CBSE TEST PAPER-04

CLASS - XII CHEMISTRY (Chemical Kinetics)

[ANSWERS]

Topic: - Half life period Temperature dependence.

1. Hydrolysis of ethyl acetate when concentration of water is very large , is an example of

pseudo first order reaction.

CH3COO C2H5 + H2O → CH3 COOH + C2H5OH.

2. For a first order reaction , the half life period is

0.693
T1/2 =
k

0.693
3. t1/2 =
k
0.693
= −14
= 1.26 × 1013 s
5.5 ×10 sec -1

4. 0.011 55 min-1

2.303 [ R ]o
5. t= log
k [ R]
2.303 2 × 10−3
= log
3 × 10−2 min -1 5 × 10−4
2.303
= log 4 (log 4 = 0.6021)
3 × 10−2
= 46.22 min.

6. Arrhenius equation
K = A e –Ea/RT
Where K = rate constant , T = absolute temperature
Ea = Activation energy, R = gas constant.

7. K = A e-Ea/RT
When Ea = 0
K = A e -0/RT

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 = A. e0
K=A
∴ Rate of reaction will not depend upon the temperature if activation energy is
zero.

8. T1 = 295K T2 = 305K
 TT   k 
Ea = 2.303 R  2 1   log 2 
 T2 − T1   k1 
K2 = 2k1
 305 × 295  2k
Ea = 2.303 ×8.314 ×   log 1
 305 − 295  k1
= 2.303 × 8.314 × 8997.5K log 2
= 51855.2 J/mol (log2 = 0.3010)

9. 22.0 KJ/mol.

10.

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