Nama : Anisa Nurjanah

NIM : 1702528

Chapter 2
2.33 The nitride ion, N32, can be a monodentate or a bridging ligand. Name the following
compound:

Jawab: Ammonium tetrabromo-tantalum(IV)- -nitrogentetrabromo-tantalum(IV)

2.34 Write formulas for the following compounds:

(a) Pentaammine(dinitrogen)ruthenium(II) chloride
Jawab: [Ru(NH3)1(N2)]Cl2
(b) Aquabis(ethylenediamine)thiocyanatocobalt(III) nitrate
Jawab: [Co(H2O)(en)2(SCN)](NO3)2
(c) Sodium hexaisocyanochromate(III)
Jawab: Na4[Cr(CN)6]

2.35 Write formulas for the following compounds:

(a) Bis(methylamine)silver(I) acetate
Jawab: [Ag(NH2CH3)2]CH3COO
(b) Barium dibromodioxalatocobaltate(III)
Jawab: Ba[Co(ox)2Br2]
(c) Carbonyltris(triphenylphosphine)nickel(0)
Jawab: [Ni{P(C6H5)3}3(CO)]

2.36 Write formulas for the following compounds:

(a) Tetrakis(pyridine)bis(triphenylarsine)cobalt(III) chloride
Jawab: [Co(C5H5N)4(As(C6H5)3)2]Cl3
(b) Ammonium dicarbonylnitrosylcobaltate(2I).
Jawab: NH4[Co(CO)2NO]
(c) Potassium octacyanomolybdenate(V)
Jawab: K4{Mo(CN)8}
(d ) Diamminedichloroplatinum(II) (Peyrone’s salt)
Jawab: [Pt(NH3)2(Cl)2]

2.37 Write formulas for the following compounds:

(a) Hexaamminecobalt(III) pentachlorocuprate(II)
Jawab: [Co(NH3)6][Cl5Cu]
(b) Tetrakis(pyridine)platinum(II) tetrachloroplatinate(II)
Jawab: [Pt(C5H6N)4](PtCl4)
(c) Diamminebis(triphenylphosphine)palladium(II) bis(oxalato)aurate(III)
Jawab: [Pd(NH3)2(pph3)2][Au(ox)2]

2.38 Write formulas for the following compounds:

(a) (Ethylenediamine)iodonitritochromium(III)-m-dihydroxotriamminechloro-cobalt(III) sulfate
Jawab:

(b) Bis(ethylenediamine)cobalt(III)-m-isocyano-m-
thiocyanatobis(acetylacetonato)chromium(III) nitrate
Jawab: [Co(en)2-mu-(N=-C,SCN)Cr(acac)2](NO3)

2.39 Write formulas for the following compounds:

(a) Pentamminechromium(III)-m-hydroxopentamminechromium(III) chloride
Jawab:
(b) Diammine(ethylenediamine)chromium(III)-m-bis(dioxygen)tetraamminecobalt(III) bromide.
Jawab:

2.40 Write the formulas for the following two compounds:

(a) Dichlorobis(pyridine)tungsten(III)-m-dichlorodichlorobis(pyridine)tungsten(III)
Jawab:

(b) Ammonium dichloroiodotungsten(III)-m-bromo-m-chloro-m-iododichloroiodotungstate(III)

Jawab:
Chapter 3

3.1 Two compound have the formula C2H6O. One, known as common grain alcohol
or ethanol, is composed of the ethyl (C2H5-) radical bound to hydroxyl (-OH)
group, whereas the second, dimethyl ether, an extremely volatile organic solvent
not suitable for human ingestion, has two (CH3-) groups bound to a central
oxygen atom. Classify these compounds. Are they (a) isomers, (b) structural
isomers, and/or (c) stereoisomers ? more than one of these terms may apply.

Jawab :
 C2H5OH
 CH3-O-CH3

Kedua senyawa tersebut adalah isomer, yang termasuk isomer struktur.

Karena memiliki struktur yang sama sedangkan rumus molekulnya
berbeda, dan bukan stereoisomer.

3.15 Draw structural for the following compound :

(a) Cis-carboylchlorobis(tryphenylphospine)iridium(I)
(b) Trans-chlloronitrotetraamminechromium(III) nitrate
(c) Trans-diammine-trans-dinitrobis(pyridine)cobalt(III) nitrate

Jawab :
(a)
IrCOCl(pph3)2

Co Cl

Ir

PPh3 PPh3

(b)
 [Cr(NH3)4(NO2)Cl](NO3)

Cl
NH3
H3N
NO3
Cr
H3N NH3
Cl

(c)
[Co(Py)2(NO2)2(NH3)2]NO3

Py
NH3
O2N
NO3
Co
H3N NO2
Py

3.16 How many additional internal mirrors places are there in the first four parts of
figure 3.7? draw diagrams that illustrate these additional places.

3.17 Draw structural formlas for the following compounds :

(a) Potassium trans-dichlorobis(oxalate)cobaltate(III)
(b) (acetylacetonato)-cis-dichloro-trans-bis(triphenylarsine)rhenium(III

Jawab :
(a)
k3[CoCl2(ox)2]

Cl C2O4

Co K3
C2O4 Cl

(b)

Acac Asph3

Ru
Asph3
Cl2