1ST DAY PRACTICE SHEET (MOLE)

Q.1* Which one would be larger: an atomic mass unit based on the current standard or one based on the mass
of a Be-9 atom set at exactly 9 amu?
Q.3 Flourine reacts with uranium to produce uranium hexafluoride, UF6, as represented by this equation
U(s) + 3F2(g)  UF6(g)
How many fluorine molecules are required to produce 2.0 mg of uranium hexafluoride, UF6, from an
excess of uranium ? The molar mass of UF6 is 352 gm/mol.
Q.4 What total volume, in litre at 600°C and 1 atm, could be formed by the decomposition of 16 gm of
NH4NO3 ? Reaction : 2 NH4NO3  2N2 + O2 + 4H2O(g).
Q.5 Calculate mass of phosphoric acid required to obtain 53.4g pyrophosphoric acid.

Q.6 Titanium, which is used to make air plane engines and frames, can be obtained from titanium tetrachloride,
which in turn is obtained from titanium oxide by the following process :
3 TiO2(s) + 4C (s) + 6Cl2 (g)  3TiCl4(g) + 2CO2(g) + 2CO (g)
A vessel contains 4.32 g TiO2, 5.76 g C and; 6.82 g Cl2, suppose the reaction goes to completion as
written, how many gram of TiCl4 can be produced ? (Ti = 48)
Q.7* Copper forms two oxides. For the same amount of copper, twice as much oxygen was used to from the
first oxide than to form the second one. What is the ratio of the valencies of copper in the first and second
oxides? [2:1]
Q.8* What is the maximum number of moles of CO2 that could be obtained from the carbon in 4 moles of
Ru2(CO3)3?
Q.10 Potassium superoxide, KO2, is used in rebreathing gas masks to generate oxygen :
KO2(s) + H2O(l)  KOH (s) + O2 (g)
If a reaction vessel contains 0.158 mol KO2 and 0.10 mol H2O, how many moles of O2 can be produced?
Q.11 One gram of an alloy of aluminium and magnesium when heated with excess of dil. HCl forms magnesium
chloride, aluminium chloride and hydrogen. The evolved hydrogen collected at 0°C has a volume of
1.12 litres at 1 atm pressure. Calculate the composition of the alloy.
Q.12 A sample containing only CaCO3 and MgCO3 is ignited to CaO and MgO. The mixture of oxides
produced weight exactly half as much as the original sample. Calculate the percentages of CaCO3 and
MgCO3 in the sample.
Q.14 A sample of mixture of CaCl2 and NaCl weighing 4.22 gm was treated to precipitate all the Ca as
CaCO3 which was then heated and quantitatively converted to 0.959 gm of CaO. Calculate the percentage
of CaCl2 in the mixture.
Q.15 When 4 gm of a mixture of NaHCO3 and NaCl is heated, 0.66 gm CO2 gas is evolved. Determine the
percentage composition of the original mixture.
Q.16 A power company burns approximately 474 tons of coal per day to produce electricity. If the sulphur
content of the coal is 1.30 % by weight, how many tons SO2 are dumped into the atmosphere each
day?
Q.17 Calculate the percent loss in weight after complete decomposition of a pure sample of potassium chlorate.
KClO3(s)  KCl(s) + O2(g)

Q.19 Cyclohexanol is dehydrated to cyclohexene on heating with conc. H2SO4. If the yield of this reaction is
 75%, how much cyclohexene will be obtained from 100 g of cyclohexanol ?
C6H12O con
.
H 2SO 4
 C6H10
Q.20 How many grams of 90% pure Na2SO4 can be produced from 250 gm of 95% pure NaCl ?

Q.22 2PbS + 3O2  2PbO + 2SO2

3SO2 + 2HNO3 + 2H2O  3H2SO4 + 2NO
According to the above sequence of reactions, how much H2SO4 will 1146 gm of PbS produce?
Q.24 Sodium chlorate, NaClO3, can be prepared by the following series of reactions:
2KMnO4 + 16 HCl  2 KCl + 2 MnCl2 + 8H2O + 5 Cl2
6Cl2 +6 Ca(OH)2  Ca(ClO3)2 + 5 CaCl2 + 6H2O
Ca(ClO3)2 + Na2SO4  CaSO4 + 2 NaClO3
What mass of NaClO3 can be prepared from 100 ml of concentrated HCl (density 1.18 gm/ml and 36%
by mass)? Assume all other substances are present in excess amounts.
Q.25 P4S3 + 8O2  P4O10 + 3SO2
Calculate minimum mass of P4S3 is required to produce 1 gm of each product.
Q.26 By the reaction of carbon and oxygen, a mixture of CO and CO2 is obtained. What is the composition
by mass of the mixture obtained when 20 grams of O2 reacts with 12 grams of carbon ?
Q.27 In a determination of P an aqueous solution of NaH2PO4 is treated with a mixture of ammonium and
magnesium ions to precipitate magnesium ammonium phosphate Mg(NH4)PO4. 6H2O. This is heated
and decomposed to magnesium pyrophosphate, Mg2P2O7 which is weighed. A solution of NaH2PO4
yielded 1.054 g of Mg2P2O7. What weight of NaH2PO4 was present originally?
Q.28 0.80 g of the chloroplatinate of a mono acid base on ignition gave 0.262g of Pt. Calculate the mol. wt of
the base.
Q.29 A mixture of nitrogen and hydrogen. In the ratio of one mole of nitrogen to three moles of hydrogen, was
partially converted into NH3 so that the final product was a mixture of all these three gases. The mixture
was to have a density of 0.497 g per litre at 25°C and 1.00 atm. What would be the mass of gas in
22.4 litres at 1 atm and 273 K? Calculate the % composition of this gaseous mixture by volume.
Q.30 0.6872 gm of an organic compound gave on complete combustion 1.466 gm of carbon dioxide and
0.4283 gm of water. A given weight of the compound when heated with nitric acid and silver nitrate gave
an equal weight of silver chloride. 0.3178 gm of the compound gave 26.0cc of nitrogen at 15°C and
765 mm pressure. Deduce the empirical formula of the compound?
Q.12 124 gm of mixture containing NaHCO3, AlCl3 & KNO3 requires 500 ml, 8% w/w NaOH solution
[dNaOH = 1.8 gm/ml] for complete neutralisation. On heating same amount of mixture, it shows loss in
weight of 18.6 gm. Calculate % composition of mixture by moles. Weak base formed doesn't interfere
in reaction. Assume KNO3 does not decompose under given conditions.
Q.13 If the yield of chloroform obtainable from acetone and bleaching powder is 75%. What is the weight of
acetone required for producing 30 gm of chloroform ?
Q.14 A sample of impure Cu2O contians 66.67% of Cu. What is the percentage of pure Cu2O in the sample?
Q.15 Equal weights of mercury and iodine are allowed to react completely to form a mixture of mercurous and
mercuric iodide leaving none of the reactants. Calculate the ratio by weight of Hg2I2 and HgI2 formed
(Hg = 200 , I = 127)
Q.1 latter Q.3 1.0 ×1019 Q.4 50.14 litre

Q.5 58.8 g Q.6 9.12 Q.7 2:1

Q.8 12 mol Q.10 0.1185

Q.11 Al = 60%; Mg = 40% Q.12 CaCO3 = 28.4%; MgCO3 = 71.6%

Q.14 45% Q.15 63 % , 37%

Q.16 12.3 Q.17 39.18 Q.19 61.5 gm

Q.20 320.3 gm Q.22 470.4 gm

Q.24 12.9 gm Q.25 1.1458 Q.26 21 : 11 Q.27 1.14 gm

Q.28 92.70 g/mol Q.29 12.15gm, N2 = 14.28 % H2 = 42.86%, NH3 = 42.86 %

Q.30 C7H10NCl
Q.12 AlCl3 = 33.33; NaHCO3 = 50; KNO3 = 16.67 Q.13 9.4 gm

Q.14 75% Q.15 0.532 : 1.00