Ch1.

Solutions
Type 3. Multiple choice questions

Remembering

Q1. Colligative properties depends upon:-

a) Nature of solute particles dissolved in solution. b) Number of particles of solute in solution.

c) Physical properties of solute particles dissolved in solution. d) Nature of solvent particles.

Ans. (b) Number of particles of solute in solution.

Q2. The unit of ebullioscopic constant is:-

a) K Kg mol-1 b) mol Kg k-1 c) Kg mol-1 k-1 d) K mol Kg -1

Ans. (a) K Kg mol-1

Q3. The porous membrane used in Reverse osmosis plant is made up by :-

a) Cellulose acetate b) Potassium nitrate c) Mercuric Iodide d) Starch

Ans. (a) Cellulose acetate

Understanding
Q4. An un ripen mango placed in a concentrated salt solution to prepare pickle shrivels because :-

a) of endosmosis b) it loses water due to reverse osmosis

c) it gains water due to reverse osmosis d) it loses water due to osmosis.

Ans. (d)
Q5. Low concentration of oxygen in tissues of people living at high altitude is due to:-

a) Low temperature b) Low atmospheric pressure

c) High atmospheric pressure d) Both low temperature and high atmospheric pressure

Ans. (b)
Q6. The value of Henry’s constant KH is:-

a) greater for gases with higher solubility b) greater for gases with lower solubility

c) constant for all gases d) not related to the solubility of gases.

Ans. – (b)

Q7. Which of the following aqueous solutions should have highest boiling point:-

a) 1.0 M NaOH b) 1.0 M Na2SO4 c) 0.5 M NaOH d) 2.0 M Na2SO4

Ans. d) 2.0 M Na2SO4

Q8. Which of the following factor affect the solubility of gaseous solute in the fixed volume of the liquid solvent:-
i) Nature of solute ii) Temperature iii) Pressure
 (a) (i) and (iii) at constant T (b) (ii) only (c) (ii) and (iii) only (d) (iii) only

Ans. (a)
Q9. Characteristics of an ideal solution is:-

a) Obey Raoult’s law, ΔHmix = 0, ΔVmix ≠ 0 b) Obeys Raoult’s law, ΔHmix ≠0, ΔVmix = 0

c) Does not obey Raoult’s law, ΔHmix = 0, ΔVmix = 0 d) Obeys Raoult’s law, ΔHmix = 0, ΔVmix= 0
Ans. (d)

Q10. Solution of NaCl freezes at lower temperature than water because-

a) It is a volatile solute b) It is a double salt

c) It is a coordination compound d) It is a non- volatile solute

Ans. (d) It is a non- volatile solute

Applications
Q11. The concentration of solution with its vapour pressure is related in terms of

a) mole fraction b) parts per million c) mass percentage d) molality

Ans. (a) mole fraction

Q12. Maximum amount of solid solute that can be dissolved in specified amount of given liquid solvent does not depends
upon:-
a) Temperature b) Nature of solute c) Pressure d) Nature of solvent
Ans. (c) Pressure
Q13. In comparison to 0.01 M solution of glucose, the depression in freezing point of 0.01 M MgCl2 solution is:-
a) Same b) Twice c) Three times d) Six times

Ans. (c) Three times

Q14. Which of the following is incorrect for ideal solution:-
a) ΔHmix= 0
b) ΔVmix = 0
c) Does not obey Raoult’s law over entire range of concentration
d) A – A, B – B, interaction is equal to A – B interaction

Ans. (c) does not obey Raoult’s law over entire range of concentration

Q15. If molarity of the dilute solution is doubled, the value of the molal depression constant(Kf) will be:-
a) doubled b) halved c) tripled d) Unchanged

Ans. (d) Unchanged

Q16. Solution A contains 7g/L of MgCl2 and solution B contains 7g/L of NaCl. At room temperature, the osmotic
pressure of :-
a) Solution A is greater than B b) both have same osmotic pressure
c) Solution B is greater than A d) Can’t determine
Ans. (c) Solution B is greater than A
Q17. Van’t Hoff factors x, y and z for association, dissociation and no change of solute in the
solution respectively are in the order:-

a) x< y < z b) x> z > y c) x< z < y d) x> y > z

Ans. (c) x < z < y

Analysing and Evaluation

Q18. What is the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride

a) 0.541 b) 0.459 c) 0.514 d) 0.489

Ans. (b) 0.459

Q19. 18 g of glucose is dissolved in 1 kg of water. At what temperature will water boil at 1.013 bar ? Kb for water is 0.52
K kg mol-1
a) 373.2K b) 378.2K c) 381.5K d) 383.2K

Ans. (a) 373.2K

Q20. An antifreeze solution is prepared from 222.6 g of ethylene glycol and 200 g of water . What is the molality of the
solution?
a) 15.97m b) 19.57 m c) 17.07 m d) 17.95m

Ans. (d) 17.95m

Q21. Calculate the amount of benzoic acid required to prepare 250ml of 0.15 M solution in methanol.

a) 4.575 g b) 5.475g c) 4.015g d) 5.015g

Ans. – (a) 4.575g

Q22. Which one of the following electrolytes has the same value of Van’t Hoff factor (i) as that
of Al2(SO4)3 (if all are 100% ionized)
a) K2SO4 b) K3[Fe(CN)6] c) Al(NO3)3 d) K4[Fe(CN)6]
Ans. (d) K4[Fe(CN)6]
Q23. Vapour pressure of water at 293 k is 17.535 mm Hg. Calculate the vapour pressure of water at 293 K when 25 g of
glucose is dissolved in 450 g of water.
a) 15.44 mm Hg b) 15.43 mm Hg c) 17.44 mm Hg d) 17.04 mm Hg

Ans . ( c ) 17.44 mm Hg

Q24. Of the following 0.10 M aqueous solutions, which one will exhibit largest freezing point depression-
a) KCl b) C6H12O6 c) Al2(SO4)3 d) K2SO4
Ans. (c) Al2(SO4)3
Q25. 1 mole of liquid A and 2 moles of liquid B, make a solution having a total vapour pressure of 38 torr. The vapour
pressure of pure A and pure B are 45 torr and 36 torr respectively. The described solution-
a) is an ideal solution b) shows negative deviation
c) is a minimum boiling azeotrope d) has negative ΔV
Ans. (b) shows negative deviation
ARMY PUBLIC SCHOOL
PGT-CHEMISTRY
ARUN SINGH