WWW.IITVIDYA.

COM STOICHIOMETRY
1. For the redox reaction, 7. On repeated combustion 10 ml of a
2
HBiO3  Mn  MnO4  BiO  .......  ....... mixture of carbon monoxide and nitrogen
required 3 ml of oxygen for combination.
(equation not balanced), the correct What was the was the volume of
coefficient of the reactants and products nitrogen? [All volumes are measured
for the balanced chemical equation are : under identical conditions]
HBiO3 Mn2+ H+ (a) 7/2 ml (b) 4 ml
(a) 5 2 2 (c) 7 ml (d) 17/2 ml
(b) 2 5 2 8. How many grams of phosphoric acid
(c) 5 2 1 would be needed to neutralize 100 g of
magnesium hydroxide? The molecular
(d) 5 1 2
weights are H3PO4 = 98 and Mg(OH)2 =
2. HNO3 oxidises NH4 ions to nitrogen 58.3).
and itself gets reduced to NO2. The moles (a) 66.7 g (b) 252 g
of HNO3 required by 1 mol of (NH4)2SO4
(c) 112 g (d) 168 g
is
9. A mole of potassium chlorate is
(a) 4 (b) 5
thermally decomposed and excess of
(c) 6 (d) 2 aluminum is burnt in the gaseous
3. Weight of one atom of an element is product. How many moles of aluminium
oxide are formed?
10 1023 g. The number of gram atom of
(a) 1 (b) 1.5
element in 60 kg is N0  6.02 1023
molecule) (c) 2 (d) 3
10. 1 mole of N2H4 loses ten moles of
(a) 0.99 (b) 9.9 102 electrons to form a new compound Y.
(c) 1103 (d) 3.6 103 Assuming that all the nitrogen appears in
the new compound, what is the oxidation
4. To 10 ml of baryta solution 20 ml of 0.1 state of nitrogen in Y? (There is no
NH2SO4 was added and the excess acid change in the oxidation state of
required 4 ml of 0.1 N NaOH. The hydrogen).
molarity of baryta Ba(OH)2 solution is
(a) –1 (b) –3
(a) 0.1 M (b) 1.6 M
(c) +3 (d) +5
(c) 0.04 M (d) 0.08 M
11. A mixture of CH4, N2 and O2 is enclosed
5. The amount of wet NaOH containing n a vessel of one litre capacity at 0°C.
15% water required to prepare 70 litre of The ratio of partial pressures of gases is
0.5N solution is 1 : 4 : 2. Total pressure of the gaseous
(a) 1.65 kg (b) 1.4 kg mixture is 2660 mm. The number of
molecules of oxygen present in the vessel
(c) 16.5 kg (d) 140 kg is
6. The oxidation number of central metal
6.02 1023
atom in Co  NH3 5 Br  C2O4 is (a) (b) 6.021023
22.4
(a) +3 (b) +1 (c) 22.4 1022 (d) 1000
(c) –1 (d) 0 12. In an experiment 50 ml of 0.1 (M)
solution of a salt reacted with 25 ml of
 0.1 (<) solution of sodium sulphite. The (iv) Mg3N2 –3
half equation for the oxidation of sulphite
ions (a) (i) (b) (ii)

SO32  aq  H2O e  SO42 aq  2e

(c) (iii) (d) (iv)
18. The molecular formula of a non
In the oxidation number of metal in the stoichiometric tin oxides (containing Sn
salt was 3, what would be the new (II) and Sn (iv) is Sn4.44O8 . The molar
oxidation number of metal?
ratio of Sn (II) to Sn (iv) is
(a) 0 (b) 1 approximately.
(c) 2 (d) 4 (a) 1 : 8 (b) 1 : 6
13. 0.45 gm of acid (mol. wt = 90) was (c) 1 : 4 (d) 1 : 1
exactly neutralized by 20 ml of 0.5 (M)
19. How many litres of Cl2 at STP. will be
NaOH. The basicity of the given acid is
liberated by the oidation of NaCl with
(a) 1 (b) 2 10 g KMnO4?
(c) 3 (d) 4 (a) 3.54 litres (b) 7.08 litres
14. 25 ml of a 0.1 (M) solution of a stable (c) 1.77 litres (d) None of these
cation of transition metal z reacts exactly
20. The oxidation state of carbon in
with 25 ml of 0.04 (M) acidified KMnO4
potassium tetrafluoroborate is
solution. Which of the following is most
likely to represent the charge in oxidation (a) +2 (b) +3
state of z correctly? (c) +4 (d) –3
 2 2 3
(a) Z  Z (b) Z Z 21. Which of the following reaction in
neither oxidation nor reduction?
(c) Z3  Z4 (d) Z2  Z4
15. During the oxidation of (a) CrO24  Cr2O72
2 1
Mn to MnO4 by PbO2 in acidic (b) Cr  CrCl3
medium, the number of moles of acid
consumed per mole of Mn2 ion is: (c) 2S2O32  S4O62

(a) 4 (b) 1/2 (d) VO24  V2O3

(c) 2 (d) None of these 22. Which of the following reactions
16. The sum of the oxidation numbers of all hydrogen peroxide is acting as a reducing
the carbons in C6H5CHO is agent?

(a) +2 (b) 0 (a) 2FeCl2  2HCl  H2O2  2FeCl3  2H2O

(c) +4 (d) –4 (b) Cl2  H2O2  2HCl  O2
17. Oxidation state of nitrogen is incorrectly (c) 2HI  H2O2  2H2O  I2
given for
Compound Oxidation state (d) H2SO3  H2O2  H2SO4  H2O

(i) CO NH3 5 Cl Cl2 0 23. 0.116 g of C4H4O4 (A) is neutralized by
0.074 g of Ca  OH 2 . Hence protonic
(ii) NH2OH –1
 
hydrogen H in (A) will be
(iii)  N2H5 2 SO4 –2
(a) 1 (b) 2
 (c) 3 (d) 4 30. Temporary hardness is due to HCO3 of
24. During the disbraportination of I2 to Mg2 and Ca2 . It is removed by
iodine ions, the ratio of iodate land addition of CaO.
iodinde ions formed in alkaline medium
is Ca  HCO3 2  CaO  2CaCO3  H2O
(a) 1 : 5 (b) 5 : 1 Mass of CaO required to precipitate 2 g
(c) 3 : 1 (d) 1 : 3 CaCO3 is :
25. In an experiment 20 mL of a decinormal (a) 2.00 (b) 0.45 g
HCl solution was added to 15 mL of a (c) 0.28 g (d) 1.12 g
decinormal AgNO3 solution. AgCl was
precipitated 31. Hardness of water is measured in terms
of ppm (parts per million) of CaCO3. It is
(a) 10 mL (b) 20 mL the amount (in g) of CaCO3 present in
(c) 30 mL (d) 5 mL 106 g H2O. In a sample of water, 10 L
required 0.45 g of CaO the remove
26. 28NO3  3As2S3  4H2O  6AsO34  temporary hardness is:
28NO  9SO24  *H What will be the Ca  HCO3 2  CaO  2CaO3  H2O
equivalent mass of As2S3 in above
reaction Temporary hardness is:

M.wt. M.wt. (a) 200 ppm CaCO3

(a) (b)
2 4 (b) 100 ppm CaCO3
M.wt. M.wt. (c) 2CaCO3 (d) 25 ppm CaCO3
(c) (d)
24 28 32. Permanent hardness is due to SO24
27. When 0.273 g of Mg is heated strongly in Cl of Ca2 and Mg2 and is removed
a nitrogen (N2) atmosphere, 0.378 g of
by the addition of Na 2CO3
the compound is formed.
(a) Mg3N2 (b) 0.5 mol Cl2 CaSO4  Na 2CO3  CaCO3  Na2SO4
(c) Mg2N3 (d) MgN CaCl2  Na 2CO3  CaCO3  2NaCl
28. A sample of ammonium phosphate In hardness si 100 ppm CaCO3, amount
 NH4 3 PO4 contains 3.18 mol of H of Na2CO3 required to soften 10 L of hard
atoms. The number of mol of O atoms is water is:
the sample is : (a) 2.12 g (b) 0.106 g
(a) 0.265 (b) 0.795 (c) 10.6 g (d) 1.06 g
(c) 1.06 (d) 3.18 33. H2O2 reduces K3Fe(CN)6 to K4Fe(CN)6
29. 0.5 mol of BaCl2 is mixed with 0.2 mol in basic medium. In this reaction which
of  NH4 3 PO4 . Maximum number of of the following gas is evolved?
mol of barium phosphate formed in this (a) H2 (b) O2
reaction is: (c) N2 (d) (CN)2
(a) 0.1 (b) 0.2 34. One gram of a sample of CaCO3 was
(c) 0.3 (d) 0.5 strongly heated and the CO2 liberated
absorbed in 100 ml of 0.5 M NaOH.
Assuming 90% purity for the sample,
 how much ml of 0.5 M HCl would be 40. When arsenic sulphide is boiled with
required to react with the solution for the NaOH, sodium arsenite and sodium
alkali for the phenolphthalein end point? thioarsenite are formed
(a) 73 ml (b) 41 ml xAs2S3  yNaOH  xNa3AsO3 
y
(c) 82 ml (d) 97 ml xNa3AsS3  H2O. What are the values
2
35. 7 g of a mixture of KClO3 and KCl are of x and y?
strongly heated, 2.50 g of O2 are
produced. The residue on analysis proves (a) 1, 6 (b) 2, 8
to be only KCl. Calculate the weight (c) 2, 6 (d) 1, 4
fraction of KCl in the original mixture.
41. Which one of the following reactions
(a) 0.0886 (b) 0.123 involves oxidation-reduction?
(c) 0.886 (d) 0.213 (a) NaOH  aq   CO2  NaHCO3  aq 
36. In a thermit reduction 100 g of Al are
made to react with 200 g of Mn3O4. The (b) 3SiF4  4H2O  2H2SiF6  H4SiO4
reaction is (c) 3HNO2  HNO3  H2O  2NO
8Al  3Mn3O4  4Al2O3  9Mn, which
reactant is present excess? How many (d) CuO  2HCl  CuCl2  H2O
grams of Mn are obtained? [Atom
42. An element forms two different sulphates
weights ; Al = 27, Mn = 55]
in which its weight% is 28 and 37. What
(a) 44.11 (b) 144.1 g is the ratio of oxidation numbers of the
(c) 72.06 g (d) 100.22 g element in these sulphates?
(a) 1 : 2 (b) 1 : 3
37. In the equation aSn  bHCl  cHNO3
yielding SnCl4 and NO, what are a, b (c) 2 : 1 (d) 3 : 2
and c? What is the equivalent weight of 43. When one gram of hydrated metal
HNO3? chloride is heated, 0.8523 g of anhydrous
chloride is obtained. If the equivalent
(a) 4, 8, 4 ; 63 (b) 3, 8, 3 ; 31.5 weight of the metal is 68.2, which of the
(c) 3, 10, 4 ; 31.5 (d) 3, 12, 4 ; 21 formulae will not fit in?
38. A compound containing only sodium, (a) MCl.2H2O (b) MCl2.2H2O
nitrogen and oxygen has 33.33% by (c) MCl.H2O (d) MCl3.3H2O
weight of sodium. What is the probable
oxidation number of nitrogen in this 44. x g of a certain oxide of nitrogen were
compound (salt)? slowly passed over heated copper to yield
copper oxide CuO and nitrogen gas. The
(a) –3 (b) +3 increase in weight of copper was 5.33 g.
(c) –2 (d) +5 4l of N2 gas at 14°C and 754 mm were
also obtained. What is the formula of the
39. When ZnS is boiled with strong nitric
oxide?
acid, the products are zinc nitrate,
sulphuric acid and nitrogen dioxide. (a) N2O5 (b) NO2
What are the changes in the oxidation (c) NO (d) N2O
numbers of Zn, S and N?
45. Using the data of the preceding problem,
(a) +2, +4, –1 (b) +2, +6, –2 calculate (i) the value of x and (ii) the
(c) 0, +4, –2 (d) 0, +8, –1 weight of copper consumed.
(a) 5.05g, 21.15g (b) 10.1g, 21.15g
 (c) 10.1g, 10.7g (d) 5.05g, 10.7g (c) molecular weight/6
46. Two gaseous oxides of the same element (d) molecular weight/3
contain respectively 63.7% and 46.7% of
51. 5 ml of 3 N HCL, 10 ml of 1 M H2SO4 and
the element. Suggest a probable value for
the atomic weight of the element. N
30 ml of of another monobasic acid are
3
(a) 21.1 (b) 17.51
mixed and the resulting solution is made
(c) 7.01 (d) 14.03 to one litre. The normality of the mixture
47. CN is oxidized by NO3 in presence of is
acid: N
(a) N (b)
aCN  bNO3  cH  a  b NO  aCO2  5
c N N
HO (c) (d)
2 2 10 20
What are the values of a, b, c in that 52. For the reaction 2FeCr2O4 + 7Na2O2 →
order? 2Na FeO2 + 4Na2 CrO2 + 2Na2O
(a) (b) Choose the correct statement from the
(c) (d) following

48. One gram of Na3AsO4 is boiled with (a) The oxidation number of iron changes
from 3 to 2 and oxidation number of
excess of solid Kl in presence of strong
HCl. The iodine evolved is absorbed in chromium is unchanged.
Kl solution and titrated against 0.2 N (b) The oxidation number of chromium
hyposolution. Assuming the reaction to
changes from + 3 to + 6 while that of
be
iron changes from +2 to +3
AsO34  2H  2I   AsO33  H2O  I2
(c) The oxidation number of iron changes
calculate the volume of thiosulphate hypo from 2 to 3 and that of chromium
consumed. [Atomic weight of As = 75]
changes from 6 to 3
(a) 48.1 ml (b) 38.4 ml
(d) Bromine is reduced as well as
(c) 24.7 ml (d) 30.3 ml
oxidized.
49. How many grams of Zn of 90% purity
would be needed to reduce 8.5 g of 53. Which of the following statements is
NaNO3 in presence of alkali? (Atomic correct with respect to the reaction
weight of Zn = 65.4) 3Br2 + 6CO3–2 + 3H2O → 5Br– + 6HCO3–
(a) 32.2 g (b) 29.1 g + BrO3–?
(c) 19.8 g (d) 23.11 g a. CO3–2 is reduced and Br is oxidised
50. The equivalent weight of KlO3 in the b. There is no change in the oxidation
reaction number of bromine
 c. Bromine is reduced and water is
2Cr  OH3  4 O H  KlO3  2CrO4 
oxidised
5H2O  Kl is equal to
d. Bromine is reduced as well as oxidised
(a) molecular weight
(b) molecular weight/2
54. If 0.5 of BaCl2 is mixed with 0.2 mole of a contraction of 2.5 v ml and a further
Na3PO4, the maximum number of moles of contraction of 2v ml with caustic potash,
Ba2 (PO4)2 that can be formed is its formula is
(a) 0.20 (b) 0.10 (a) CH4 (b) C2H6
(c) 0.70 (d) 0.50 (c) C2H4 (d) C2H2
55. The oxidation number of oxygen in Cl2O 61. A solution containing 0.05 mole of SO2
and H2O2 are respectively Cl2 in water will be completely neutralized
(a) –2 and + 1 (b) + 2 and + 1 by

(c) – 2 and – 1 (d) + 2 and – 1 a. 50 ml of 4.0 M NaOH

56. Which one of the following compounds b. 100 ml of 1 M NaOH
has iron in its highest oxidation state? c. 50 ml of 0.5 M KOH
(a) K2FeO4 (b) K4Fe(CN6 d. 50 ml of 1 M KOH
(c) Fe(CO)5 (d) FeO2
62. An oxide MO2 of an element M contains
57. In the redox reaction 72.72% of oxygen by weight. In another
Zn + NO3– + H+ → 4Zn+2 + NH4+ + 3H2O oxide of the element, the percentage
weight of oxygen is 47.06. This oxide has
the correct coefficients for the reactants
are the simplest formula

Zn NO3– H+ (a) MO (b) M2O3

(a) 2 1 5 (c) M3O4 (d) M3O2
(b) 5 3 8 63. The oxidation numbers of oxygen in
O2PtF4 and superoxide ion are respectively
(c) 4 1 10
(d) 3 2 5 (a) – 2, – 2 (b) – 2, – 1
1 1 1
58. The red pigment in blood contains 0.32% (c)  2,  (d)  , 
iron by weight. Molecular mass of the 2 2 2
pigment is 70,000 g mol–1. The number of 64. In the redox reaction, MnO4– + I2 + H+ →
iron atoms in each molecule of the IO3– + H2O, MnO4– and I2 would react in
pigment is (atomic weight of Fe = 56) the molar ratio of
(a) 1 (b) 2 (a) 1 : 2 (b) – 2, – 1
(c) 3 (d) 4 1 1 1
(c)  2,  (d)  , 
59. An element is converted to its bromide and 2 2 2
the bromine precipitated as AgBr. Atomic 65. Which of the following is not a
weight of A = 91.2. 0.722 g of the bromide disproportionation reaction?
gives 1.32 g of AgBr. Valency of the
a. 4KClO3 → 3KClO4 + KCl
element A is (Ag = 108; Br = 80)
b. 2Cu+ → Cu2+ + Cu
(a) 2 (b) 4
c. 5X– + XO3– + 6H+ → 3X2 + 3H2O
(c) 3 (d) 5
60. If v ml of a gaseous hydrocarbon, after d. 4P + 3NaOH + 3H2O → PH3 +
explosion with excess of oxygen, showed 3NaH2PO2
66. A gaseous hydrocarbon was mixed with b. 25 ml of 0.2 M KMnO4
7.5 times its volume of oxygen and c. 25 ml of 0.6 M KMnO4
exploded. The residual gas occupied 5
times the volume of the hydrocarbon. On d. 15 ml of 0.1 M KMnO4
passing through KOH solution, there was 71. In which of the following reaction,
further contraction of 4 times the volume oxidation occurs?
of the hydrocarbon. The simplest formula
a. V2O5 to Na3VO4
of the hydrocarbon is
b. Fe2+ to [Fe(CN)6]3–
(a) C4H10 (b) C4H8
(c) C4H6 (d) C4H4 c. Cu2+ to [Cu(NH3)4]2+

67. 61.5 g of saturated solution (at 250(C) of a d. [ZnO2]2– to Zn2+

divalent metal sulphate is made upto 250 72. A 20 mL solution of Na2SO3 required 30
ml 25 ml of this made up solution mL of 0.01 M K2Cr2O7 solution for the
produces 1.357 g of dry BaSO4 with oxidation to Na2SO4. Hence molarity of
excess BaCl2. The solubility of the metal Na2SO3 solution is
suplhate at 250C in gm 100 g of water is
(a) 0.015 M (b) 0.045 M
(a) 14.2 (b) 16.6
(c) 0.030 M (d) 0.0225 M
(c) 17.4 (d) 19.2
73. Which of the following is not a
68. 1.00 g of metal oxide, when completely disproportionation reaction?
converted gave 2.33 g of the
a. 4Sn + 10HNO3 → 4Sn (NO3)2 +
corresponding sulphate. The atomic mass
NH4NO3 + 3H2O
of the metal = 90 g mol–1-. A formula that
corresponds to these results is b. 2TiCl2 → Ti + TiC4
(a) M2O (b) MO c. 3AlCl → AlCl3 + 2 Al
(c) MO2 (d) M2O3 d. 2C6H5CHO + H2O → C6H5CH2OH +
69. 0.01 mole of a compound was dissolved in C6H5COOH
water and the solution passed through a 74. The advantage of using KO2 as gas masks
high capacity cation exchange column. in spaceships is that is absorbs CO2, at the
The emergent solution required 40 ml of same time releasing oxygen. If 0.001 mole
1.0 M NaOH solution. The compound of KO2 is present in an atmosphere
could have been containing 22.4 cm3 of CO2 at STP free
a. CuSO4. 5H2O from moisture, what will be the volume of
O2 released at STP?
b. CuSO4. (NH4)2 SO4. 6H2O
(a) 22.4 cm3 (b) 11.2 cm3
c. Cu(NO3)2. 3H2O
(c) 16.8 cm3 (d) 44.8 cm3
d. CuCl2. H2O
75. If 20% by weight of nitrogen is present in
70. Which of the following solutions will a compound, the molecular weight of the
exactly oxidize 25 ml of an acid solution compound may be
of 0.1 M Fe (II) oxalate?
(a) 144 (b) 28
a. 25 ml of 0.1 M KMnO4
(c) 100 (d) 140
76. 15 ml of pure O2 is subject to silent
electric discharge, when only 10% of its is
converted to ozone. The volume of the
resulting mixture and the volume that
remains after absorption in turpentine are
respectively.
(a) 14.5 ml, 13.5 ml (b) 12 ml, 10 ml
(c) 15 ml, 13.5 ml (d) 20 ml, 15 ml
77. Three isotopes of an element have atomic
mass numbers M, (M + 1) and (M + 2). If
the mean atomic mass number is (M +
0.5), the abundance ratio of the three
isotopes given in the order is
(a) 1 : 1 : 1 (b) 4 : 1 : 1
(c) 3 : 2 : 1 (d) 2 : 1 : 1
78. 0.8 g of an organic acid of molecular
weight 192 requires 0.5 g of NaOH for
complete neutralization. The number of
replaceable hydrogen atoms in the acid is
(a) 2 (b) 3
(c) 4 (d) 1
79. A solution of 0.01 mole of a compound in
water was passed through an efficient
cation exchange column. The emergent
solution require 20 ml of 1.5 M NaOH
solution for neutralisation. The compound
may be
a. KCl. MgCl2. 6H2O
b. MgSO4. 7H2O
c. Al2Cl6. 12H2O
d. Cu(NO3)2. 3H2O
80. A mixture of 0.02 mole of KBrO3 and 0.01
mole of KBr was treated with excess of Kl
and acidified. The volume of 0.1 M Na2 S2
O3 solution required to consumed the
liberated iodine will be
(a) 100 ml (b) 120 ml
(c) 150 ml (d) 80 ml
81. In the reaction, X– + XO3– + H+ → X2 +
H2O, the molar ratio in which X– and XO–
react is
(a) 1 : 5 (b) 5 : 1
(c) 2 : 3 (d) 3 : 2
82. Hg(IO6)2. oxidizes Kl to I2 in acid medium
and the other product containing iodine is
K2Hgl4. If the I2 liberated in the reaction
requires 0.004 mole of Na2S2O3, the
number of moles of Hg5 (IO6)2 that has
reacted is
(a) 10–3 (b) 10–4
(c) 2.5 × 10–4 (d) 2.5 × 10–2
83. In which of the following reactions,
reduction occurs?
a. Cu(OH)2 + 4NH3 → [Cu(NH3)4] (OH)2
b. V2O5 → Na3VO4
c. K2Hgl4 → 2Kl + Hgl2
d. N2O → NH2OH
84. The following equations are balanced
atomwise and chargewise.
(i) Cr2O72– + *H+ + 3H2O2 → 2Cr3+ +
7H2O + 3O2
(ii) Cr2O72– + *H+ + 5H2O2 → 2Cr3+ +
9H2O + 4O2
(iii) Cr2O72– + 8H+ + 7H2O2 → 2Cr3+ +
11H2O + 5O2
The prekcise equation / equations
representing the oxidation of H2O2 is/are
(a) (i) only (b) (ii) only
(c) (iii) only (d) all the three
85. H2O2 differs O3 in the reaction
a. Oxidation of PbS to PbSO4
b. In liberating I2 from Kl
c. In decolourizing acidified KMnO4
d. In oxidizing K4Fe(CN)6 to K3Fe(CN6)
86. Choose the correct statement/statements
 (i) Oxidation state of oxygen in O2 [PtF6] (c) 60% (d) 66%
1
is  91. How many litre of O3 at S.T.P. will be
2 needed to completely oxidize 10 ml of 0.4
(ii) Oxidation states of Fe in Fe3O4 are +2 M Kl into l2
and +2
(a) 0.448 (b) 0.0448
(iii)Oxidation states of sulphur in S2O32–
are +4 and zero (c) 4.48 (d) 2.24

(a) (i) only (b) (ii) only 92. Volume V1 ml of 0.1 M K2Cr2O7 is needed
for complete oxidation of 0.678 g N2H4 in
(c) (iii) only (d) all the three
acidic medium. The volume of 0.3 M
87. Which of the following reactions is KMnO4 needed for same oxidation in
favoured by a base? acidic medium will be
a. CiO3– + Fe2+ → Cl– + Fe3+ 2 5
(a) V (b) V
2–
b. MnO4 + Cl2 → MnO4– + Cl –
5 1 2 1
c. MnO3– + H2O2 → Mn2+ + H2O + O2 (c) 113V1 (d) can’t say

d. [Fe(CN)6]3– + H2O2 → [Fe(CN)6]4– + 93. In which of the following redox reaction

H2O + O2 ‘n’ factor of every reactants is non
fractional
88. Which of the following are
disproportionation reactions? a. CsBr + Br2 → CsBr3

(i) UO2+ + Cr2O72– + H+ → UO22+ + Cr3+ b. Mn3O4 → Mn++

+ H2O c. Kl  l 2 water
 Kl3
(ii) Cl2 + OH– → CKO– + Cl– H2O d. NaNH2 + N2O → NaN3 + H2O
– – –
(iii) HO2 + Br + H2O → OH + Br2 94. For 1.34 × 10–3 moles of KBrO3 to reduce
(iv) C6H5CHO + OH– → C6H5COO– + into bromide 4.02 × 10–3 of Xn+ ion is
C6H5CH2OH needed. New oxidation slate of X is
(a) (i) and (ii) (b) (ii) and (iii) (a) n + 2 (b) n – 2
(c) (ii) and (iv) (d) (iii) and (iv) (c) 2 (d) – 2
89. How many mg of quick lime is required to 95. When 143.6 mg ZnSO4.xH2O is heated in
remove hardness of 1 kg of hard water the absence of air, 40.5 mg yellow residue
having 366 ppm of HCO3– and Ca++ as the is obtained. Value of x is
only cation (a) 7 (b) 5
(a) 72 mg (b) 84 mg (c) 6 (d) 2
(c) 168 mg (d) 170 mg 96. In which of the following reaction
90. 1 gm of a mixture of CaCO3 and NaCl equivalent weight of oxidant is not defined
reacts completely with 120 ml of N/10 a. 2BrO3– + 12H+ + 10e– → Br2 + 6H2O
HCl. The percentage of NaCl in the
mixture is b. BrO3– + 6H+ + 6e– → Br– + 3H2O

(a) 40% (b) 50% c. 3Br2 + 6CO32– + 3H2O → 5Br– +

BrO3– + 6HCO3–
 d. CaOCl2 + H2O → Ca(OH)2 + Cl2
97. 35 ml sample of hydrogen peroxide gives
off 500 ml of O2 at 270C and 1 atm
pressure. Volume strength of H2O2 sample
will be
(a) 10 volume (b) 12.8 volumes
(c) 11 volume (d) 12 volume
98. Percentage of free SO3 in an oleum bottle
labeled 113.5% H2SO4 is
(a) 40 (b) 60
(c) 50 (f) 45
99. When BrO3 ion reacts with Br– ion in acid
solution Br2 is liberated. The equivalent
weight of KBrO3 in this reaction is
(a) M/8 (b) M/3
(c) M/5 (d) M/6
100. 1 gram molecule of chlorine combines
with a certain weight of a metal giving 111
g of its chloride. The same weight of the
metal displaced chloride. The same weight
of the metal displaced 2 g of hydrogen
from an acid. The atomic weight of the
metal (assuming its valency to be 2) is
(a) 40 (b) 20
(c) 80 (d) None of these
101. A solution containing both Na2CO3 and
NaHCO2 was treated with excess of CaCl2
solution and filtered. The precipitate
weighed m1 grams. On adding NaOH in
drops to the filtrate avoiding excess, a
further m2 grams was precipitated. If after
adding excess CaCl2, the solution (had not
been filtere(d) was simply boiled and then
filtered, what would be the total weight of
the precipitate?
a. (m1 + m2) grams
b. (m1 + m2/2) grams
c. (m1 + m2)/2 grams
d. (m2 + m1/2) grams
102. Polyethylene can be produce from calcium
carbide according to the following
sequence of reactions
CaC2 + H2O → CaO + HC ≡ CH
nHC ≡ CH + nH2 ≡ (~ CH2 –– CH2 ~)n
The mass of polyethylene which can be
produce from 20.0 kg of CaC2 is
(a) 6.75 (b) 7.75
(c) 8.75 (d) 9.75
103. Versene, a chelating agent having
chemical formula C2H4N2 (C2H2O2N(a)4.
If each mole of this compound could bind
1 mole of Ca2+, then the rating of pure
versene expressed as mg of CaCO3 bound
per gm of chelating agent is
(a) 100 mg (b) 163 mg
(c) 200 mg (d) 263 mg
104. A solution contains Na2CO3 and NaHCO3.
10 ml of the solution required 2.5 ml of
0.1 M H2SO4 for neutralization using
phenolphthalein as indicator. Methyl
orange is then added when a further 2.5 ml
of 0.2 M H2SO4 was required. The amount
of Na2CO3 and NaHCO3 in 1 litre of the
solution is
(a) 5.3 g and 4.2 g (b) 3.3 g and 6.2 g
(c) 4.2 g and 5.3 g (d) 6.2 g and 3.3 g
105. In cyanide method, silver metal is obtained
as : 2K[Ag(CN)2] + Zn → K2[Zn(CN)4] +
2 Ag in this:
a. Ag has been oxidized and Zn gas been
reduced
b. Ag has been reduced and Zn has been
oxidized
c. Both the metals have been oxidized
d. Both the metals have been reduced
106. Oxidation number of Cr in the following
compounds are x, y, z and w.
 K[CrO(O2)(OH)], K3[Cr(O2)- (i) NaN3 1. +5
4](NH3)3,
(ii) N2H4 2. +2
x y
1
[Cr(O2)2], CrO2Cl2 (iii) NO 3. 
3
z w (iv) N2O5 4. –2
These values are
(a) 6, 13, 5, 6 (b) 4, 4, 4, 6 (i) (ii) (iii) (iv)
(c) 4, 5, 4, 6 (d) 4, 5, 6, 6 a. 3 4 2 1
107. 40 mL of 0.05 M solution of b. 4 3 2 1
sesquicarbonante (Na2CO3. NaHCO3.
2H2O) is titrated against 0.05 M HCl. X c. 3 4 1 2
mL of HCL is used when phenolphthalein d. 4 3 1 2
is the indicator and y mL of HCl is used
when methyl orange is the indicator in two
separate titration hence (y – x) is
(a) 80 mL (b) 30 mL
(c) 120 mL (d) None
108. For a given mixture of NaHCO3 and
Na2CO3 volume of a given required is x
mL with phenolphthalein indicator and
further y mL required with methyl orange
indicator. Hence, volume of HCl for
complete reaction of NaHCO3 is
(a) 2x (b) x/2
(c) y (d) (y – x)
109. In an experiment 50 ml of 0.1 M solution
of a salt reacted with 25 ml of 0.1 M
solution of sodium sulphite. The half
equation for the oxidation of sulphite is;
SO32– (aq) + H2O(l) → SC42– (aq) +
2H+(aq) + 2e– If the oxidation number of
metal in the salt was 3, what would be the
new oxidation of metal?
(a) 0 (b) 1
(c) 2 (d) 4
110. Match List I (Compounds) with List II
(oxidation state of nitrogen) and select the
correct answer using the codes given below
the lists –
List – I List – II