. A 153. D 154. D 155. B 156. C 157. C
158. D 159. D 160. C 161. D 162. B 163. B 164. B 165. B 166. C 167. D
168. B 169. A 170. C 171. B 172. A 173. A 174. D 175. A
–3
176. 10.43 177. 4.3 × 10 178. (I) 37.9 2 (II) 7.732 & 3.86 5 179. C alc ium
180. 4.48

FIITJEE 13