Data Komposisi Gas Alam Data gas alam masuk package b

BM Fraksi
No. Komponen %mol Jam
(kg/kmol) mol (X)

1 CH4 16.04206 81.46 0.8146 0:00

2 C2H6 30.06844 3.28 0.0328 2:00
3 C3H8 44.09482 3.13 0.0313 4:00
4 i-C4H10 58.1212 0.6 0.006 6:00
5 n-C4H10 58.1212 0.77 0.0077 8:00
6 i-C5H12 72.14758 0.28 0.0028 10:00
7 n-C5H12 72.14758 0.59 0.0059 12:00
8 C6H14 86.17396 0.42 0.0042 14:00
9 CO2 44.0087 6.15 0.0615 16:00
10 N2 28.0134 3.32 0.0332 18:00
11 Ar 39.948 0 0 20:00
12 H2 2.01568 0 0 22:00
13 H2S 34.08068 8.32 0.0832 Total
Total 584.9833 108.32 1.0832 Rata - Rata
Rata-Rata 44.9987154 8.3323076923 0.083323

Data steam keluar package boiler Data Komposisi udara kering

Steam Press Steam flow Suhu steam

Jam (kg/cm2) (ton/jam) boiler outlet (C) Komposisi %volume
0:00 45.2 81.65 404 CO2 0.04
2:00 45.1 80.51 403 N2 78.09
4:00 44.9 81.65 400 Ar 0.93
6:00 45.2 79.38 400 O2 20.95
8:00 45.3 80.51 401 Total 100.01
10:00 44.4 80.51 401
12:00 44.2 80.51 403
14:00 44.6 79.38 403
16:00 44 79.38 403
18:00 44 81.65 402
20:00 44 80.51 402
22:00 44 80.51 402
Total 534.9 966.15 4824
Rata - Rata 44.575 80.5125 402
ata gas alam masuk package boiler Data Boiler feed water

BFW
BFW BFW
Gas flow P gas alam BFW eco eco
Jam Pressure flow
(m3/jam) (kg/cm2) inlet (C) outlet
(kg/cm2) (ton/jam)
(C)
3085.5 3 0:00 53.5 89.59 103 150
3085.5 3 2:00 52.5 90.72 103 150
3085.5 3 4:00 53 87.32 103 151
3085.5 3 6:00 53 86.18 103 151
3085.5 3 8:00 53 86.18 103 151
3085.5 3 10:00 53 87.31 103 151
3085.5 3 12:00 54 89.59 103 151
3085.5 3 14:00 54 88.45 103 151
3085.5 3 16:00 55 87.32 103 150
3085.5 3 18:00 55 87.32 103 151
3085.5 3 20:00 55 87.32 103 151
3085.5 3 22:00 53 87.32 103 151
37026 36 Total 644 1054.62 1236 1809
3085.5 3 Rata - Rata 53.6667 87.8850 103 150.75 Rata - Rata

posisi udara kering Data Komposisi gas buang

(data diambil dari K3, agustus 2019)
BM Komponen %xi Fraksi (X)
(kg/kmol)
44 CO2 2.41 0.0241
28.0134 O2 14.4 0.144
39.948
31.998
143.9594
 Data Flue Gas

T. Econ inlet
T. Econ T. Econ
Jam (from
inlet outlet
dearator)

0:00 103 363 187

2:00 103 364 188
4:00 103 363 187
6:00 103 363 187
8:00 103 363 187
10:00 103 363 187
12:00 103 363 187
14:00 103 363 187
16:00 103 364 187
18:00 103 364 187
20:00 103 364 187
22:00 103 364 187
Total 1236 4361 2245
Rata - Rata 103 363.4167 187.0833
PERHITUNGAN NERACA MASSA

Flue gas

BFW
Package Boiler 2007 UA

Udara
Gas Alam

Asumsi : Reaksi pembakaran berjalan sempurna

Neraca Massa Masuk

Mencari berat molekul rata - rata gas alam

No. Komponen BM (kg/kmol) %mol Fraksi mol (X)

1 CH4 16.0421 81.46 0.8146
2 C2H6 30.0684 3.28 0.0328
3 C3H8 44.0948 3.13 0.0313
4 i-C4H10 58.1212 0.6 0.006
5 n-C4H10 58.1212 0.77 0.0077
6 i-C5H12 72.1476 0.28 0.0028
7 n-C5H12 72.1476 0.59 0.0059
8 C6H14 86.1740 0.42 0.0042
9 CO2 44.0087 6.15 0.0615
10 N2 28.0134 3.32 0.0332
11 Ar 39.9480 0 0
12 H2 2.0157 0 0
13 H2S 34.0807 8.32 0.0832
Total 584.9833 108.32 1.0832

Konsumsi gas alam masuk boiler

Konsumsi gas alam : (%mol x mol gas alam masuk)

Mol gas alam

No. Komponen %mol Fraksi mol (X)
(kmol/jam)
1 CH4 81.46 0.8146 137.7455
2 C2H6 3.28 0.0328 137.7455
 3 C3H8 3.13 0.0313 137.7455
4 i-C4H10 0.6 0.006 137.7455
5 n-C4H10 0.77 0.0077 137.7455
6 i-C5H12 0.28 0.0028 137.7455
7 n-C5H12 0.59 0.0059 137.7455
8 C6H14 0.42 0.0042 137.7455
9 CO2 6.15 0.0615 137.7455
10 N2 3.32 0.0332 137.7455
11 Ar 0 0 137.7455
12 H2 0 0 137.7455
Total 100 1652.9464

Kebutuhan O2 secara teoritis untuk pembakaran se

Basis 1 kmol Natural Gas yang dibakar Reaksi ke-

Reaksi 1 CH4 + O2 -> CO2 + 2H2O 1

Reaksi 2 C2H6 + 3,5O2 -> 2CO2 + 3H2O 2
Reaksi 3 C3H8 + 5O2 -> 3CO2 + 4H2O 3
Reaksi 4 i-C4H10 + 6,5O2 -> 4CO2 + 5H2O 4
Reaksi 5 n-C4H10 + 6,5O2 -> 4CO2 + 5H2O 5
Reaksi 6 i-C5H12 + 8O2 -> 5CO2 + 6H2O 6
Reaksi 7 n-C5H12 + 8O2 -> 5CO2 + 6H2O 7
Reaksi 8 C6H14 + 9,5O2 -> 6CO2 + 7H2O 8
Total

Total kmol O2 289.1348 kmol/jam

Kg O2 9251.73427 kg/jam
Kmol udara 1380.11822 kmol/jam
Kg udara 39825.0573 kg/jam
Kmol N2 1077.73432 kmol/jam
Kg N2 30191.0025 kg/jam

basis : 1 kmol NG yang dibakar

O2 CO2 H2O
Komponen %Kmol
koefx%mol koefx%mol koefx%mol
CH4 0.8146 1.6292 0.8146 1.6292
C2H6 0.0328 0.1148 0.0656 0.0984
C3H8 0.0313 0.1565 0.0939 0.1252
i-C4H10 0.006 0.039 0.024 0.03
n-C4H10 0.0077 0.05005 0.0308 0.0385
i-C5H12 0.0028 0.0224 0.014 0.0168
 n-C5H12 0.0059 0.0472 0.0295 0.0354
C6H14 0.0042 0.0399 0.0252 0.0294
Total 2.09905 1.0976 2.0029

CO2 yang dihasilkan

CO2 1.0976 kmol CO2 inert 0.0615
massa CO2 48.3039 kg m.CO2 inert 2.7065

total CO2 akhir 51.0105 kg

1.1591 kmol

Total mol flue gas dry basis (kmol)

100%/%CO2 flue gas x total CO2 akhir
48.0954 kmol
2116.6176 kg

O2 pada flue gas 6.9257 kmol

O2 yang dibutuhkan utk rx pembakaran
2.0991 kmol
67.1654 kg

O2 Excess
%O2 excess x kebutuhan O2
0.0479 kmol

Total O2 di udara masuk

O2 pd flue gas + O2 rx pembakaran+O2 excess
9.0727 kmol
290.3089 kg
O2 dalam flue gas
O2 udara inlet - O2 reaksi
223.1435 kg

C
N2 masuk (dlm udara)
%N2 dlm udara/100% x total mol flue dry basis
37.5577 kmol
1052.1196 kg
N2 masuk (dlm NG)
128.1095 kg

H2O yang dihasilkan dari reaksi

2.0029 kmol
36.0828 kg

Komposisi flue gas Hasil (kmol)

 CO2 1.1591
CO 0
O2 6.9257
N2 37.5577
H2O 2.0029

SCALE UP :

Gas Alam Flue Gas

CO2
Burner

Udara Fluegas
Komposisi Massa (kg) Komposisi Massa (kg)
O2 290.3089 N2 1052.1196
N2 1052.1196 H2 O 36.0828
CO2 51.0105
O2 223.1435
CO -
Total 1342.4285 1362.3564

Neraca massa
Input = Output
Gas alam + udara = flue gas
Gas alam
flue gas - udara
19.9279 kg/jam
faktorisasi scale up
kg inlet (aktual) NG / kg gas alam basis (dari bu ajeng)
144.1656

Total CO2 output scale up

7353.9568 kg/jam

O2 input scale up
41852.5562 kg/jam

O2 Output scale up
32169.6161 kg/jam

N2 Scale up
151679.4477 kg/jam
Total N2 inlet
N2 scale up + N2 di dlm NG
151807.5572 kg/jam

H2O flue gas output scale up

5201.9047 kg/jam 288.7492709927 kmol/jam

Blowdown H2O
Total input - (steam MS + Total Flue gas)
Total input ### kg/jam
Steam MS 80512.5 kg/jam
Total flue gas ### kg/jam
blowdown H2O 7244.3905 kg/jam
Total H2O Output
H2O flue gas output scale up + Steam MS + Blowdown
92958.7952 kg/jam

Komposisi Neraca Massa

Neraca Massa
No. Komponen
Input (kg/jam) Output (kg/jam)
1 CH4 1800.0397 0
2 C2H6 135.8508 0
3 C3H8 190.1120 0
4 i-C4H10 48.0356 0
5 n-C4H10 61.6457 0
6 i-C5H12 27.8264 0
7 n-C5H12 58.6342 0
8 C6H14 49.8543 0 Input (kmol/jam)
9 CO2 372.8131 7353.9568 8.4714
10 N2 151807.5572 151807.5572 5419.1050
11 O2 41852.5562 32169.6161 1307.9741
12 H2O 87885.0000 92958.7952 4878.3534
Total 284289.9253 284289.9253
UA Steam

Bm x n
13.0679 berat molekul rata - rata gas alam :
0.9862 (£𝐵𝑀 𝑥 𝑛)/£𝑛 21.8725 kg/kmol
1.3802
0.3487
0.4475 NM air package boiler
0.2020 BFW masuk 87.8850 ton/jam
0.4257 87885 kg/jam
0.3619 middle steam keluar 80.5125 ton/jam
2.7065 80512.5 kg/jam
0.9300
0.0000 Konsumsi gas alam masuk boiler :
0.0000 3085.5000 m3/jam
2.8355 Mol gas alam : O2 Excess :
23.6922 3085500.0000 L/jam 2.2833 %
137745.5357 mol/jam 0.022833
137.7455 kmol/jam

Konsumsi gas alam Massa gas alam

BM (kg/kmol)
(kmol/jam) masuk (kg/jam)
16.0421 112.2075 1800.0397
30.0684 4.5181 135.8508
 44.0948 4.3114 190.1120
58.1212 0.8265 48.0356
58.1212 1.0606 61.6457
72.1476 0.3857 27.8264
72.1476 0.8127 58.6342
86.1740 0.5785 49.8543
44.0087 8.4714 372.8131
28.0134 4.5732 128.1095
39.9480 0.0000 0.0000
2.0157 0.0000 0.0000
550.9026 137.7455 2872.9214

han O2 secara teoritis untuk pembakaran sempurna : CO2 yang dihasilkan dari pembakaran

Konsumsi gas alam Kebutuhan O2

Koefisien O2 Reaksi ke-
(kmol/jam) (kmol/jam)
2 112.2075 224.4150 1
3.5 4.5181 15.8132 2
5 4.3114 21.5572 3
6.5 0.8265 5.3721 4
6.5 1.0606 6.8942 5
8 0.3857 3.0855 6
8 0.8127 6.5016 7
9.5 0.5785 5.4960 8
Total 124.7010 289.1348 Total
kmol
kg
Output (kmol/jam)
167.1023
5419.1050
1005.3633
5159.9915
 Data Komposisi udara kering

BM BM x n
Komposisi %volume Fraksi (X) (kg/kmol) (Kg/kmol)

N2 78.09 0.7809 28.0134 21.8757

O2 20.95 0.2095 31.998 6.7036
 Total 99.04 0.9904 60.0114 28.5792

BM Rata-Rata Udara
28.8563 kg/kmol

CO2 yang dihasilkan dari pembakaran sempurna H2O yang dihasilkan dari pembakar

Konsumsi gas alam Kebutuhan CO2

Koefisien CO2 Reaksi ke-
(kmol/jam) (kmol/jam)
1 112.2075 112.2075 1
2 4.5181 9.0361 2
3 4.3114 12.9343 3
4 0.8265 3.3059 4
4 1.0606 4.2426 5
5 0.3857 1.9284 6
5 0.8127 4.0635 7
6 0.5785 3.4712 8
124.7010 151.1895 Total
 Data Komposisi gas buang (flue gas)
(data diambil dari K3, agustus 2019)

Komponen %xi Fraksi (X)

CO2 2.41 0.0241

O2 14.4 0.144
2O yang dihasilkan dari pembakaran sempurna

Konsumsi gas Kebutuhan H2O

Koefisien H2O
alam (kmol/jam) (kmol/jam)
2 112.2075 224.4150
3 4.5181 13.5542
4 4.3114 17.2457
5 0.8265 4.1324
5 1.0606 5.3032
6 0.3857 2.3141
6 0.8127 4.8762
7 0.5785 4.0497
Total 124.7010 275.8905
PERHITUNGAN NERACA PANAS

Fraksi mol Massa gas alam BM

No. Komponen %mol
(X) masuk (kg/jam) (kg/kmol)
1 CH4 81.46 0.8146 1800.0397 16.0421
2 C2H6 3.28 0.0328 135.8508 30.0684
3 C3H8 3.13 0.0313 190.1120 44.0948
4 i-C4H10 0.6 0.006 48.0356 58.1212
5 n-C4H10 0.77 0.0077 61.6457 58.1212
6 i-C5H12 0.28 0.0028 27.8264 72.1476
7 n-C5H12 0.59 0.0059 58.6342 72.1476
8 C6H14 0.42 0.0042 49.8543 86.1740
9 CO2 6.15 0.0615 372.8131 44.0087
10 N2 3.32 0.0332 128.1095 28.0134
11 Ar 0 0 0.0000 39.9480
12 H2 0 0 0.0000 2.0157
Total 100 2872.9214 550.9026

Q1 (Qgas inlet natural gas)

T gas inlet 29 C 302 K R
T ref 25 C 298 K tau

heat capacity komponen natural gas (Smith,Van Ness, 635)

Kj/kmol.K
Komponen A B C D
CH4 1.702 0.009081 -2.164E-06 0
C2H6 1.131 0.0019255 -5.56E-06 0
C3H8 1.213 0.0028785 -8.82E-06 0
i-C4H10 1.677 0.0037853 -1.19E-05 0
n-C4H10 1.935 0.0036195 -1.14E-05 0
i-C5H12 2.35 0.0046821 -1.48E-05 0
n-C5H12 2.464 0.0045351 -1.41E-05 0
C6H14 3.025 0.0033722 -1.68E-05 0
CO2 5.457 0.001045 0 -1.16E+05

Q2 Flue Gas
T gas inlet 103.0000 C 376 K R
T ref 25 C 298 K tau

Komponen A B C D
CO2 5.457 0.001045 0 -1.16E+05
O2 3.639 5.06E-04 0 -2.27E+04
N2 3.28 5.93E-04 0 4.00E+03
 H2O 3.47 1.45E-03 0 1.21E+04

Q3 udara inlet
T gas inlet 30 C 303 K R
T ref 25 C 298 K tau

Komponen A B C D
O2 3.639 5.06E-04 0 -2.27E+04
N2 3.28 5.93E-04 0 4.00E+03

Q4 (Q pembakaran natural gas)

Komponen Fraksi (x) HHV kj/NM3 HHV kj/mol HHV Total

CH4 0.8146 39840 892.97376 727.4164
C2H6 0.0328 102790 2303.9351 75.5691
C3H8 0.0313 159220 3568.7571 111.7021
i-C4H10 0.006 178660 4004.4852 24.0269
n-C4H10 0.0077 173160.7143 3881.2243 29.8854
i-C5H12 0.0028 198070 4439.541 12.4307
n-C5H12 0.0059 202373.5166 4536 26.7624
C6H14 0.0042 287530 6444.6974 27.0677
CO2 0.0615 0 0 0
TOTAL 1034.86077355
Q4 HHV Total 142547451.6423

Q5 BFW in
T BFW in 103 C 217.4 F
P BFW in 53.6667 kg/cm2 763.3015 psi
m.BFW in 87885 kg/jam
Dari steam tabel (saturated steam) di dapat H (Qern, 817)
T H (kJ/kg)
212 180.07
217.4 185.5105
220 188.13

Q5 16303590.293 kj/jam

Q6 (Q steam MS Out)
T steam 402 C 755.6 F
P steam 44.575 kg/cm2 633.9902 psi
m. Alir steam 80512.5 kg/jam
Dari steam tabel (superheated steam) di dapat H (Qern, 819)
Data 1
T 700 P 600 H 1351.1
 T 700 P 633.990225 H 1348.9606
T 700 P 700 H 1345

Data 2
T 800 P 600 H 1407.7
T 800 P 633.990225 H 1406.1704
T 800 P 700 H 1403.2

Data 3
T 700 P 633.990225 H 1348.9606
T 755.6 P 633.990225 H 1380.7692
T 800 P 633.990225 H 1406.1704

Q6 111169180.22 kj/jam

Neraca Panas Q input = Q Output

Komponen Input (kj/jam) Output (kj/jam) Q gas inlet + Q udara inlet +
Q1 (Qgas inlet natural gas) 17687.026558
Q2 Flue Gas 15986140.90384 Q loss
Q3 udara inlet 981533.72025 Qinput
Q4 (Q pembakaran natural gas) 142547451.64 %heat loss
Q5 BFW in 16303590.293
Q6 (Q steam MS Out) 111169180.215
Qloss 32694941.56278
TOTAL 159850262.68 159850262.6816 kj/jam

Efisiensi Package Boiler

79.5465 %

efisiensi desain package boiler 2007 UA

85%

efisiensi aktual package boiler 2007 UA perbulan desember

60%an
 Komposisi Neraca Massa

Mol gas alam masuk

(kmol/jam) No. Komponen Neraca Massa
112.2075 Input (kg/jam) Output (kg/jam)
4.5181 1 CH4 1800.0397 0
4.3114 2 C2H6 135.8508 0
0.8265 3 C3H8 190.1120 0
1.0606 4 i-C4H10 48.0356 0
0.3857 5 n-C4H10 61.6457 0
0.8127 6 i-C5H12 27.8264 0
0.5785 7 n-C5H12 58.6342 0
8.4714 8 C6H14 49.8543 0
4.5732 9 CO2 372.8131 7353.9568
0.0000 10 N2 151807.5572 151807.5572
0.0000 11 O2 41852.5562 32169.6161
137.7455 12 H2O 87885.0000 92958.7952
Total 284289.9253 284289.9253

8.3145 kj/kmol.K
1.0134

Q1
Komponen Q (kj/jam)
CH4 15791.239542815
C2H6 181.5387299094
C3H8 183.8798484862
i-C4H10 47.7590569043
n-C4H10 70.3610209328
i-C5H12 31.0383511282
n-C5H12 69.045468655
C6H14 48.5916129986
CO2 1263.5729261675
Total 17687.026557997

8.3145 kj/kmol.K
1.2617

Q2
Komponen Q (kj/jam)
CO2 517642.0979633
O2 2351752.0362816
 N2 12355216.265334
H2O 761530.50426029
Total 15986140.903839

8.3145 kj/kmol.K
1.0168

Q3
Komponen Q (kj/jam)
O2 192471.24946558
N2 789062.47078378
Total 981533.72024936

T P (Psi) H (kJ/kg)
kj/kg 700 633.9902 1348.9606
 kj/kg 755.6 633.9902 1380.7692
kj/kg 800 633.9902 1406.1704

kj/kg
kj/kg
kj/kg

kj/kg
kj/kg
kj/kg

put = Q Output
as inlet + Q udara inlet + Q pembakaran NG + Q BFW in = Qsteam + gas outt + Q loss

32694941.5627845 kj/jam
159850262.681624 kj/jam
20.4535 kj/jam
Input (kmol/jam) Output (kmol/jam)
8.4714 167.1023
5419.1050 5419.1050
1307.9741 1005.3633
4878.3534 5159.9915