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International Class
CATIONS
IDENTIFICATION
Andari Rahmadhani
D500194024
Purpose
Systematic qualitative analysis, cations agree on five classes based on the
properties of cations for some reagents. By using the so-called special group
reagents, we can determine whether there are no groups of cations, and can also
contain these groups by further examination. The group reagents used for the
most common cations are hydrochloric acid, hydrogen sulfide, and ammonium
carbonate. This classification is based on what is requested with these reagents
by forming a precipitate or not. So we may say that the classification of cations is
the most common, based on the differences in the chlorides, sulfides and
carbonates of the cations (Vogel, 1990: 203).
Pb2+
Dilute hydrochloric acid (or soluble chloride): white precipitate in a cold, not
too runny solution
Dilute sulfuric acid (or dissolved sulfates): white precipitate, lead sulfate
Hg+
Dilute hydrochloric acid or soluble chlorides: mercurium (I) chloride
(calomel) precipitate
Ag+
Hg2+
Hydrogen sulfide (gas or saturated water solution): in the presence of dilute
hydrochloric acid, a white precipitate of mercurium (II) chlorosulfide is
formed, which decomposes when further hydrogen sulfide is added, and
finally a black precipitate of mercurium (II) sulfide is formed.
Potassium cyanide (poison): does not cause any changes in aqueous solution
(difference from other ions from the copper sub-group)
Tin (II) chloride: when added in moderation: white and silky precipitate,
mercurium (I) chloride (calomel)
Dry test : All mercury compounds, irrespective of their valency state, form
mercury metal when heated with excess anhydrous sodium carbonate.
Bi3+
Hydrogen sulfide (saturated water solution gas): bismuth sulfide black
deposits
Ammonia solution: white base salt with various compositions. Insoluble
precipitates in excessive reagentia difference from copper or cadmium)
sodium hydroxide in regensia reacts with bismuth (III) ions, then bismuth
(III) hydroxide is reduced by tetrahydroxostanate (II) ions, bismuth metal
and hexahydroxostanate ions are formed.
Cu2+
Hydrogen sulfide (gas or saturated water-solution): black precipitate, copper (II) sulfide
Ammonia solution if added in very small amounts: blue precipitate of a basic salt (copper sulphate base)
Potassium cyanide (poison): when very little is added, a yellow copper (II) cyanide precipitate is formed
Catalytic Test : (a) is fairly rapid; reaction (b) is a slow one, but is
enormously acceler• ated by traces of copper.
Dry test
a. Blowpipe test When copper compounds are heated with
alkali carbonate upon charcoal red metallic copper is obtained but
no oxide is visible.
b. Borax bead Green while hot, and blue when cold
after heating in the oxidizing flame; red in the reducing flame, best
obtained by the addition of a trace of tin.
c. Flame test Green especially in the presence of halides, e.g. by
moistening with concentrated hydrochloric acid before heating.
Cd2+
Hydrogen sulfide (gas or saturated water solution): yellow cadmium sulfide
precipitate
Ar3+
Hydrogen sulfide: arsenic (III) sulfide yellow precipitate
Ar5+
Hydrogen sulfide, does not occur immediately precipitate in the presence of
dilute hydrochloric acid.
Sb3+
Hydrogen sulfide: orange-red stibium trisulfide deposit, Sb2O3, from
not-so-acid solutions.
Potassium iodide solution: the color becomes red due to the formation of
complex salts.
Reagentia rodamina-B: blue staining with quintuevalent stibium (validated
5).
Reagents of phosphomolybdic acid: blue molybdenum is produced by
stibium (III) salts.
Sb5+
Hydrogen sulfide: red-orange precipitate stibium pentasulfide, Sb2S5, in an
acidic solution
Sn2+
Hydrogen Sulfide: lead (II) sulphide brown deposition, SnS, from a solution
that is not too acidic
Sn4+
Hydrogen Sulfide: Yellow sulphide (IV) sulfide, SnS2, from dilute acid
solution.
+
Tdk ada Tdk larut Larut Larut
Berlebi
perubahan [Cd(CN)4]2
h
-
SnCl2 ↓ Putih ↓ HgCl2
+
Berlebi ↓ Hitam Hg
h
Air ↓ Putih
BrO(NO)2
Fe2+
Sodium hydroxide solution: white precipitate iron (II) hydroxide
Fe3+
Ammonia solution: red brown deposits such as gelatin from iron (III)
hydroxide
Hydrogen sulfide gas: in acidic solutions reduce iron (III) ions to iron (II)
and form sulfur as a milky-white precipitate
The reduction of iron (III) ions to iron (II) in acidic solutions can be
achieved with various substances
Oxidation of iron (II) ions to iron (III) oxidation occurs slowly when exposed to air
Distinction determination tests for iron (II) and iron (III) ions
Dry tests
b. Borax bead test With a small quantity of iron, the bead is yellowish-brown while
hot and yellow when cold in the oxidizing flame, and pale green in the reducing flame;
with large quantities of iron the bead is reddish-brown in the oxidizing flame.
Cr2+
Ammonia solution: face like a green gray to blue gray
7. Chromate Test. Chromium (III) ions can be oxidized to chromate in several ways
9. Dry test
b. Borax bead test The bead is coloured green in both the oxidizing
and reducing flames, but is not very characteristic
c. Fusion with sodium carbonate and potassium nitrate in a loop of platinum wire
or upon platinum foil or upon the lid of a nickel crucible results in the formation of a
yellow mass of alkali chromate.
Ammonia solution: if there are no ammonium salts, a little ammonia will precipitate
alkaline salt.
Ammonium sulfide solution: black cobalt (II) sulfide precipitate from a neutral or basic
solution.
Rubeanic acid (or ditio-oxamide) reagents: brownish-yellow deposits, nickel salts and
copper give blue and black deposits respectively.
Dry test
b. Borax bead test This gives a blue bead in both the oxidizing and reducing flames.
Cobalt metaborate Co(BO,),, or the complex salt Na,Co(BO,),, is
Ni2+
Sodium hydroxide solution: green nickel (II) hydroxide precipitate, insoluble precipitate in
excessive reagents.
Ammonia solution: green nickel (II) hydroxide precipitate, which dissolves in excess
reagency the solution turns dark blue.
Ammonium sulfide solution: black nickel sulfide precipitate from a neutral or slightly
alkaline solution.
Hydrogen sulfide (gas or saturated water solution): only a portion of nickel settles slowly as
nickel sulfide from neutral solution.
Potassium cyanide solution (POISON): nickel green (II) cyanide precipitate, precipitate
dissolved in excessive reagents.
Dry test
b. Borax bead test This gives a blue bead in both the oxidizing and reducing flames.
Cobalt metaborate Co(BO,),, or the complex salt Na,Co(BO,),, is
Mn2+
Sodium hydroxide solution: manganese (II) hydroxide precipitate. Firstly white, insoluble
deposits in excess reagency.
Ammonia solution, deposition of manganese (II) hydroxide which was (originally) white,
precipitation did not occur if there were ammonium salts.
Ammonium sulfide solution: pink manganese (II) sulfide sediment, the sediment also
contains weakly bound water.
Lead oxide and concentrated nitric acid: by boiling a dilute solution of manganese (II) ions
Sodium bismuthate: when this solid is added to the cold solution of manganese (II) ions in
diluted nitric acid, it produces a permanganate solution.
Potassium periodate
Formaldoxymal reagents: red staining with a solution of manganese (II) salts that are basic.
Dry Tests :
Borax bead test, a bead produced in flame by small amounts of manganese salt
Melting test, melting each manganese compound with sodium carbonate and an oxidizing
agent
Zn3+
Sodium hydroxide solution: precipitate like white gelatin, namely zinc hydroxide
forms complexes with a number of metal ions, which can be extracted with carbon
tetrachloride.
Group IV : Ba2+,Sr2+,Ca2+
Group reagent: IM solution of ammonium carbonate.
The reagent is decomposed by acids (even by acetic acid), when carbon dioxide gas is formed:
Ba2+
Ammonia solution: no barium hydroxide deposits occur because of their relatively high
solubility
Ammonium carbonate solution: white deposits of barium carbonate, which are soluble in
acetic acid and in dilute mineral acids.
Ammonium oxalate solution: white deposits of barium oxalate Ba(COO)2, which are only
slightly soluble in water, but are dissolved easily by dilute acetic acid and by mineral acids.
Dilute sulfuric acid: white barium sulfate BaSO4, which is fine-grained, heavy, and practices
insoluble in water, almost insoluble in dilute acid and in a solution of ammonium sulfate,
and dissolves quite well in boiling concentrated sulfuric acid.
Sodium rodizonate reagents: reddish-brown deposits, that is, barium salt from rodizonic
acid in neutral solutions.
Water and ether free ethanol: a 1 + 1 mixture of these solvents does not dissolve barium
nitrate anhydrous or barium chloride.
Dry test (staining): barium salts, when heated in an incomplete bunsen (bluish) flame, give
the flame a yellowish-green color.
Sr2+
Ammonia solution: no deposits
Dilute sulfuric acid: strontium sulfate white precipitate, solubility of the precipitate cannot
be ignored.
Saturated calcium sulfate solution: strontium sulphate white precipitate, formed slowly in
a cold state, but faster by boiling.
Ammonium oxalate solution: strontium oxalate white precipitate, precipitate only slightly
soluble in water.
Water-free ethanol and ether: a mixture of 1 + 1 of these solvents, does not dissolve
anhydrous strontium nitrate, but dissolves anhydrous strontium chloride.
Dry test (staining): volatile strontium compounds, especially their chlorides, give a
distinctive red-karmin color to the bunsen flame that is not bright.
Ca2+
Ammonia solution: no deposits, because calcium hydroxide dissolves quite a lot.
Dilute sulfuric acid: calcium sulphate white precipitate, CaSO4 is quite significant in water,
which is more soluble than barium or strontium sulfate.
Potassium chromate solution: no precipitate from dilute solutions, nor from concentrated
solutions in the presence of acetic acid.
Potassium hexasianoferate (II) solution: white salt mixture. In the presence of ammonium
chloride, this test will be more sensitive.
Reagents of sodium dihydroxitartrate osazone: yellow salts of calcium salts that are very
little soluble.
Reagents of picrolonic acid: typical rectangular crystals and calcium picrolonic in neutral or
acetic acid solutions. Strontium and barium also give deposits but with different crystalline
shapes
Dry test (staining): volatile calcium compounds, giving a yellowish red color to the bunsen
flame
Group reaction: cations of the fifth group do not react with hydrochloric acid, hydrogen
sulphide, ammonium sulphide or (in the presence of ammonium salts) with ammonium
carbonate.
Mg +
Ammonia larvae: partial precipitation of white magnesium hydroxide such as gelatin
Sodium carbonate solution: a white, large-volume precipitate, that is, basic carbonate,
which is insoluble in an alkaline solution, but is easily soluble in acids and ammonium salts
Quinalizarin reagensia: blue precipitate or blue staining like cornflower with magnesium
salts
Dry test (dry pipe test) All magnesium compounds when ignited on charcoal
in the presence of sodium carbonate are converted into white mag• nesium oxide,
which glows brightly when hot. Upon moistening with a drop or two of cobalt nitrate
solution and reheating strongly, a pale-pink mass is obtained.
K+
Sodium hexanitritocobaltate (III) Na3 [Co (NO2) 6] solution: yellow precipitate potassium
hexanitritocobaltate (III)
Tartaric acid solution (or sodium tartrate hydrogen solution): white crystalline precipitate
potassium hydrogen tartrate
Hexagloroplatinic (IV) (H2 [PtCl6]) acid reagents: yellow potassium hexachloroplatinic (IV)
precipitate
Test for sodium hexanitritocobaltate (III) -silver nitrate: insoluble K2Ag [Co (NO2) 6]
compound
Dry test (staining on) :Potassium compounds, preferably the chloride, colour the
non-luminous Bunsen flame violet (lilac).
Na +
Uranyl magnesium acetate solution: Yellow crystalline precipitate, sodium magnesium
Uranyl acetate NaMg (UO2) 3 (CH3COO) 9.9H2O, from concentrated solutions
Uranyl Zinc Acetate Reagensia: Yellow crystals of sodium zinc Uranyl Acetate, NaZn (UO2) 3
(CH3COO) 9.9H2O
Dry test (staining test) : The colour is not visible when viewed through two
thicknesses of cobalt blue glass.
NH4 +
Sodium hydroxide solution: ammonia gas released when heated, a mixture of mercurium
(II) amidonitrate and a black mercurium precipitate is formed
Saturated sodium hydrogen tartrate solution: white precipitate ammonium tartrate acid
which is similar but slightly more soluble than the associated potassium salt, from which
the precipitate can be distinguished by the release of ammonia gas, when the precipitate is
heated with a solution of sodium hydroxide
Tanal-silver nitric acid test, to produce silver black tanic acid precipitates silver in the
presence of ammonia
Ammonia formation test. Put a drop of test solution or a small amount of solid in the micro
test tube, and add a drop of 2M sodium hydroxide solution. attach a small piece of red
litmus paper to the glass hook, and put the cover in place. The paper turns blue
Dry test All ammonium salts are either volatilized or decomposed when heated
to just below red heat. In some cases, where the acid is volatile, the vapours
recombine on cooling to form a sublimate of the salt, e.g. ammonium chloride.
Equipment
a.Glass objects
d. Bunsen burner
e. Wood clamp
h. Spatel