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Sembar Formation of Lower Cretaceous present in the lower Indus and Milovac, 2011; Zhu et al., 2011; Davie et al., 2012; Zhu et al.,
basin was selected. The location map of the study area is shown in 2012) but there are several factors such as thickness, porosity,
Fig. 1. The chronostratigraphic chart of the lower Indus Basin is saturation, burial depth, formation temperature and pressure, fractures,
presented in Fig. 2. From this chart it is clear that shales of various brittleness etc. have significant role in the development of shale gas
ages’ range from the Paleocene to the Lower Cretaceous are present play (Zhu et al., 2012). The organic content present into shales has
in the study area. The shales of Sembar and Goru formations of lower specific density, radioactivity and electrical resistivity values that affect
Cretaceous age can be act as potential shale gas play in the lower wireline log and seismic responses (Zhu et al., 2011). Thus, shale gas
Indus basin. reservoirs can be characterized through logs and seismic.
Organic-rich shales are usually composed of three components
CHARACTERIZATION OF ORGANIC-RICH SHALES i.e., rock matrix, solid organic matter and the void space, while non-
Conventional petroleum system comprises by source, reservoir organic rocks are composed of the rock matrix and the void space.
and seal rocks in which carbonates and sandstones generally act as The schematic diagram of organic-rich rock showing various maturity
reservoir rocks whereas shales act as a source and cap rock. In the last levels is presented in Fig. 3. In mature source rocks, under the action
few years, shales have been considered as a good reservoir because of of temperature, pressure and burial time a portion of the solid organic
its high porosity, low permeability and organic-richness (Arogundade matter is converted into liquid or gaseous hydrocarbons. This liquid
and Sohrabi, 2012). Thus, at the same time these shales may be or gaseous hydrocarbon termed as petroleum fluid moves into the void
considered as source, reservoir and seal rocks in unconventional spaces and displacing the formation water or increases the saturation
reservoirs and have large variability in mineralogical, elastic and of formation fluids. This physical movement and transformations of
physical properties from basin to basin and even within the basin fluids affect the porosity, density and resistivity of the hosting rocks
(Harilal and Tandon, 2012). For example, the Barnett shale is mudstone and hence reflected in their respective electric logs. Passey et al. (2010)
dominated; the Bakken Shale is composed by silt grains, dolomite showed with the help of scanning electron microscope (SEM) images
and quartzitic sand, and the Marcellus shale contains about 60% that the solid organic matter has nano-porosity. However, the kerogen
quartz (Monk et al., 2011). present into an immature source rock has no void spaces.
Seismic reflection and wireline logging techniques are generally Shale gas reservoirs are capable of self-generation and self-store
used to characterize conventional reservoirs (Jun-Yu et al., 2012; Zhang hydrocarbons. Because of this unique physical property of organic
et al., 2013; Chen et al., 2014; Khalid et al., 2014; Khalid et al., 2015; matter in shale gas reservoirs, high wireline log response is expected
Chatterjee et al., 2016; Das et al., 2017; Singha and Chatterjee, 2017; for sonic transit time, electrical resistivity, gamma ray and low density
Das and Chatterjee, 2018; Khalid et al., 2018). However, the seismic as compared to non-organic shales. Thus, integrated techniques are
characterizations of unconventional reservoirs are not well established. available to differentiate organic and non-organic shales and to
Although some rock physics models for shale gas characterization calculate TOC by using well logs and other data (Passey et al., 2010;
have been proposed by some workers (Parasad et al., 2009; Vernik Sun et al., 2013).
Generally, gamma ray (GR) log is used to differentiate shales from et al. (2010), the response of resistivity log is also associated with the
other lithologies in sedimentary areas. The presence of organic matter degree of maturity. In highly mature reservoirs resistivity values can
in shales has an impact on GR log response as discussed by Schmoker be significantly lower than the same reservoir at lower thermal
(1981). It indicates overall uranium and clay content in association of maturities. The density log is used to find out volume of kerogen or
organic-richness. Some empirical relationship exists between uranium TOC. The presence of less denser organic matter (kerogen) may
and organic matter therefore, spectral gamma ray tools have been used decrease the values of density log in organic-rich interval. Combined
to quantify organic matter into the rocks (Rider, 2002). The use of with the resistivity log, density log gives the extremely valuable results
electrical resistivity log is very common to identify fluid type into the in organic-rich source interval (Passey et al. 2010). The use of sonic
pores of reservoir rocks. In organic-rich shale intervals, the response log can enhance the level of confidence in the determination of TOC
of electrical resistivity log increases dramatically. According to Passey when combined with the resistivity log (Passey et al. 2010).
Fig.3. Schematic diagram showing various stages of organic shale Determination of TOC and Mineralogy
and its essential ingredients. In the first step, TOC and volume of kerogen are determined along
with mineralogy, effective porosity and water saturation in the organic-
rich shale interval. As TOC is the primary indicator on the basis of
WORKFLOW AND METHODOLOGY which one can declare a shale formation to be act as a shale gas play.
Shale gas play is generally characterized by intermediate to high In general, TOC is measured from the lab analysis of organic shales
volume of kerogen, higher effective porosity, lower clay volume, low samples or core cuttings however, in those areas where core cutting is
concentration of water, high bulk modulus and lower Poisson’s ratio not available, the use of wireline logs is very common to deduce the
(Carcione et al., 2011). Petrophysical analysis in combination of TOC. In this study, core samples were not available, which is
wireline logging and core analysis is the starting point of the insufficient to represent the TOC values of whole organic-rich shale
optimization of shale gas play. Seismic data interpretation and analysis interval, therefore wireline logs were used to estimate TOC in the
characterize the shale play away from the well control in the whole shale intervals.
field. Further, rock physics is a tool to link elastic properties of porous Among different methods of TOC estimation from wireline logs,
rocks and fluids with petrophysical properties of the rock-fluid ∆logR technique (Passey et al., 1990) is most commonly used for the
composite. To analyze the impact of fluid properties especially, gas, estimation of TOC in organic-rich shale interval however, the TOC
TOC and volume of kerogen on seismic properties of hosting rock estimated by this method is in not in close agreement with the measured
following work flow is established with a high level of confidence. values (Sun et al., 2014) therefore we also used Schmoker’s method
(Schmoker and Hester, 1983) to compute TOC in organic-rich intervals
Computation of Vitrinite Reflectance and Level of Maturity of Sembar shale. ∆logR technique is based on the separation between
Thermal maturity is one of the basic parameters required for the the deep electrical resistivity log curve and the bulk density, neutron
evaluation of shale gas play in shale gas prospecting. Thermal maturity and sonic logs in which deep electrical resistivity log is paired with
or level of maturity (LOM) – a unitless quantity – of a source rock, one of the porosity logs. With the help of level of maturity (LOM) the
indicates quality of the source rock in terms of producible oil, gas or resistivity-porosity log curve overlay is converted into TOC.
gas condensates. Various methods are in practice to measure LOM In ∆logR technique, two log curves such as sonic and density logs
e.g., vitrinite reflectance, thermal alteration index and Tmax, or estimated with respect to resistivity log curve are plotted against depth of
using burial and thermal history of the basin (Rezaee and Chehrazi, investigation. The overlay of the two log curves indicates to the baseline
2005). In the presence of core samples, Rock – Eval prolysis technique and the corresponding log value at this overlay is called baseline
(Shiri et al., 2013; Kadkhodaie and Rezaee, 2017) is used to identify resistivity (Rb), baseline sonic (Dtb) and baseline density (rb). The
type and LOM of organic matter in shales. LOM determines the source baseline represents the boundary between organic and non-organic
shale interval. The separation between baseline value and
corresponding log value is defined as ∆logR that is directly related to
TOC as demonstrated in Eq. 1 and 2.
σ = 0.5 (VP2 – Vs2 ) / ( VP2 – Vs2 ) (9) Table 2. Level of thermal maturity with respect to vitrinite reflectance of
Sembar Shale encounterted in study wells computed by using Hood et al.
Where µ is shear modulus, ρ is density g/cm3, K is bulk modulus (1975) maturity table.
and σ is the Poisson’s ratio. The elastic properties of all these Well Vitrinite Level of Thermal
constituents used in rock physics model are given in Table 1. name reflectance maturity maturation
(%Ro) (LOM)
Table 1. Elastic properties of different constituents of shale gas reservoir used S-01 0.87 10 Oil window
in rock physics modeling (Mavko et al., 2009) K-01 1.21 11.2 Wet gas window
D-01 1.03 10.8 Oil window
Density Bulk modulus Shear modulus
Kh-01 0.66 9 Oil window
(g/cm3) (GPa) (GPa)
Quartz 2.65 37 43 Table 3. Log derived porosities of the Sembar shales intervals encountered in
Clay 2.5 21.5 9 four wells of the study area.
Dolomite 2.85 95 45 Well Name Depth interval (m) Porosity range
Kerogen 1.4 6.8 2.02 K-01 3800 – 3860 0.06 – 0.14
Oil 0.7 0.6 0 Kh-01 1900 – 1990 0.08 – 0.16
Gas 0.12 0.06 0 D-01 3600 – 3870 0.08 – 0.13
Water 1.04 2.25 0 S-01 3420 – 3490 0.03 – 0.14
Fig.6. (a) Interpreted seismic section showing reflector of Sembar Shales, (b) Reflections strength showing signature of shale layers and (c)
Phase section showing internal layering within shaly section, the western end of the study.
(c) (d)
Fig.7. TOC computation and demarcation of organic-rich intervals in the Sembar shales by using density/resistivity logs overlay for wells
(a) S-01, (b) D-01, (c) K-01 and (d) Kh-01 respectively.