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Butane

An alkane with four carbon atoms

Butane is an organic compound with the


chemical formula C4H10. It is an alkane
with four carbon atoms. It is used as a fuel
(sometimes with propane) and in aerosol
cans.
Butane

Names

Preferred IUPAC name


Butane[3]
Systematic IUPAC name
Tetracarbane (never recommended[3])
Other names
Butyl hydride[1]
Quartane[2]

Identifiers
CAS Number 106-97-8  

3D model (JSmol) Interactive image

Beilstein Reference 969129

ChEBI CHEBI:37808  

ChEMBL ChEMBL134702  

ChemSpider 7555  

ECHA InfoCard 100.003.136

EC Number 203-448-7

E number E943a (glazing


agents, ...)

Gmelin Reference 1148

KEGG D03186  

MeSH {{{value}}}

PubChem {{{value}}}
RTECS number EJ4200000
UNII 6LV4FOR43R  

UN number 1011

SMILES {{{value}}}

Properties
Chemical formula C4H10

Molar mass 58.12 g·mol−1

Appearance Colorless gas

Odor Gasoline-like or
natural gas-like[1]

Density 2.48 kg/m3 (at 15 °C


(59 °F))

Melting point −140 to −134 °C; −220


to −209 °F; 133 to
139 K
Boiling point −1 to 1 °C; 30 to 34 °F;
272 to 274 K
Solubility in water 61 mg L−1 (at 20 °C
(68 °F))

log P 2.745

Vapor pressure ~170 kPa at 283 K [4]

kH 11 nmol Pa−1 kg−1

Conjugate acid Butanium


Magnetic -57.4·10−6 cm3/mol
susceptibility (χ)

Thermochemistry

Std enthalpy of −126.3–−124.9 kJ


formation ΔfHo298 mol−1

Std enthalpy of −2.8781–−2.8769 MJ


combustion ΔcHo298 mol−1
Specific heat capacity, 98.49 J K−1 mol−1
C

Hazards

NFPA 704 1
4
0
 

Explosive limits 1.8–8.4%

U.S. Permissible none[1]


exposure limit (PEL)

Except where otherwise noted, data are given


for materials in their standard state (at 25 °C
[77 °F], 100 kPa).

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Infobox references
Aerosol spray cans often contain Butane

Uses of Butane
Butane is sold in canisters, for cooking
and camping. It is also used as fuel in
cigarette lighters, and as propellant in
aerosol sprays or deodorants. Some kinds
of Butane are used in refrigerators.

Mixtures with Propane are known as LPG.

Dangers
Butane can be hazardous. Inhalation can
lead to death by asphyxiation due to
displacement of oxygen in the lungs.
Contact with the skin can lead to frostbite.
If the gas is mixed with air and ignighted it
is prone to explode like many other fuels
that are volatile

References
1. "NIOSH Pocket Guide to Chemical
Hazards #0068" . National Institute for
Occupational Safety and Health
(NIOSH).
2. Hofmann, August Wilhelm Von (1
January 1867). "I. On the action of
trichloride of phosphorus on the salts
of the aromatic monamines" .
Proceedings of the Royal Society of
London 15: 54–62.
doi:10.1098/rspl.1866.0018 .
http://rspl.royalsocietypublishing.org/c
ontent/15/54 . Retrieved 20
September 2018.
3. "Front Matter". Nomenclature of
Organic Chemistry : IUPAC
Recommendations and Preferred
Names 2013 (Blue Book). Cambridge:
The Royal Society of Chemistry. 2014.
p. 4. doi:10.1039/9781849733069-
FP001 . ISBN 978-0-85404-182-4.
"Similarly, the retained names ‘ethane’,
‘propane’, and ‘butane’ were never
replaced by systematic names
‘dicarbane’, ‘tricarbane’, and
‘tetracarbane’ as recommended for
analogues of silane, ‘disilane’;
phosphane, ‘triphosphane’; and
sulfane, ‘tetrasulfane’."
4. W. B. Kay (1940). "Pressure-Volume-
Temperature Relations for n-Butane".
Industrial & Engineering Chemistry 32
(3): 358–360.
doi:10.1021/ie50363a016 .

Other websites
International Chemical Safety Card
0232
NIOSH Pocket Guide to Chemical
Hazards
n-Butane Molecule of the Month
Molview from bluerhinos.co.uk See
Butane in 3D
Computational Chemistry Wiki
World LP Gas Association (WLPGA)
LP Gas Association: Propane and
Butane in the UK
Global BioSciences In-Situ
Bioremediation utilizing Butane
Butane Viscosity as function of
temperature and pressure
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