TABLA N° 04: CÁLCULO DE LOS PESOS Y DEL NÚMERO DE MOLES DE SUSTANCIAS INICIALES:

R 5 mL de HCl 3N CH3COOH C2H5OH CH3COOC2H5 H2O

E
A. W (g) n HCl puro n H2O W (g) n W (g) n W (g) n W (g) n N total
moles moles moles moles moles
1 0.01515 0,25736 3.7499 0.0426125
5.1854
2 0.01515 0.25722 3.5741 0.0406147 0.9629 0.05349 0.31071
5.1829
3 0.01515 0.26046 2.7219 0.0317261 1.9317 0.10732 0.36778
5.3313
4 0.01515 0.26037 1.5862 0.018025 3.0001 0.16667 0.42705
5.2397
5 0.01515 0.26461 0.9719 0.0110443 3.5457 0.19698 0.46159
5.3159
6 0.01515 0,26002 4.2077 0.07011283 0.7751 0.01685
5.2334
7 0.01515 0.28329 3.1699 0.05283107 1.6044 0.0347922
5.6523
8 5.1719 0.01289 0.2611 2.11508 0.0352 2.3436 0.05094 ---------- ----------
9 5.233 0.01289 0.2646 1.3173 0.0189 2.3529 0.05115 ---------- ----------
10 5.21 0.01289 0.2633 ---------- ---------- 3.5086 0.0763 0.8513 0.009673
11 5.1972 0.01289 0.2626 ----------- ---------- 2.2028 0.0479 1.8362 0.0209
12 5.2826 0.01289 0.2673 --------- ---------- 2,7132 0.0589 1.5303 0.0174
13 5,1981 0.01289 0.2626 --------- ---------- 0.8064 0.01753 3.46424 0.0393
14 5.3649 0.01289 0.2569 4.2001 0.0700 ---------- ---------- 0.887 0.009967
15 5.1454 0.01289 0.2719 3.1011 0.0516 ---------- ---------- 1.8021 0.01432
16 4.99 0.01289 0.2511 2.0232 0.0337 ---------- ---------- 2.392 0.0272
17 5.303 0.01289 0.2685 1.0534 0.0176 ---------- ---------- 3.5448 0.0403
18 5.1998 0.01289 0.26274 --------- --------- 1.1062 0.02404 1.7564 0.01996 0.974 0.05411 0.31685
19 5.136 0.01289 0.25919 0.7695 0.01282 0.97 0.02109 2.6046 0.02960
20 1.0831
5.3123 0.01289 0.26899 ---------- ---------- 0.6977 0.01516 1.7641 0.02004 1.0261 0.05700
TABLA N° 05: RESULTADOS DE LA TITULACIÓN DE UNA ALICUOTA DE MUESTRA CON NaOH ESTANDARIZADO , DETERMINACIÓN DEL
NÚMERO DE MOLES DE ÁCIDO ACÉTICO EN EL EQUILIBRIO Y DETERMINACIÓN DE LA CONSTANTE DE EQUILIBRIO EN FUNCIÓN DE LAS
CONCENTRACIONES;
R Masa Masa Titulación con NaOH estanderizado Nº meq Nº meq Nº meq de Mol/L, en el equilibrio
total de de 2mL Vol. Gasto FACTOR Gasto de de CH3COOH
muestra de B parcial A/B TOTAL NaOH HCl [HAc]𝑒𝑞 [EtOH]𝑒𝑞 [𝐴𝑐𝐸𝑡]𝑒𝑞 [H2O]𝑒𝑞 Kc
A (g) muestra (mL) (mL) (mL)
B (g)
1 9.5867 1.9499 2 19.8 4.92 97.41 43.8345 15.15 28.6845 0.028685 0.028685 0.013928 3.87091 3.8709
2 9.7154 2.0783 2 19.1 4.633 89.636 40.3362 15.15 25.1871 0.025187 0.025187 0.015428 6.94362 6.9436
3 9.8954 1.9827 2 17.4 4.9909 86.8917 39.1013 15.15 23.95 0.02395 0.02395 0.00778 4.6635 4.664
4 7.9197 2.0004 2 13.4 3.9590 53.0506 23.8728 15.15 8.723 0.00872 0.00872 0.009302 51.1395 51.139
5 10.2146 2 10.7 4.7996 51.3537 23.1092 15.15 7.96 0.00796 0.00796 0.003084 22.0796 22.079
6 10.2146 2.3002 2 35.9 4.4407 154.4227 69.4902 15.15 56.59 0.05659 0.030373 0.013523 53.446 53.446
7 9.4264 1.4981 2 23.6 5.2176 123.13 55.4085 15.15 40.259 0.040259 0.02222 0.012572 4.158 4,1581
8 9.462 1.963 2 15.4 4.8202 74.2307 33.4780 12.8705 20.5875 0.0206 0.0445 0.0146 0.2605 4.1690
9 8.4168 2.3293 2 13.2 3.6134 47.35 21.35 12.8705 8.4795 0.0104 0.0426705 0.0084795 0.2731 5.2183
10 9.5425 1.9152 2 8.1 4.9825 40.3583 18.2015 12.8705 5.331 0.005331 0.081631 0.004329 0.2589 2.5757
11 8.974 1.8336 2 14.8 4.894 72.4312 32.6665 12.8705 19.796 0.0198 0.0678 0.0011 0.2428 1.19866
12 7.5792 1.5632 2 13.7 4.8485 66.4245 29.9574 12.8705 17.0869 0.0171 0.0759 0.0003 0.2502 0.05783
13 9.4618 2.1642 2 15.8 4.3724 69.0939 31.1594 12.8705 18.2889 0.0183 0.03583 0.021 0.2443 7.8242
14 10.4321 2.111 2 38.8 4.9418 191.741 86.4752 12.8705 73.6046 0.073605 0.003605 0.00636 0.268295 6.3407
15 9.7109 2.0461 2 33.1 4.7405 156.9105 70.7666 12.8705 57.8961 0.05789 0.0062961 0.0142 0.2534 9.8724
16 9.3651 2.0043 2 28.5 4.6725 133.1662 60.0579 12.8705 47.1874 0.0472 0.0135 0.0137 0.2376 5.1085
17 9.8065 2.0312 2 27.8 4.8279 134.2156 60.5312 12.8705 47.6607 0.04766 0.0301 0.01023 0.2384 1.7004
18 8.9694 1.9705 2 12.5 4.5518 56.8975 25.6607 12.8705 12.7903 0.01279 0.03688 0.00713 0.30406 4.98122
19 9.4763 2.0990 2 21.1 4.5147 95.2602 42.9624 12.8705 30.092 0.03836 0.030092 0.012328 0.24918 2.5836
20 8.5756 2.0595 2 12.5 4.16 52 23.452 12.8705 10.5815 0.0110581 0.02574 0.001079 0.315409 0.6573