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Keywords:
Introduction:
Davidovits [1988] proposed that an alkaline liquid could be used to react with the silicon (Si)
and the aluminium (Al) in a source material of geological origin or in by-product materials
such as fly ash and rice husk ash to produce binders. Because the chemical reaction that takes
place in this case is a polymerization process, he coined the term "Geopolymer to represent
these binders. Research is shifting from the chemistry domain to engineering applications and
commercial production of geopolymer concrete.
Unlike ordinary Portland / Pozzolana cements, geopolymers do not form C-S-H gel
(calcium-silicate-hydrates) for matrix formation and strength, but utilize the
polycondensation of silica and alumina and a high alkali content to attain structural strength.
There are two main constituents of geopolymers, namely the source materials and the alkaline
liquids. The source materials for geopolymers based on alumina-silicate should be rich in
silicon (Si) and aluminum (Al). These could be natural minerals such as kaolinite, clays, etc.
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Alternatively, by-product materials such as fly ash, GGBS, silica fume, slag, rice-husk ash,
red mud, etc can be used as source materials. The choice of the source materials for making
geopolymers depends on factors such as availability, cost, type of application, and specific
demand of the end users. The alkaline liquids are from soluble alkali metals that are usually
sodium or potassium based. The most common alkaline liquid used in geopolymerization is a
combination of sodium hydroxide (NaOH) or potassium hydroxide (KOH) and sodium
silicate or potassium silicate.
Objectives:
Objectives of the project are summarized as follows:
Methodology
Geopolymer tiles:
The present study involves the manufacturing of geopolymer tiles using geopolymer.
Flexural strength, water absorption, abrasion resistance of the tiles will be tested.
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Retrofitting of concrete structures using gp (gp-frp):
Tests on tiles:
• Modulus of rupture.
• Water absorption.
• Abrasion resistance.
1. Modulus of rupture:
The values of modulus of rupture of tiles are shown in table 5.1.The tiles manufactured
using different molarities of NaOH solution and solution-to-binder ratio are tested in
testing machine and the values of breaking load are noted. Then the modulus of rupture
is calculated using the above formula. It is found that for molarity 10M and solution-to-
binder ratio 0.35 the modulus rupture of tile is 16.3 Mpa which is more than the required
as per IS 13754:1993.
The values of water absorption of tiles are shown in table 5.2.The dry weight of tiles are
noted down and are kept in a container completely filled with water for 24 hours. And
after 24 hours tile is taken out and weighed. Then the water absorption is calculated
using the above formula. It is found that for molarity 10M and solution-to-binder ratio
0.35 the water absorption of tile is 7.23% which is in the range of 6-10% as specified in
IS 13754:1993.
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3. Abrasion test:
The values of abrasion resistance of tiles are shown in table 5.3.The loss in mass of
specimens is noted down after the experiment. Then the loss in volume is calculated
using the above formula. Abrasion resistance is expressed in terms of loss in volume. It
is found that for molarity 10M and solution-to-binder ratio 0.35 the abrasion resistance
of tile is 462 mm3 which is less than 540 mm3 as specified in IS 13754:1993.
Conclusion:
Manufacturing process of geopolymer tiles is simple and easy compared to
conventional tiles.
Extra water added to mixture is important parameter which governs the surface
finish.
The percentage increase in axial load for confined cylinders as compared to UCC
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is 114.7% for a maximum axial shortening of 8.0 mm.