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JOURNAL GEOLOGICAL SOCIETY OF INDIA

Vol.94, September 2019, pp.319-327

Effect of Kerogen and TOC on Seismic Characterization of Lower


Cretaceous Shale Gas Plays in Lower Indus Basin, Pakistan
Perveiz Khalid1*, Jahanzeb Qureshi2, Zia Ud Din1, Sami Ullah1 and Javed Sami2
1
Institute of Geology, University of the Punjab, 54590 Lahore, Pakistan.
2
Department of Space Science, University of the Punjab, 54590 Lahore, Pakistan
E-mail: perveiz.geo@pu.edu.pk*; ziauddinpu@yahoo.com; samiullah1101@gmail.com; jzebqureshipu@gmail.com;
javedsami_pu@yahoo.com

ABSTRACT shales requires to focus on the anisotropy resulting from various


Unconventional energy resources such as shale gas are orientations of clay minerals and pores in the shale rock matrix
becoming an increasingly important exploration and production (Carcione, 2000; Wenk et al., 2007; Lonardelli et al., 2007; Dewhurst
targets. Organic-rich shales are widely distributed in the et al., 2011; Slatt and Abousleiman, 2011).
sedimentary basins of Pakistan. Among these shales, organic-rich The impact of total organic contents (TOC) and volume of kerogen
Sembar shale of the lower Cretaceous age is a strong potential on seismic response of organic-rich shale have received more attention
shale gas play in the lower Indus basin of Pakistan. However, (Aziz et al., 2018). Several workers tried to model the effect of these
seismic and petrophysical characterization of this organic-rich parameters on seismic properties of organic shale with the help of
shale is not well understood because of the complex dependency rock physics model (Carcione et al., 2011; Vernik and Milovac, 2011;
of the seismic and petrophysical properties of these rocks on Li et al., 2015; Aziz et al., 2018). Zhu et al. (2012) proposed an
mineralogical, heterogeneities, organic matter, clay content improved rock physics model for shale gas plays. The impact of volume
and thermal maturity. Therefore, to understand the seismic and of kerogen on the anisotropy of shales was studied by Sayers (2013).
elastic character of Sembar shales, rock physics modeling and Amplitude versus offset analysis of shale gas plays was done by Zhu
seismic attribute analysis have been done. The results reveal that et al. (2011) and Sayers (2013) on the basis of proposed rock physics
in-situ mineral composition, total organic content (TOC) and models, especially for organic-rich shales. Meanwhile, Sun et al. (2013)
thermal maturity can influence significantly in inverse order to modeled seismic responses of shale gas reservoirs based on anisotropic
the seismic and elastic parameters of organic-rich shale. This wave equations. Kerogen content has a significant impact on the
work will facilitate the workers to interpret shale gas play and seismic properties due to its low density (Passey et al., 2010). However,
develop the exploration and production strategies for gas the combined impact of TOC and volume of kerogen on seismic
exploration and production. signatures of shale gas play has not been well investigated. The
objective of this work is to analyze the combined effect of TOC and
INTRODUCTION volume of kerogen on seismic properties of organic-rich shales.
Major production of natural gas is from conventional reservoirs, Almost each sedimentary basin of Pakistan has thick deposits of
however, since last decade a significant amount of gas has been organic-rich shales (Kazmi and Jan, 1997; Ahmed et al., 2013). The
recovered from unconventional reservoirs because of advancement in Indus basin is the largest basin of Pakistan, which covers about 60%
exploration and production technology and high demand of gas (Lüning area of the country (Khalid et al., 2014). This basin is classified into
and Kolonic, 2003). The unconventional reservoirs such as organic- three parts: upper, lower and central. The well and seismic data indicate
rich shales, tight sands, coal bed methane, etc. have a huge amount of that organic-rich shales of various ages are present into all the three
hydrocarbon gas and are widely distributed in different sedimentary parts of the Indus basin (Kazmi and Jan, 1997). According to an
basins of the world (Boyer et al., 2011). Among these unconventional estimate, the country has been bestowed with more than 200 TCF
reservoirs, shale gas is the major unconventional reservoir that is (trillion cubic feet) of unconventional gas reservoirs within the organic-
present in a very large amount as compared to other unconventional rich shales. The organic-rich shales of Sembar and lower Goru
reservoirs. This important unconventional reservoir is characterized formations are widespread in the middle and lower Indus basin of
by very low permeability (< 1 milli darcy) and sufficiently good porosity Pakistan (Ahmed et al., 2013). In the middle Indus basin, dry gas is
(Holditch, 2006; Alexander et al., 2011; Sunjay, 2011; Das and producing from these shales (Haider et al., 2012). Sembar shale is a
Chatterjee, 2018). In the last few years, shale gas reservoirs have proven source rock and potential shale gas play in the basin because it
emerged as an explorable energy source. However, the extraction of fulfills all the requirements – TOC, level of maturity, burial depth,
gas from these reservoirs is still challenging. The departure of seismic thickness and brittleness – to be act as a shale gas play (Ahmed et al.,
and elastic behavior of shale gas from conventional gas reservoirs is 2013). However, the impact of mineralogy, clay content, TOC, volume
one of the distinguishing features (Passey et al., 2010; Sunjay, 2011). of kerogen etc. on seismic signatures of shales is not studied until
Due to this unconventional behavior, the generalized characterization now. Only Aziz et al. (2018) proposed a workflow to estimate TOC in
of the shale gas reservoir is very crucial. This unconventional behavior Sembar shales from seismic reflection data in a particular site. Thus,
is due to a very large variation in mineralogy, total organic carbon exploration of shale gas plays requires a deeper understanding of
(TOC), thermal maturity, geological and depositional setting (Roth, relationship between mineralogy, TOC, volume of kerogen and elastic
2010; Zhu et al., 2012). Thus, it is difficult to obtain dynamic properties properties of organic shales. A rock physics model is fundamental to
of reservoir and, therefore, to characterize gas reserves. Conventional establish and understand the relationship between these parameters
rock physics models do not concentrate on the anisotropy present in (Khalid et al., 2016; Khalid et al., 2018). To see the impact of TOC
the shale gas reservoirs. However, the rock physics model for organic and volume of kerogen on seismic signatures of shales the shales of

0016-7622/2019-94-3-319/$ 1.00 © GEOL. SOC. INDIA | DOI: 10.1007/s12594-019-1312-8


Fig.1. Location map of the study area with respect to lower Indus basin of Pakistan and regional map.

Sembar Formation of Lower Cretaceous present in the lower Indus and Milovac, 2011; Zhu et al., 2011; Davie et al., 2012; Zhu et al.,
basin was selected. The location map of the study area is shown in 2012) but there are several factors such as thickness, porosity,
Fig. 1. The chronostratigraphic chart of the lower Indus Basin is saturation, burial depth, formation temperature and pressure, fractures,
presented in Fig. 2. From this chart it is clear that shales of various brittleness etc. have significant role in the development of shale gas
ages’ range from the Paleocene to the Lower Cretaceous are present play (Zhu et al., 2012). The organic content present into shales has
in the study area. The shales of Sembar and Goru formations of lower specific density, radioactivity and electrical resistivity values that affect
Cretaceous age can be act as potential shale gas play in the lower wireline log and seismic responses (Zhu et al., 2011). Thus, shale gas
Indus basin. reservoirs can be characterized through logs and seismic.
Organic-rich shales are usually composed of three components
CHARACTERIZATION OF ORGANIC-RICH SHALES i.e., rock matrix, solid organic matter and the void space, while non-
Conventional petroleum system comprises by source, reservoir organic rocks are composed of the rock matrix and the void space.
and seal rocks in which carbonates and sandstones generally act as The schematic diagram of organic-rich rock showing various maturity
reservoir rocks whereas shales act as a source and cap rock. In the last levels is presented in Fig. 3. In mature source rocks, under the action
few years, shales have been considered as a good reservoir because of of temperature, pressure and burial time a portion of the solid organic
its high porosity, low permeability and organic-richness (Arogundade matter is converted into liquid or gaseous hydrocarbons. This liquid
and Sohrabi, 2012). Thus, at the same time these shales may be or gaseous hydrocarbon termed as petroleum fluid moves into the void
considered as source, reservoir and seal rocks in unconventional spaces and displacing the formation water or increases the saturation
reservoirs and have large variability in mineralogical, elastic and of formation fluids. This physical movement and transformations of
physical properties from basin to basin and even within the basin fluids affect the porosity, density and resistivity of the hosting rocks
(Harilal and Tandon, 2012). For example, the Barnett shale is mudstone and hence reflected in their respective electric logs. Passey et al. (2010)
dominated; the Bakken Shale is composed by silt grains, dolomite showed with the help of scanning electron microscope (SEM) images
and quartzitic sand, and the Marcellus shale contains about 60% that the solid organic matter has nano-porosity. However, the kerogen
quartz (Monk et al., 2011). present into an immature source rock has no void spaces.
Seismic reflection and wireline logging techniques are generally Shale gas reservoirs are capable of self-generation and self-store
used to characterize conventional reservoirs (Jun-Yu et al., 2012; Zhang hydrocarbons. Because of this unique physical property of organic
et al., 2013; Chen et al., 2014; Khalid et al., 2014; Khalid et al., 2015; matter in shale gas reservoirs, high wireline log response is expected
Chatterjee et al., 2016; Das et al., 2017; Singha and Chatterjee, 2017; for sonic transit time, electrical resistivity, gamma ray and low density
Das and Chatterjee, 2018; Khalid et al., 2018). However, the seismic as compared to non-organic shales. Thus, integrated techniques are
characterizations of unconventional reservoirs are not well established. available to differentiate organic and non-organic shales and to
Although some rock physics models for shale gas characterization calculate TOC by using well logs and other data (Passey et al., 2010;
have been proposed by some workers (Parasad et al., 2009; Vernik Sun et al., 2013).

320 JOUR.GEOL.SOC.INDIA, VOL.94, SEPT. 2019


Fig.2. General stratigraphic section showing major chronostratigraphic units in the Lower Indus Basin, Pakistan (Khalid et al., 2014; Azeem et
al., 2017).

Generally, gamma ray (GR) log is used to differentiate shales from et al. (2010), the response of resistivity log is also associated with the
other lithologies in sedimentary areas. The presence of organic matter degree of maturity. In highly mature reservoirs resistivity values can
in shales has an impact on GR log response as discussed by Schmoker be significantly lower than the same reservoir at lower thermal
(1981). It indicates overall uranium and clay content in association of maturities. The density log is used to find out volume of kerogen or
organic-richness. Some empirical relationship exists between uranium TOC. The presence of less denser organic matter (kerogen) may
and organic matter therefore, spectral gamma ray tools have been used decrease the values of density log in organic-rich interval. Combined
to quantify organic matter into the rocks (Rider, 2002). The use of with the resistivity log, density log gives the extremely valuable results
electrical resistivity log is very common to identify fluid type into the in organic-rich source interval (Passey et al. 2010). The use of sonic
pores of reservoir rocks. In organic-rich shale intervals, the response log can enhance the level of confidence in the determination of TOC
of electrical resistivity log increases dramatically. According to Passey when combined with the resistivity log (Passey et al. 2010).

JOUR.GEOL.SOC.INDIA, VOL.94, SEPT. 2019 321


rock quality either it can produce oil, gas or condensates. Since core
data was not available for this study therefore, Ro of the Sembar
Formation was computed from burial history (Sweeney and Burnham,
1990) using the software module Petromod. Peter (1986) describes
the thermal maturity parameters based on the maximum temperature
(Tmax) to determine the dimensions of oil windows Hood et al. (1975)
develop a single scale which synthesizes several existing indices of
organic maturity based on coal rank. The scale relates LOM to vitrinite
reflectance among other indicators is shown in Fig. 4.

Fig.3. Schematic diagram showing various stages of organic shale Determination of TOC and Mineralogy
and its essential ingredients. In the first step, TOC and volume of kerogen are determined along
with mineralogy, effective porosity and water saturation in the organic-
rich shale interval. As TOC is the primary indicator on the basis of
WORKFLOW AND METHODOLOGY which one can declare a shale formation to be act as a shale gas play.
Shale gas play is generally characterized by intermediate to high In general, TOC is measured from the lab analysis of organic shales
volume of kerogen, higher effective porosity, lower clay volume, low samples or core cuttings however, in those areas where core cutting is
concentration of water, high bulk modulus and lower Poisson’s ratio not available, the use of wireline logs is very common to deduce the
(Carcione et al., 2011). Petrophysical analysis in combination of TOC. In this study, core samples were not available, which is
wireline logging and core analysis is the starting point of the insufficient to represent the TOC values of whole organic-rich shale
optimization of shale gas play. Seismic data interpretation and analysis interval, therefore wireline logs were used to estimate TOC in the
characterize the shale play away from the well control in the whole shale intervals.
field. Further, rock physics is a tool to link elastic properties of porous Among different methods of TOC estimation from wireline logs,
rocks and fluids with petrophysical properties of the rock-fluid ∆logR technique (Passey et al., 1990) is most commonly used for the
composite. To analyze the impact of fluid properties especially, gas, estimation of TOC in organic-rich shale interval however, the TOC
TOC and volume of kerogen on seismic properties of hosting rock estimated by this method is in not in close agreement with the measured
following work flow is established with a high level of confidence. values (Sun et al., 2014) therefore we also used Schmoker’s method
(Schmoker and Hester, 1983) to compute TOC in organic-rich intervals
Computation of Vitrinite Reflectance and Level of Maturity of Sembar shale. ∆logR technique is based on the separation between
Thermal maturity is one of the basic parameters required for the the deep electrical resistivity log curve and the bulk density, neutron
evaluation of shale gas play in shale gas prospecting. Thermal maturity and sonic logs in which deep electrical resistivity log is paired with
or level of maturity (LOM) – a unitless quantity – of a source rock, one of the porosity logs. With the help of level of maturity (LOM) the
indicates quality of the source rock in terms of producible oil, gas or resistivity-porosity log curve overlay is converted into TOC.
gas condensates. Various methods are in practice to measure LOM In ∆logR technique, two log curves such as sonic and density logs
e.g., vitrinite reflectance, thermal alteration index and Tmax, or estimated with respect to resistivity log curve are plotted against depth of
using burial and thermal history of the basin (Rezaee and Chehrazi, investigation. The overlay of the two log curves indicates to the baseline
2005). In the presence of core samples, Rock – Eval prolysis technique and the corresponding log value at this overlay is called baseline
(Shiri et al., 2013; Kadkhodaie and Rezaee, 2017) is used to identify resistivity (Rb), baseline sonic (Dtb) and baseline density (rb). The
type and LOM of organic matter in shales. LOM determines the source baseline represents the boundary between organic and non-organic
shale interval. The separation between baseline value and
corresponding log value is defined as ∆logR that is directly related to
TOC as demonstrated in Eq. 1 and 2.

∆ log R = log10 (R/Rb) + 0.02 × (∆t – ∆tb ) (1)

∆ log R = log10 (R/Rb) + 2.50 × (ρ – ρb ) (2)

The empirical relationship between TOC in clay-rich rocks and


∆logR is
TOC = (∆log R) x 10(2.297 – 0.1688 × LOM) (3)
where, TOC represents to total organic carbon content taken in
percentage (%), LOM is level of maturity. The relationship between
volume of kerogen (Vkr), TOC, density of pore fluid (ρf), formation
bulk density (ρb), density of kerogen (ρkr), and porosity (f) is given by
Vernik and Milovacet (2011):
TOC ρ b − ρ f φ
Vkr = × (4)
Ckr ρ kr (1 − φ )
where, Ckr is a constant of maturity whose value is in the range of
0.7–0.85 depending on the maturity level. The density of kerogen varies
Fig.4. Relation of Ro to another thermal maturity indicator known as 1.2 – 1.4 g/cm3 depending on the maturity. According to the results of
Level of Organic Metamorphism (LOM) (modified after Hood et al., the geochemical analysis of the samples of this organic shale kerogen
1975). of Type II/III (Peters and Cassa, 1994) is present.

322 JOUR.GEOL.SOC.INDIA, VOL.94, SEPT. 2019


Wireline and Seismic Integration RESULTS
The integration of seismic data interpretation to wireline logs is a In this study, we used wireline logs of four wells: K-01, D-01, S-
powerful tool to make results more accurate and reliable (Khalid et 01 and Kh-01 from the lower Indus Basin, Pakistan, where Sembar
al., 2018). shale is encountered and has a good level of maturity in terms of
vitrinite reflectance as depicted in Fig. 5. According to the burial history
Rock Physics Modeling and Attribute Analysis technique the level of maturity is a function of depth as demonstrated
Rock physics provides an important link between various micro- in Fig. 5. The vitrinite reflectance of the Sembar shales is in the range
scopic properties and macroscopic physical properties of rocks and of Ro ~0.7 % - 1.2 % encountered in the four wells. The maximum
fluids (Das et al., 2018). Rock physics modeled is used to quantify the value of Ro is about 1.2 %, in K-01 well where Sembar Formation is
effect of volume of kerogen, porosity and TOC on seismic properties encountered at a depth of 4240 m and the minimum value of Ro is
of organic-rich Sembar shale. It is assumed the mixture of kerogen about 0.7 % in Kh-01 well where depth of this organic shale is about
and hydrocarbon-filled pores has non-zero shear modulus (Passey et 3485 m. These values of Ro show that the shales of Sembar Formation
al. 1990). The method proposed by Carcione (2001) based on the falls in mature level mainly in oil window except in well K-01 where
effective medium theory of Kuster and Toksöz (1974) is used to vitrinite reflectance value falls in wet gas window (Alexander et al.,
estimate the elastic moduli of the mixtures (kerogen, oil, gas, water) 2011). These Ro values further correlated with Hood et al. (1975) coal
and the organic-rich shales. The saturation of kerogen, oil, gas and rank table (Fig. 4) to determine the LOM. The estimated level of
water are represented by Sk, S o, Sg and Sw respectively. The bulk maturity with respect to vitrinite reflectance of the Sembar Shale is
modulus of the oil/gas/water mixture (Kogw) is estimated by the formula presented in Table 2. The source rock interval in the Sembar Formation
proposed by Wood (1931): was marked by using well-known Passey’s method (Passey et al. 1990).
−1
This shale formation is easily mapable on 2D seismic section as
S S g Sw  presented in Fig. 6 where it is sandwiched between Upper Jurassic
K ogw = o + +  (5)
K
 o K g K w  Chiltan Limestone (lower contact) and Goru Formation of the
Cretaceous (upper contact). The lower contact is very sharp with high
Where, Ko, Kg, and Kw are the bulk moduli of oil, gas and water amplitudes due to strong impedance contrast between Sembar shales
respectively. Since, the input parameters used in the rock physics and Chiltan Limestone. The shaly sequence is identified with low
modeling are extracted from wireline logs data, therefore, the resultant amplitudes. Some high amplitude anomalies in Sembar Formation are
elastic parameters of shales are only representing to vertical direction due to thin bed intercalations of sandstone and limestone. These thin
under the isotropic assumption and can be used to establish the bed intercalations can be inferred from phase attributes and subtle
relationship between kerogen, TOC and elastic properties of organic discontinuities are inferred from reflection strength attribute as depicted
shales in vertical wells. In this study, the relationship proposed by in Fig. 6b & c.
Castagna et al. (1985) is used to find out compressional and shear
wave velocities for silicates rocks: TOC, Volume of Kerogen and Porosity of Sembar Shales
Due to lack of core data, conventional well data including: gamma
Vs = (Vp – 1.36) / 1.16 (6) ray, resistivity, sonic and density are used for TOC calculation.
According to the observations and analysis based on Passey et al.
where VP is P– wave velocity and VS is shear wave velocity in (1990) density/resistivity logs overlay method, the Sembar shale is
km/sec. VP is calculated from sonic log run in the study wells. The composed by clay, quartz, dolomite, hydrocarbon-saturated kerogen,
other elastic parameters of organic-rich shale such as shear, bulk and fluid-saturated pores in shale matrix. The computed TOC by the
modulus and Poisson’s ratio can be obtained by using the following above mentioned method in shales intervals encountered in all four
relationship of P– and S– wave velocities with density: wells is plotted in Fig. 7 along with lithological variations. The average
range of TOC in Sembar organic shales encountered in these four
µ = ρ × Vs2 (7) wells is 0.8 % – 6 %, thus showing poor to good potential of
unconventional shale gas reservoir. Total organic content in organic
4 Sembar shales estimated in four wells is plotted as a function of
K = ρ × (VP2 − VS2 ) (8)
3 neutron porosity (f) and volume of kerogen (Vkr) in Fig. 8. The average

σ = 0.5 (VP2 – Vs2 ) / ( VP2 – Vs2 ) (9) Table 2. Level of thermal maturity with respect to vitrinite reflectance of
Sembar Shale encounterted in study wells computed by using Hood et al.
Where µ is shear modulus, ρ is density g/cm3, K is bulk modulus (1975) maturity table.
and σ is the Poisson’s ratio. The elastic properties of all these Well Vitrinite Level of Thermal
constituents used in rock physics model are given in Table 1. name reflectance maturity maturation
(%Ro) (LOM)

Table 1. Elastic properties of different constituents of shale gas reservoir used S-01 0.87 10 Oil window
in rock physics modeling (Mavko et al., 2009) K-01 1.21 11.2 Wet gas window
D-01 1.03 10.8 Oil window
Density Bulk modulus Shear modulus
Kh-01 0.66 9 Oil window
(g/cm3) (GPa) (GPa)
Quartz 2.65 37 43 Table 3. Log derived porosities of the Sembar shales intervals encountered in
Clay 2.5 21.5 9 four wells of the study area.
Dolomite 2.85 95 45 Well Name Depth interval (m) Porosity range
Kerogen 1.4 6.8 2.02 K-01 3800 – 3860 0.06 – 0.14
Oil 0.7 0.6 0 Kh-01 1900 – 1990 0.08 – 0.16
Gas 0.12 0.06 0 D-01 3600 – 3870 0.08 – 0.13
Water 1.04 2.25 0 S-01 3420 – 3490 0.03 – 0.14

JOUR.GEOL.SOC.INDIA, VOL.94, SEPT. 2019 323


Fig.5. Level of maturity in terms of vitrinite reflectance (Ro) with respect to burial depth for Sembar formation encountered in S-01, K-01, D-01
and Kh-01 wells drilled in lower Indus Basin of Pakistan.

Fig.6. (a) Interpreted seismic section showing reflector of Sembar Shales, (b) Reflections strength showing signature of shale layers and (c)
Phase section showing internal layering within shaly section, the western end of the study.

324 JOUR.GEOL.SOC.INDIA, VOL.94, SEPT. 2019


(a) (b)

(c) (d)
Fig.7. TOC computation and demarcation of organic-rich intervals in the Sembar shales by using density/resistivity logs overlay for wells
(a) S-01, (b) D-01, (c) K-01 and (d) Kh-01 respectively.

porosity of shale intervals in each wells is presented in Table 3. It is


evident from the figure that TOC has direct relation with effective
porosity. The maximum TOC is estimated in Kh-01 well (about 6%)
where porosity is also maximum upto 16%. The minimum content of
TOC is computed in D-01 well where TOC~ 0.8% corresponding to
intermediate porosity values. The volume of kerogen varies in the
range of 0 – 20% in all wells. The increase in porosity and volume of
kerogen result in increase in TOC. However, TOC is a first order
function of volume of kerogen whereas TOC is less dependent on
change is porosity.

Effect of TOC and Volume of Kerogen on Seismic Properties of


Sembar Shales
To see the effect of TOC and volume of kerogen on elastic and
seismic properties such as P-wave velocities, saturated bulk modulus
of incompressibility, shear modulus and Possion’s ratio of organic-
rich Sembar shales are plotted in 3D surface as a function of TOC and
volume of kerogen and presented in Fig. 9. It is clear from the modeling
results that an inverse relationship between P-wave velocities and TOC
exists in the organic-rich intervals. P-wave velocity reduces in organic- Fig.8. 3D surface plot showing the interdependency of volume of
rich shale intervals as compared to non-organic shales. The correlation kerogene, effective porosity and TOC in organic-rich shale intervals
between TOC and silica contents into the organic shale seems to be of Sembar Shale encountered in four wells under investigation drilled
positive whereas an inverse correlation between TOC and the clay in lower Indus Basin, Pakistan.

JOUR.GEOL.SOC.INDIA, VOL.94, SEPT. 2019 325


Fig.9. Effect of volume of kerogene and TOC on (a) P-wave velocity, (b) Saturated bulk modulus of incompressibility, (c) Shear modulus of
incompressibility and (d) Poisson’s ratio of organic-rich shale intervals of Sembar Shale encountered in four wells under investigation drilled in
lower Indus Basin, Pakistan.

content is noted. Thus, the dependency of seismic velocities on TOC References


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(Received: 14 January 2019; Revised form accepted: 27 May 2019)

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