1. Calculate or sketch titration curves for the following acid–base titrations.

a. 25.0 mL of 0.100 M NaOH with 0.0500 M HCl

b. 50.0 mL of 0.0500 M HCOOH with 0.100 M NaOH
c. 50.0 mL of 0.100 M NH3 with 0.100 M HCl
d. 50.0 mL of 0.0500 M ethylenediamine with 0.100 M HCl
e. 50.0 mL of 0.0400 M citric acid with 0.120 M NaOH
f. 50.0 mL of 0.0400 M H3PO4 with 0.120 M NaOH
5. Tartaric acid, H2C4H4O6, is a diprotic weak acid with a pKa1 of 3.0 and a pKa2 of 4.4.
Suppose you have a sample of impure tartaric acid (purity > 80%), and that you plan to
determine its purity by titrating with a solution of 0.1 M NaOH using an indicator to signal
the end point. Describe how you will carry out the analysis, paying particular attention to
how much sample to use, the desired pH range for the indicator, and how you will calculate
the %w/w tartaric acid.

6. The following data for the titration of a monoprotic weak acid with a strong base were
collected using an automatic titrator. Prepare normal, first derivative, second derivative, and
Gran plot titration curves for this data, and locate the equivalence point for each.

Volume of NaOH pH Volume of NaOH pH

(ml) (mL)
0.25 3.0 49.95 7.8
0.86 3.2 49.97 8.0
1.63 3.4 49.98 8.2
2.72 3.6 49.99 8.4
4.29 3.8 50.00 8.7
6.54 4.0 50.01 9.1
9.67 4.2 50.02 9.4
13.79 4.4 50.04 9.6
18.83 4.6 50.06 9.8
24.47 4.8 50.10 10.0
30.15 5.0 50.16 10.2
35.33 5.2 50.25 10.4
39.62 5.4 50.40 10.6
42.91 5.6 50.63 10.8
45.28 5.8 51.01 11.0
46.91 6.0 51.61 11.2
48.01 6.2 52.58 11.4
48.72 6.4 54.15 11.6
49.19 6.6 56.73 11.8
49.48 6.8 61.11 12.0
49.67 7.0 68.83 12.2
49.79 7.2 83.54 12.4
49.78 7.4 116.14 12.6
49.92 7.6
1.a. 25.0 mL of 0.100 M NaOH with 0.0500 M HCl
NaOH + HCl  NaCl + H2O
M 2,5 mmol x
R OH- = 2,5 mmol
S V = n/M
OH- = H+ V = 2,5 mmol/0,05 M
H+ = 2,5 mmol V HCl= 50 mL

b. 50.0 mL of 0.0500 M HCOOH with 0.100 M NaOH

HCOOH + NaOH  HCOONa + H2O

M 2,5 mmol x
R
S
OH- = H+ V = n/M
H+ = 2,5 mmol V = 2,5 mmol/0,1 M
OH- = 2,5 mmol V NaOH= 25 mL

c. 50.0 mL of 0.100 M NH3 with 0.100 M HCl

NH3 + HCl  NH4Cl
M 5 mmol x
R
S
OH- = H+ V = 5 mmol/0,1 M
H+ = 5 mmol V HCl= 50 mL
V = n/M

d. 50.0 mL of 0.0500 M ethylenediamine with 0.100 M HCl

+ 2 HCl  2 NH4Cl + C2H6

M 2,5 mmol x
R
S
OH- = H+ V = n/M
H+ = (2,5 x 2) mmol V = 5 mmol/0,1 M
H+= 5 VHCl= 50 mL
 e. 50.0 mL of 0.0400 M citric acid with 0.120 M NaOH
+ 3 NaOH  C6H5O7Na3 + 3 H2O

M 2 mmol x
R
S
OH- = H+ V = n/M
OH- = (2 x 3) mmol V = 6 mmol/0,12 M
OH- = 6 mmol V NaOH= 50 mL

f. 50.0 mL of 0.0400 M H3PO4 with 0.120 M NaOH

H3PO4 + 3NaOH  Na3PO4 + H2O
M 2 mmol x
R
S
OH- = H+ V = 6 mmol/0,12 M
OH- = (2x3) mmol V NaOH= 50 mL
V = n/M

5 Asam tartarat, H2C4H4O6 , adalah asam lemah diprotik dengan ap K a1 dari 3.0 dan
ap K a2 dari 4.4. Misalkan Anda memiliki sampel asam tartarat tidak murni (kemurnian>
80%), dan Anda berencana untuk menentukan kemurniannya dengan melakukan titrasi
dengan larutan 0,1 M NaOH menggunakan indikator untuk menandai titik akhir. Jelaskan
bagaimana Anda akan melakukan analisis, memberikan perhatian khusus pada berapa banyak
sampel untuk digunakan, kisaran pH yang diinginkan untuk indikator, dan bagaimana Anda
akan menghitung% w / w asam tartarat.
Untuk melakukan analisis kita terlebih dulu harus memperkirakan pH saat titik ekuivalen
agar dapat menggunakan indikator yang tepat.
Semisal terdapat 100 mL H2C4H4O6 tidak murni, Mr= 150, berarti H2C4H4O6 yang ada
sebesar 80 mL atau 80 gram.
n H2C4H4O6 = 80/150
n H2C4H4O6 = 0,53 mol
H+ yang terurai =
=
=
H2C4H4O6 + 2NaOH ↔ Na2C4H4O6 + 2H2O

M 0,53
R
S

𝑘𝑤 𝑥 𝑀
garam dari asam lemah dengan basa kuat akan bersifat basa, [OH-]=√ 𝑘𝑎