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T2 PAPER
~.mER SPE 48! I
6200 North Central Expressway
Dallas, Texas 75.206
By
@)Com’right 1974
American Institute of MiningIMe~aIlu-rgical, and Petroleum Engineers, Inc.
Th~S paper ~JeS p~epa~ed for the Permian Basin Oil Recovery Conference of the SocietY of
.-r,
Petroleum Engineers of AIME, to be held in Midland, Tex., March 11-12, 1Y(4. Permission to cGpY
is restricted to an abstract of not more than 300 words. Illustrationsmay not be copied. The
abstract should contain conspicuousacknowledgmentof where and by whom the paper is presented.
Publication elsewhere after publication in the JOURNAL OF PETROLEUM TECHNOLOGY or the SOCIETY OF
PETROLEUM ENGINEERS JOURNAL is usually granted upon request to the Editor of the appropriate
journal provided agreement to give proper credit is made.
Discussi~n of this paper is invited. Three c~pies of any discussion should be sent to the
Society of Petroleum Engineers office. Such discussion may be presented at the above meeting and,
the pq?er> may be considered for publication in one of the two SPE magazines.
‘witP.
15. Sour Crude. A crude oil which will as an effort to circumventthe Re=glations.
emit a sour gas when in equilibrium This is not to say that greater than 5W0
at atmosphericpressure. air could not be utilized in the tail-gas
incineratorfor cooling purposes. However,
16. Source. A point of origin of air for the purpose of calculatingthe allowable
contaminants,whether privately or emission rate for pollutants from the incinera-
publicly owned or operated. Upon tor, 5W0 excess air shall be the maximum
request of a source owner the Execu- allowed. Any activity which might be illegal
tive Director shall determine whether and noticeable during daylight hours, done
multiple processes emitting air con- during the hours of darkness to escape de-
taminants from a single point of emission tection,.also comprises a circumventive
wiu be treated as a single source or activity. Examples of such activity would
as a multiple sources. -1
incltitie7.-:.o honvy
f~-....a..-. hydrocarbonswith smokej
burning tank bottoms, burning parafin, or
17. Standard Conditions. A condition at by-passing abatement equipment normally used
a temperature of 70% and a pressure during daylight hours.
.l..Al,,+a
of 14.7 pounds per square iiichl
~LJou&~.-.
Pollutant concentrationsfrom an incin- The Nuisance provision of the Generai Rules is
erator will be correctedto a condition to provide an effective means for dealing
of 5C$ excess air if the incinerator with situationswhere air pollution problems
is operating at greater than 5~0 excess may not be adequatelyhandled by specific
air. regulations. Rule 5 of the General Rules
states that no person shall cause a condition
18. Sulfur Compounds. All inorganic or of air pollution such as to adversely affect
organic chemicals having an atom Or human health or welfare, animal life> vegetation
atoms of sulfur in their chemical or property, or as to interferewith the
structure, normal use and enjoyment of animal life,
vegetation, Or property. If a facility pro-
19. Sweet Crude Oil and Gas. Those crude cessing hydrocarbons is emitting into the air
petroleum hydrocarbonsthat are not certain compounds not covered by specific
r!
sour” as defirled. re=tiations,and these compounds are inter-
fering with a person’s normal use &z6 enjoyw=nt
20. Upwind Level. The representative of his property in whatever way, this consti-
con”centratlon ---~-...~m
n+c
of aii’~ULltiuil&A.a
.... tutes a violation of the General Rules of
flowing onto or across a property as the Board by the operators of the processing
measured at any point. facility. The possibility exists that offen-
sive odors may be created at any hydro-
21. Visible Emissions. Particulate or carbon processingfacility. Problems
gaseous matter which can be detected associatedwith odors eminating from such a
<y the human eye. The radiant energy facility may be effectively controlledby
from an open flame shall not be con- the General Rule on Nuisance.
sidered a visible emission under this
definition. Rule 7 of the General Rules states that the
Executive Director and the appropriate local
air po31ution control agency shall be notified
Rule 4 of the General Rules is the Board’s as soon as possible of any major upset con-
statement on any attempt to circumventthe dition which causes or may cause excessive
Re=wlations. C&cumve~tion may be thought emissions as defined by the Act or ReQ@a-
of as an attempt by an operator to misrepresent tions of the Board. A major upset is defined
emissions at any given point in time by as an upset over which the operator has no
applying certain operating procedures that immediate control. However, it would not
might not be present under ordinary operating be practical for the Board to concern itself
conditions. Introducing excess air or re- statewidewith all upsets which meet this
ducing feedstock to a given process in an general definitionbut are of extremely short
effort to demonstrate less emissions than duration. In general, any upset which can
could be expected during normal operating be corrected in 10-15 minutes, and is correc%-
conditionsmay be construed as circumvention. ed, can be.considereda minor upset. The
For example, tple~ta~f of t.b.e
B~ard operator of such
~QWS OIIIy5(3?0
excess air to be used in the .,a source should make record
ca+c ~.o
of the upset but noz rep~i% s’uek.
up....
calculationof the allowable S02 emission L%
~f~eE~e~,JtiveDirector. Records of such
rate from the tail-gas incineratorof a minor upsets will serve three purposes:
sulfur recovery Imit. The use of greeter
than 5@ air in the calculationof such an 1. A member of the Boardfs staff may ob-
allowable would be interpretedby the staff serve an excessive emission and question
.10 CW AIR AND THE PETR RTIMTNT)TJSTRY
---- TN WEST
--.—-—-- -- —-. —-— TEXAS
—— SPE 4811
the operator of the source as to why such flared, concentrationof hydrogen sulfide
an emission took place. If records are in that gas, and probable duration of the
properly kept, the source operator will outage. He would also notify the local air
be able to respond with the statement pollution control agency, if any, giving the
that a minor upset had occurred during same information. The plant uperator would
that period. then fill out a Report Form for Notification
Requirementsand send this form to the Execu-
2. If complaintsare received from the gen- tive Director in Austin. The Board is not
eral public concerningemissions during so naive as to expect immediatenotification
a minor upset, the source operator will of upsets when action is required on other
be able to respond to the investigator fronts by a source operator in order to pre-
and the complainantby referring to prop- serve human or animal life or protect property.
erly kept records. Rowever, as soon as practicallypossible,
the source operator should report the upset
3. Frequent upsets may indicate to the source to the proper agents.
owner that maintenance should be performed
on abatement equipment, etc. Rule 8 is similar to Rule 7 in that it allows
emissions in excess of the Re=@_ationsto
Upsets of longer duration constitutemajor exist, but as a result of ylanned maintenmce.
upsets and must be handled accordingly. A The Rule requests that ten days advance
suitable reaction to a major upset condition written notice be given to the Executive
which produced excessive emissions would be Director in Austin concerningthe details of
as follows: a planned maintenance outage that might
cause excessive emissions from a facility.
1. The source operator should notify the A copy of the notice should be mailed to
region~ office by phone relating the the regional office. Emission levels to be
details surroundingthe upset. allowed during planned maintenanceprocedures
may be determinedby the Executive Director
?
-. A Report Form for NotificationRequirements, of the Board, as stated in Rule 12.2 of the
similar to the one shown in Fiogure2%should General Rules. An exampie of plaiiiied wx?&nten-
be completed and sent to Austin. ance requiring notificationof the Board
muld be the outage of a boiler used to pro-
In addition,thelocal air pollution control duce steam for use in a smokeless flare.
agency, if any, should be notified. In Region Many of these boilers must be inspected
6, the only active local air pollution control periodicallyby the state for safety
program is operated by and within the Ector reasons. Since the boiler inspection must
County Health Department. It should be men- be scheduled,this constitutesa planned
tioned that non-routine conditions,whether maintenance outage. The source operator
minor or major, that occur regularly over an should notify the Executive Director of the
extended period of time are not considered time and approximate duration of the outage
upsets covered by this Rule. Such re=gular as required on the Report Form for Notifica-
‘.ipSe*S ZR cor2sidered an integral part of the tion Requirements. The reason for report-
daily uperation of the source for compliance ing such pl~ed ~intenance would, .be ~na~ ~ne
purposes. Poor facility maintenance,poor op- outage of the boiler would mean that no
erating techniques, or failure to maintain steam would be available to the smokeless
air pollution control equipment at appropriate flare system. If material must be flared in
efficienciesat all times, will not be accepted the flare system during this outage, excessive
as excuses for upset conditions. visible emissions could result.
An example of a situationwhich would require Rule 9 of the General Rules states that any
notification of an upset to the Board would persons operating a source which emits air
be the failure of a sulfur recovery unit pollutants into the air of the state shall,
processing the acid gas from a gas processing upon request of the Board or the Executive
plant to function properly. The inlet acid Director, conduct samplin~ to characterize
gas from the gas processing plant to the sulfur such emissions. It also states that the
plant would have to be routed through a proper results of such sampling should be forwarded
flare or incinerator in order that examination to the Executive Director. Although the
of condensers,reactor ‘Deals,etc., Wlight6E= @fie ~ta~es the Executive Director can specify
termine the cause of the malfunction of the the method by which sampling will be done,
unit. This flaring or incinerationwould the operator of a source may elect to pro-
probably result in excessive ground level pose to the Executive Director an alternate
concentrationsof sulfur dioxide. The proper method of sampling the emissions from his
response of the plant operator would be to facility. If that alternatemethod is accepted
call the regional office giving the details by the Executive Director, the operator of
-,..
01”Xne uvset such as ..n.w,n+
of g~~ tQ ~~
w,,UU... the source may use that alternate method to
m 48u CHARLES GIU?GORYSHORT 111
characterizethe emissions from his facility breaks and oil spills, if disposal by,any
and report the results of such sampling to other means is not practical.
the Executive Director. It should be emphasized
that no monitoring is required of any source Visible emissions from a stationary flue
unless specificallyrequired by the Executive are not to exceed an opacity of thirty per
Director. Copies of all sampling data collec- cent averaged over a five-minuteperiod.
ted as a result of a requirement of Rule 9 If the stationary flue was constructedafter
shall be retained by a source operator for January 31, 1972, the visible emissions must
at least 5 years. not exceed twenty per cent opacity averaged
over a five-minuteperiod. These are opacitY
Many requests have been received by the Execu- readings as taken by a qualified observer. The
tive Director to allow an alternate nethod of Board recognizes a qualified observer as one
monitoring by material balance to be used who has successfullycompletedthe state’s
in fulfillmentof Rule 9 requirements. The course on evaluating visible emissions and
general position of the Executive Director been recertifiedwithin the previous six
has been to require sampling by in-stack methods ~TLorJ~pL.s
. ~+e ~&Qo~ On visible emissions
to determine the in~tial complianceposture is offered in Odessa every six months. Defi-
of a facility. If, during this stack sampling, nite dates, times, and locations may be ob-
material balance tests are performed on the tained from the Region 6 Office.
facility and these tests support and agree
with the stack sample, the alternate method Regulation I also states that no visible
of monitoringusing material balance cal- emissions may be permitted from a waste gas
culations may be allowed. flare for more than five minutes in any two-
hour period. The waste gas flare referred
Rule 12 states that under certain conditions to in this Reo@ation is one which is attempt-
the Executive Director may allow exemptions ing to c~lete~ combust all,waste process
from certain Rules and Regulations of the hydrocarbons from a processing facility. Rtie
Board. Careful inspection of this Rule by 103.2 of Reo@Lation I is not referring to
a source operator will reveal whether an the sometimesvisible whi~emissions from
operator’sparticular problem might fall in an acid gas flare at a gas processing plant.
an area where the Executive Director has
authority to limit the applicabilityof a REGULATION II
Rule or Re.@iation.
Rules governing the operation of Sulfur
A particularly importantpart of the General Recovery Units processing acid gas from gas
Rules pertains to the right of persons to processing plants are stated in Regulation
petition the Board to consider any air pollu- II. Specifically,Rule 201.03 gives the
tion control problem that he might have. allowable emission rate of sulfur dioxide
The Board and the staff are aware that in for a specified standard effective stack
many cases solutions to problems concerning height and stack effluent flow rate. This
air pollution control are not found easily. allowable may be found from Table 1 and/or
If the operator of a source has a problem Figure 3. However, if the effective stack
which he believes deserves special considera- height is less than the standard effective
~iOn for---
UIl~- h~c +h~ ~nortunity
~e~~~?.,..=----...--==-.
h. stack height, as found in Table 2 and/or
to petition the staff and/or the Board for an Figure ~, the allowable emission rate ~id~~
%udience. In cases where a person has not be reducedby multiplying it by the following:
achieved compliancewith the Re@l.ations,he
(
may request a variance from certain Regula- Effective Stack Height 2
tions of the Board. The Board will review such Standard Effective Stack Height)
a request in view of past complianceefforts,
economic hardships, etc. lhe effective stack height of the stack at
a sulfur recovery facility may be calculated
REGULATION I using the following equation:
Te = Stack exit temperature in degrees until December 31, 1976, to find or manufac-
Rankine (%) ture appropriate supplies of low-sulfur fuel.
Other than ground level concentration re- dioxide in the acid gas use such flares in
strictions,the only restriction on a.liquid conjunctionwith their acid gas treating
fuel fired steam generator, furnace, or units. It may be possible to reduce the
heater is a 440 ppm, by volume, allowable supplementalfuel gas to the flare without
in-stack concentrationof sulfur dioxide. causing a deteriorationin the combustion
characteristicsof the flare. These are
Due to the shortage of comparativelylow- two areas in which the interest of fuel
sulf’urfuels for use in firing heaters and conservationand adequate air pollution con-
boilers, many companiesmay find it necessary trol may be satisfied by careful engineering
to operate facilities on a temporary basis using evaluation.
high-sulfur fue~~. ‘I% B~ard has specified
that any person expecting excessive sulfur In addition to rules governing emissions of
dioxide emissions as a result of such tem- sulfur dioxide, Regulation II of the Board
porary operation using high-sulflu fuels contains Rules for the control of hydrogen
should file a Temporary Fuel Shortage Control sulfide emissions. A maximum ground level
Plan as outlined by Regulation II. The concentrationof 0.08 ppn for a thirty-
acceptance of such a plan by the Board de- minute sample is allowed if the downwind
pends on the operator’s ability to show the concentrationof hydrogen sulfide affects
non-availabilityof low-sulfur fuels as well a property used for residential,business,
as the predicted consequencesof the usage of or commercialpurposes. A maximum ground
high-sulfhr fuels for temporary shortages. level concentrationof 0.12 ppm for a thirty-
Any person who must operate under his Tem- minute sample is allowed if the downwind
porary Fuel Shortage Plan should notify the concentrationof hydrogen sulfide affects
Executive Director of the Board and the local only property used for other than resi-
air pollution control agency, if any, as soon dential, recreational,business, or commercial
as possible of the fuel shortage causing the PWoses, such as industrialproperty and
utilization of his plan. Notification of vacant tracts and range lands not normally
such a situation should include the estimated occupied by people. An allowable emission
duration of the shortage as well as any signif- rate for a stack emitting hydrogen sulfide
icant consequencesthat may be caused by utili- can be calculatedusing methods shown in
zation of the Plan. Any person who operates Appendix A of Regulation II.
under a Temporary Fuel Shortage Control Plan
must submit to the Board semi-annuallya For property where the source of hydrogen
record of the fiels used at his facility sulfide emissions is a bulk storage facility
during the preceding six months, as well as for sour crude, the emission rate will have
any efforts he has made to avoid future use to be determinedby ground level sampling at
of his Temporary Fuel Shortage Control Plan. the facility. For the purposes of such sam-
ML- ..--.--L“.
LlleLcaDull +-fiW
~~~o,firiP1g
~,2c~A
~ ShioV+,~.Ue pling, the property line for a crude oil
- --o-
Control Plan is to give operators of sources storage facility shall be outside the area
!P?7Ml 1 CHARLES GREGORY SHORT 113
obviously set aside for oil and/or gas pro- generallybecomes more difficult after a source
duction. The production area wL1l generally is already built and in operation. A minimum
be inside a fence or caliche pad or other- of expense, because the control of air pollu-
wise cleared area provided for the installa- tion from a source already in operation is
tion and use of the storage facility. This generally more complex and requires considera-
method of property line determination bly more down time than would have been required
obviously assumes the owner or operator of if controls were designed and implemented
.. . ~ .
mot,gwn or lease
an oIL am gas lease doe. ... before start-up of the facility. Msny times
the surface rights associatedwith his the permits system wili require cmtrols
mineral lease. These procedures also which may not seem to be justifiable. However,
apply to facilitieswhere stored water experience has shown in many cases that the
or other stored material might cause sig- controls have paid for themselves in recovery
nificant amounts of hydrogen sulfide to be of products or by-products. In addition,
released into the air. there have often been design errors in process
informationsubmitted to our permit system
.. .—--- a .~a b~nmqht
REGULATION which have ‘beenalscuv=~-eu=..ti.s-o.. to the
attention of the potential source operator
Regulation V, Control of Air Pollution from prior to the constructionof the facility. As
Volatile Carbon Compounds, is not applica- a result of the above reasons, and the re-
ble in any counties within Air Quality quirements of the Act, the following procedures
Control Region 6 at this time. form general .midelines for use of the permit
system:
REGULATION VI
1. Engineering design of source is completed.
Until this point in the paper, the Control
of Air Pollution by Permits for New Con- 2. Particular attention is given to the loca-
struction or Modification,Regulation VI, tion of the source.
has purposely been ignored. This is in
order that most of the importantpoints 3. A general applicationto construct a
pertaining to the Board’s permit system source is completed and submittedto
may be discussed at one time. Rule 601 the Board.
and 602 of Reg~ation VI state:
4. A constructionpermit with appropriate
Rule 601. Section 3.27 (a) and Section prwisions is received.
3.28 (a) of the Texas Clean
Air Act require any person 5. Constructionof the facility is started.
who plans to construct any
new facility or to engage in 6. The Board is given thirty days notice
the notificationof any exist- prior to start-up of facility.
ing facility which may emit
air contaminantsinto the air 7. The facility begins operation.
of this State to obtain a
constructionpermit from the 8. Emissions of the facility are character-
Texas Air Control Board ized as required by constructionpermit.
befc-.
Au -..O
anv actual work is
begun on the facility, and 9. Within sixty days aIfter start-up of tke
to obtain an operatingpermit facility, an operating permit is requested,
from the Texas Air Control and sampling data, if any, is submitted.
Board in order to continue
to operate the facility after 0. An operating permit is received.
a sixty day start-up period.
At this point it should be noted that many
Rule 602. The owner of the facility or sources are small enough that, although they
the operatwof the facility emit air contaminantsinto the air of the State,
authorized to act for the owner contaminantsare present in such small amounts
is responsible for applying that the sources can be considered insignificant.
for and obtaining a permit to In order to allow the permit engineers to exam-
construct and operate. ine only the proposed sources which will be
significant,a list of exemptions from permit
The Texas Air Control Board considers procedures has been prepared, and is available
—. s
;i-~one
control of alr poliuticiiby per.m... from the Executive Director upon request. If
of the most effective means of controlling a Potential source is included in the ii~t
air pollution with a minimum of time, of exemptions, it is automaticallyexempt from
expense, and effort. A minimum of time, any and all permit procedures. No written
because control of air pollution problems request need be made to the Board unless a
.14 CLEAN AIR AND THl?PETROL M INDUSTRY IN WEST TEXAS SPE 4811
sCxl.Zz ce opera.t~rhas special questions concern- or decreased production from an oil or gas
ing l~hetheror not a source might qualify -,
well or as a resul~ of origi~lal iM!OHeCt
for one of these exemptions. If an operator sizing of differentparts of the facility.
believes his proposed source to be insignifi- Using exemptions 76 and 77 can be beneficial
cant, he should petition the Board in writing. to an operator in producing oil smd gas
In his letter to Austin, he should state the immediatelyand complyingwith all Regulat-
basic parameters which describe the operation ions of the Texas Air Control Board. A
of the source he desires to construct.Based typical procedure to be used incorrectly
on this information,the permit section will. applying exemptions 76 and 77 would be as
either uphold or deny his request for an follows:
exemption. If denied, he must submit a
complete permit package and obtain a construc- 1. The well is completed.
tion permit before constructionis started.
2. Exemption 76 is invokeq and separators,
Two exemptions relating to facilities on oil tanks, treaters, and other necessarY
or gas producing properties deserve special ~teria~ are b~~~~b.t%Q the well site
mention. These exemptions, 76 and 77, are in order to produce the oil and/or gas.
as follows: Exemption 76 requires that all emissions
,.+ka-+h=n
to tineatmosphere UWG.
.Q+.ock-tSdC
. ... .. -.
1. Gas fired internal combustionengines 16. Gas turbines of less than 20,000 hp
of less than 2000 hp and engine trains burning sweet natural gas.
of less than 5000 hp total.
17. A stationar.vtank, reservoir, or other
2. Natural gas or LP gas fired combustion container u~ed for the storaie of
units with rated fuel consumptionless liquid petroleum gas (L.P.G.), if
than 10,000 standard cubic feet per hour. such tank, reservoir, or other container
is a pressure vessel capable of main-
3. Equipment used exclusivelyto store taining working pressures sufficient
or hold dry natural gas. at all times to prevent vapor or gas
loss to the atmosphere.
4. Containers,reservoirs, or tanks used
exclusively for unheated storage of REGULATION VIII
organic materials with initial boiling
point of 300°F or greater. Reg~a,tion VIII, Control of Air Pollution
Emergency Episodes, does not apply to
5* Containers,reservoirs, or tanks used Region 6 because no priority I levels of any
exclusively for the storage of fuel of the appropriatepollutants have been
oil with a gravity of 25 degrees API recorded in the Region.
or lower; or for the storage of lubri-
cating oils. SUMMARY
13. Natural gas or LP gas fired emulsion Rules and Regulations,Texas Air Control Board.
treaters with rated fuel consumptionof
less than 10,000 standard cubic feet
per hour.
SULlwR RECOVERYPLANTS
1,000 214
2,000 305
396
l;ro 487
5,000 579
6,000 6’70
7,000 759
8,000 845
9,000 929
10,000 1012
20,000 1766
30,000 2447
40,000 s084
50,000 3690
TABLE 2
SULFUR RECOVERYPLANTS
STANDARDEFFECTIVESTACK HEIGHT
BASED ON SPECIFICFLOW R4TES
100 85
500 96
1,000 109
2,000 129
3,000 148
4,000 164
5,000 178
6,000 192
7,000 204
8,000 215
9,000 226
10,000 236
20,000 311
30,000 366
40,000 411
50,000 450
60,000 484
80,000 544
100,000 595
Interpolationand extrapolateion of the data for stack effluentflow rates
less than or equal~ 4,000 scfm shall be accomplishedby the use of the
equationHe = 7.4 @.L + 0.091 ~ 0“5, where He is ~& ~~~~~~~~~f’f~gt ~~~
-J
stack height in feet and q is the stack effluent flow rate in scfm. Inter-
polation and extrapolationof the data for stack efl-~uentin excess of b,000
scfm shall be accomplishedby the use of the equationHe . 5.8q 0.402.
I I I
,.
t-
U--U-T--TM”
d
1~
SO.!c
W-,7A
,.es
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I 1 I I I I I
..CUC.S . ..1!. .I,CNCLL ‘**M i ‘*TLm k“’Nb”’’Lam
b \~ J
....,,7” CULse*SO.
I
“,..
~-x
,,m”#
u...
COMA,
u-f,
1. Abilene-WichitaFalls
2. ‘o-Lubbock
3. Austin-Waco
4. Brownsville-Laredo(Harlingen)
5. Corpus Christi-Victoria
6. Midland-Odessa-SanAngelo
7 Un,,c+nn-cslveston
b; ‘F;;<.~;rth
9. San Antonio
“.,-l O_..AL--”“.Tm.7<.inns-~~lJtheBSt T
=Lu. i)uublleL1l Ll”uL.JAk----
(Beaumont)
*11 . El Pa-ruces-Alamogordo
*12. ‘rt-Texarkana.-Tyler
+Interstate Regions
Cities where Regional Office is located is underlined.
FORM NO. AG-6($969)
Level of Emissions (give basis for estimate): Physical and Chemical Composition,Rate,
Concentration,and Duration
...+a.+-~~;.~d
Measures (to be) Taken to Prevent Recurrence (if nub UG”G.>ILA..U
@j give date when
measures will be submitted)
Fig. 2
STANDARDFFFECWEI:;ACK HFIGHT (ft) 1,000
10
I I 1 1 ZIlr
I 1 1 1 I II
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7
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