JOURNAL OF BASIC CHEMICAL PRACTICUM V

"CONTINUOUS VARIATIONS AND STOICIOMETRY"

BY
NI PUTU AYU SUWARNI
(1913071003)

CLASS 1A
S1 SCIENCE EDUCATION
DEPARTMENT OF PHYSICS AND SCIENCE THEACING
FACULTY OF MATHEMATICS AND NATURAL SCIENCES

UNIVERSITAS PENDIDIKAN GANESHA

SINGARAJA
2019
 EXPERIMENT 5
CONTINUOUS VARIATIONS AND STOICIOMETRY

I. Purpose
Students can prove the stoichiometry of chemical reactions based on
changes in the price of physical properties.

II. Basic Theory

The basis of this experiment is the JOB method or the continuous
variation method. In this method a series of observations are made with the
same total molar quantity, but each repertoire of molar quantities varies
(varies). One particular physical characteristic is chosen to be examined,
for example mass, volume, temperature, and absorption. Because the
quantity of reagents is different, changes in the price of the physical
properties of this system can be used to predict the stoichiometry of the
system.If a graph of the physical properties of the observed (measured)
flow of the reaction quantity is drawn, a maximum or minimum point is
obtained that corresponds to the system's stoichiometric point.This
situation states the ratio of reagents in compounds.

III. Tools and Materials

Tools
-2 pieces of 100mL beaker
-10 beaker 50mL
-1 cup measuring 10 ml, 50 ml
-2 drops of pipette
Ingredients / substances :
-CuSO4 1 M
-NaOH 2 M, 1 M
-HCl 1 M
-H2SO4 1 M
IV. Work Procedures
1. System stoichiometry CuSO4-NaOH
a. Use 1 m CuSO4 solution and 2 M NaOH. Put 40 mL NaOH into the
beaker and record the temperature.
b. While stirring, add 10mL of CuSO4 solution that has been measured at
initial temperature and observe the temperature of the mixture. (Note:
the temperature of the CuSO4 solution must be adjusted to the
temperature of the NaOH solution in the beaker before mixing)
c. Repeat the experiment, using 20mL NaOH and 30mL CuSO4 ; 10 mL
NaOH and 40 mL CuSO4; 30 mL NaOH and 20 mL CuSO4 solution.

2. Acid-base stoichiometry
a. Into 5 50mL beakers, enter 5,10,15,20 and 25 mL of NaOH solution
and enter 5 other beakers respectively 5,10,15,20, and 25 mL of HCl
solution.
b. The temperature of each type of solution is measured, recorded, then
the average price is taken (this is the initial temperature, TM)
c. The two solutions are mixed in such a way that the volume of the
mixture of acid and base solution is always fixed, which is 30 Ml.
d. Temperature changes that occur during this mixing are observed and
recorded as the final temperature, TA.
Thus the price of delta T is obtained for each mixing of acid and base
solutions

e. Next, graph the delta T (y axis) and acid-base volume (x axis)

f. Do the same experiment with a mixture of NaOH and H2SO4.
What differences might there be compared to previous experiments.
V. Observation Result
1. Stoikiometri CuSO4-NaOH
NaOH CuSO4 TM TA
(mL) (mL)

2. a. StoikiometriNaOH-HCl
NaOH HCl TM TA
(mL) (ML)
0 30
5 25
10 20
15 15
20 10
25 5
30 0

2. b.Stoikiometri NaOH-H2SO4

NaOH H2SO4 TM TA
(mL) (ML)
0 30
5 25
10 20
15 15
20 10
25 5
30 0

1. Stoichiometry Graph CuSO4-NaOH

 2. Stoichiometry GraphNaOH-HCl

3. Stoichiometry GraphNaOH-H2SO4
VI. Discussion
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VII. Conclusions
1. Stoikiometri CuSO4-NaOH

2. StoikiometriNaOH-HCl

3. Stoikiometri NaOH-H2SO4

VIII. References
Subagia,I Wayan and Sya’ban.2004. Materi Praktikum Kima Dasar I.Singaraja

Singaraja, November2, 2019

Supporting lecturer, Do it,

(Dr. I Nyoman Suardana, M.Si) (Ni Putu Ayu Suwarni)

NIP. 19661123993031001 NIM. 1913071011