Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Main Date: 01-04-19
Time: 09:00 AM to12:00 Noon CODE-A Max.Marks:360
KEY SHEET
CHEMISTRY
1 1 2 4 3 1 4 4 5 1

6 1 7 3 8 2 9 4 10 3

11 3 12 2 13 1 14 2 15 1
16 2 17 4 18 1 19 1 20 2

21 1 22 4 23 1 24 1 25 1

26 3 27 2 28 4 29 1 30 4

PHYSICS
31 4 32 2 33 4 34 1 35 4

36 2 37 2 38 4 39 3 40 4

41 3 42 2 43 3 44 2 45 2
46 1 47 2 48 2 49 2 50 2

51 3 52 2 53 2 54 1 55 3

56 4 57 2 58 3 59 2 60 2

MATHS
61 1 62 3 63 3 64 2 65 1

66 2 67 2 68 4 69 2 70 3

71 3 72 3 73 2 74 3 75 4
76 1 77 4 78 4 79 4 80 2

81 2 82 1 83 2 84 1 85 2

86 1 87 2 88 4 89 2 90 2
Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
SOLUTIONS
CHEMISTRY
H 3.5 103
T   350 K
1. S 10

T > 350 k then G  ve, reaction is spontaneous

2. Conceptual
3. en bidenatate ligand CN 
cc
4. LiAlH 4 reduces
–COOH,-CHO,-CN, and a also provided it is in
conjugation with benzene ring and a carboxylic group
E 0 Cell  ve , so G 0  nFE 0  ve
5. G 0   RT ln e k
 G 0   ve , so k  1

rc
 0.732  0.999
6. ra
rc  0.732  ra  146.4 pm

7. Conceptual
0.059V
ECell  log K c
8. 2

0.059V
0.46V  log K c
2
0.46V  2
 log Kc   15.6
0.059V
K c  Anti log 15.6   3.98  1015
9. Atomic size decrease, Electro negativity increase
Br H


 Br 


10. is aromatic and stable and backward reaction of ionization
H


is suppressed. So AgBr is precipitated. formed from 1 is anti aromatic

and unstable. And ionization is reversible

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
2 and 4 are stabilized by resonance and de generate carbocation and Br  .

1
11. E  w0  mv 2
2
hc hc 1 2
  mv
 0 2

1 2 1 1 
mv  hc   
2   0 

2hc  1 1 
v2    
m   0 

2hc  0   
v  
m  0  

12. Due to acidic hydrogen  C  C  H  present it gives ethane with C2 H 5 MgBr .It

decolorized Br2 / H 2O as

C C

It has bond as well as C  C 

1) has no acidic atom

3) Has no double bond
4) Cannot react with both RMgx as well as Br2 / H 2O

13. The lone pair of (b) is a part of aromatic sextet. The lone pair of (c) is not a part
of aromatic sextet, but when donated interrupts cyclic delocalization of  -
electron cloud lone pair of (a) is free from conjugation and can be donated
14. Conceptual
15. Inert pair effect
16. G 0  2.303RT log K

 2.303  8.314  298  log 1.7  107 

= -41.2 kJ
17. Calcinations is the process of heating the ore below its melting point can absence
of air to remove volatile Impurities
MgCO3  MgO  CO2

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
18. Only unsubstituted amides give Hoffmanns’ hypobromite reaction 4) is not an
amide
19. Liquid dispersed in gas

HO  C   CH 2 5  NH 2 C   CH 2 5  N
n
O O H
20. X is . So Y is
21. NaCl Glucose
i1  i i2  1
1   2
i1C1RT  i2C2 RT
i1C1  i2C2
1.2 1 7.2 1
i1    1  ; i1  1.95
58.5 vlitres 180 vletres
22. H 2O2 KMnO4
nf =2 
n f  5  MnO4 
 Mn 2 
N1V1  N 2V2

n  meq I =  nmeq II

N1  100 =100 1 5
N1  5 N
H 2 O2 Vs MnO4 .  n f   3  MnO4  MnO2 
MnO4

N1V1  N 2V2
5  10  1 3 V2 
500
V2  ml
3
23. Suppose the initial concentration in the first case is
a mol L1.Then  A0 1  a,  t1/ 2 1  50 min
a
 A0 2  ,  t1/ 2 2  25 min
2
We know that for a reaction of nth order
1
t1/2  n 1
 A0 
n 2 n 1
 t 1  A0 2
 1/2 
  A0 2 
 
 t1/ 2  2  A0 1n1   A0 1 
Substituting the values, we get

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
n 1 n 1 1 n
50  a / 2  2 1 2
  or    
25  a  1 2 1
Or 1-n = 1 or n = 0
Hence, the reaction is of zero order
24. Conceptual


OCH 3 OCH 3
Br  Br
25.
Br Br
Br

 Cl 
OCH 3 OCH 3
Cl
OCH 3

26. It is Fridel crafts acylation

AlCl3 

 HCl
  OH
Tautomerisation

Cl C

O O
OH
Zn


27. Conceptual
28. Cysteine contains S-atom.
proline is a secondary amine
2 -amines doesnot give carbylamine test
3
2
NH
3 3
 en 2 Co Co  en  2

OH
1
29.
30. Reactions of KMnO4

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s

PHYSICS
31. Using 2nd eq. Of motion
1
S  ut  a.t 2
2
1
 3i  4 j 5  . i  j .25
   
2

= 15i  20 j  12.5i  12.5 j

= 37.5i  32.5 j
s  r2  r1

 r2  37.5i  32.5 j  2i  6 j

= 39.5i  38.5 j

2 2
r2   39.5   38.5  55m

yx c
32. 
z  x 100
5 x0 4 x0

3 3  c
4x
2 x0  0 100
3
x0
3  c
2 x0 100
3

C= 500 C
I
33. Figure of merit = 0.004 A/div

1 1 
C.s =  
Fom 0.004 1

I = 0.004
I g max  0.04  50
 4 10 3  50 101
 20 10 2  0.2

V= IR
20 = 0.2 [30+R]

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
100= 30+R
R= 70
R1 30 3
34.  
R2 70 7

R1  10
1
R2

R1  10  R2

3 R2
 10  R2
7
12.5 R
12.5  R  3
17.5 7

R = 20 
35. Applying parallel axes principle
2m.R 2  MR 2 
IOO1  2  MR 2 
2  4 

MR 2
MR 2  2 MR 2 
= 2
7 MR 2

2

36.   rF

= Fr sin 
12.5 = 5.5 sin 
125 1 
Sin  =  
25 2 6

eN 2 A N
37. L  is co n s t
l l

3 2
l 2. a
N l  4 L la 2
l
dp dp
38. F kt 
dt dt
dp  k .t.dt

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
4p t

 dp   k.t.dt
p 0

KT 2
3P 
2
6p
T2 
k

6p
T
k
I
39. x
H

magnetic moment 25  10 6
I  3
Volume 102 
I 25 106 106
X 
H 50 103

 0.5  103

 5  10 4

g1
40. 
l
 1 g
 .
 2 g

1 g
  . 
2 g

g   2 , A

 1 12 A1
 ,
 2 g

1 4  102
 
2 10

= 2  10 3 rad/s

v v 12
41. D1 , D2 semi i  600 i    0.02
R R 600
42. U   PE cos  U= 2 10 19  1500 cos 450

2  1500 1019 2 15 1017

  = 15 2 1017 J
2 2

Sec: Sr. ICON ALL Page 8

Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
43. mb sb  600  T   M w SW T  27   M C S c T  27 
0.5  400  600  T   0.60  4200 T  27   800 T  27 
200(600 – T) = 0.6.  4200 . T  27   800 T  27 
(600-T) = (0.6) (21) (T-2) + 4(T-27)
= T-27 [12.6+4] = (T-29).(16.6)
= 600+448.2 = 17.6 T
T = 60
mV Bqr Bqd
44. r V 
Bq m m

K1 g 1 g 2 2 1
45. Max K .E  m 2 A2   A  L , KE  m   L   mgL 2
2 l 2 L 2

1 3
Length is tripled K2  mg  3 L   22  mgL 22 1   2
2 2
1
mgL 2
K1 2 3 1
 K1  K 2 K 2  3K1
K 2 3 mgL 2 2 2
2

46. changing in length in both rods are same

l   l   l11   1  l2 2   2

5   200  40    T  30  4

5  160
5 160  T  30   4 T  30   2000 C
4
x y 2 2
47. K  V x F y A Z ML1T 2   2T 1   MLT 2   LT 
Comparing the powers of x,y,z
48. 
80  2   mr 2  m2    160  m 1  10 
2

80  f 2  10a

80  f 2  10a

160  20a

8a

a  R
8  1 
8

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
P 1 2p 2  30 103  36 109
49. l  0 E02 C  E0  
A 2 0 Ca 3 108 15 10 6

1 2 3
 
1 2  3
50. V0 B 1 1 1  2V
1 1 1 3
 
1 1 1

l lR 2 R2 R
51. T  2  2 T 
g GM m m

T1 R 1 M2 5 2m R 1
   .  2.  T  5 2 sec.
T2 R2 M1 T m 2R 2

52. Equation of AM wave is

 AC  Am sin  m t   sin  ct 

Am  Ac  7
Am  Ac  3
From the fig
Am  5, Ac  2

1 1
m  2   2   2 105
Tm 10  s

1 1
c  2   2   4  104
Tc 5 s

So answer is 5  2sin  2  105 t   sin  4  104 t 

 

53. Given VT = Const. WKT PV  nRT

PV PV
V  const T 
nR nR

PV 2  const  x  2 polytropic

R
Cx   CV
1 x
R 5 5 3R
=  R  RR 
1 2 2 2 2
3R 3
Q  ncx T  1.  T  RT
2 2

54. 50 g 1000 C  10 g  750 C  800 C

A B

50  S A  100  80   10  S B   80  75

 50  S A  20  10  SB  5  SB  20S A

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
1 1 1  1 1 
55.  K  2  2   k    ...........1( Mto N )
 3 4   9 16 

1  1 1 1 1
1
 K  2  2   k    ...........2 ( Nto L)
 2 3  4 9

1  1 16  9  / 16  9 7 7 7
     1 
2   9  4  / 9  4 4  5 20 20


56. i=e r1  r2   300 (For min deviation)
2
1 1
1 sin i  2   I = 450
2 2

57. For max intensity on screen

d sin   n
n 2000 n
sin   n 
d 7000 3.5

Max value of sin  = 1

N = -3,-2,-1,0,1,2,3  7 maximas
58. 3  3 cap in parallel 4+4+4=12
4 4
4  F is series with 4  F   2 F
8
12  2 12
12  F & 2  F in series =  F
14 7

59. 
I net  qE  g u  B 

 g  3i  4 j   g u  B 
  Fnet .S  3q  4q  7q

hc
60.    eV1 ……………………………..1
1

hc
   eV2 …………………………..2
2

1=2
1 1
hc     e  v1  v2 
 1 2 

 1 1  200
 1240      1240   3.1V
 200 400  200  400

Sec: Sr. ICON ALL Page 11

Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
MATHS
tan x  y sin x  x cos x  0 
61. lt 2
 lt 2  form 
x 0 x tan x x  0 x sin x  0 
1
= using L1 hospital rule 
3

62. Tan 1
x  1 Tan 1 x   3)  0

   
As Tan 1 x   , 
 2 2

So, Tan 1 x  3  0x

Thus, Tan 1 x  1  0  Tan 1 x  1

x    , tan1

2b 2
63. Length of latus rectum 8
a

b 2  4a
1
2b  2ae
2

2b= ae
Now b 2  a 2  e2  1  3b 2  a 2

4b 2 2
e  2

3b 3

64.
y
C  at , 2at 
2

x
 0, 0  A

B  a 2a 
 2, 
t t 

Difference of the ordinates

2a 1
d  2 at   2a t 
t t

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
at 2 2at 1
1 2 a  1
Area  a / t2 1  a 2 t  
2 t  t
0 0 1

 1  2
2a  t   
 t a

But according to the question the distance of B & C from the axis of the parabola

is 
a

  2
x 5 y 7 z  2
65.    r1  say 
3 1 1
x 3 y 3 z  6
   r2  say 
36 2 1

X= 3r1  5  36r2  3

Y= r1  7  3  2r2

And z  r1  2  4r2  6

On solving we get
5 10
X=21, y  ,Z 
3 3

66. Contrapositive of P  q is given by  q  p

67. A(2,0) ,B(0,2) ,C(4,6) midpoint of BC is D(2,4) , equation of AD is x = 2

x/ 4
sin 2 x
68.   2{ sin 2
dx
0  2
x  cos x   2sin 2 x.cos 2 x}
2


4
sin 2 x
I dx
0  sin 2 2 x 
2 1 
 2 

4
sin 2 x
 dx put t  2 x
0
1  cos 2 2 x

1  /2 
= Tan 1  cos t   
2 0 8

Sec: Sr. ICON ALL Page 13

Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
xc
69. y
x 2  3x  2
Disc  0 y
Disc  0

1 c  2
n
2
70. x   r  n Cr  ; n  10
r 0

n n 1
n
x  n Cr C r 1
r 0

n  n 1
n
x  n  Cn  r C r 1
r 0

x  n.2 n 1 cn 1 ; n  10, x  10.19 c9

x 1 19
 . c9  646
1430 143

71. 8 x 2  10 x  3  0

 2 x  1 4 x  3  0
1 3
x ,
2 4
1 1
  , 
2 4

1 1 1 1
  n   n      24  6
n 0 1   1  1  1  1 3
2 4
40 2
72. P = probability of getting black ball  
60 3
2
 q  1 p  1  1 / 3 & n  15
3

 Mean = np= 15  2  10
3

Mean 1
 3
variance q

73. z  z  3  2i

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
2 2
z   z  3  4

2 2
z  z 6 z 94

z  13

z  13 / 6

3 1 3
1 1 1
  
 q r s t  1 2 3
74.  4  p   2  3  4    4 1 2 1 1
        
3 4
1 2 1 3
 

Taking limit as  tends to 

1 1 1
P= 1  1 1  4
1 1 3

75. c   b  c
 
76. 28th term of A. P is = 0
a+27 d = 0  a  27d ……………………..1
72th term a  71d 27 d  71d 44d 4
Now    
39th term a  38d 27d  38d 11d 1

2
77. Put 3x  5  t 2  dx  t.dt
3

2t 2
 G.I   dt
2t 2  13

 13 
  1  2  dt
 2t  13 
13 1
t dt
2   13 
2

t2   
 2 

13  2 
t tan 1  t   C
2  13 

13  2 
= 3x  5  .tan 1  . 3 x  5   C
2  13 

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
13 2
K1  , K2 
2 13

 K1 K 2  1

78. f is not 1-1 as f(0) = 0 & f( -1) =0

f is also not onto as for y = 1
79. f  x    x  1 x  2  x  1 x  2 cos x

cos x  cos x x 0

  cos x x 0

h  x  x x is differential at x = 0

 x  1 x  1 is differentiable at x = 1
Also f(x) is not differentiable at x = 2
dy
80. y  ex  ex
dx
dy
1,e
 e1  e
dx

Eq.. tgt at (1,e) with scope m =e

y-e = e(x-1)
 ex  y  0
1
Area bounded =  e x dx  1 1 e
2 

1 e
e x  
 2
y

1, e 

 x
1, 0 

e e e
e1  e    e  0  =
2 2 2

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Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
81. 2  a  b  c   24k  a  b  c  12k

 a  5k b  4k , c  3k

16  9  25
CosA  0
24
25  9  16 3
CosB  
30 5
25  16  9 4
Cos C  
40 5

(p,q,r) = (0,3,4)
dy 2 dz
82.   x  y   1 z2
dx dx
dz
  dx Put x+y = Z
1 z2 
dy dz
 tan 1 z  x  c 1  
dx dx
 tan 1  x  y   x  c
Sub x= 0, y=1
  
 c solutoinis x  y  tan  x  
4  4
2b2
83.  10  b 2  5a and 2ae  2b
a

a 2  a 2e2  5a a 2e2  b 2

a  ae2  5  a 2e2  5a  ae2  5

x2 y 2
Now a= 10 and b 2  50  
100 50
1 The point on the ellipse is 5 2,5 
84. s= {1,2,3……..30] sum of the elements in s = 465
B=subset of s such that sum of the elements = 459
B not contain 6 or (1,5) or (2,4) or {1,2,3}
4
So no of possible subset of s = 4 Req. prob =
230
x2 y z 1
85. Eq. of the plane is 1 3 3 0
1 2 1

 3  x  2   2  y   1 z  1  0

3x+2y+z-7 = 0
Sec: Sr. ICON ALL Page 17
Sri Chaitanya IIT Academy 01-04-19_Sr.ICON ALL_JEE-Main_GTM-2_Code-A_Key & Sol’s
Sub (  2,  ,   then 2    1
30 30
86.  x  5   x  5   a0  a1 , x  a2 x 2  ..............  a30 x 30

a0  a1 , x  a2 x 2  .............a30 x 30

 2  30 C0 x30  30 C2 x 28 .52  ...... 30 C30 530 

a0  2.530 , a1  0, a2  230 C2 .528

30
C2 .528 15.29.528 15.29 87
‘ a2    =
a0 530 530 25 5

87. f(k) = 4 m ( 4,8,12,16,20 }

For k = 5,10,15,20
5
Thin can be done in P4 ways and remaining 16 elements can mapped to the
16 elements in 16! ways
Total no. of ways = 5!,16!
88. Let the eq. of the circle is x 2  y 2  2 gx  2 fy  c = 0
It passes through (0,4b)
 16b 2  8bf  c  0..........1

2 g 2  c  8a  g 2  c  16a 2

c  g 2  16a 2 substituting in (1)

16b 2  8bf  g 2  16a 2  0

Locus of the (g,f) is

 x 2  8by  16  b 2  a 2   0 represents a parabola
ax x
89 f x   f '  x   0x
2
b2   a  x  c  x2
2

f is decreasing for all xR

2 A 3
90. A B  100 and  10  A  1000
B

2 1 1
 A  10 and B  1  BAT BT  B A1  1. 
10 10

Sec: Sr. ICON ALL Page 18