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UNIVERSIDAD NACIONAL DE INGENIERIA

FACULTAD DE INGENIERÍA DE PETRÓLEO, GAS NATURAL Y PETROQUÍMICA

X FERIA Y CONCURSO DE PROYECTOS

Simulation and analysis of a Dew Point Control Plant


Paredes Tocas, J.P.; Ubillas Alcalde, C.U; Carrero Sánchez, K.A.; Llamocca Manco, J.J.
Procesos de gas natural, sección A.

Abstract: In the present experience, the UniSim Design R451 commercial simulator will simulate the process
followed by a dew point control plant to condition 75 MMSCFD (output capacity) to operate in a field of gas
condensates. The gas processed in the unit has a Dew Point of 30 ° F at 800psig thus complying with the required
dew point specifications for a sales gas; Likewise, the liquid current complies with the 13RVP required in this
document.

1. INTRODUCTION liquid extracted from the gas during the dew point
control operation. The medium pressure separator
The dew point of a mixture of hydrocarbons depends functions as a three-phase separator. It separates the
on the composition of the gas and on the pressure and gas that changes due to the decrease in the pressure of
temperature at which the hydrocarbons of said water and liquid hydrocarbon. Water will be treated
mixture, as in the case of natural gas, will begin to and possibly part of it will be used as irrigation. The
condense and enter the liquid phase. liquid hydrocarbon will be stabilized using a
condensate stabilizer.
Heavy hydrocarbon removal may be necessary to
avoid downstream clogging or to meet sales gas 1.1 Objectives
specifications. When the gas is cooled, the dew point
of the hydrocarbons is lowered, which causes the  Perform the simulation of a dew point control
heavy hydrocarbons to condense and be removed. The plant.
methods that can be used to condense heavy  Analyze the results obtained and the function of
hydrocarbons from a gas stream are as follows: each of the equipment to be used for each of the
stages in the plant.
 Joule-Thomson Expansion.
 Refrigeration technology (propane, 2. MATERIALS AND METHODS
refrigerant mixture, etc.)
 Turbo expansión 2.1. Materials
 Membrane technology
2.1.1. UNISIM Design R451 Commercial Simulator
DESCRIPTION OF THE CURRENT PROCESS
Figura 1. UNISIM Design R451 simulator work
SCHEME
environment
The flow from the Wellhead will go to the Slug
Catcher. The gas processing plant will process the gas,
liquid hydrocarbons and water from Slug Catcher. The
gas collected by the Slug Catcher will be sent to a
high-pressure separator, then to a glycol dehydration
unit, and to the dew point control plant based on
mechanical cooling.
Slug Catcher liquid will reduce its pressure to
approximately 280 psig as it flows to the medium
pressure separator. After that, it is combined with the
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Teléfono: 481-1070 (Anexo: 6050)
Correo electrónico: feria.proyectos@fip.uni.edu.pe
Source: UNISIM Design R451 Simulator
2.2. Methodology: Figure 2. Flow chart of a dew point control plant
The stages are two: (sheet1).

2.2.1. Collection of information: Information was


obtained from the file sent by the teacher of the course,
including the composition of the natural gas to be
analyzed and the conditions of the compressor,
pressure drop and its efficiency.

NOMENCLATURE
% molar: Molar Percentage
Flow Rate: [MMscfd]
Pressure: [psig]
Temperature: [°F]

Table 1. Composition and data of natural gas (input


current) Source: File sent by the teacher.

Figure 3. Flow chart of a dew point control plant


(sheet2).

Source: File sent by the teacher Source: File sent by the teacher.

2.2.2. Operation Considerations: It was carefully 2.3. Simulation procedure


analyzed whether the process simulator that was used
supported the simulation with the existing database The problem is based on the Margarita EPF plant.
and the necessary unit operations. The simulation was
carried out in steady state, where results were obtained 1) See how to change units in: Tools /
very similar to the real ones. The fluid package Preferences / Variables.
selected to perform the simulation is that of Peng 2) Create a reservoir stream indicating the
Robinson, recommended according to the literature composition and conditions at which it arrives
for this process. at the plant.
3) Saturate the input current to account for water.
2.2.2. Simulation Development: This experience was 4) Simulate the control valve to adjust the
carried out using as a simulation tool UNISIM R451,
operating pressure of the plant to 1000 psi.
where the design of a dew point control plant will be
5) Simulate the intake air cooler to adjust the
developed (Figure 2).
feed entering 130 ° F.

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6) Simulate the condensate control valve and the Figure 4. General flow diagram of the spray point control
two-phase medium pressure Slug Catcher IP plant.
280 psig.
7) Simulate a high-pressure scrubber and a
glycol filter.
8) Simulate the glycol unit with the Component
Splitter tool. Making the water flow to the
bottom.
9) Simulate the cooling system (E-103, E-104
and V-106). Consider the C3 cooling from 45 Source: Own elaboration in UNISIM Design R451.
psia to 295 psia and the C / T 1 heat exchanger
housing in the first approach.
3. RESULTS AND DISCUSSION
10) Preheat the cold liquid stream with cooling
3.1 Results
propane downstream of the condenser using
the E-105 heat exchanger. Mix the condensate 3.1.1. Part 1: SEPARATION (SLUG
and the liquid stream V-106 to the IP separator CATCHER)
V-102. This first part covers the first 7 points of the procedure
11) Separate the HC current from the V-102. shown above, in which the inlet current from the
Current 7 will be 33% for stabilizing reflux. wellhead was saturated, and then a control valve and a
Use the divisor parameter. cooler were used to condition the current at the input
12) Insert a C / T heat exchanger to preheat the of the two-phase slug catcher.
column feed to 180 ° F.
13) Insert a 14-stage non-reflux condensate Figure 5. Flow chart of the stage of the first separation
stabilizer. The feeding will enter the 7th with a slug catcher.
theoretical stage. Other feed in stage 1. The
only specification will be 13 RVP at the
bottom. The maximum pressure is 150 psig.
14) Cool the condensate stream to 130 ° F with an
air cooler.
15) Compress the steam above the head to HP in
two stages. Consider the air cooler outlet
temperature of 133 F.
16) Combine the V-102 vapors with the vapors of
the upper column compressor. Compress HP.
Source: Own elaboration in UNISIM Design R451.
17) Introduce compressed vapors upstream of the
V-104 filter. Table 2. Table of results of the conditioning simulation for
18) Change the output temperature HX to 100 ° F. the separation of the input current.
19) Consult and solve the problem with E-101.

Source: Own elaboration in UNISIM Design R451.

3.1.2. Part 2: DEHYDRATION OF NATURAL


GAS
In this second part, points 8 and 9 of the procedure
were developed, in which the simulation of a high-
pressure separator and the use of the component
splitter tool that simulates a glycol gas dehydration
system is shown.
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Teléfono: 481-1070 (Anexo: 6050)
Correo electrónico: feria.proyectos@fip.uni.edu.pe
Figure 7. Flow chart of the glycol regeneration process.
High-pressure separator:
After the current coming from the wellhead passes
through the slug catcher, the collected gas is sent to a
separator at high pressure. It was considered to place a
cooler to simulate a possible condensation of the gas
due to a pressure drop in the line that Follow the gas
from the slug catcher to the high-pressure separator.

Natural gas dehydration: Component splitter


Throughout the dew point control plant, prior to the
mechanical cooling process to control the dew point, a
natural gas dehydration treatment is necessary. Source: DEW POINT CONTROL PLANT
Absorption is the most common technique for SIMULATION EXERCISE
dehydration. In it, the water vapor from the gas stream
is absorbed into a liquid solvent stream. Glycols are At the bottom of the absorber comes a rich water -
the most commonly used absorbent liquids since they glycol mixture that passes through the reflux
have properties that adapt to the criteria of commercial condenser coil and goes to the "flash" tank. The
application. Therefore, to satisfy gas specifications aqueous glycol mixture passes through the heat
and prevent the formation of hydrates, dehydration of exchanger rich glycol - poor glycol and goes to the
Natural gas becomes necessary. regenerating tower in which, the absorbed water is
Because there is no absorption tower in the simulator, distilled from the glycol by heat application, at a
the component splitter tool was used to simulate the pressure very close to atmospheric. The regenerated
contact tower used for glycol dehydration. dry glycol that is hot leaves the reboiler towards the
Commonly the dehydration process is made up of two accumulator where it cools due to the exchange with
sections: the rich glycol that returns, then it is pumped to the
glycol / gas heat exchanger and returned to the top of
 Absorption
the absorber.
 Glycol Regeneration
Table 3. Table showing the conditions of dehydrated
For the plant under analysis there is also the gas at the splitter outlet.
regeneration section, which was considered not
necessary to simulate because they did not have the
necessary specifications, but it is correct to mention its
importance and the description of its operation. [5]

Source: Own elaboration in UNISIM Design R451.


Figure 6. Flow chart of the process of dehydration of
the gas stream from the slug catcher.
Figure 8. PT chart for dehydrated gas.

Source: Prepared by the author in UNISIM Design R451. Source: Utilities tool in UNISIM Design R451.

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Teléfono: 481-1070 (Anexo: 6050)
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Table 4. Table showing the points of the dew point  compressor
curve for DEHYDRATED GAS.
 air coolers or condensers

Following the propane circuit, we see that it is a


simple refrigeration cycle consisting of:
 Expansion
 Evaporation
 Compression
 Condensation

The refrigeration cycle begins in the propane tank


(this equipment is not available in the simulator) from
which the propane that is preheated with the liquid
Source: Utilities tool in UNISIM Design R451.
current leaving the V-100 comes out, then passes
Table 5. Table showing the molar composition of through a separator or also known as economizer of
DEHYDRATED GAS. propane which is responsible for separating the
gaseous and liquid phase of the propane stream from
the tank. Subsequently, the liquid that leaves the
economizer (V-101) passes through a JT throttle
valve in which its pressure is reduced from 295 psia
to 45 psia in order to go to the chiller where it will
exchange heat with the dehydrated gas by cooling and
evaporating it So propane. The vaporized propane
passes to the propane scrubber to ensure that no liquid
Source: Prepared by the author in UNISIM Design R451. enters the compressor, the flow of gas from the chiller
joins with the outgoing gas of the economizer to pass
through the compressor and bring the pressure to 295
3.1.3. Part 3: MECHANICAL psia and finally used an air cooler to reduce the
REFRIGERATION (DEW POINT CONTROL) temperature of the gas and pass it back to the propane
In order to meet the requirements of the dew point for tank.
the sale of natural gas, the propane cooling process The dehydrated gas stream cooled with the propane
stream enters the V-100 separator, from which the
was used. For this, the gas must be cooled to a
gas with the specified dew point conditions comes
designated temperature that will depend on these dew out of the stop.
point specifications. This will be the minimum
cooling requirement. Figure 9. Flowchart of the cooling process with C3

For the selection of the refrigerant used in the


mechanical refrigeration section, propane was taken
into account.
Equipment used in the refrigeration process:
 propane tank
 economizer
 chiller
 propane scrubber
Source: Own elaboration in UNISIM Design R451.
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Teléfono: 481-1070 (Anexo: 6050)
Correo electrónico: feria.proyectos@fip.uni.edu.pe
Table 8. Table showing the molar composition of the
Table 6. Table showing the conditions of the REFRIGERATED GAS.
refrigerated gas.

Source: Own elaboration in UNISIM Design R451.

Figure 10. PT chart for REFRIGERATED GAS. Source: Own elaboration in UNISIM Design R451.

3.1.4. Part 4: CONDENSED STABILIZING


TOWER
The tower is composed of 14 theoretical plates and
will have two feed streams, a feed that will enter
through the plate 1 and that is composed of 33% of the
liquid hydrocarbons that leave the three-phase
separator (V-102) and the other 77 %, which will be
preheated to 180 ° F by exchanging heat with the flow
of funds from the stabilizer tower; This stream will
Source: Utilities tool in UNISIM Design R451. enter plate number 7.
This tower will have as its only specifications 150psig
Table 7. Table showing the points of the dew point of pressure at the top and Steam Pressure Reid of
curve for the REFRIGERATED GAS.
13psig at the bottoms; The bottom will be used as a
fluid to preheat the column feed and then go through a
cooler to bring it to a temperature of 130 ° F.
On the other hand, the vapors that leave the column
will mix with the V-102 separator gases and go
through a three-stage process to bring them to high
pressure and then mix it with the V-101 separator gas
stream.

Figure 11. Flow chart of the condensate stabilization


stage.

Source: Utilities tool in UNISIM Design R451.

Source: Own elaboration in UNISIM Design R451.

Av. Túpac Amaru 210 – Rímac, Lima 25, Perú


Teléfono: 481-1070 (Anexo: 6050)
Correo electrónico: feria.proyectos@fip.uni.edu.pe
Table 9. Table showing the properties of condensates Figure 12. Flow chart of the compression stage.
that leave the stabilizer tower.

Source: Own elaboration in UNISIM Design R451.

Table 10. Table showing the properties of the gas from


the stabilizer tower.

Source: Own elaboration in UNISIM Design R451.

Table 11. Table showing the properties of the gas at


the exit of the compression process.

Source: Own elaboration in UNISIM Design R451.

In the table shown it can be seen that the condensates


comply with the specification of a 13 psig RVP.

3.1.5. Part 5: STEAM COMPRESSION Source: Own elaboration in UNISIM Design R451.
The gas that leaves the stabilizer tower leaves at a low
Pressure (150 psig) so it must be compressed at a much
higher Pressure (close to the inlet pressure), to join 3.2 Discussion
with the steam current that leaves the Separator and In this section we analyze and compare the results of
perform The process already described. the dew point of the gas leaving the component splitter
This will be achieved through a three-stage (DEHYDRATED GAS) and the gas of the current 9
compression process, each consisting of a separator, a leaving the mechanical refrigeration cycle (GAS
compressor and a cooler. The separator is to separate REFRIGERATED).
liquids from gases and thus prevent liquid from
entering the compressor; which the second separator We observe that in the whole process of the plant there
will be one of the three-phase type, to eliminate the is a pressure range <970-1000> psig for the gas
maximum amount of water in the stream; The chillers approximately. Ç
are placed to reduce the temperature that is gained in Now for the dehydrated gas stream we analyze Table
the compressor, all this occurs in three stages to 4 and taking into account the pressure at which the
improve the efficiency of the process. current is taken (980psig) we obtain a dew point of
Finally, the gas stream that leaves the entire 83ºF.
compression process joins the gas stream of the On the other hand, for the refrigerated gas stream we
separator to enter the Splitter and eliminate the analyze Table 7 and taking into account the pressure
remaining water. of 970 psig at which this current is found, we obtain a
dew point of 30ºF.
In addition, comparing the molar compositions of both
streams (tables 5 and 8), we can see that in the
Av. Túpac Amaru 210 – Rímac, Lima 25, Perú
Teléfono: 481-1070 (Anexo: 6050)
Correo electrónico: feria.proyectos@fip.uni.edu.pe
refrigerated gas there are a greater proportion of light
components such as methane and ethane, however, for  Pressure increases of 350 psi are considered for
the dehydrated gas there is a greater composition of each of the compressor in the vapor compression
the heavy hydrocarbon components which indicates section.
that by cooling the gas in addition to lowering the dew
point of hydrocarbons, this propane cooling also
causes heavy hydrocarbons to condense and be 5. CONCLUSIONS
removed.  It was possible to control the Dew Point of a gas
stream from a wellhead, to maintain the quality of
4. CONSIDERATIONS: the gas and avoid the possible formation of
hydrates, which, as we know this causes damage
 Although the project was designed to to the equipment and possible obstruction in the
produce 75MMSCFD, in the results we process pipes.
obtained 76.68 MMSCFD this due to the  The specification of 13 RVP was guaranteed in the
various assumptions made with flow stream of the stabilizer column, which
discretion throughout the simulation. guarantees a safer way to stabilize the
condensates.
DEHYDRATION STAGE  From Table 7, for a Pressure of 800psig the Spray
Point is approximately 30 ° F. Normally the Spray
 It was considered to place a cooler to simulate a Point specifications for the sales gas at a typical
pressure of 800psig is 15 to 30 ° F; According to
possible condensation of the gas by a pressure
this, the process and the considerations made in
drop in the line that follows the gas from the slug
the simulator are adequate to achieve these
catcher to the high-pressure separator. specifications.
 A Set Point (Set-1) was used between stream 48
(Wet Gas) and stream H2O (Water leaving the 6. BIBLIOGRAPHIC REFERENCES
Splitter) using the Comp Molar Flow (H2O) as a [1] S. Mokhatab, Handbook of Natural Gas
variable, since all the water entering will be Transmission and Processing, 1 ed., GULF,
removed to the splitter. 2006, pp. 295-296.
[2] M. Martinez, Ingeniería de Gas, Principios y
MECHANICAL REFRIGERATION STAGE
Aplicaciones. Deshidratación de Gas
Natural., Ingenieros Consultores, S.R.L.
 V-103 separator is placed for safety; since, as we
[3] Control de punto de rocío, áreas de
know we must prevent the entry of liquid to the K-
negocio, OSL Iberia.
100 compressor, because this could damage the
[4] Operación de plantas de procesamiento
compressor equipment.
de Gas Natural, Osignermin, Jessica Gomez
 In the propane cycle, a V-103 stop was used
Pocomucha.
because the simulator does not have a purifying
[5] Simple Dew Point Control – HYSYS
device whose function is to prevent liquid propane
v10
from entering the compressor area.
 A pressure drop equal to zero was considered for
the air cooler.

CONDENSATE STABILIZATION

 The condensate stabilizer tower is designed to


minimize starting time and safely stabilize
condensates when working with a lower Reid
Vapor Pressure.

COMPRESSION STAGES
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Teléfono: 481-1070 (Anexo: 6050)
Correo electrónico: feria.proyectos@fip.uni.edu.pe

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