Standard Reduction Potentials at

298K
Half-Reaction Eºred, V
–
Li + e  Li(s)
+
-3.05
K+ + e–  K(s) -2.925
Cs+ + e–  Cs(s) -2.92
Ba2+ + 2 e–  Ba(s) -2.90
Sr2+ + 2 e–  Sr(s) -2.89
Ca2+ + 2 e–  Ca(s) -2.87
Na+ + e–  Na(s) -2.7144
La3+ + 3 e–  La(s) -2.52
Ce3+ + 3 e-  Ce(s) -2.48
Mg2+ + 2 e–  Mg(s) -2.3568
Al3+ + 3 e–  Al(s) -1.676
Ti2+ + 2 e–  Ti(s) -1.63
Zr4+ + 4 e–  Zr(s) -1.53
Mn2+ + 2 e–  Mn(s) -1.18
N2(g) + 4 H2O(l) + 4 e–  4 OH– + N2H4(aq) -1.16
2 H2O(l) + 2 e–  H2(g) + 2 OH– -0.83
Cd(OH)2 + 2 e–  Cd(s) + 2 OH– -0.82
Zn2+ + 2 e–  Zn(s) -0.7621
Cr3+ + 3 e–  Cr(s) -0.74
Co(OH)2 + 2 e–  Co(s) + 2 OH– -0.73
Ni(OH)2 + 2 e–  Ni(s) + 2 OH– -0.72
U4+ + e–  U3+ -0.61
PbO(s) + H2O(l) + 2 e–  Pb(s) + 2 OH– -0.58
Fe(OH)3 + e–  Fe(OH)2 + OH– -0.56
HPbO2– + H2O(l) + 2 e–  Pb(s) + 3 OH– -0.54
2CO2(g) + 2H+ + 2 e–  H2C2O4(aq) -0.49
S(s) + H2O(l) + 2 e–  HS– + OH– -0.48
Bi2O3 + 3 H2O(l) + 6 e–  2Bi(s) + 6 OH– -0.46
Fe2+ + 2 e–  Fe(s) -0.440
Cr3+ + e–  Cr2+ -0.41
Cd2+ + 2 e–  Cd(s) -0.4022
PbSO4(s) + H+ + 2 e–  Pb(s) + HSO4– -0.356
Tl+ + e–  Tl(s) -0.3358
Ag(CN)2– + e–  Ag(s) + 2 CN– -0.31
Ni2+ + 2 e–  Ni(s) -0.28
Co2+ + 2 e–  Co(s) -0.277
V3+ + e–  V2+ -0.26
N2(g) + 5 H+ + 4 e–  N2H5+(aq) -0.23
 Standard Reduction Potentials at
298K
Cu(OH)2(s) + 2 e–  Cu(s) + 2 OH– -0.22
Mo3+ + 3 e–  Mo(s) -0.20
CuI(s) + e–  Cu(s) + I– -0.185
AgI(s) + e–  Ag(s) + I– -0.151

Sn2+ + 2e---> Sn(white) -0.136

CrO42– + 4 H2O(l) + 3 e–  Cr(OH)3(s) + 5 OH– -0.13
Pb2+ + 2 e–  Pb(s) -0.1266
2 Cu(OH)2(s) + 2 e–  Cu2O(s) + 2 OH– + H2O(l) -0.09
O2(g) + H2O(l) + 2 e–  HO2– + OH– -0.08
2 H+ + 2 e–  H2 (SHE) 0.0000
Ag(S2O3)23– + e–  Ag(s) + 2 S2O32– +0.01
NO3– + H2O(l) + 2 e–  NO2– + 2 OH– +0.01
S4O62– + 2 e–  2 S2O32– +0.0238
CuCO3(s) + 2 e–  Cu(s) + CO32– +0.0541
AgBr(s) + e–  Ag(s) + Br– +0.095
TiO2+ + 2 H+ + e–  Ti3+ + H2O(l) +0.10
CuCl(s) + e–  Cu(s) + Cl– +0.14
S(s) + 2 H+ + 2 e–  H2S(g) +0.141
Cu2+ + e–  Cu+ +0.153
Sn4+ + 2 e–  Sn2+ +0.1539
SO42– + 4 H+ + 2 e–  H2O(l) + H2SO3(aq) +0.1576
HSO4– + 3 H+ + 2 e–  H2O(l) + H2SO3(aq) +0.17
S(s) + 2 H+ + 2 e–  H2S(aq) +0.1739
SbO+ + 2 H+ + 3 e–  Sb(s) + H2O(l) +0.21
AgCl(s) + e–  Ag(s) + Cl– +0.2221
Saturated Calomel (SCE) +0.2412
IO3– + 3 H2O(l) + 6 v  I– + 6 OH– +0.26
Hg2Cl2 + 2 e–  2 Cl– + 2 Hg +0.2680
Bi3+ + 3 e–  Bi(s) +0.286
BiO+ + 2 H+ + 3 e–  Bi(s) + H2O(l) +0.32
UO22+ + 4 H+ + 2 e–  U4+ + 2 H2O(l) +0.33
Cu2+ + 2 e–  Cu(s) +0.3394
Ag2O(s) + H2O(l) + 2 e–  2 Ag(s) + 2 OH– +0.34
Fe(CN)63– + e–  Fe(CN)64– +0.3557
 Standard Reduction Potentials at
298K
VO2+ + 2 H+ + e–  V3+ + H2O(l) +0.36
ClO4– + H2O(l) + 2 e–  ClO3– + 2 OH– +0.36
O2(g) + 2 H2O(l) + 4 e–  4 OH– +0.40
Ag2CrO4(s) + 2 e–  2 Ag(s) + CrO42– +0.446
H2SO3 + 4 H+ + 4 e–  S(s) + 3 H2O(l) +0.45
IO– + H2O(l) + 2 e–  I– + 2 OH– +0.49
Cu+ + e–  Cu(s) +0.5180
I2(s) + 2 e–  2 I– +0.5345
I3– + 2 e–  3 I– +0.5354
H3AsO4(aq) + 2 H+ + 2 e–  H3AsO3(aq) + H2O(l) +0.559
MnO4– + 2 H2O(l) + 3 e–  MnO2(s) + 4 OH– +0.59
2 HgCl2 + 4 H+ + 2 e–  Hg2Cl2 + 2 Cl– +0.6011
BrO3– + 3 H2O(l) + 6 e–  Br– + 6 OH– +0.61
Hg2SO4 + 2 e–  2 Hg(l) + SO42– +0.6152
I2(aq) + 2 e–  2I– +0.6195

ClO3-+ 3H2O(l) + 6e---> Cl-+ 6OH +0.62

O2 + 2 H+ + 2 e–  H2O2(l) +0.6237
O2 + 2 H+ + 2 e–  H2O2(aq) +0.6945
PtCl42– + 2 e–  Pt(s) + 4 Cl– +0.73
ClO2– + 2 H2O(l) + 4 e–  Cl– + 4 OH– +0.76
BrO– + 3 H2O(l) + 2 e–  Br– + 2 OH– +0.76
Fe3+ + e–  Fe2+ +0.769
NO3– + 2 H+ + e–  NO2(g) + H2O(l) +0.78
Hg22+ + 2 e–  Hg(l) +0.789
Ag+ + e–  Ag(s) +0.7991
Hg2+ + 2 e–  Hg(l) +0.8519
HO2– + H2O(l) + 2 e–  3 OH– +0.88
ClO– + H2O(l) + 2 e–  Cl– + OH– +0.89
2 Hg2+ + 2 e–  Hg22+ +0.920
NO3– + 3 H+ + 2 e–  HNO2(aq) + H2O(l) +0.9275
NO3– + 4 H+ + 3 e–  NO(g) + 2 H2O(l) +0.96
VO2+ + 2 H+ + e–  VO2+ + H2O(l) +1.0004
HNO2(aq) + H+ + e–  NO(g) + H2O(l) +1.0362
Br2(l) + 2 e–  2 Br– +1.065
Br2(aq) + 2 e–  2 Br– +1.0978
 Standard Reduction Potentials at
298K
2 IO3– + 12 H+ + 10 e–  6 H2O(l) + I2(s) +1.2093
O2 + 4 H+ + 4 e–  2 H2O(l) +1.2288
MnO2 + 4 H+ + 2 e–  Mn2+ + 2 H2O(l) +1.23
Cr2O72– + 14 H+ + 6 e–  2 Cr3+ + 7 H2O(l) +1.33
Cl2(g) + 2 e–  2Cl– +1.3601
PbO2(s) + 4 H+ + 2 e–   Pb2+ + 2 H2O(l) +1.46
2 ClO3– + 12 H+ + 10 e–  Cl2 + 6 H2O(l) +1.47
MnO4– + 8 H+ + 5 e–  4 H2O + Mn2+ +1.5119
2 BrO3– + 12 H+ + 10 e–  6 H2O(l) + Br2(l) +1.5131
Ce4+ + e–  Ce3+ +1.61
2 HClO + 2 H+ + 2 e–  Cl2(g) + H2O(l) +1.63
H5IO6 + H+ + 2 e IO3– + 3 H2O(l) +1.64
PbO2(s) + HSO4– + 3 H+ + 2 e–  PbSO4(s) + 2 H2O(l) +1.685
MnO4– + 4 H+ + 3 e–  MnO2(s) + 2 H2O(l) +1.70
H2O2 + 2 H+ + 2 e–  2 H2O(l) +1.776
Co3+ + e–  Co2+ +1.842
S2O82– + 2 e- 2 SO42– +2.01
O3(g) + 2 H+ + 2 e–  O2(g) + H2O(l) +2.07
F2(g) + 2 e–  2 F– +2.87
F2(g) + 2 H+ + 2 e–  2 HF(aq) +3.06