1543400386a1812 PDF

C321
C321
C321
Indian Association of Physics Teachers
NATIONAL STANDARD EXAMINATION
IN CHEMISTRY (NSEC) 2018-19
Date of Examination – 25th November, 2018

Paper Code : C321
SOLUTION
[4]
INDIAN ASSOCIATION OF CHEMISTRY TEACHERS

NATIONAL STANDARD EXAMINATION IN CHEMISTRY(NSEC) 2018-19
CODE : C321 | (Date : 25.11.2018)
1. Which of the energy values marked as, I, II and III in the following diagram, will change by the addition
of a suitable catalyst?
Energy
II
III
I
Progress of reaction
(A) II only (B) I and II (C) II and III (D) III only
Ans. (C)
Sol. Catalyst decreases activation energy of both forward and backward reaction but no change in Hreaction .
2. The product ‘X’ in the following reaction is.
Cl
+ H2SO4
COOH X
OH
(A) a reacemic mixture of ester (B) an optically inactive ester
(C) an optically active ester (D) a meso ester
Ans. (C)
Alcohol C–O bond will not

* break in the formation of ester
Sol. so product is optically active
OH
3. At 298 K, change in internal energy for the complete combustion of fullerene, C60(s), an allotrope of
carbon, and the enthalpy of formation of CO2 (g) are - 25970 kJ mol–1 and –393 kJ mol–1 respectively.
The enthalpy of formation of C0 (s) at 298 K is :
(A) –2390 kJ (B) 4.95×104 kJ (C) 2.60×104 kJ (D) 2390 kJ
Ans. (D)
 60CO2 (g); U  –25970kJmol1
Sol. C60 (s)  60O 2 (g) 
H  U  ngRT  U ( ng  0)
Hreaction  [60Hf CO2 ] – [60  Hf O2  Hf C60 ]
–25970 kJ = 60 × (–373) – Hf C60
Hf C60  2390kJ
CORPORATE OFFICE : Paruslok, Boring Road Crossing, Patna-01

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CODE : C321 | (Date : 25.11.2018)
4. Which of the following is not paramagnetic

(A) S2– (B) N2– (D) O2– (D) NO
Ans. (A)
Sol. S 2  Diamagnetic nature
O 2  Diamagnetic nature
So Ans : (A), (C)
but Ans. (A)
S 2  total e– = 18
1s22s22p63s23p6 (more number of paired e–)
5. Solubility product of AgCl is 1.8×10–10. The minimum volume (in L) of water required to dissolve 1 mg
of AgCl is close to :
(A) 0.5 (B) 7.5 (C) 50 (D) 0.75
Ans. (A)


Sol. AgCl  
 Ag  Cl

S2 = 1.8 × 10–10
S S S
103
S = 1.34 × 10–5 
143.5  V(L)
100
V(L) =  0.5
143.5  1.34
6. The complex [M(en)(Br)2(Cl)2 ] has two optical isomers. Their configurations can be represented as:
Cl Br Cl Cl
Cl Br Br Cl
Br Cl
en en
(A) (B)
Cl Br Br
Br en en
Cl Br
en en Br Br
Cl Br Br
Cl
en en
(C) (D)
Cl Br Cl Br Cl Cl
Br Br Cl Cl
Ans. (D)

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CODE : C321 | (Date : 25.11.2018)
Sol. [M(en)Br2CI2]
Br Br
N Br N CI
en M en M
N CI N CI
CI Br
CI
N Br
en M
N Br
CI
7. A sample of water from a river was analyzed in the presence of metal ions and the observations were
recorded as given below :
The water sample is likely to contain

(A) Ba2+ (B) Cu2+ (C) Li+ (D) Mg2+
Ans. (D)
Sol. Sea-water contain a lot of MgCI2
MgCI2  Na2CO3  H2O  Mg(OH)2  MgCO3 (White ppt.)
8. The lattice enthalpy and enthalpy of solution in water for solid NaCl are 753 kJ mol–1 and 5 kJ
mol–1 respectively (fig above). If the solution enthalpies of Na+ and Cl– are in the ratio 6:5, the enthalpy
of hydration of Na+ ion is :
(A) 408 kJ mol–1 (B) –412 kJ mol–1 (C) –408 kJ mol–1 (D) –412 kJ mol–1
Ans. (C)
Sol. Let solution enthalpy of Na+ = –6x
and solution enthalpy of Cl– = – 5x


NaCl(s)  
 Na (aq) H  753
 
Na  H2O  Na (aq) H  –6x
Cl  H2O  Cl (aq) x  –5x

NaCl  H2O    
 Na (aq)  Cl (aq); H  5
753 – 6x – 5x = 5
11x = 748
x = 68
HSoln (Na  )  –6  68  –408 kJ

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CODE : C321 | (Date : 25.11.2018)
9. The gaseous product obtaind on reaction of BF3 with LiH is :
(A) HF (B) H2 (C) B2H6 (D) F2
Ans. (C)
Sol. 8BF3  6LiH  B 2H6  6Li[BF4 ]
[B2H6 is a colourless gas sensitive order].
10. The equilibrium constant K for the reversible reaction A=B is 2×103 at 350 K. The rate constants of
the forward reaction in the presence andabsence of a suitable catalyst at the same temperature are
5×104 s–1 respectively. The rate constant of the reverse reaction in the absence of the catalyst is :
(A) 2×10–3 s–1 (B) 2.5×10–1 s–1 (C) 1.6×10–7 s–1 (D) 1.25×10–2 s–1
Ans. (No Option)
 Kf  K 
Sol.  K   f  K eq
 b  without catalyst  K b  with catalyst
4  10 6
 2  103
Kreverse
4  10 6
K reverse   2  10 9
2  103
11. The number of stereoisomers possible for the following compound :
CH=CH–C(CH3)=CH–CH=CH–C(CH3)=CH–CH2OH
(A) 4 (B) 2 (C) 16 (D) 32
Ans. (C)
Sol. Assymmetric molecule having four double bonds = 2n = 24 = 16

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CODE : C321 | (Date : 25.11.2018)
V0bP
12. An adsorption isotherm equation proposed by Langmuir is of the form V  where V is the
(1  bP)
volume of gas adsorbed at pressure P. For a given adsorbate/ adosrbent system, V 0 and b are
constants. The dependence of V on P can be depicted as :
I/V I/V
(A) (B)
I/P I/P
V 1/V
(C) (D)
P P
Ans. (B)
V0bp
Sol. V 
1  bp
1 1 1 1
  
V V0b p V0
Y = mx + c
13. For the reaction 4NO2 (g)  O2 (g)  2N2 O5 (g), Hreaction  112kJ. If the N2O5 is assumed to be
formed in the reaction as a solid, Hreaction will be ( Hreaction of N2O5 is 54 kJ mol–1)
(A) –220 kJ (B) –4 kJ (C) –166 kJ (D) –332 kJ
Ans. (A)
Sol. 4NO2 (g)  O 2 (g)  2N2O5 (g);  H  –112

2N2O 5 (g)  2N2 O5 (s); H  –54  2
4NO2 (g)  O 2 (g) 
 2N2O5 (s); H  –220

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CODE : C321 | (Date : 25.11.2018)
14. Urea, CO (NH2)2, decomposes at 90º Cas CO(NH2 )2 (aq)  NH4 (aq)  OCN (aq) Experimental data
obtained for the reaction is given in the following plot :
[CO(NH2) 2](M)
0.1
0.08
0.06
0.04
0.02
0
0 10 20 30
Time (h)
From the graph it can be inferred that

(A) Average rate of the reaction is the same for successive time intervals of 10 h
(B) Unit of rate constant of the reaction is h–1
(C) Rate constant of the reaction is the lowest at 30 h
(D) The reaction is of zero order
Ans. (B)
Sol. At a interval of 10 h, concentration of reactant each times become half, hence it is first order of
reaction and unit of rate constant = h–1
15. If for an aqueous solution of a weak acid, pH = pKa +2 at 25ºC, the approximate fraction of the acid in
the dissociated form is :
(A) 1.1 % (B) 0.99 % (C) 99.0 % (D) 9.9 %
Ans. (C)


Sol. HA  
H  A

H  A  C.C
Ka  
HA C(1   )
pH = pKa + 2
–logH+ = –logKa – log10–2
H+ = Ka × 10–2
K a  102  C
Ka 
C(1   )
1  1 1 1
 ; 1
 100  100
100
  0.99  99%
101

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CODE : C321 | (Date : 25.11.2018)
16. 2.0 L of N2 gas kept at 25º C and 5 atm pressure were exp[anded isothermally against a constant
pressure of 1 atm unitl the pressure of the gas reaches 1 atm. Assuming ideal behaviour, reversible
work of expansion in this process (in J) is close to :
(A) 810 J (B) –194 kJ (C) –810 kJ (D) 338\90 kJ
Ans. (A)
Sol. P1 = 5 atm, V1 = 2L
P2 = 1 atm, V2 = ?
P1V1 = P2V2
V2 = 10L
W = –1atm[10–2] = –8 atm L = –8×101.325 J
= –810.65
17. The compound which would undergo a reaction with ammonia by SNI mechanism is :
Br
(A) (B)
Br
Br
(C) (D)
Br
Ans. (D)
Br
Sol. gives stable carbocation
18. The daily energy requirement of a teenager is 7800 kJ. As calculatd from the data given in the table
below, the amount of glucose he has to consume (g) per day assuming that the entire energy be
requires comes from the combustion of glucose is :
(A) 262 (B) 500 (C) 131 (D) 250

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CODE : C321 | (Date : 25.11.2018)
Ans. (B)
Sol. C6H12O6 + 6O2  6CO2 + 6H2O
H  {6(–286)  6(–394)}  {–1273}  –2807
7800
Mole of C6H12O6 required =  2.77
2807
Mass of glucose = 2.77 × 180 = 500 g
19. The pressure inside two gas cylinders oif volume 25 m3 and 50 m3 are 10 kPa and 20 kPa respectively.
The cylinders are kept at the same temperature and sepearated by a valve. What is the pressure in
the combined system when the valve is opened?
(A) 30 kPa (B) 15 kPa (C) 16.7 kPa (D) 2.5 kPa
Ans. (C)
Sol. P × 75 = 25 × 10 + 50 × 20 = 250 + 1000 = 1250
1250
P  16.66 K Pa
75
20. Aluminium and copper are extracted from their oxide and sulphide ores respectively. Which of the
following is correct.
I. Copper is extracted by the auto reduction of copper oxide by copper sulphide
II. Aluminimum cannot be obtained by chemical reduction due to its strong affinity for oxygen
III. In electrometallurgy of Al, graphite is used as cathode to avoid reoxidation of Al into Al2O3 by
preventing formation of O2.
IV. Sulphide ores of copper are difficult to be reduced than the oxide ores :
(A) I, II, IV (B) II and III (C) II and III (D) II and IV
Ans. (A)
Sol. Factual
21. Which of the following graphs describes the relationship between [H3O+] and [OH–] in an aqueous
solution at a constant temperature?
[HO ]
[HO–]
(A) (B)
0 +
[H 3O ] 0 +
[H3O ]
[HO–]
[HO–]
(C) (D)
0 [H3O ]
+
0 +
[H3O ]

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CODE : C321 | (Date : 25.11.2018)
Ans. (D)
Sol. [H3O  ][OH ]  K w

xy  constant [Rectangular hyperbola]
22. From the given standard electrode potentials
Sn4  (aq)  2e   Sn2 (aq) Eº  0.15 V

 
Br2 (1)  2e  2Br (aq) Eº  1.07 V
The approximate free energy change for the process
2Br– (aq)+ Sn4+(aq)  Br2 (1)+Sn2+ (aq) is :
(A) 177.6 kJ (B) 355 kJ (C) –177.6kJ (D) –355 kJ
Ans. (A)
Sol. Eocell  0.15  1.07  0.92 V
G  –nEocell  F
= –2 × (–0.92) × 96500 = 177.6 kJ
23. Number of moles of KClO3 that have to be heated to produce 1.0 L of O2 (g) at STP can be expressed
as :
(A) 1/3(1/22.4) (B) 1/2 (1/22.4) (C) 2/3(1/22.4) (D) 3/2(22.4)
Ans. (C)
Sol. 2KClO3  2KCl  3O 2

1L
1
Mole of O2 = mole
22.4
2
Mole of KClO3 = mole
3  22.4
24. The sequence of reagents required for the following conversion is
(A) (i) B2H6/H2O2/OH– (ii) Na (iii) C2H5I (B) (i) HCl (ii) C2H5ONa
(C) (i) H3O+ (ii) Na (iii) C2H5OH (D) (i) H3O+ (ii) Na (iii) C2H5Cl
Ans. (D)
CH2–CH3
+
Sol. H3O Na Cl
OH ONa O

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CODE : C321 | (Date : 25.11.2018)
25. Among the following, number of oxygen atoms present is the maximum in
(A) 1.0 g of O2 molecules (B) 4.0 g of O atoms (C) 1.0 g of O3 (D) 1.7 g of H2O
Ans. (B)
1 N
Sol. (A)  2NA  A Oatom
32 16
4 N
(B)  1NA  A Oatom
16 4
1 N
(C)  3NA  A Oatom
48 16
1.7 1.7
(D)  1NA   1NA Oatom
18 18
26. Which of the following elements will exhibit photoelectric effect with light of the longest wavelength?
(A) K (B) Rb (C) Mg (D) Ca
Ans. (B)
Sol. Rb has very low ionization energy with respect to other show longest wave length is observed in Rb.
27. Compound ‘X’ in the following reaction is
(i) O3
(ii) Zn/H2 O
X 
(iii) Cl2 /NaOH
 COOH  ((CH2 )4 ) COOH
Adipic Acid
(iv) H3O
CH3
CH3 CH3
(A) (B) (C) (D)

CH3 CH3
CH3
Ans. (C)
CH3
O3/Zn O O Cl 2/NaOH
HOOC–CH2–CH2–CH2–CH2–COOH
Sol. H3O
+
CH3
28. The standard molar entropies of H2 (g), N2 (g) and NH3 (g) are 130, 190 and 193 J mol–1 K –1


 NH3 (g) (  Hreaction  45 kJ) to be in
respectively. For the reaction 1/2 N2 (g) + 3/2H2 (g) 
equilibrium, the temperature must be equal to
(A) 464 K (B) 928 K (C) 737 K (D) 354 K

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CODE : C321 | (Date : 25.11.2018)
Ans. (A)
1 3  
Sol. N2  H2   NH3
2 2
3 1 
S  193    130   190  = –97
2 2 
 G   H  T S
45000
Tequilibrium   463.91 464
97
29. Density of Co2 gas at 0°C and 2.00 atm pressure can be expressed as
(A) 2 gm–3 (B) 4 g m–3 (C) 4 × 103 kg m–3 (D) 8 g L–1
Ans. (No Option)
Sol. PM  dRT
PM 2  44
d(g / L)   = 3.93 g/L
RT .0821 273
3.93  10 3 kg
 = 3.93 kg/m3
103 m3
3.93  10 3 kg
 = 3.93 kg/m3
103 m3
30. The maximum number of moles of CH3I consumed by one mole of crixivan, a drug used against
AIDS is
Ph
OH OH
N
H
N N
N
O
HN O
Crixivan
(A) 2 (B) 3 (C) 5 (D) 7

Ans. (B)
CH3
Ph
N CH OH
3
OH
N N
N H
Sol. CH3 H C–N
3 O O

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CODE : C321 | (Date : 25.11.2018)
31. Concentration of K+ ions inside a biological cell was found to be 25 times higher than that outside.
The magnitude of the potential difference between the two sides of the cell is close to (2.303 RT/F
can be taken as 59 mV; difference in concentrations of other ions can be taken as negligible.)
(A) 4.2 mV (B) 195 mV (C) 82 mV (D) –82 mV
Ans. (C)
Sol. K   e  K
2.303RT 1
E diff.  log
F 25
= 59 mV × 1.4 = 82 mV
32. The standard redox potential for the reaction 2H2O  O2  4H  4 e  is –1.23V. If the same reaction
is carried out at 25°C and at pH = 7, the potential will be
(A) –0.82 V (B) –3.28 V (C) 0.82 V (D) –1.18 V
Ans. (A)
0.059 4
Sol. E  1.23  log PO2  PH 
4
= –1.25 – .059 log 10–7
= –1.23 + .413 = – .817 = –0.82 V
33. The order of pKa values of the following acids is
COOH COOH
COOH OH COOH
OH HO OH
(I) (II) (III) (IV)
OH OH
(A) IV > I > III > II (B) III > IV > I > II (C) II > I > III > IV (D) II > III > I > IV
Ans. (D)
COOH COOH COOH COOH

HO OH OH OH
Sol.
OH OH

Acidic strength order 
1
Acidic strength order 
pka
34. If the radius of the hydrogen atom is 53 pm, the radius of the He+ ion is close to
(A) 75 pm (B) 38 pm (C) 106 pm (D) 27 pm

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CODE : C321 | (Date : 25.11.2018)
Ans. (D)
RH 53pm
Sol. RHe    26.5pm  27pm
z 2
35. A substance X was heated at constant pressure and the temperature observed at various times of
heating was plotted as given below:
80
70
e
60
d
50
Temperature (0°C)
40
30
c
20
10
b
0
a
–10
–20
0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30
Time (minute)
Which of the following is/are correct?
(I) Melting point of X is –5°C
(II) Solid and liquid forms of X coexist in the region b
(III) Boiling point of X is 55°C
(IV) Solid and liquid forms of X coexist in the region d
(A) I and IV (B) II and III (C) III only (D) I, II and III
Ans. (B)
Sol. ln Region (b)


 Liq is present hence both solid and liquid coexist & in region d
Solid 


liq 
 vap equlibrium is shown here 55ºC is boiling point.
36. The major product of the following reaction is
NMe 2
conc.HNO3
conc. H2SO4
NMe2 NMe2
NMe2
NMe2 NO2
(A) (B) (C) (D)

O2N NO 2 NO2
NO2 O2N

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CODE : C321 | (Date : 25.11.2018)
Ans. (C)
Me Me
N Me +
HN Me
H
Sol.
strong with drawing group
acting as meta directing group
37. In which of the following, all the bond lengths are not the same?
(I) IF4 (II) BF4 (III) SF4 (IV) TeCl4

(A) I, II, IV (B) II, III, IV (C) I, III, IV (D) I, II, III
Ans. (C)
 sp3 d
: F4  
 3
Sol. : SF4  sp d  axial bond length > equatorial bond length.

 sp 3d
: TeCI4 
38. Among the following, the reaction/s that can be classified as oxidation-reduction is/are
(I) Cr2O72 (aq)  2OH (aq)  2 CrO42  H2O(1)
(II) SiCl4 (1)  2Mg(s)  2MgCl2 (1)  Si(s)
(III) 6Cl2 (1)  12KOH(1)  2KClO3 (s)  10KCl 6H2 O(1)
(IV) 2H2O2  2H2O(1)  O2 (g)
(A) I and IV (B) I, II and III (C) II, III and IV (D) IV only
Ans. (C)
Sol. In first oxidation number does not change hence is not a redox
Cr2O72  20H 
 2CrO4  H2O
4 0 2 0
SoCl4  2Mg 
 2MgCl2  Si
0 5 1
6Cl2  12KOH  2KClO3  10KCl
1 2 0
2H2O2 
 2H2O(l)  O2 (g)
39. Among the following pairs, the one in which both the compounds as pure liquids can show significant
auto ionization is
(A) H2O and H2S (B) BrF3 and ICl3 (C) PF5 and PCl5 (D) HF and HCl
Ans. (B)
Sol. 2BrF3 (  ) 
 BrF2  BrF4
2CI3 ( )  CI2  CI4

[ 18 ]

CODE : C321 | (Date : 25.11.2018)
40. The number of quaternary and chiral carbon atoms present in elatol, isolated from and algae are
respectively
Br
HO
Cl
Elatol
(A) 2,3 (B) 4, 2 (C) 3, 2 (D) 1,3
Ans. (A)
Br
3 CH3
OH
4 *
* 2
CH3
Cl
Sol. *
1
CuS
1, 2  are quanternary carbons
1, 3, 4  are chiral carbons
41. Compound X (pKa  15) and Y (pKa  10), both produce H2 on treatment with sodium metal and
both yield a mixture of isomers on mononitration. X and Y respectively are
OH
OH OH
O
(I) (II) (III) (IV)
IV
(A) IV, I (B) III, II (C) III, I (D) I, III

Ans. (D)
pKa = 15 pKa = 10
OH
OH
(x) (y)
Sol.
nitration
ortho + para ortho + para

[ 19 ]

CODE : C321 | (Date : 25.11.2018)
42. A crystal of KCl containing g small amount f CaCl2 will have

(A) vacant Cl– sites
(B) vacant K+ sites and a higher density as compared to pure KCl
(C) vacant K+ sites and a lower density as compared to pure KCl
(D) K+ ions in the interstital sites
Ans. (C)
Sol. One Ca++ will replace two K+ hence vacant K+ ions site and lower density observed.
43. In the following reaction, the values of a, b and c, respectively are
aF2 (g)  b OH (aq)  c F  (aq)  dOF2 (g)  eH2 O(1)

(A) 3, 2, 4 (B) 3, 4, 2 (C) 2, 2, 4 (D) 2, 2, 2
Ans. (D)
Sol. 2F2  2OH 

 2F   OF2  H2 O
44. The monosaccharide present in the following disaccharide is
O O
CH2OH CH2OH
OH OH
OH O OH
OH OH
CHO CH 2OH CH2OH

CHO
H OH HO H O O
HO H H OH H OH HO H
H OH HO H HO H H OH
(A) (B) (C) (D)
HO H H OH H OH HO H
CH2OH CH2OH CH2OH CH2OH
Ans. (A)
Sol. Conceptual
45. The IUPAC name of the complex [Pt(en)(NH3 )(Cl)2 (ONO)][Ag(CN)2 ]is
(A) monoamminedichlorido(ethane-1,2-diammine)nitritoplatinum(IV) dicyanoargentate(I)
(B) monoaminebischlorido(ethane-1,2-diamine)nitroplatinate(IV) dicyanosilver(I)
(C) monoaminebishclorido(ethane-1,2-diammine)nitritoplatinate(IV) dicyanoargentate(I)
(D) monoamminedichlorido(ethane-1,2-diamine)nitritoplatinum(IV) dicyanoargentate(I)

[ 20 ]

CODE : C321 | (Date : 25.11.2018)
Ans. (D)
4 1
Sol. [Pt(en)(NH3 ) CI2 (ONO)]1[Ag(CN)2 ]
Monoammine dichloridonitritoPt(IV) dicyanoargentate(I)
46. The correct order of basicity of the following species is
–
– –
O –
(I) O (II) NH (III) (IV) CH2
(A) III < IV < II < I (B) III < I < II < IV (C) III < II < I < IV (D) IV < I < I < III
Ans. (B)
Sol. –ve charge on less EN atom becomes more basic
47. Which among the following is nonlinear?
(A) N3 (B) ClF2 (C) Br3 (D) BrCl2
Ans. (D)
N3   sp 

[ CIF2 ]   sp3 d linear
Sol.

Br3   sp3 d 
[BrCI2 ]  sp3 V  shape
48. The compound most likely to lose water on protonation is
OH
OH OH OH
(A) (B) (C) (D)
Ans. (A)
OH
–H2O
Sol.
Aromatic
stable carbocation

[ 21 ]

CODE : C321 | (Date : 25.11.2018)
49. The Newman projection shown is the same as :

C2H5
H3C CH3
H C2H5
H
H H
I II III IV
(A) I and IV (B) II and III (C) III and IV (D) I and II
Ans. (C)
Sol. Conceptual
50. Which one of the following is not used as a monomer for the synthesis of a high molecular weight
silicone polymer ?
(A) MeSiCI3 (B) Me2SiCI2 (C) Me3SiCI (D) PbSiCI3
Ans. (C)
Sol. Only dimer form
51. In YBa2Cu3O7-x, a superconducting oxide that got George Bednorz and Karl Muller the Noble prize in
1986, Cu can exist in both +2 and +3 oxidation state and their proportion depends on the value of ‘x’.
In YBa2Cu3O7-0.5.
(A) 0.5 moles of Cu are in +3 oxidation state
(B) 5% of Cu is in +3 oxidation state
(C) All the Cu is in +3 oxidation state
(D) All Cu is in +2 oxidation state
Ans. (D)
Sol. YBa2Cu3O70.5
Cu   x; Cu3  3  x
3  2  2  [2 x  (3  x)3]  13
9–x = 6
x=3

[ 22 ]

CODE : C321 | (Date : 25.11.2018)
52. Compound ‘Y’ (molar mass = 88.12g mol–1) containing 55.52% carbon, 9.17% hydrogen and 36.31%
oxygen gives a reddish - brown precipitate in Fehling’s test ‘Y’ is.
OH
O
(A) (B)
OH O
O OH
(C) HO O (D) O O
Ans. (A)
Sol. C4H8O2 Aliphatic Aldehydes will give positive Fehlings test
53. The IUPAC name of the following compound is :
Br
CI
(A) 1-Bromo-4-chloro-3-ethenylbutane (B) 4-Bromo-1-chloro-3-ethenylbutane
(C) 3-(Bromomethyl)-5-chloropent-1-ene (D) 3-(Bromomethyl)-1-chloropent-4-ene
Ans. (C)
1
2
4
3 Br
Sol. Cl 5
parent chain
54. The correct order of boiling points of the following compound is :
O OH NH2 OH
I II III IV
(A) III < IV < II < I (B) I < III < IV < II (C) I < II < III < IV (D) IV < III < I < III
Ans. (B)
Sol. Boiling point order
RCOOH  ROH  R  NH2  Alkane

55. Which of the following is a strong oxidising agent ?
(A) AICI3 (B) TICI3 (C) NF3 (D) PCI3

[ 23 ]

CODE : C321 | (Date : 25.11.2018)
Ans. (B)
Sol. TiCl3 :Tl 3  e   Tl 1

Tl+ is more stable than Tl+3 due to inert pair effect. So ans. (B).
56. The molecule in which all atoms are not coplanar is :
(A) CH  C  C  CH2 (B) CH  CH  CH
(C) CH  C  CH2 (D) CH  CH  CH  CH2
Ans. (C)
Sol. CH  C  CH2
57. The most stabel radical among the following is :
(A) (B) (C) (D)
Ans. (D)
Sol. (extended conjugation becomes more stable)
58. During World War II, soldiers posted at high altitudes experienced crumbling of the tin butons of thir
uniforms into a grey powder. This can be attributed to :
(A) Oxidation of tin
(B) Interaction with nitrogen in the air at low pressure
(C) Change in the crystal structure of tin
(D) Reaction of tin with water vapour in the air
Ans. (C)
Sol. Factual

[ 24 ]

CODE : C321 | (Date : 25.11.2018)
59. The molecular that can exhibit tatuomerism are :

O O
O CHO
O
I II III IV
(A) I, IV (B) II, III (C) III, IV (D) I, II
Ans. (C)
OH
OH
Sol.
III IV
60. A scientist attepmts to replace a few carbon atoms in 1.0g of diamong with boron atoms or nitrogen
atoms in separate experiments. Which of the following is correct ?
(A) The resulting material with B doping will be an n-type semiconductor
(B) The resulting material with B doping will be a p-type semiconductor
(C) B doping is NOT possible as B cannot form multiple bonds
(D) The resulting material with N doping will be a p-type semiconductor.
Ans. (B)
Sol. Borm doping result p type same centre nitrogen doping result N-type semiconductor.
61. Compound ‘P’ that undergoes the sequence of reactions given below to give the product Q is :
O
i: excess CH3 OH
P  ii:iii:PCC
 
CH3 MgBr

iv: H3 O
Q
O O O OH
(A) (B) (C) (D)

HO HO
OHC OHC
Ans. (B)
O
OMe OMe OMe OMe
Sol. O
CH3OH pcc CH3MgBr
+
H3O
HO HO O

[ 25 ]

CODE : C321 | (Date : 25.11.2018)
62. The most stable Lewis structure of N2O is :
(A) O = N = N (B) N = O = N (C) N – N = O (D) O – N = N

Ans. (D)
Sol. N  N   O
 
N  N   O  1  N  N  O
–ve charge an higher more stable EN atom is more stable.

63. The major product ‘X’ formed in the following reaction is :
 i:
n  C4 H9 CI, anhyd. AICI3
 
ii: HNO3 , H2 SO 4
X
(A) (B)
O2N
NO2
(C) (D)
O2N
NO2
Ans. (C)
CH2
AICI3
CI 
HNO3/H2SO4
Sol.
O2N

[ 26 ]

CODE : C321 | (Date : 25.11.2018)
64. Which of the following accounts best for the fact that F– is smaller than O2– ?
(A) F– has a larger nuclear mass than O2–
(B) F– has a larger nuclear charge than O2–
(C) F– is more polarizable than O2–
(D) F– is more electronegative than O
Ans. (B)
Sol. Factual
65. The correct sequence of reagents from those listed below for the following conversion is :
(I) NaNH2 (II) Br2 (III) H2/Pd-C, quinoline (IV) H3O+

(A) IV – I – III (B) III – IV – I (C) II – I – III (D) I – II – III
Ans. (C)
Br2 Br
Br
NaNH2
Sol.
H2/Pd–C quinoline
66. An orbital among the following that has two radial nodes and two angular nodes is :
(A) 3d (B) 4p (C) 4f (D) 5d
Ans. (D)
Sol. 5d radius node = n –  –1= 5 – 2 – 1 = 2
angular node    2

[ 27 ]

CODE : C321 | (Date : 25.11.2018)
67. The compound ‘X’ undergoing the following reaction is :
(i) dil. aq. NaOH

(ii) H+
X C8H4O3
(iii) acid K2Cr2O7
(iv) Heat
Cl
Cl OH
Cl
(A) (B) (C) (D)
COOH
COOH COOH COOH
Ans. (C)
Cl OH
dil.aq. NaOH
COOH COOH
+
K2Cr2O7/H
COOH
COOH

Sol.
O
O
68. A dilute solution of an alkali metal in liquid ammonia is :
(I) blue in colour (II) conducts electricity
(III) paramagnetic (IV) an oxidising agent
(A) (I) and (III) (B) (II) and (IV) (C) (I), (II) and (III) (D) (I) and (III)
Ans. (C)
Sol. A dilute solution of an alkali metal in liquid ammonia is blue colour, high conductivity, paramagnetic &
high reducing power.

[ 28 ]

CODE : C321 | (Date : 25.11.2018)
69. The reactions from those given below that involve a carbocation intermediate are :
(i) + HI
Cl NH2
(ii) + NaNH2 + NaCl
(iii) OH + HCl OH + H2 O
(A) (i), (ii) and (iii) (B) (i) and (ii) (C) (i) and (iii) (D) (ii) and (iii)
Ans. (C)
Sol. (i) H+
OH
(iii) H+
70. The C–O bond length is the shortest in :

(A) [Cr(CO)6 ] (B) [Mo(CO)6] (C) [Mn(CO)6]+ (D) [V(CO)6]–
Ans. (C)
fast w.r.t. i
l1   l2 

Sol. I. Cr  : C  O: II. Mo  : C  O :
Slowest Fast
+  l3   l4 
III. Mn  :C  O Slowest IV. V 
 : C  O:
Fast
l4  l2  l1  l3
71. The rate of the reaction between two reactants X and Y can be expressed as R = k[X] 2[Y]. In an
experiment, the initial rate of the reaction was found to be R1 when the initial concentrations of X and
1
Y are [X0] and [Y0]. Another experiment was performed in which [X0] was taken as [X0 ] . What
2
should be [Y0] in this experiment to get the initial rate as 0.5 R1 ?
1
(A) 4[Y0 ] (B) [Y0 ] (C) 2[Y0 ] (D) [Y0]
2

[ 29 ]

CODE : C321 | (Date : 25.11.2018)
Ans. (C)
Sol. R  k[X]2 [Y]
R1  k[X0 ]2 [Y0 ]
2
1 
0.5R1  k  X  [Y]
2 
Y 1

4Y0 2
Y  2Y0
72. Among the following, the compound that has the highest dipole moment is :
(A) CH3COOCH3 (B) CH3CONH2 (C) CH3COC2 H5 (D) CH3COCl
Ans. (B)
O
Sol.
CH3–C–NH2
It has more resonance, more charge separation, leads to more dipole moment
73. A common method to clean acid spills is to use Na2CO3(Molar mass 106 g). If 50.0 mL of 0.75 M HCl
is spilt on a wooden surface, the amount of Na2CO3 required is :
(A) 3.75 g (B) 7.5 g (C) 2.0 g (D) 4.0 g
Ans. (C)
150
Sol. 5.0  .75  milimole HCI
4
150
Mole Na2CO3   103
8
150
Mass   106  10 3 = 1.987g = 2gm
8
74. The spin-only magnetic moments of [Fe(NH3)6]3+ and [FeF6]3– (in units of BM) respectively are :
(A) 1.73 and 1.73 (B) 5.92 and 1.73 (C) 1.73 and 5.92 (D) 5.92 and 5.92
Ans. (D)
Sol. [Fe(NH3)6]+3  actually this complex is not available so metal ligand interaction is very weak and
hence NH3 acts as W.F.L
3d5  n  5, µ  35  5.92
[FeF6 ]3  3d5

[ 30 ]

CODE : C321 | (Date : 25.11.2018)
 F is W.F.L
So, n = 5, µ  35  5.92
75. The major product of the following reaction is :
(i) Br Cl, Mg, ether
1 mole
CH3COCH2COOC2H5
(ii) H3O+
CH3
(A) Cl C(OH)CH 2COOC2H5 (B) Cl COCH2COCH3
CH3
(C) Br C(OH)CH2COOC2H5 (D) Br COCH2COCH3
Ans. (A)
O
O
CH3 CH2 –C–OEt
Sol.
Ketone is more reactive than ester
towards nucleophilic substitution
76. The standard electrode potential (E0) of the Daniel cell is 1.1 V and the overall cell reaction can be
represented as Zn(s) + Cu2+(aq)  Zn2+(aq) + Cu(s).
Under which of the following conditions will the cell potential be higher than 1.1 V ?
(A) 1.0 M Zn2+, 1.0 M Cu2+ (B) 1.2 M Zn2+, 1.2 M Cu2+
(C) 0.1 M Zn2+, 1.0 M Cu2+ (D) 1.0 M Zn2+, 0.01 M Cu2+
Ans. (C)
o 0.59 Zn1
Sol. Ecell  1  1  log 1
2 Ca
Zn2
To make Ecell greater than 1.1, log term should be nagetive  1  Zn2  Cu2
Cu2

[ 31 ]

CODE : C321 | (Date : 25.11.2018)
77. Penicillamine is used in the treatment of arthritis. One molecule of penicillamine contains a single
sulphur atom and the weight percentage of sulphur in penicillamine is 21.49%. Molecular weight of
penicillamine in g/mol is :
(A) 85.40 (B) 68.76 (C) 125.2 (D) 149.2
Ans. (D)
21.49
Sol. Molecular weight ×  32
100
3200
Molecular weight =  148.9
21.49
78. An ion exchange resin, RH2, can replace Ca2+ in hard water as
RH2  Ca2  RCa2  2H

When a 1.0 L hard water sample was passed through the resin, all H+ ions were replaced by Ca2+
ions and the pH of eluted water was found to be 2.0. The hardness of water (as ppm of Ca2+) in the
sample of water treated is :
(A) 50 (B) 100 (C) 125 (D) 200
Ans. (D)
Sol. H  102 mol / L
10 2
Ca    5  10 3 mole
2
5  10 3  40  10 6
ppm of Ca2+ = = 200
103
79. The analysis of three different binary oxides of bromine(Br) and oxygen(O) gives the following result:
Compound Mass of O combined with 1.0 g of Br
X 0.101 g
Y 0.303 g
Z 0.503 g
(I) Compound Y is Br2O3 (II) Compound Z is Br2O5
(II) Compound Z is Br2O7 (IV) Compound Y is Br2O5
(A) (I) and (III) (B) (II) and (IV) (C) (III) and (IV) (D) (I) and (II)
Ans. (C)
1
Br  1.0 2
80
Sol. X Br2O
0.101
O  0.101 1
16

[ 32 ]

CODE : C321 | (Date : 25.11.2018)
1
Br  1.0 2
80
Y Br2O3
0.303
O  0.303 3
16
1
Br  1.0 2
80
Z Br2O5
0.503
O  0.503 5
16
80. Which of the following statement/s is/are correct ?

(I) Number of significant figures in 2345.100 is three
(II) 0.00787 rounded to two significant figures is written as 0.787 × 10–2
(III) 340 rounded to two significant figures is written as 0.34 × 103
(IV) The number of significant figures in 0.020 is two
(A) (II) and (III) (B) (III) and (IV) (C) (I), (II) and (IV) (D) (III) only
Ans. (B)
Sol. (I) 2345.100 has seven significant figure.
(II) 0.787 × 10–2 has three significant figure.
(III) 0.34 × 103 has two significant figure.
(IV) 0.0020 has two significant figure.

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C321

Date of Examination – 25th November, 2018

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Alcohol C–O bond will not

–25970 kJ = 60 × (–373) – Hf C60

Hf C60  2390kJ

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4. Which of the following is not paramagnetic

Sol. S 2  Diamagnetic nature

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The water sample is likely to contain

MgCI2  Na2CO3  H2O  Mg(OH)2  MgCO3 (White ppt.)

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9. The gaseous product obtaind on reaction of BF3 with LiH is :

(A) HF (B) H2 (C) B2H6 (D) F2

Sol. 8BF3  6LiH  B 2H6  6Li[BF4 ]

[B2H6 is a colourless gas sensitive order].

Ans. (No Option)

11. The number of stereoisomers possible for the following compound :

(A) 4 (B) 2 (C) 16 (D) 32

Sol. Assymmetric molecule having four double bonds = 2n = 24 = 16

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Sol. 4NO2 (g)  O 2 (g)  2N2O5 (g);  H  –112

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From the graph it can be inferred that

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(A) 262 (B) 500 (C) 131 (D) 250

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Sol. [H3O  ][OH ]  K w

Sn4  (aq)  2e   Sn2 (aq) Eº  0.15 V

Sol. Eocell  0.15  1.07  0.92 V

Sol. 2KClO3  2KCl  3O 2

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(A) (B) (C) (D)

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(A) 2 (B) 3 (C) 5 (D) 7

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COOH COOH COOH COOH

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(A) (B) (C) (D)

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(I) IF4 (II) BF4 (III) SF4 (IV) TeCl4

2CI3 ( )  CI2  CI4

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(I) (II) (III) (IV)

(A) IV, I (B) III, II (C) III, I (D) I, III

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