B.Tech. 'Ihird Semester (Iood, Pulp.

& Paper, Oil & Paint, PeEo Technology) (CGS)

r1002 - Applied Physical Chemistry - II : 3 CT 02
l'. Pages: 2 AT - 2122
'Iime : rhree llours ll|'
[]l|,4ill$N Max. Marks : 80

Notes : l. Answer lhree questio[ Iiom Section A ard ahree question from Section B
2. Duc credit will be given to neatness add adequate dimeosions.
3. Assume suitable data whercver necessary.
4. Illustrate your answer necessary with the help ofncal sketches.
5. Discuss the reaction, mechanism wherever necessary.
6. Use ofpen Illuc/Black inkirefill only for *riting the arswer book.
SEC'TION - A
l. a) Derivc the formula for weight average molecular $eight of macromolecules. 5

b) Explain what is the effect of struclure on properties ofmacromolecules 4

c) Define. 4
i) lntrinsic viscosit,y. ii) Osmosis
OR
2. a) Cive the applications ofdoped conducting polymers. 4

b) How molccular weight ofmacromolecules is determine by viscosity measwement 5

method.

c) How macromolecules are classified. 4

3. a) State thc principle ofpotentiometic titration. Explain the determinalion ofNeutralization 5

point oftitration between strong acid and strong base.

b) What is the effect ofdilution ofan electrol,,tic solution on specific and equivalent {
conductance?

c) 'lhe EMf ofconcentration cell: {

PbiPbsoa lCusoa(at = 0.022)iCuSOl(a t 0.0064) lPbSO4 lPbis 0.Ql l8 v at 298k
Calculate the transference number ofcopper ions.
OR
{. a) tlow hydrogen ioo concentration is determined. 5

b) tlow activity and activity coemciem zLre dctcrmined. 4

c) Derivo Nernst equation 4

5. a) What is Gibb's free energy? Derive Gibb's Helmholtz equation 6

b) Define. 4
i) Work tunction. ii) Chemiccl lotential

c) show that 1Y(r-l) = a6n5s1t;

t
*here , = !P.
Cv
OR

AT - 2122 I P.T.O
6. u) Gire thc pressure-volume and volume-leittpcrature relationship for ideal gas. 6

b) State first law ol-thcrmodynimic 1

c) Explain Camor cycle and deive cquation ,bI efficienc) ofhcar engine. l
SECTTON - I]
a) Whal is quantum yieldl Describe thc expcrirnental method ofdelermination ofquantum 5
yield.

b) Givc the application of lR-spectroscop) t

c) l)istibguish photo-chenrical reaction tom thermal rcaction I
OR
8 a) Give thc applicalion oINMR spcctroscop). 4

b) Ho*'moment ofincflia is d('tcrmincd-

c) L,xplain \\ilh e\crnlle. Pholoch,jmi(al rca.jlron.. I

9 a) Derive an integrated rate oquation olspecitic rete constant for second ordcr reactiorl in 5
which rcactants have unequal irdtial conccntmtion.

b) Explain the Ostwald's isolation mcthod. 4

. c) I'talfJifc disintegration oi mdium is I 590 years. Calculate th. rate constant in S 1 and also I
how many years will be laken for disinteSration 01 707o.

10. a) Show that,

tt/2 = conslant; firr tirst order reaction

b) Write the chaBclcristics oizerc orcler ,reit cl ions J

c) Detine Kn and K* and .lL-rive their inter-rclation d

11. a) State the importart characteristics ofcatalyst 6

b) Derive BIT equation. 1

c) Delinc. {
i) Auto catalyst. ii) Chemisorplion.
OR
12. a) o* surface area offrnc poudcr is determine by BET adsorption isotherm 6

b) How adsorption arc classified. 1

c) Explain $e conccpt ofacid basc catalysis- I

AT - 2r22